AZODYES SALT 2,4,6-TRIBROMO PHENOL complex

C6H5O-Na+ PHENOL (Purple solution)

Na(s) (White precipitate)
NaOH Br2 (aq)
Neutral FeCl3 (aq)
DIAZONIUM SALT PHENOL
C6H5N2+Cl- C6H5OH
NaNO3/H2SO4 ALCOHOL ALCOHOL
T<10oC
+ +
BENZOIC ACID ARYLAMINE AMMONIUM SALT CARBOXYLIC ACID SALT
C6H5COOH C6H5NH2 RNH3+Cl-
MNO4-/H2SO4 (aq) HCl (aq) NaOH (aq)
Sn/c.HCl
Reflux Reflux Reflux
Reflux
ALKYLBENZENE NITROBENZENE HCl (aq) (POLY)AMIDE (POLY)ESTER
C6H5R RX/FeX3 C6H5NO2 RCONH2 R – COO - R
RO-Na+/H2SO4
c.HNO3/c.H2SO4
ROH/H2SO4 Cat.
50-60oC Acid chloride
Cat. Reflux
Br2/FeBr3 Reflux PCl5(s)
BROMOBENZENE ARENE AMINE CARBOXYLIC ACID ACID CHLORIDE
C6H5Br C6H6 CnH2n+1NH2 CnH2n+1COOH RCOCl
R –NH2 LiAlH4 H2O/HCl (aq) R - COOH Na(s)
NaBH4 Reflux NaOH

CYCLOALKANE Alcoholic NITRILE SALT

LiAlH4 H+/Cr2O72-
CnH2n Pt/Ir cluster Pt/Ir cluster NH3
HCN/KCN
R-CN NaBH4 Reflux RCOO-Na+
On Al2O3 On Al2O3

400-600oC HCN/KCN
SiO2 or Al2O3 Br2 /UV light
ALKANE + ALKENE ALKANE HALOGENOALKANE ALDEHYDE
CnH2n+2 + CnH2n CnH2n+2 X2 CnH2n+1X H+/Cr2O72- CnH2n+1CHO
Pt or Heat HX Alcoholic R - CHO
SiO2
R-X Warm LiAlH4 2,4-DNP
H2 / Ni(s) NaOH PCl5(s) NaBH4
Aqueous NaOH NaBr/H2SO4
H2O(g) (steam) Reflux I2/P
H3PO4 / T>100oC y H+/Cr2O72-
BRANCHED ALKANE ALKENE ALCOHOL I
Warm 2,4-DNP
CnH2n+2 CnH2n XS Conc. H2SO4 CnH2n+1OH IIy KETONE 2,4-DINITROPHENYL
LiAlH4
C=C Reflux R - OH IIIy NaBH4 R – CO - R HYDRAZONE
Na(s) (Yellow/orange crystalline solid)
NaOH + 2-
H /Cr2O7
Reflux NO REACTION
ADDITION POLYMERS SALT
-[CH2-CH2]N- RO-Na+
Paul T-C 2006