SULIT 454111 Chemistry Kertas 1 September

1114 jam

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PERSIDANGAN KEBANGSAAN PENGETUA-PENGETUA SEKOLAH MENENGAH MALAYSIA (PKPSM) CAW ANGAN MELAKA

PEPERIKSAAN PERCUBAAN SIJIL PELAJARAN MALAYSIA 2007

CHEMISTRY

Kertas 1 Satujam lima bel as minit

JANGAN BUKA KERT AS SOALAN INI SEHINGGA DIBERIT AHU

1. Kertas soalan ini mengandungi 50 soalan

2. Jawab semua soalan

3. Jawab dengan menghitamkan ruangan yang betul pada kertas jawapan

4. Hitamkan satu ruangan sahaja bagi setiap soalan

5. Rajah tidak dilukis mengikut skala kecuali dinyatakan

6. Anda dibenarkan menggunakan kalkulator saintifik yang lidak boleh diprogramkan.

Kertas soalan ini mengandungi 39 halaman bercetak.

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The figure below shows the set-up of the apparatus to study Process I

lid

Process I

Bromine gas (brown)

air

Bromine gas (brown)

What is Process I ?

A Condensation

B Evaporation

C Diffusion

D Sublimation

2 What is the definition of a mole?

A The volume occupied by 6.02 X 1023 particles

B The atomic mass of a substance which consists of 6.02 X 1023 atoms

C The molecular mass of a substance which consists of 6.02 X 1 023 molecefes

D The quantity of substance which has the same number of particles as the number of atoms in 12 g ofCarbon-12

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5 When steam condenses, the particles

A become smaller size

B lose energy to their surroundings

C move futher apart

D vibrate about fixed positions

6 The figure below shows an electron arrangement of v"

How many protons and electrons does an atom of Y contain?

Proton Electron
A 8 8
B 12 10
C 12 12
D 8 10
7 What can we deduce from the symbol 4 ?
2~e A An atom of helium contains two electrons

B An atom of helium has two protons and four neutrons in its nucleus

C Helium has a proton number of 4

D Helium occurs as a diatomic molecule

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8 The relative formula mass of ammonium phosphate, (NH4)3P04 is r Relative atomic mass ofH=1, N=14, 0=16 and P=J 1]

A lJJ

B 141

C 149

D 159

9 Rouge is a pigment which contains 2.8 g of iron combined with 1.2 g of oxygen.

What is the chemical formula of this pigment? r Relative atomic mass ofFe=56 and 0=161

A FeO

B Fe20)

C FeJ02

D Fe304

10 A metal X can exist as X2+ and X3+ ions. The possible formulae for its sulphates would be

I XS04
II X2S04
III X2(S04)3
IV XJ(S04)2
A I and II only
B I and III only
C II and III only
D II, III and IV only 454111

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11 Which of the following electron arrangements is found in a noble gas atom?

A

B 2.1

C 2.8

D 2.8.2

12 The following table shows the proton number and nucleon number of atom X

Proton number 9

Nucleon number 19

Which of the following shows the position of X in the Periodic Table of elements?

Group

Period

A B C D

4

17

2

17

4

13 The table below shows the position of2 elements, P and Q, in the Periodic Table of Elements.

Elements Group Period
P 1 3
Q 17 3 Which of the following is true about elements P and Q ?

A The atoms of P are smaller than the atoms of Q

B Atoms of P have stronger attraction for other electrons

C The number of positive charges in the nucleus of P is less than Q

D Atoms of Q have a higher tendency than P to release electrons

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14 The chemical symbol of an element T is as shown:

P:l ~

What would be the electron arrangement of the ion formed by an atom ofT?

A 2.8

B 2.8.2

C 2.8.8

D 2.8.8.8

15 The electron arrangement of atom X =0 2.8.7. What is the formula of the ions formed from X?

16 The electron arrangements of 2 atoms X and Yare as shown:

x

Y

Which of the following is true when X react with Y?

A X receives electrons

B Y receives electrons

C The compound formed has a formula ofXY2

D The compound formed is made up of molecules

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17 The proton numbers of a few elements are as shown:

Element Proton Number
H I
Na II
Mg 12
S 16 With the atoms of which element would chlorine atoms combine by sharing electrons?

I H

II Na

III Mg

IV S

A I only

B II only

C II and III only

D I and IV only

18 It is discovered that a compound with formula WZ dissolves in water. What inference can you make about the compound?

A It is not a covalent compound

B The compound ionizes in water

C The compound will not dissolve in an organic solvent

D The intermolecular forces between the particles are very weak

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19 The following diagram shows the apparatus set up for an elelctrolysis.

Which of the following cannot be E ?

A Ammonium hydroxide

B Sodium Chloride

C Ethanoic acid

D Ether

20 An experiment has been carried out to determine the relative position of three metals X, Y and Z in the electrochemical series by using the displacement reaction. The results are as shown :

Mixture Results
X + solution of Y Y deposited
X + solution of Z No reaction
Y + solution of Z No reaction
Z + solution of Y Y deposited Which of the following shows the correct relative position of X, Y and Z in the electrochemical series?

A X, Y,Z B Y,X,Z C Z,X, Y

D Z, Y,X

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21 Which of the following compounds is a soluble base?

A Aluminium oxide

B Copper(II) oxide

C Iron(III) oxide

D Sodium oxide

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22 The pH scale below shows the position of five aqueous solutions P, Q, R, S and T, of equal concentration.

p

Q

S

R

T

7
pH Scale
What could the aqueous solutions be ?
Ethanoic sulphuric ammoma sodium
acid acid aqueous chloride
A P Q R S
B Q P S R
C Q P T S
D S T Q R 14

sodium

hydroxide T

T

R

P

23 What is the concentration of hydrogen ions in 0.05 mol dm-J sulphuric acid?

A 0.025 mol dm-J

B 0.050 mol dm-J

C 0.100 mol dm-J

D 0.250 mol dm-J

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24 Which of the following equations best represents the actual reaction between hydrcchloric acid and sodium hydroxide solution?

A H+ + OH- ~ H2O
B H2 + ;12 O2 ~ H2O
C 2H+ + 02- ~ H2O
D Na+ + cr ~ NaCI 25 The neutralization reaction between nitric acid and barium hydroxide solution is shown in the equation below

2HN03 + Ba(OHh ~ Ba(N03h + 2H20

10.0 ern:' of 0.1 mol dm" barium hydroxide solution was titrated with O.lmol dm-3 of nitric acid. What is the volume of the nitric acid?

A 40 cm3

B 30 crrr'

C 20 cm3

D 10 crrr'

26 Air polluted by sulphur dioxide was passed through the apparatus shown in the diagram below.

air-

Which of the following solutions could be used as Z to show the presence of sulphur dioxide?

A acidified potassium manganate(VII)

B aqueous iron(II) sulphate

C aqueous potassium iodide

D limewater

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27 The following scheme shows four stages A, B, C and D in the conversion of sulphur to sulphuric acid. In which stage is the catalyst used?

A

B

Sulphur

Air

Air

Concentrated sulphuric acid

o

1 Concentrated C sulphuric acid

oleum

Water

28 Which of the following mixtures of elements forms the most suitable alloy for manufacturing of racing bicycle which is light and firm?

A copper and nickel
B iron and carbon
C stanum and copper
D aluminium and copper 29 Which of the following pairs shows the correct monomer for making the polymer?

A

H H

I

H-C-C-H

I I

H H

H H

, I

H-C-C-O-H

I I

H H

H H

I I

c=c

I I

CI H

B

c

D

CH. H

I I

c=c

I I

CH, H

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poIymM

H H H H

I I I I

-C-c-c-c-

I I I I

H H. H H

H H H H

I I I I

-c-c-o-c-c-o-

I I I I

H H H H

H H H H

I I I I

-c-c-c-c-

I I I I

CI H Cl H

CH, CH, CH, CH,

I I I I

-c-c-c-c-

I I I I

H H H H

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30 The followings are the properties of glass. Which of the followings are true? low melting point.

II they are good insulators of heat.
III resistant to chemicals
IV hard but brittle
A I and II only
B III and IV only
C I, III and IV only
D II, III and IV only 31 Compound A is an organic compound. When heated strongly, which of the following gases is released?

A Oxygen

B Hydrogen

C Carbon dioxide

D Ethane

32 The chemical equation shows a chemical reaction that took place.

A B C D

x y
Hydration Hydrogenation
Hydrogenation Hydration
Substitution Dehydration
Oxidation Reduction 454111

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33 Which of the following is the IUPAC name for the structural formula shown?

H

) H--C-H )

H-C-H H H H H

H-~--~-c':-c!:-c':-I-f

I J I I I

H-C-H HI-I 1-1

) H- .-H

H--C-H Ilr

I

H

A 3-ethyl-4-methylheptane B 4-methyl-2-ethylhexane C 5-ethyl-3-methylheptane D 2-ethyl-4-methylhexane

34 Which of the following is correct regarding the physical properties of pentene, CsHJO?

A Pentene is denser than hexene.

B Pentene exists in the form of gas at room temperature

C Complete combustion ofpentene will produce 4 moles of carbon dioxide gas. D Pentene is insoluble in water but is soluble in organic solvent.

35 Which of the following best explains the statement below?

Combustion ofhexene is sootier than that of hexane

A Hexane molecule has more hydrogen atoms than hexene molecule. B The van der Waals' forces between hexene molecules are stronger.

C Percentage by mass of carbon in hexene molecule is higher than that in hexane molecule.

D

The size of hexene molecule is larger.

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36 In a reaction temperature will increase the rate of reaction because it will

A lower the activation energy of the rection

B increase the energy of particles involved in the reaction C decrease the effective collision of particles involved

D increase the rate of collision among the particles

37 The table shows the volume of oxygen gas obtained at regular intervals for the decomposition of hydrogen peroxide, H202

Time(min) Volume of oxygen gas (em:')
0 0
1.0 5.5
2.0 10.0
3.0 14.0
4.0 17.5
5.0 20.0 The everage rate of decomposition of hydrogen peroxide from the second minute to the fourth minute is

A 17.5 cm3 min']
B 12.5 cm ' min']
C 3.75 crrr' . ·1
mm
D 4.17 cm3 .. ]
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38 The graph below shows the volume of gas produced against time for the reaction of potassium carbonate and hydrochloric acid

A

L- >:

TiIne(sec)

The gradient of the graph decreases with time because A catalyst is not used

B temperature of reaction decreases C volume of mixure decreases

D concentration of hydrochloric acid decreases

39 Which of the following will increase the frekuency of collision?

Use reactant with larger size

II Increase the concentration of reactant

III Increase the temperature of reaction IV Remove the product of reaction

A IV only

B II and IV only C I1 and III only

D I, III and IV only

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40 The equation below shows one of the reaction to produce hydrogen gas

2HCl + Zn ~ ZrrCl, + H2

Which of the following would increase the rate of production of hydrogen gas?

A Increase the time of reaction

B Increase the volume of acid

C Increase the size of granulated zinc

D Increase the tempereture of the mixture

41 Which of the following chemicals can oxidise chloride ions to chlorine?

A Potassium manganate (VII)

B Iron(III) sulphate

C Aqueous bromine

D Potassium

42 Which of the following is an oxidising agent?

A Hydrogen gas

B Potassium manganate(VIl)

C Potassium Iodide

D Ammonia

43

A patient claims that other people are reading his mind and controlling his thoughts

Which of the following types of medicine is most appropriate in treating the above symptoms

A Psychotherapeutic medicine B Hormones

C Analgesic

D Antibiotics

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44 A series of experiment was carried out to investigate the reactivity of metals K Y and Z. The following results were obtained.

r- Mixture Result
X+ oxide ofY No reaction.
Y+ oxide ofZ Reaction occurred.
X + oxide ofZ Reaction occurred. Which of the following is the correct sequence for the reactivity of the metals in ascending order?

A X,Y,Z

B Z,KY

C Y,Z,X

D Y,X,Z

45 The figure bellows shows the energy profile diagram for a reaction between X and Y to produce Z.

Energy

What is the heat of reaction?

A Ez - EJ

B EJ- E2

C E3 - EI

D E3 - Ez

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46 Which of the following is an exothermic reaction?

A The heating of hydrated copper(II) sulphate

B The heating of sodium thiosulphate

C Dissolving ammonium chloride in water

D Rusting process

47 The fiqure below shows the change in the heat of combustion of a few alcohols.

Methanol ( CH30H )

Heat of combustion increases

The increase in the heat of combustion of alcohols as shown is due to

A an increase in the sootiness of the alcohols when burnt

B an increase in the reactivity of alcohols

C an increase in the relative molecular mass

D an increase in the carbon and hydrogen atoms per molecule of alcohol

48 Which of the following pairs regarding traditional medicines and their uses is correct?

A B C D

Traditional medicine Use
Long jack (Eurycoma longifolia) To relief asthmatic attack
Aloe vera To treat skin wounds
Garlic To treat stomach wind
Ginseng To treat malaria 454111

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49 A mixture carbon powder is heated strongly as shown.

Carbon powder + oxide of metal L

Evaporating dish

Which of the following shows the arrangement of the metals in the reacti vity series in ascending order?

A M,N,L

B L,M,N C L,N,M D N,L,M

50 Which of the following is one of the possible products formed when palm oil is boiled in concentrated sodium hydroxide solution?

I Sodium chloride II Glycer I

III Sodium palmitate IV Sodium stearate

A II and III only
B I, II and III only
C II, III and IV only
D I, II, III and IV 454]/]

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SULIT 454112 Chemistry Kertas 2 September

2112 jam

Nama

Tingkatan LI -'

PERSIDANGAN KEBANGSAAN PENGETUA-PENGETUA SEKOLAH MENENGAH MALAYSIA (PKPSM)

CA WANGAN MELAKA

PEPERIKSAAN PERCUBAAN SIJIL PELAJARAN MALAYSIA 2007

CHEMISTRY

Kertas 2 Duajam tiga puluh minit

JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU

1. Kertas ini mengandungi tiga bahagian,Bahagian A, Bahagian B dan Babagian C.

2. .Jawab semua soalan dalam Bahagian A satu soalan daripada Bahagian B dan satu soalan daripada Bahagian C.

3. .Jawapan kepada ketiga-tiga bahagian ini hendaklah diserahkan bersama.

4. Jawapan bagi Babagian A hendaklah ditulis dalam ruang yang disediakan dalam kertas soalan. Langkah penting dalam kira-mengira hendaklah ditunjukkan.

5. Jawapan bagi Bahagian B dan Bahagian C hendaklah ditulis pada kertas tulis yang disediakan. Anda diminta menjawab dengan lebih panjang untuk Babagian B, dan Bahagian C tetapi jawapannya mestilah jelas dan logik.Dalam jawapan anda, persamaan, gam bar rajah, graf dan cara lain, yang sesuai untuk menjelaskan jawapan anda boleh digunakan.

6. Rajah tidak dilukis mengikut skala.

7. Dalam huraian anda, nama bahan kimia (bukan simbol a/au formulanya) hendaklah digunakan.

8. Markah maksimum yang diperuntukkan ditunjukkan dalam kurungan pada hujung tiap-tiap soalan atau bahagian soalan.

9. Penggunaan kalkulator saintifik yang tidak boleh diprogramkan adalah dibenarkan.

Untuk kegunaan pemeriksa
Bahagian No. Markah
1
2
A 3
4
5
6
Jumlah
B 7
8
Jumlah
C 9
10
Jumlah
Jumlah Besar Kertas soalan ini mengandungi 33 halaman bercetak

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BAHAGIAN A

(60 markah]

Jawab semua soa/an da/am bahagian ini.

Masa yang dicadangkan untuk menjawab Bahagian A ialah 90 mini!

1 An experiment is carried out to determine the melting point of solid X .. Solid X is heated using water bath. The temperature of X is recorded at 30 seconds intervals as shown below

(a) Draw the set up of the apparatus to carry out this experiment.

[3 marks]

(b) Draw the arrangement of particles in X at 77°C

[ 1 mark]

(c) On the graph paper, draw the graph of temperature against time for the heating of X

[3 marks]

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(d) Show on your graph, how the melting point of X is determined

[1 mark]

(e) Explain why there is no change in temperature from 60 second to 120 second.

[2 marks]

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2 The table below shows the proton numbers of a few elements.

Elements Proton Numbers
R I
S II
T 14
r----- W 18
X 19 (a) Write the electron arrangement of W

(b) Give a reason why W is not reactive

(c) Elements S and T are located in the same period

(i) State the element with a bigger atomic size.

(ii) Explain your answer in (c)(i)

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[ I mark]

[ I mark]

[ I mark]

[2 marks]

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(d) (i) What can be observed when X reacts with oxygen?

[ 1 mark]

(ii)Write a chemical equation to represent the reaction that takes place in d)(i).

[ 1 mark]

(e) S reacts in the same way as X with water.

(i) Which is more reactive towards water?

[ I mark]

(ii) Explain why.

[2 marks]

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3 The diagram below shows the apparatus set up to study the effect of concentration of electrolyte on the products of electrolysis

II. ...... '" ...

- ~ - ~ - -

Sodium chloride solution

Experiment I: Electrolysis of very dilute sodium chloride solution

Experiment II : Electrolysis of concentrated sodium chloride solution (a) In Experiment I

(i) What can be observed at the anode?

[ I mark]

(ii) Write an equation to represent the reaction that takes place at the anode.

[ I mark]

(iii) What is the redox process that takes place at the anode?

[ 1 mark]

(b) In Experiment II,

(i) Which electrode will give a different compared to Experiment I ?

[ 1 mark]

(ii) Name the product formed at the electrode in (b) (i).

[ I mark]

(iii) Write an equation for the. reaction that takes place in (b) (i).

[ 1 mark]

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(c) 2 cnr' of potassium iodide solution is poured into the test tube which contain gas produced at the anode in Experiment II

(i) What can be observed?

[ 1 mark]

(ii) Write an ionic equation for the reaction in (c).

[ 1 mark]

(iii) State the substance that is reduced in (c) (ii)

[ 1 mark]

(iv) Give a reason for your answer in (c) (iii)

[ 1 mark]

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4 Figure A and Figure B below show two different methods of preparing soluble salt and insoluble salt.

Metal oxide powder

FlgNI't! A Preporing nJlllbk sals

SolmionX ~ • ~Solution y

~

.

salt

(a) Mixing two soluttnn

Filler papers

FlfP4re B Preparillg 111801111114 sail

(b) Filtering and washing

(c) Drying UI. salt

(a) Which salt is insoluble?

You are given two salts: lead(ll) iodide and copper (II) sulphate salts.

(b) Name the reaction used to prepare the insoluble salt in (a).

[ I mark)

x

(c) (i) Suggest a name for X and Y to prepare the salt in (a) as shown in Figure B.

[ 1 mark

y

(ii) Write down the ionic equation for the reaction in (c) (i).

[2 mark:

[2 mark

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(d) For the soluble salt,

(i) State the acid used.

[ I mark]

(ii) Write down the chemical equation to produce the soluble salt in (d)(i).

[ I mark]

(e) The following reaction can be used to prepare copper (II) chloride.

Access of copper (II) carbonate is added to react with 50 cnr' of 2 mol dm-3 hydrochloric acid to form the salt.

Calculate the mass of the salt formed.

[ Relative atomic mass for the salt formed = 135 ]

[2 marks]

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5 Figure below shows the structural formulae of compounds J, K and L

CompoundK

Compound L

H H H H

I I I I

H-C-C-C=C

I I I

H H H

CompoundJ

H H H H

I I I I

H-C-C-C-C-OH

I I I I

H H H H

H H H 0

I I I II

H-C - C-C - C -OH

I I I

H H H

(a) State the homologous series for compounds J and K

Compound J :

Compound K:

[2 marks

(b) In the figure given, circle the functional group of compound L.

[ 1 mar1

(c) (i) Name the compound K

[ 1 marl

(ii) Another compound, M, is in the same homologous series as K. M has five carbon atom. Write the molecular formula for M.

[ 1 marl

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(d) Draw the structural formula for another isomer of compound J. Name the isomer.

[2 marks

(e) When compound K is added into a test tube containing acidified potassium dichromate(VI) solution and heated for a few minutes, compound L is form,

(i) State one observation for this experiment

[ 1 mark

(ii) Write a chemical equation for this reaction.

[2 mark

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6 The figure below shows an experiment to study the effect of different metals on the rusting of iron The pairs of metals are tied together and soaked in a mixture of sodium chloride and potassium hexacyanoferate(III) solution.

mixture of sodium chloride and potassium hexacyanoferate(III)

metal X

Iron nails

Test tube A

Test tube B

(a) What is the function of

(i)the sodium chloride solution?

[ 1 mark

(ii) the potassium hexacyanoferate(III) solution?

(b) Metal X is below iron in the Electrochemical Series.

State the observation in test tube A after two days.

[ 1 mark]

(i)Give an example ofX.

[ 1 mark]

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(ii)Write the half equation to show what happened to iron.

[1 mad

(iii)Name the reducing agent in test tube A.

[ 1 marl

(c) In test tubeB, iron does not undergo any chemical change, but the mass ofY decreases.

(i)Give a reason for this observation.

[ 1 marl

(ii)Give an example ofY.

[ 1 mar

(d) Based on this experiment, suggest a way to prevent iron from rusting.

[1 mad

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Section B

[20 marks]

Answer any one question

7 (a) The figure below shows the standard representation for an atom of element Na

(23:] ~

State three types of information that can be deduced? Draw the electron arrangement for an atom of element Na

[6 marks

(b) The following figure shows the empirical formula of glucose:

[ C "20

(i) What is the meaning of empirical formula?

(ii) The relative molecular mass of glucose is 180, determine the molecular formula of glucose

[4 mark

(c) (i) A chloride of iron contains 2.80 g of iron and 5.32 g of chlorine.

Determine the empirical formula of the compound. [ Relative atomic mass: Fe = 56, Cl = 35.5 ]

[4 marks] (ii) Write a chemical equation to represent the reaction between iron and chlorine.

Calculate the volume of chlorine gas that react completely with 2.80 g iron. [ 1 mole of gas occupied 24 dm} at room temperature and pressure]

[6 marks]

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8 (a) The table below shows the data obtained when 2.0 g of calcium carbonate granules were added to 20.0 crrr' of 0.1 mol dm" hydrochloric acid in a conical flask.

(i) Based on table, draw a graph of volume of gas against time

[4 marks

(ii) From the graph, determine

• the average rate of reaction for the whole reaction

• the rate of reaction at 210 seconds

[4 marks

(iii) Explain why potatoes fried in boiling oil cooks faster than potatoes boiled in boiling water.

[2 marks

(iv) By using the collision theory, explain how temperature affects the rate of

reaction.

[4 marks

(b) The table below shows three types of food additive and their functions

Type of food Function
additive
X To slow down or prevent the growth of microorganisms
so that food can be ke21 for a IO'!Ber geriod.
y To prevent oxidation that causes rancid fats and
fruits from turning brown
Z To improve and restore the taste of food State the type of food additive X, Y and Z . State one example each.

[6 marks

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Section C

[20 marks]

Answer anyone question

9 (8) The table b I

h

h

b

f

t X d Y

e ow sows t e proton num ers 0 two e emen s, an
Element Proton number
X 1
Y 11 Explain how both X and Y can react with a named element in Group 17 to form two different types of compounds. In your explanation, attach any useful diagram. [ 11 marks:

(b) (i)State two properties of an ionic compound.

(ii) Describe an experiment, using electrical energy, how you prove that one of the compounds formed in (a) is an ionic compound. Explain how you arrive at the conclusion.

[9 marks

10 The following information is about the heat of reaction

One mole of ethanol produces 1317 kJ of heat energy when it is completely burnt.

(a) What is the meaning of heat of combustion of ethanol?

[2 marks

(b) The heat of combustion on ethanol can be determined in the school laboratory. (i) Draw a labelled diagram to show the set upof apparatus that can be used to determine the heat of combustion of ethanol. [3 marks]

(ii) Based on the diagram in (b) (i), describe briefly how to determined the heat 0: combustion of ethanol. Your answer should consist of the followings:

• Procedure of the experiment

• Tabulation of data

• Calculation

[7 marks [2 marks [3 marks [3 marks

• Three precautions taken to obtain accurate results.

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454113

454113 Chemistry Kertas 3 September

1 112 hours

NrumeL_ ~

Form

PERSIDANGAN KEBANGSAAN PENGETUA-PENGETUA SEKOLAH MENENGAH MALAYSIA (PKPSM) CAWANGAN MELAKA

PEPERIKSAAN PERCUBAAN SIJIL PELAJARAN MALAYSIA 2007

CHEMISTRY

Kertas 3

Satu jam tiga puluh minit

JANGAN BUKA KERT AS SOALAN INI SEHINGGA DIBERIT AHU

1. Tuliskan nama dan tingkatan pada ruang yang disediakan.

Untuk kegunaan pemeriksa sahaja
Soalan Markah Markah
Penuh diperolehi
1 . 15
2 18
Jawapan
3 15
Laporan
2
Jumlah 50 2. Kertas soalan ini adalah dalam dwi bahasa ..

3. Calon hendaklah membaca arahan pada halaman 2 dan 3.

Kertas soalan ini mengandungi 15 halaman bercetak

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INFORMA nON FOR CANDIDATES

1. This question paper consists of three questions. Answer all questions.

2. Write your answer for Question 1 and 2 in the spaces provided in the question paper.

3. You may use equations, diagrams, tables, graph and other suitable methods to explain your answer.

4. Show your working, it may help you to get marks.

5. If you wish to change your answer, neatly cross out the answer that you have done.

Then write down the new answer.

6. The diagrams in the questions are not drawn to scale unless stated

7. Marks allocated for each question or part question are shown in brackets.

8. The time suggested to answer each of the questions is 30 minutes.

9. You may use a non-programmable scientific calculator.

10. Hand in your answer sheets at the end of the examination

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Marks awarded :

Mark Description
3 Excellent The best response
2 Satisfactory An average response
1 Weak An inaccurately response
0 No response or wrong response 454113

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Answer all question.

1. Figure 1 shows an experiment to construct an electrochemical series by measuring the voltage of a pair of metals in a simple voltaic cell


Othe
r
t-- r-
- - - - -
f- - - Sodi
t- - - -
-
- - - - solu
- - - - -
"- - - r metal

coppe

um nitrate tiOll

Figure 1

o

6

Experiment 1

Experiment 2

o

6

6

o

Experiment 3

Experiment 4

Figure 2

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Figure 2 shows the reading on the volmeter in different sets of experiment

(a) Write the voltage for each experiment in the spaces provided in the table below

Experiment Positive Negative VoltageN
terminal terminal
I Copper magnesium
2 Copper iron
3 Copper lead
4 Copper zinc (b) Arrange the metals in (a) in the electrochemical series, starting with the metal with the highest tendency to release electron.

[3 marks] (c) What is the relationship between the relative position of a pair of metals in the electrochemical series with the voltage of the voltaic cell constructed?

[3 marks]

(d) Write the equation of the reactions which occur at the negative terminal for Experiment 1

[3 marks]

(e) Predict the voltage of the voltaic cell formed by tin (stanum) and copper

[3 marks]

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2. The table below shows the data obtained in two experiments carried out by a student to study the decomposition of hydrogen peroxide.

Times/minutes 0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0 6.5
Experiment I 0 3.0 5.5 8.0 10.5 13.0 15.0 16.5 18.0 19.5 20.5 21.5 22.5 23.5
Volume/cm3
Experiment II 0 6.0 10.5 15.0 18.5 21.5 24.5 27.0 29.0 31.0 X 34.0 35.0 36.0
Volume/em? In Experiment 1,8 crrr' of2.0 mol dm" hydrogen peroxide solution is added to 42 crrr' of distilled water and 2g of manganese(IV) oxide. The total volume of gas produced was recorded every 0.5 minute.

In Experiment II, 8 crrr' of 3.0 mol drn" hydrogen peroxide solution is added to 42 crrr' of distilled water and 2 g of manganese(IV) oxide. The total volume of gas produced was recorded every O.sminute.

(a) Name the gas produced in the above experiment.

[3 marks]

(b) State the hypothesis of the experiment.

[3 marks]

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(c) The figure below shows the burette reading at 0 minute and the burette reading at 5 minutes respectively in Experiment II.

Determine the value of X, the volume of gas collected at 5 minute.

[3 marks]

(d) (i) Using the same axes, plot the graphs of the volume of gas against time for Experiment I and II on the same graph paper.

[3 marks]

(ii) Predict the volume of the gas produced at 7.5 minute for Experiment II from the graph in (d)(i).

[3 marks]

e) What inference can be made in these experiments?

[3 marks]

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3. Rajah di bawah menunjukan dua botol bahan kimia yang berlebel X dan Y . Bahan terse but ialah heksana dan heksena

Anda dikehendaki merancang satu eksperimen untuk menentukan dua bahan kimia ini. Dengan ujian ini bahan X dan Y dapat di lebel dengan betul. Jawapan anda hendaklah mengandungi perkara berikut

(a) Penyataan masalah

(b) Pembolehubah yang terlibat

(c) Senarai bahan dan radas

(d) Prosedur

(e) Penjadualan data

[15 markah]

KERT AS SOALAN T AMAT

454113

Scheme

y Peper 1 & 2

4541

PERSIDANGAN KEBANGSAAN PENGETUA-PENGETUA SEKOLAH MENENGAH MALAYSIA (PKPSM)

CA W ANGAN MELAKA

PEPERIKSAAN PERCUBAAN SIJIL PELAJARAN MALAYSIA 2007

MARKlNG SCHEME CHEMISTRY

Paper 1 and Paper 2

UNTUK KEGUNAAN PEMERIKSA SAHAJA

2

SKEMAPERMARKAHAN PEPERIKSAAN PERCUBAAN SPM 2007 CHEMISTRY 4541/1 DAN 4541/2

c

A

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A

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3

1. Functional diagram shows

2. Thermometer, X, water and bunsen burner/heat is labelled

3. X level must below water level

I. Size of particles are same

2. Are arrange closely pack

3. At least 3 rows, 3 columns

I. Both axis are labelled and with unit

y axis; temperature/X' and x axis; tirne/s

2. Uniform scale (size of graph must be bigger)

3. All points are transfercd correctly and best fit curve I The melting point is marked accurately on the graph]

1. Heat energy is absorbed

2. to overcome the forces between particles

10

2.8.8

the atoms have achieved stable electron arrangement

(i) S

(ii)- atoms of S have a higher nucleic charge

- the valence electron attracted more closely to the nucleus

(i) bursts into fire II white fume/zwhitc solid formed

(ii) 4X + O2 ~ 2X20

(i) X

(ii)-atoms of X are bigger

1

4

(i) gas bubbles formed

(ii) 40I:-f --+ 21 I2 0 + O2 + 4c-

(iii) oxidation

(i) anode

(ii) Chlorine gas reieased

(iii) 2Cr ----7 Cl , + 2e-

(i) the mixture turns brown

(ii) Cl, + 2r ----7 h + 2Cr

(iii). Chlorine

(iv). Chlorine atom receives electron II oxidation number of

chlorine decreases II chlorine acts as oxydising agent

lead (II) iodide

precipitation reaction II double decomposition

(i) potassium iodide solution and lead (II) nitrate solution

(ii) Pb21 --L 2r ~ Pbl ,

. correct chemical formula for reactants and product . balanced chemical equation

(i) sulphuric acid

number of mol of hydrochloric acid, n MV= 2 X 50 =, 0.1 mol

1000 1000

number of mol of copper(II) chloride = 0.1 moll2 =0.05mol

the mass ofcopper(II) chloride produced = 0.05 X 135 =6.75 g

10

1 2

2

10

5

I. J : Alkene 2. K : Alcohol

(i) Butanol

H

I

H H H H

I I I j

H-c-C=C-C--H

I I

H

I

H-'C-H

I

H

I

H

H

H-C-C'=C

I

H H

I + I

(i) Orange solution turn to green II Smell of vinegar II The product change blue litmus paper to red

(ii) I + I

CH)Cl-hCl-hCH20H + 2[0] -- CH3CH2CH2COOH + H20

10

(i)an electrolyte to increase the rate of rusting. (ii) to determine the presence of Fc3-i-

(i) dark blue precipitate

(ii) copper I lead / any metal lower than iron in the Electrochemical Series

(iii) Fe ---'> Fe2+ + 2e

(iv) iron

(i) Y loses electrons to form ion Y

(ii) zinc / magnesium / any metal higher than iron in the Electrochemical Series

connect iron with sacrificial metal/metal that is more electropositive than iron.

6

1. The proton number is II II Number of proton is II

2. Nucleon number is 23 II Atomic mass is 23

3. Number of neutron = 23-11 = 12

4. Nucleus contains I I P and 12n

5. Position of electron circulating the nucleus

6. Correct number shell consists of electron

(i) Formula that show simplest ratio number of atoms of each element in compound

(ii) I. Relative molecular mass for n(CH20) 12n + 211 + 16n = 180

180 II

2. n = 6

(i)

~~-~~~~-,~~~~---~~~-,---~~~~~~~-~-,

Element Fe I CI

-----~--~---~~~~~~~~-----~--~~--~----

I. Mass/g 2.80 I 5.32

2. No. of mo I~~ -2---. 8-0-1 5-6--=-0-.-0-5 5.-3--2-/3-5-. S--=---cO-. 1-5-------iJ

3. , Ratio of molesl I' 0.0510.05 = 1 0.15/0.05 = 3 I

I Simplest ratio .

4. Empirical formula = feCI3 (ii) I. Formula of the reactants

2. Formula of products

3. Balance equation

~ ~ ~

2Fe + 3el2 -> 2FeCb

4. No. of moles Fe = 2.80/56 = 0.05 mol

5. No. of moles Cl2 = (0.05 x 3)/2 = 0.075 mol

6. Volume of Cb = 0.075 x 24 = 1.8 drrr' / 1,800 cm '

20

7

(i) I. Roth axis are labelled and with unit

y axis; volume/em.' and x axis; tirne/s

2. Uniform scale (size of graph must be bigger)

3. A II points are transfered correctly

4. Best fit curve

(ii) 1. Average rate of reaction = 19.01120

2. = 0.0528 cm3s-1

3. Construct tangen at 210 s

4. 0.052 crrr's' 0.050:<:: k:<:: 0.054

Boiling point of oil is higher than boiling point of water At higher temperature potatoes is faster to cook

(ii i) I.
2.
(iv) I.
2.
3.
4. The higher the temperature, rate of reaction increase

High temperature, kinetic energy of particles increasc/zparticles moves faster

Collision frequency between particles increase Effective collision frequency increase

Type of food additive Example
1.1 X = Preservatives 4. I Salt/Sugar/Vinegar/Sodium
: nitrite/Sodium nitrate/Benzoic
acid/Sodium benzoate
2. Y = Antioxidants 5. Ascorbic acid/Sodium citrate/
3. Z = Flavourings 6. Monosodium glutamate/
I aspartame/sugar/salt/vinegar/] ester] ~

1 1+1

·1 lei LJ 1+1 20

1 the atoms of both X and Y have 1 valence electron

2 chlorine (eg) atoms have 7 valence electrons

3 X forms a covalent compound with chlorine

4 Y forms an ionic compound with chlorine

5 I X atom shares 1 pair of electron with 1 chlorine atom

6 r diagram showing electron arrangement in XCI]

7 a Y atom donates the valence electron to a chlorine atom II

a chlorine atom receives an electron from a Y atom

8 to achieve stability in the electron arrangement.

9 To form Y + and cr ions.

lOY + and cr ions attract one another to form a compound

11 [diagram showing electron arrangement of YCI]

1 1 1

(i)[ any 2 of the following:

with high melting or boiling point dissolves in water. does not dissolve in

8

(ii)[ diagram - apparatus set up for testing conductivity labeling: carbon electrode, YCI, heat, galvanometer]

put some solid YCl into a crucible switch on circuit] and heat needle deflects

current flows

shows there are charges / ions moving freely YCI consists of ions

Heat of combustion of ethanol is the heat energy released When 1 molc of ethanol completely burnt

(1)

wind shield

1------ Th e rm ornete r

spirit lamp ~_ ethanol --.l1----+t--VVO 0 den bloc k

(ii).Procedure :

- 200 crrr' of water is measured and poured into a copper can and

the copper can is placed on a tripod stand

- the initial temperature of the water is measured and recorded

- a spirit lamp with ethanol is weighed and its mass is recorded

- the lamp is then placed beneath the copper can and the wick of

The lamp is lighted up immediately

- the water in the can is stirred continuously until the temperature of the water increases by about 30°C.

- the flame is put off and the highest temperature reached by the

\]J "jpr ;" rpt'Arrl"rl

20

3

9

Data

The highest temperature of water The initial temperature of water Increase in temperature, e

t2
II
f2 - t I
m2
ml Mass of lamp after burning Mass of lamp before burning Mass of lamp ethanol burnt, m

Calculation:

Numher of mole of ethanol, C2HsOH, n

m 46 The heat energy given out during combustion by ethanol

the heat energy absorbed by water = m c O kJ

Heat of combustion of ethanol m c e kJmorl

n

There precautions taken to achieve accurate results0(any three)

• make sure the flame from the combustion of ethanol touches the bottom of the copper can. / the spirit lamp

is placed very close or just beneath the bottom of the copper can.

• stir the water in the copper can continuously 1

the spirit lamp must be weighed immediately (because the ethanol is very volatile)

• a wind shield must he used during experiment

2

Detail

----------------- __ -----

[ Able to state the inferens correctly following the statement belowl

2.5,0.8, 0.4"-, _I._I --t- _

[ Able to state any 3 of the no below]

l Ahle to state any 2 of the no below]

[ Able 10 arangge all in correctly oder ]

Example, Mg, Zn_,_F_e_, _P_b_, C_u ~ ti ~ ..

JAble to arangge any 4 the correctly] _

[A ble to arangge any 3 the correctly or any 4 but reverslyJ / 1

------~-~

[Able to relate the pair of metal and the voltage base on electrochemical

series]

_L3_

----------, I

[Able to relate the pair of metal and the ampere base on electrochemical II

series] 2

The pair of metals, which are positioned at a further distance in the electrochemical series, will produce a bigger cell voltage.

r Idea to relate the pair of metal and the voltage base on electrochemical series]

[ Able to writein symbol halence chemical equation]

Mg ~ Mg 2+ +2c

[Able to write in symbol unbalaence chemical equation J

Mz ~ Mz 2+ -I e

\

2

3

2

3

., I

[:?:?, ._\-' J

1-1 _[ ".". _b_etv_v_e_'e_n O_._8_< __ a_n_S_I1_Fe_r_,_' 1_. 0_] 1- _:_J.

[Able to pridict between 1.0 <answer<1.5]

r Able to pridict between

0.4 <answer<0.8]

i --~ _ __j

l [Able to name the gas] I

I Oxygen gas

I

I [Able to write symbol of the gas]

~2

I r Able to write symbol of the oxygen] I

I [OAble to state the relationship between the manipulated variable and.

responding variable]. I
The higher the hydrogen peroxide concentration, the higher the
decomposition rate of hydrogen peroxide I 3 :
[ Able to state the relationship between the manipulated variable and
responding variable inaccurately 1. 2
_~
I
i
[ Able to state any idea about the hypothesis ].
1
, I
X is (49.5-17.0) = 32.5 em 3
3
[answer without unit] 2
[answer without caculatio!!.L [ 1 i
- - -- -_.---- 4

[ Able to draw graph correctly and completely in the same axis]

The axis is labeled and with units The scale are constant

All the point are correctly transferred The curve are correctly draw

The size of the graph are more than 50% of the graph paper

3

[Able to draw graph correctly in the same axis I

The axis is labeled and with II without units The scale arc constant

All the point are 90% correctly transferred The curve arc correctly draw

~,~:, _~he si7.e ofth~e graph are more than 50% of the graph paper

I [Able to draw graph correctly in the same axis]

I The axis is labeled and with II without units All the point are 80% correctly transferred The curve are correctly draw

The size of the graph are more than 50% of the graph paper

__ j_3J

1 2 I

(Answer with unill 38.0 cm3 (±0.5 cm')

f---------------------

[Answer without unit]

38.0

---

38

[Able to infer correctly]

2

I

The higher the concentration of hidrogen peroxide the higher the rate of I 3

decomposition/reaction I i

The concentration of hydrogen peroxide in Experiment IT is higher -

-J compared to the concentration of hydrogen peroxide in Experiment 1. 2

_1 [idea to i~rerl ==r_ 1 J

5

Able to give the problem statement accuratefy] TI 10w X and Y can be differentiated by using r acidified Potasium i 3 I nangganate 7/ bromine water]. ?

Able to give the problem statement inaccurately]

12

!

I

X and Y can be differentiated by using [Potasium mangganate ).

Able to give an idea about the problem statement of the experiment

Able to state the correct procedure]

-------------i---~

I

I

I

) (2-3) hexane and hexene are poured into two different est tubes.

i) Three drops of bromine water are added into the test tubes. ii) The test tubes arc closed with stoppers.

v) The mixtures are shaken.

!) The observations are recorded.

Able to state the procedure to conduct the experiment F# Procedure no. 2, 3, 4 and 5

i -A-b-l-e-t-O-'~-'t-a-te-. a-n-id-e-~a-a-b-o--ut-t-h-e-h-Y-'P-o-t-h-es-i-s---- --~-.----- 1-1 .

t# Procedure no. 2, 3 and 4 I

Able to state complete material and apparatus to conduct the experiment

.ists of apparatus and materials: Test tubes, dropper, stopper, iromine water Ii]

~xample ,

vfaterial : bromine water, reagent X and Y

'\pparatus : Test tube, dropper, stopper

3

2

3

Able to state material and apparatus to cO,nduct the, experiment -] ---.~-~, sts of apparatus and materials: Test tubes, dropper, stopper,

omine water

I Example, 2

Material : bromine water, reagent X and Y

Apparatus: Test tube

6

[Able to slate material and apparatus to conduct the experiment]
Example, 1
Material : bromine water, reagent X and Y
Apparatus: Test tube
j
I
[Able to state the procedure to conduct the experiment 1 3
[ Able to state the procedure to conduct the experiment ]
2
l) ## Procedure no. 1, 2, 4 and 5 i
c--
I l Able to state the minimum procedure to conduct the experiment ]

## Procedure no. 1 and 2
,
[ Able to make a labeled tabulation of data J
Example,
:) r-r- I
Test tube observation ~
X I
I Y I
I ,
I + __ 1

3

J

7

T: Able to make a fahulalinn of data 1

I TCS~UbC I _J

[Able 10 make an ideafor tabulation of data]

c-- -~

L_____ _J

for report

If the total mark for Question 3 is 12 and above, the score for report is 2.

i

Ifthe total mark for Question 3 is 8 to 11 , the score for report is 1. I

__ L_J

SKEMA PEMARKAHAN T AMA T