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The objectives of this work focused on studying the coordination chemistry towards transition
metals of polycarboxylate multidentate ligands which present a semiflexible behavior such as
1,4 phenylenebis(oxy)diacetic acid, 1,2 phenylenebis(oxy)diacetic acid and the hybrid
multidentate ligands 1,2 phenylenebis(thio)diacetic acid and
N,N,N’N’ 1,2 phenylene diaminetetraacetic acid which contain different donor sites
(S, O and N, O respectively) being in this way suitable for selective coordination to specific
transition metals.
The synthesis of mononuclear building blocks for the rational preparation of coordination
polymers was also taken into account.
CM
MY
CY
CMY
Coordination Polymers
of Polycarboxylates:
Design, Synthesis and Structures
PhD Thesis - Ioana Grosu