An electron is moving with a kinetic energy of 4.

55 x 10–25 J. What will be de Broglie wavelength for this electron?

(A)    5.28 x 10–7 m               (B)    7.28 x 10–7 m

(C)    2 x 10–10 m                  (D)    3 x 10–5 m

Suppose 10–17J of energy is needed by the interior of human eye to see an object. How many photons of green light (λ =
550 nm) are needed to generate this minimum amount of energy?

(A)    14                             (B)    28

(C)    39                             (D)    42

The velocity of electron in the ground state hydrogen atom is 

2.18 x 106 ms–1. Its velocity in the second orbit would be

(A) 1.09 x 106 ms–1              (B)    4.38 x 106 ms–1

(C) 5.5 x 105 ms–1                (D)    8.76 x 106 ms–1-

The ionization energy of the ground state hydrogen atom is 

2.18 x 10–18J. The energy of an electron in its second orbit would be

(A)    –1.09 x 10–18 J             (B)    –2.18 x 10–18J

(C)    –4.36 x 10–18J              (D)    –5.45 x 10–19J

A 1 MeV proton is sent against a gold leaf (Z = 79). Calculate the distance of closest approach for head on
collision.

For which of the following species, Bohr theory doesn’t apply

(A)    H                              (B)    He+

(C)    Li2+                           (D)    Na+

Predict the hybridization for the central atom in POCl3,

Out of the three molecules XeF4, SF4 and SiF4 one which has tetrahedral structures is
 (A) All of three                  (B) Only SiF4
 (C) Both SF4 and XeF4        (D) Only SF4 and XeF4
 Among the following compounds in which case central element uses d-orbital to make bonds with
attached atom
 (A) BeF2                             (B) XeF2 
 (C) SiF4                              (D) BF3

 When NH3 is treated with HCl, state of hybridisation on central nitrogen

 (A) Changes from sp3 to sp2
 (B) Remains unchanged
 (C) Changes from sp3 to sp3d
 (D) Changes from sp3 to sp

How much should the pressure be increased in order to decrease the volume of the gas by 5% at constant temperature?

                          (A) 5%                                                                                (B)  5.26%

                          (C) 10%                                                                                (D)  4.26%

.           In what ratio by mass carbon monoxide and nitrogen should be mixed so that partial pressure exerted by each is
same?

                          (A) 1:1                                                                                     (B)  1:2

                          (C) 2:1                                                                                   (D)  3:4