MATERIALE PLASTICE ‘+ materiale plastice Bucareg- Reni *elastomeri hn ab 2020) Dd Yo $8, m0, sepembrie 2012 ‘+ materiale composite + sintezd, caracterizare, inginerie CCUPRINS GR. Peu, AS. Sarvestan LL. Palade ode esige molecarpeninananacompoatepoimeielncaie, IN Mohammadian. A. Ke Hagh Uele apete pind masurarie iametreornanofixelrpolacrontlice ate Sunita Andreea Moga. X. Goga, Hadar Novlemostate peruse men matical CGeorgeseu 1 Steanesct M. Botan. Lorena Delean Fecare suniapeibuleneetaou pe teria ese psa H.Globan, {Buta C. Ghita Sut pind proces de tunare a produsserindustiale dn cause 4M Manoe,C Siescu, Meda-Lavinla Negrutt, Lavinia Ardelean, Diana Bude i Romina Erahareatomeconica 9 une protee pata fixe mello polmerce cn spr paaotal arab Daniela Tana Tador 1. Parausan, A Hadar \aidrea prin analzarnodalaa modeller nor lai cu scout eazate din materia pas Matlanaloana Strom D- Dodenelu, Sarbese, Svana Cana, avila Aedelean, tara Castina Rusu. Carmen Todea Molecular Constitutive Model for Entangled Polymer Nanocomposites (ATL eu ALIREZA S, SANESTAM LU LAN PLADE "aera al Nile Egor, Reise ata se, Dept of Mahia, YP, USA ese, Depannen oa! ges fae Sc meal Seles, Cano, ME ws "vst de yon, CAS sta Care RSE PSone ce tates. Bi esl nN 4 molecular rheological model for amephoushamopobmers filed with naoparcsis resented. The ers are won agglomerte a teat enersetal wah ie payers The model apples staatonsit ‘whic te pene ler afiny rls) teak The essential pss reresented ithe model ees ‘han reno, the sowing dun of itson da 0 ene teractions polymer and les chain Sterch, an cantor era Mactan The mode shasedon inst obtained orm eerste ston Of the snctre and dynamics ofthese systems. Te chan population compose of fe, dang am bridging ca, e. thse tht at sce tne dons omc ile, contac one filer or mate les rege Ate os cokes ase hss aaa ree cee, he representa chal repats nl hen ee, we contour length Macuatons are perormed a times Reaxuton correc by bath ie rene an the paces of chain attachment detatet fo ‘ome er site he second process octet fis, eating to oetaaton io chants {ines agreement it experimental observations. The parameters entering the model can be cate ‘ase on the meolgy’of he nea polner a base of ests a ston of te respecte ied Keywords: ving of poy nano compass relation: contour length Aetton tbe reer Uthzarea sicar de conderare stars fopotierzable in adultes ig palpare pn ets aver Dope wing Nica, 8 Cinpoesu, \ Rusu, Monit Andronache, iprna Sefanesa Prpreaesiuctole als composiclorrestoralvenano smicrofate M.Wonammacian, A. Asal, Mottaghtalab, A. K. Haght Polymer nanocomposites represen a new class of of regular particulate composites, reinforcement is Spaleasttecareaapidaa mateleloreakate dn poles lara elecroplacae nutes of sgiieant currentinteret Te tention they haat panicuate composites, reinforcenent i CR leh, 1 Prasach, Lege : frceive is due othe hope that novel combinations of Swi sation, whsch pons susy an ecoe Iitenta detector supe conor inarice a sicior composite rafosate ci Hbe neiteuple Properiescan be obsinedby ming posmerswihnano- ft’ FE Sebesan, G, Paras, N 1. Zaharia fijects The Key requretent i thal the filers have "fe onsideratons indicat that unig con over Tes pent sabia earactersieor mecarce ale pallor de auc utiliza tensions sins tothose ol the pane chains The gata pcesings cuca Tis cage dene crt Tasutemul de aaa site decal frat Chine. teaduscf gyration setsanineralleth 4n'expetimenlal al and evr procedure by D.A Cires, Sines, D. Dodenci, Lavinia Ardley eda Vavinia Negra tele forthehateral The anobjetdimensonsdcine Sonasestnatmodchngansttufersrdsepeies A.D. Halg, i. Homma fvoter (or several) length scale. The interpay ofthese fn peer to evance alg he seta pal, deen Pastinaresnmediin deniar mete spl. Frthscaesilunces the pinsiesunderingthe aerial Sons represents fe mated behest, ‘lina Ruxandra Carat, Cristina Banu, Sorina ives, Ncoeta Burana, chavo deed, many fecent experimental studes orate te sal sale pes mpatan Soh Uidia Avadane, V Neolae ‘gest that material properties of he polymer change models oer Ihe poss to pliize with resect 0 Nolmateale compost aarsate cv apical in industria automobile ‘pon adaiton of «smal lume acon of nanometer fanoseale paraineters both tealtalrespoee and Pies, Sines, L-Flore, F . Topal, Laura Cristina Rusu, D. N Cis A Podoieana sed ler parls leg Wei et al (200) 141];Zhangand ater processing Ths ls objective of Ie eset Platine prbelorde bape preevate dit seal ners cena ca sae Ache (202 [31,2004 [0 Sterten and Zu (NE) Nor, Spcicallya constitute formulation is beng pena meledalomograie opie de certain Tine Doma Tail Oasker al (205) (21 |. Por example, the viconty, POM. Spgtieal, a consituatve formulation i being ‘ichira, Gh RE Mares tlhe lo requeney storage and lose moduli inrease Presented for the mechanical response of pa nena precede macinatuaasupacaracterisicor mec tant cerpaed othe eatpohmerandareiaivey, aocommoras mens, The componts cnadered Nee ‘Sleunor plier iain de sult, pz metode de determinar a ezsenelor mecanie Inte payne ike PMMA warsorms io ductle one Aer ae ell cepesed he ht ‘Alexandra Bolocan, D. ln, 8. Constantinescu, Ari Diana Luea,D.N. Padurarn tea ning with naroparicies (Nye (1985) [20] The development of rheologtal Molecular mocl for Teste pein corparateaplaslot ela dn polopienacucele cin rare de poliien However not al researhersreponinprowemens peat poder hes & lone hen, eal cael folie neaourte Ill properties nat one may find mulipe pots tyodlsavalable to date ae tose based te tube Ae. Bordeass iis, Roden adoro toring tothe sae mateal sem fhatcontadkteach Sincerxpnayoon by dccemresanddeceoea iced ‘onset prvi reitentamecaica a paletelrdetubineonaraizate tte These dcrepancis are atiibuted, in arto two Evan and other worker [Oo and vars (16) (6) ‘Gnpokeste amaticuivade sta, reasons Itefilersare poo dspesedonerecoversthe Rife a (184) TIT ls cas of models te as iirela Teodoreseu, Antonela Curiez, hc gop operiesexpeced forthe equtalentmictocomposite elation mecharisns ae the eptabonal techn Prapseaie moles ope ae titer subtede plaid obit pin metoda Spin-coaing Eisimdarhilervolme action Ider areweldspersed Ypevnech nrepamans am tepauonaf ne chnnwitn fhe maui, ul the polymere interaction sol Chain fe Doctors tele gg and the leans, fontolled, one may or may not obtain the desited —Sfepsogial consis du ihe onc suncaning tmancementn properties. Generalist asin the case Chay hese, he tt aw been West he‘mean fed sense and led 10 modes tha eproduce the main features ofthe theology [eg Mead and Leal (1959) [19h Mead eta. (8856) 198) [17] The third eect, ' more dic fo be predicted within the mean felt ‘approimation of chat dynamic a ato tos have been developed to cope ‘with this difficulty [anit and Marre (200 [1], 200 12), ne fal. (201) 9; Graham etal. (208) 9 Sama ts. (eons) | The linear theology of monodisperse neat ‘nels wel represented y tne cue model The fae linear aspects of the problem are less wel described ‘Accounting for chain asperay poses major prblens 2 the contling pss in such sytem felted 1s ‘omlnear eflecs of he costa velease ype, The theology of mixtures of linear monodisperse Poets and nafs is omparaiely much inore dificult to model. The problem vas adtessed in is Context of sho unentaged polymers [arvestar and Preu (204) [30 Tend polymers close tothe overap ‘esol [Sarvestan and Pe (2005) [YI eft case, the dominant response comes fom the tans hetwork of chains tht bldg filer. nthe second, Th Aiton to he secondary network ect Neier a (198) [28 |-cne tas astowing down of amis die W ‘he ental iteractons between chains a! e's Inths Wonk, hemi entangled stems are considered, In tis case te physi demanated bythe confinement of the representative chain inthe vtube™ and bY i interaction Wh les, The pomer flr inroan onskered relatively weak, Sch fal the probably of cai detachment and, poeta, reatactent} on 3 lime scale comparable with the Rouse tine of the respecne ch smaller Dut cose to ne. As wth ‘ther modes ofthe helo ol neat pliers: one hs Take assumptions about the dominant physi ana allerpto capture tin tata analal fons The hey aspect ol hepsi considered here ae presented ft Section 2. The mae presented in Section 3, whe Section 4s sued how teseassumglions ence ine Model behavior qualfative Comparison sah experimental datas presened in he closing seton The material and overview of simulation data Tne ste comigeed hte a Ne near rmonodspersehomopohmersandnanepariee ie Ber, ae speial. of ential ameter and are mpenetable forthe pojmerc chains Ther detonation dur on of the suspension neil. Tis system s representative {cemateralsf the pe tested Zhang and Archer (2109) {55}, Stemstin and Za (202) [36 and Zh ta (2105), Ho} in uh ils are rope espersd nthe mab Amite er aggomeraton ‘Theil. sao sir totbe chains of ation tn he neat bal Stuns n nth es ‘ae much ander tan Ray aio be represented, Tiss thelimiofreguapobsher compass mwhieh heer ‘ae sordes ol agntue age han eo he chars However, these cases ae comer es intresting on ‘he basis ofthe experimental evidence dieused tie Inoducion showing that entanced material properties areobiaed when and Rate comparable The molecular weight of the cha assumed o be much age ante erangement molecular weigh The lenathof ti entangernent segment idenoted by. wie the umber of such segments na chain denoted by N These aunties are those iene forthe neat ul ole ommacreseopic experiment oom somite ‘molecular simulations eres assumed that a remais Upctangedinprsence lnanoparces anise ich coords ‘hen eta re xenon sgrpieg terest ed nantes ae ty sorte nine ge (zt ae and Garay a) eae a Gt) i | Antec eee Sees ak tessa tees eke amoce tnngbe ores ioe hee eee ‘Sraftete t hecamee ans ena Plimoth rcs ca Se eae fica pea eo eee pant wi le pert eee irgeetic (ese am chemea) ache bean en sete a (Sob) Balan htha eens, Parmeter wy antec ae fel contig este a mye a ‘apo ec a a Svea sey erect ee Seng cote ee eaiage ee ec ctie! ofy 8 gic nea tes altionvantie Sptalintwesal os ecco aan gale oe a pegeane whch abou 8 ey eee on (Git being the Bolemann’sconsant he tice of sem Be arated on cae Roa cate sme as ofthe ka ees fie peter ncn purely repulse (exes ese) nets Irate blk pyar SS ‘anual nye ete hn eka fterExdng stash aera eget theme ace Wi teense at SS canon Nee CSD) kee a otic ie Saas tenatta tte cnt fiance tino inhettemesniubimeeess teciansu! ila) Ontescakfneence aah, thee ob nm sma of frotan rar fom hanger Rist chinapnacree nce sear tage sem resp gen ai iiherirecton igen ether see te etn i onra a Sino tan soe sa ‘aon it ogo cacy creer Sone Sky net ons e Soca Cah iri nea a Tes ven aes peer a Sicharo =f vrnchtaqe fa cornea Shae tn oe ibe eel te in eae hepa of ee ae insesce/bechelteherdager amet fecha ec ea Vihertesge alte Anes ds eq Simtech ne er scone sexi Sie als tim itt ea EStton phrase’ erent Threat teretinteicns ta rorctedcoiniyet Storey ton Theatr a tia neo ay ae oy eat mds ene aa NT alco te nC eames bs ht ATERUALE PLASTICE « 0 No.3 © 2012 ps dst 21) cin ee a te i ce SEB Tae ae set it an Col or ene ici ns Sta ute ee sis eee oe a Tecra Cera gO IS ‘The model The Meclogcl model presented below is based on ihesefiadings-t gen ine he sstem cons Fetes ‘ged, and of re chains ia conta no lr, darting ‘Sebi cin respectively (y+ 9, + = es “sumed tha the bide chain coma nono han Iwo ers. A schematerepresenation othe thee pes Behan Is shown in igure 1. Dangling chains are fompased rom te danging segments of ength Nand Reh dng caine ae composed of two dang ‘Segment of enh N and Nand 9 bang seine of fears sNeshy t=, Sa N being the mame t Scungeinet semen o the mene chai a treme. sei te ae ces ‘elaxation time) Rouse relaxation is neglected. sae maa ee rice ie iitneamg cesses iia teerreetea erect Fn ae ‘not appiy in such situations. The attachment lifetime can‘hing in hgh tte flows. This effec is not considered het bt canbe inclded nthe model, The tndtodynamic interactions ate neglected inthis ‘modelbotorpahnersmetsae) andor ies Hence, ‘heer exch lume plays no detente ade, Le: les are slr to meter pons Ther presence Feit only through the interaction wits the chins. The Iychodinamis ofthe ler s expected ob mporatn Iga ows and tage ile volume actos. Reptaton Let us conser a representative chin ofthe sytem, ch Besins as fee chain and Becomes at ranger angling and bridging, or remains fee. The Ianstion Drobabitis are gen byte respecte facton, and Slates tie rr ie pee thetic cetrotmassdunnga pesodu hse ‘recon (ID afin) sen a in ti neat uk by ssn )not o heresy = su /s(a), andthe noaion +) suse or The Ruse tine ofthe Segment oh Ua (>), wth ‘being the Rouse me of the entanglement segment , Mein patag Endo sedsobe omits ugh) ar) Soin The concept undering eg (12) vali ony the aachment ime f signi larger han We ese of the atempl frequency, > y(Na) This coro Is lvays lulled since oalystluaons in which the ‘tahent ie ager han te Rouse ime ole enire ‘han ha) are considered The Simplest despised wansparent form of tcf pti, ngnen ena ead (isa) ¥, However, this potential appears to be too stiff and predict avery sow relaxation associated witha Fetracton An improved verson tat nets te eflect ot ‘contain release (Amami dltlon) was developed by Her and ete (197) 16 and eads 26-Fy(oa) OH) This expression leads to an excellent match of, ‘experimental dala and theoreti! predictions forthe elation ofa ofa potmersorblends linear and $arpomers Expesio (1) reduces (1) or sal Ih order i account or al posse configura, a average over ne, (12) sperormed U6(h8) Ft sen Kd. Here, ps the probity to find a dangling end of length quay which Was eased as afunction od And by means of simulations [Ozmusul et al (2015) {23} Dianne tal (2005) 1}. Ts expresson provides En inp equation [or asa func of Hust be noted that iis procedure neglects the speed-up of Constant release die to le posers of he rm lengths Nevertless, some degre of constant reese ‘Sincoported in (15) tous the fanetonal frm ofthe potent (1) (ier and Mei (1987 1 (hai srech ie us consider agpin a represenaive chain of he population, The cain becomes at andom ee, danging or riding, Sch laces we the can dangling ot fee and cannot ean we the cain bigest ken {flows trom neastmplon ofthese maton ote) ‘ha stretch relaxation ofthe short dangling segments fond by abridging chan Is neglected, Hence, di ‘ela the ropresnttve cain seich's enabled and @) ou The variable represen the i velocity imposed by the oe The fist erm oe igh hand side represen the imposed deformation we the eco ce std relation, An apposinaon is made (16) fn a he Stechearation ime s taken lobe the Rouse tne oie ttre ch (Na nallcases. Te sethelxatian th Sa danging Segment of engih Vs he Rowse te Sine respective segment Hence the aprotinin eth {oan overestimate fhe sete elaxon tine ifpe)a he rab fora canto fol te tae efined by HEE) te average seth at gen eT denoted as TiF)= [raat Het the integra is performed over the phase space defined by APP tne averagingopeatr oe (18) eas 10 ~aheglhetsimenatci freomait cm et us consider now that all uajectories ae equal probable Then, using the ergot property fo he process, MO). and. [rriH(Fm tnt, and Pucsrneumd cg eR amen Hence, the relation remains exponential, but th characte tne changes wih he rch oftedtg ha he sate. Le noe ta a nonsiear em in Ais used int telat to a1), ng he Wa approximation ofthe inverse Eangevn function, at ObHonequatonolype 7 }erbeaerageo este ‘annatbe cblaine anymore Stress evaluation Lets considera generic lading history for which te stress evolution mist be evaluated in tens of the ‘eformation istry Assing tat sess i de bh Segment retain, destbed bythe osentaion tens icp and stretch, and thal ove can use a mula Alcompeaton pprximation, he ses ensor becom Ta | Foci oe] [ Facing | Fiano OE] ‘cae doit | oo-oPoR ‘Wher 6st modus an is expresses {Ema} Het, @ is the Dok awards tensor and B27) the {psi deformation gradient tensor etveen ines are te urine (2) reflects eft Thal the average ‘esa of he chain segrent population i computed iva weighted average oer a chai a esse. The Weis are (1 te tacton fens hat become ee forv ai tystyand "(7 pepresen tne Factonof segments surivngatime {nthe te defined time. Aedsctssed in Secon 31,8 a constant Thome ean wtite ¢ nal fo completeness, fetus note al the eave ‘ubechain dl voi evan based on he average ‘fenton ensorS(Jandthe veloc gradient using ie Approximation of “constant 8 og) =nt) Se Sumer eeu and discussion “he bettors model under aris defloration cottrets cared pen Theemphasson erie thetntuence ie vous nanos parses on ie Orel eal pot mecha eine OX pany tered re he wato-wall danced an he poe Arai These parce af represen ne ecto fe, dang and gg the mean tachment ine pare Gscussed a Secon 2, he aerge ue of» per contact ‘iw a cpl). The lah between da ihethee gs mote complicated and needs fo be ‘teninedysimtions [one e205) gue {lame (20) show he von ofthe we factors the aomalaedwalional anced. Te facto oftigg anes cas are monotone ih, ‘ie e tartan of danging Cane ices and eh decreases wi ineasing dT vans eo he ina sal tdi ca orm ges Theacons ore anostindependn’ fw inthe geo Mais tc = 1-8) Inti sy rays re considered Tei ves are genital she ference, ei oer Sie Ssylomihinobidgesintichd = 288 set the mber caning co er Mer exes aon, ie amar iotalobaned fr tens yah vey sa filer sume fnctons. Te thir stem, 8, coneponds {Gd 2248 and has a sal facion of bidgng cane. ‘he gusftem Sina age mabe ges er and conesponds od 138 [Oonne (63) Bint simasions prone by Dene et 8) [lie ery in es 4s ‘gna flect on he suc "fe pe of flow ae cond relaxation foning astpalinand srt shear fw om threat {aptinel an ans ert mods) ad int conepontng storage an oss mal Gand a the searfow cate, eel vrentne sest she ane noma es ec, the any sate aes conespndng ov an tes are aaj The vatous neaties ae eal based on he nomaled tess ag) =P 780) 2.19) andthe me unis ae a aid ye oe ive fhe efanglemen Segment). The teerence Uns ate Route te fhe en in) Sd the deinen Une #~ others be ea ‘pam The equations oft eel ae ogae in iesumptene casantdiheocye geaay taken tobe the average over he here Ace he Sprosimson's good sone approaches the ses sate Effect re delet and is goa he Stat. Conigering constancy sey Simpiesteinegaton site consul egion {ere 3 shows he rlsaon ms for be four sts Here ces were nmalasby be ae af isa Sess tthe egg oe reaaton pend The can length conaldged as = 9 enandemen {egrets afin apts the mean aaron Oe es AE(N). The pl shows gia sing ow mie ts decressing waa stoneo)= PSC) eo () ands umd ye frauen ye ean cave) al ao te ‘a= PBS x comers, ith easing the ile volume fection, Even the sfstem $2 i lected by the slow down Furthermore all filed systems exhibit a two slage felaxalion whic i reminiscent ol the vo phsical Processes involved: dsenanglement and atlachment oetnen ee igure 4 shows the storage and loss modull corresponding othe cures in ge The cures orl Se shown fr vference The igh end of the frequency Tange oferestis zi). Tews of the curves a igh Frequeney enol see here because the Reuse mes ae Tlneloedinhe model Teel Rouse reed laxaien that o sete, however, sete ea aca ths Stall ample ad lave fw rat loading. Wis seen that ie eninglement plateaus nthe tee ystems ae ‘eta alle siting) ae coserved in expeiments [Zs ta (2) (4) The atachmestidetacment process Jeo oaneslensnaf he G plateautoloweregences. ‘he plate for Sis over Han ta for 88, Fubermore thelengh athe plateau aso depends ond (or ie volute Frc) feature which te mea nie (8 ewerey foe . "6 itn oft lle age csi the a 5a of sae and se i wh he age ae mule ine meee ar Eu etty(he tnd, 10a) pag ne warmin rean a@) = PDB the mean atch ime the same nar), a Isobserved inexperimens Te should be noted that making the attachmeny detachment characteristic time polyalsperse, bul preserving the mean, changes tl in the quate Features discussed ere as longa the sbuton off ‘yeti especie mea Separate ses ive Shown thal skewang the disibulin towards shor Btacinet tines (eine ton he Suggested bythe simulation of Dionne et (28 leads to lovering or ever eiminaling the extension ol te Diateay at love frequencies. hese cases, the sore modulus decreases continuously with decreasing frequency ists forte net palmer Gita 3 ower ‘ate than for St Asmar behav seen in Pure [uel el of aeons ince ee ‘lth perils sactounted orb nereasig the electne menamenefcton coeticent (Serves and eu (2005) [3 |v experiments sen hat te ‘Seeonday plateau fons only a suffer ge ke ‘ome tacos [Stemstein and Zo (202) [I-A “Sulfiler volume actions an with hot chains, thee no plateau and G decays contac wih decrease frequen Gallows he ual equency dependence a thereat poles he prope so lower eqiences aneennG! ‘Theft ofthe mean f, (or w) i demonstrated in figures where Gand Ge show othe syste 82, ft Tyeet(Ne) and. fy 210% (Ne). Hnereasing ihe ‘acne tneeaes he lent ofthe plateau in i bein erty Teg eres ane ti (gues tu Te dated eis domo sce he je forthe ange of paareters stated he ay wo and the spatial range over which the polymer interacts feral wih he rae neat increased a un pote ayers expected fa form nt Hence the hain suture and he slacmentdeachment process tre expected tobe diferent from tose considered here Fuacheases, he bound polmer lyre creases rads ele whe he ee cain do ot ieract ‘wth th fie but ter wit Tie paper ean ad Uirlcthered dangling ends that orm te bound ler The pve ofthis problems sah aeret and cannot De Fesnted vith the models cent om Figures an show esuls forthe startup shear flow Age shows De vara ofthe fst normal sess llerence N= = éandof he norman shear sess 4, ih the stan Shear tte mulled by normale hie) curing wansien for varius ates anders Si. The stelehinduced overshot sobservedorthe tore"), Wi sete io en wo athe PE) ‘snomalzedby he Rowse — nt chan. The elatnship essential fineat —ineractionsinvobing fier particles, suntons in which the present rndel proses ony par othe sits. The fect of ting to manta the overshoot ae shear Sess don to WY uber onthe ener of | igre 8 Sows te steady sate cimensioness shear Stes and fist normal siress diferente as 2 function oe heat Tate The decrease of he shear sites at highales ‘irbuedotelaek ot comecve consi cea [Mead ta ts Aiwa tem a Slopes that ead 16 constant shearesensoal ose, ‘Thetwossioms 8! and 8 exNb the sare aac bahar Concusions °Xcantutive model forthe rheology of zolmer raoeomposts was presented Te model acts felanaion due lo chain repiation, contour length fhuctations and inches sete, i accounts for the process of ean atachmentetaciament tan ies nd incorpottes two parameters ofthe nanoscale problem These ae the ler walto-wal stance hich Higher Wi number Bowsareexpeced io ese ote ier woke traction, and an eect fluenced more significantly by hydrodynamic pohmer ler afin increasing bo ofthese pureters : Ends sing con ie aon nd eee iherelaaton plateau ia the sorage modulus cals Irequeels. the feng ofthe paeas and the gest relation nein he sya depend on bth parmeter. AchigherIrequencies, the model predicts the same entanglement ike tea in bt let at nea ses ‘These features ae also observed in expenmens, The Wissenberg number Wi (computed with spect iowartiowteqiewes ssegecst howeceiepien HM yg ‘alan of he model canbe prone based on dats Shosels ater es Ts fe dos ne appro fm Se {ern et payer ao bse onder ve fen prion xn ne rt a4 Situation ofthe suet of the respecte nano: Iselin dares of he teu dete at composite stem. Maas yeas be lane cai Da oe = fee wit ven pod owe pronounced. A Fy a eee He ato on Drea Sneases Chita ee inden aninresse ‘meget aoe te prec t d ‘faracese rela ine ofthe stem. The aw ‘acme sae Spe sures of 6 athigh equences nd ny q ‘resto metal inacearacs ine imegoon 8 iw References torn not nge of Regence 1 nf fre ats ene R, dy =, WOR ARISHONG RE HISAR, Dele The varaon ofthe longest relation characteris Sime wth (othe pole lr afinty, 1) shown ing Thee stoma bythe disentangle ee ag)=POpSayseboed we 19} Th ata ae ‘at peer” Crom Pe I, pA yon vant = aed y= Ata) aa ey oe ee un‘Nv C006), : on ‘TFETTERS, Ld, LOHSE, DJ, MILNER, 87, GRAESSLEX WW, Packing anager es a Se [4 KOLWANKAR KM. GANGA AD, “Loca ‘oan han ‘hws of eng pohmees acres, 1,9 5.2314, relaaion in sar ply ns” Macrencecales 38, 198, p 215% SNL Tati nannies Staats NG DANE ACU Fy, AGUS MIS, RC, STERNGTE SS, KNAR SK, Le ente Ca snwatone of esi conformation in pet meres armel 5 pa PARC Tae sim nin ese sbaped palmers” acomedecies 1.184, pA, Spel, Re, GaMUSLL AS, “Seco re percha 22. MCU, RC. RAKSHA. “Dues af fe cis spl ramaconens" 1 Ca Py. 20, pV) 0, ce SB SOME, WA. Mecano ‘iD, 2, THOMPSON. WANG, 5. VON MEERWALLE 0, ee ate, Some Aspects of Polyacrylonitrile (PAN) Electrospun Nanofibers Diameters Measurements In tis paper, some aspet of elecrospun ranoiverdametr measurement has been presented. The ‘met was eed a simul image ith hnnun characteris and real webs De resale shou thet thsapqroachssuccessain mating fos, acca automated measinementso elec ber amet Keywords: anspor properties, autemated measiremen,electospnnng, anafiser ameter ‘image analysis in imetyifoemamide (DMF) solvent at 405°C and ‘fret concentrations. ber dametr usualy determined fom Scanning Election Miroscopy (SEM) images oblainec a the électrospun webs (tg. 1). Due to the small Mer fimensions,high-quafiy images with appropriate magncaons are required. Nantes are considered as Hes wth diameters in trang of one oro orders of magne smal han Baise of comentonal ete Mier, Eleevospnnng Is 2 aiid method for manacunngnapoders that fombines the Def ofa contd fer dame th Br pos orage sae automated prostuetion inthis pots ah lect eld sapped elven 3 target Plata oz ofa eyinderconttang polner solvent FEjers As tnedspersonpushea hvugh the nazae ‘mecca charged jtolpohmer formed, wtih on fhvng by means af evaporation of solver, esuls in favor cient ranoers colected on te gt 4 hasbeen oud thatmomphologyonanotbers depends ‘3 many processing parameters, These parameters can br ded im Sri groups as sho ade Inde herehanbeennosiecessulmeatdeieloped terneasiomated measiringo sectospunPber diameter thie has hindered the upake ofthis process ong le proution he bjectve of ts vestigation io ‘montberdiamelet Manual metho Routine measurement of fiber diameter and its stun ane cated ou D8 Mana meth. isthe Seale is et The pals beeen two edges 0 fst ar toiheber aks ne counted Terabe ot merle ov using he eaeand the fesing dlomelers recorded, On fp image, Ihe diameter of 100 er ate measured using ts metiod Sue istogramo fer daeter esrbton spate, ‘his process very much lme-censuing and perfor Consistency and fatigue may reduce the acturac, Idenhng the edges ofthe Shes needs stendonand te mmeneuerenis ae not exit mage perpen He Mier ans cannot be season ine method quay enol de othe need of an operator for easueren [ulomating the Mber diameter measurement and lininating heise of he human opeatr nail Selon os problem, {aperimental part Mele ‘ur eletrospining apparatus consisted of a syringe urn. a0-S0K4 De power Supp an ammeter andvarogs {Ektipdences ining metal scree, bes and ser lugelsinanenosed aay cage Poco (PAN) Miers (edness =16 dex lengih =1S0nen | bright) ‘re sed prepare soko. This polymer was dssaied Image anabsis “An image ana based method was peoposed 2) foemeastg ier diameter in nonwoven eats his