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HEAT
Thermometry
1. Relation between different scales of temperature
C F 32 K 273 R
5 9 5 4
Temperature measurement
x x0
' 0
x' x 0
Temperature coefficient
x x1
2
2 x1 1x 2
Calorimetery
Specific heat
dQ
s
m d
Thermal capacity
dQ
C
d
Water equivalent
w ms C
Latent heat
dQ
l
dm
Thermal expansion
Coefficient of thermal expansion
dl
l l 0 1
ld
dS
S S0 1
Sd
dV
V V0 1
Vd
0
1
: : 1: 2 : 3
Thermal Stress
F Y
A
Change in time period of simple pendulum
t t
2
Radius of curvature of bimetallic strip
MARATHON-10
61
Heat & Thermodynamics
R
(1 2 )
HEAT TRANSFER :
Conduction
Rate of flow of heat through a conductor
dQ KA( )
h (also called thermal current)
dt l
Thermal resistance
l
RT
h KA
Temperature of interface
K 11 K 22
l l2
= 1
K1 K 2
l1 l2
Rate of flow of heat through cylindrical shell
dQ 2 K ( )
h
dt r
ln 2
r1
Rate of flow of heat through spherical shell
dQ 4 K r1r2 ( )
h
dt (r2 r1 )
Convection
dQ dQ
A and , then
dt dt
dQ
h A
dt
Where h is known as convection coefficient.
Radiation
Absorbitivity of a surface
amount of radiation energy of that particular wavelength absorbed by the surface
a
amount of radiation energy of a particular wavelength incident on the same surface
Reflectivity of a surface
amount of radiation energy of that particular wavelength reflected by the surface
r =
amount of radiation energy of a particular wavelength incident on the same surface
r 1 a
reflectivity of the perfect black body is
R 0
Stefan's law of radiation (emissive power of perfect black body)
E T 4 where = 5.67 108 J s1 m2 K4
Kirchhoff's law
e
E (constant)
a
Emissivity of a surface
Ti
T0
T3 > T2 > T1
E
T3
T2
T1
m3 m1
m2
m T = constant.
Gas Laws
Boyle’s law (Isothermal law)
V 1 P1V1 = P2V2
P
Charle’s Law (Isobaric law)
V
V T V1 = 2
T1 T2
Pressure Law (Isochoric law)
P
P T P1 = 2
T1 T2
Ideal Gas Equation
PM
PV = nRT =
RT
Avogadro’s hypothesis
N = 6.02 1023 particles per gram-mole
Dalton’s law of partial pressure
n RT
P pi where pi i
V
w PdV
V1
Q nR T PdV
2 V1
Thermodynamic Processes
Isochoric Process
f
U V P
2
w=0
f f
Q V P nR T
2 2
Isobaric Process
f
U P V
2
w P V
f f
Q 1 P V 1 nR T
2 2
Isothermal Process
U 0
V P
w nRT ln 2 nRT ln 1
V1 P2
V P
Q nRT ln 2 nRT ln 1
V1 P2
Adiabatic Process
PV = constant
TV 1 = constant
T
= constant
P 1
P V PV 1 1
U 2 2
1
P V PV1 1
w 2 2
1
Q= 0
Polytropic process
P V PV
1 1
U 2 2
1
P V P1V1
w 2 2
1
1 1
Q nR T
1 1
PdV
C process CV
ndT process
Mixture of gases
Average molecular weight
M
ni M i
ni
Molar specific heat
CP
ni CP i and C n C
i V i
ni n
V
i
Adiabatic constant
eq 1 n i
n C i P
n
i 1 n C i V
Cyclic process
Efficiency of a heat engine operating in a cyclic process
Q
1 sink
Qsource
Carnot cycle
T
1 sink
Tsource