The Jammu and Kashmir State Board of School Education Academic Division New Campus Bemina Srinagar Chemistry PAPER A Time 2:30 hrs loctet A junio, ps ol Long Answer Type Questions (S marks each) QI: draw the M.O diagram of N2+ and 022- ions, Calculate their bond order. OR Explain the various types of intermolecular forces with an example? 2: discuss elevation in boiling point as a colligative property and give its expression. OR Derive the expression for Raoul’s law in case of a solution containing non volatile solute. Q3: How does Gibb’s free energy decide the spontaneity of a process? oR ‘What is the effect of temperature on the spontaneity of exothermic and endothermic reaction (Q4: Describe Down’s process for the manufacture of sodium. OR State and explain the laws of electrolysis QS: How is sulphuric acid manufactured by contact process. oR Draw the structure of various types pf silicates. Short answer Type: 3 marks each Q6; calculate the momentum of a particle which has de-Broglie wave length of 0.2 nm(h=6.6X 10 -34K gm2s-1) Q7: Differentiate between Schottky and Frenkel defect in ionic solids. Q8: whatare the . spontaneous and non-spontaneous processes, Give an example of each. Q9: State and express Khlrausch’s law. Q10. what are units of rate constant for Zero, first and second reactions. QUI. differentiate between physiosorption and chemisorption. Q12. How is bleaching powder prepared. Very short Answer type questions: 2 marks each Q13: calculate the no. of particles per unit cell of a body centred cubic,Q14: define boiling point in terms of vapour pressure> QUS: What is activation energy? QI6: Name the allotrophs of sulphur? Multiple choice questions: 1 marks each 17. Brage's equation is : 18. For which reaction, the units of rate constant are independent of concentration, 12. The increase in the concentration of reaction leads to a change in yophillic solutions are stable due to A) charge on the particles. B) Large size of the particles C) Small size of the particles D) Layer of dispersion medium on the particles. 20. Smoke is an example of A) Colloid B) \Suspension C) Emulsion D) None of the above. 21. Zeolites are A) Sodium silicates B) Iron-silicates C) Sodium alumino silicates D) All of themtae a) lend foe G4 se rile, davon the at of ft Ss ee eer ae ay papery . “Sie Be chemin Ap eS Ba Explriny toe ead ‘ills Curl. @) wen ee oy Atdot Condorsaleow @) HCHO 4 NOH —y + Hr0 by REOOK + —y Reocl +S0,+ Het cy Reoow + ROH Conca + 40 (Gy CH, Coot tag CLH, Coo (ey Cagc0 CH + tb Ney PE 3) wale te LUPke vownes of tw tine, follscaicn Competeds (05) () Chy- CH= CHa (dy Ha CH = C5 0 NU, CH. NO. b lay tn, enced &) Ce ts NH Ce HS Chy My €) Hs - Cl — Oh, — NO Cos on . Dine the bie naTuve of Amuss 64) a Pop amet etn Ll the dicodary struchene Of protiasgames 7 UO : Etna wy Ant Wot sa dpe ove are Hey Cnncfrdr ey Short. Answer Type Bo: What is lanthanide Corbravton ? Wheat cure . Cones, temCes 2 (03) aq:- Dy the follwing « j) Legand By Cordura rusnbo, 3) a) L betreen aucleay [sim & rucleo me Diffie f (0%) an- phat are enanliowors & olaslereomtne (08) gues Bp in if we ate we NS "lees ie fuemge ede Cue: iy Picker wulone tie baw se pel fe ps fom Vary Shart—idnawer Type _ 813: ple thy LUPAC romes Of Ky [NiCew] and [vss Cs) 5] ls (02) 814) 8 Napa! bi ie er «ws te Ua Of nelly on ti wT fe i ime onda Manis 2 ay the ore from obec mate ey aig) "gh pot trams - isowsy is gets than i @)