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ACRYLONITRILE BY
AMMOXIDATION OF
PROPYLENE
GROUP MEMBERS
Waheed Ahmed
Adnan Raf
Ahmed Haroon
Shahzad Ali Zahid
(2k11-ChE-09)
(2k11-ChE-16)
(2k11-ChE-23)
(2k11-ChE-49)
1a
CONTENTS
Introduction
Process
Description
Site Selection
Hazop study and EIA
1b
Introduction
Waheed Ahmad
(2k11-Che-09)
2a
INTRODUCTION
2b
PHYSICAL PROPERTIES
colorless liquid and faint characteristic odor.
Other trade names.
Acrylonitrile polymerizes explosively.
3b
Property
Value
Molecular weight
53.06
Boiling point, 0C
Critical temperature,
0
C
Density, g/L
246.0
806.0 At 20"C
-83.55
Heat of polymerization,
kJ/mol
Ignition temperature, C
-72.4
Viscosity at 25C, cP
0.34
Heat capacity,
2.094
481.0
3c
CHEMICAL PROPERTIES
XCH2CH2COR
3d
3e
RCH2CH2CN
4a
4b
MANUFACTURING PROCESSES
Early Processes
a.
CH2OH-CH2-CN
O
CH2OH-CH2-CN
Temperature 200C
Yield 90%
CH2=CH-CN+H2O
CH2=CH-CN
temperature of 80 to 90C
C.
CH3-CHO + HCN
CH3CHOH-CN
CH3CHOH-CN (10-20) C
CH2-CH-CN + H2O
Yield 90 percent
D.
4CH2=CH-CH3+6NO
4CH2=CH-CN + 6H2O + N2
E. From Propionitrile.
CH3CH2CN
CH2 = CHCN + H2
F. From Propionaldehyde.
CH3CH2CHO + NH3
CH2=CH-CN+3H2O
H0298 -515kJ/mol
Economical
PROCESS DESCRIPTION
Raw Material
Ammonia (NH3)
Air
Propylene(C3H6)
H0298 -515kJ/mol
CH2 = CH CH3 + O2
CH2 = CH CHO + NH3
CH2 = CH CH = NH + 1/202
REACTION MECHANISM
QUENCHER
No. of Stages : 10
ABSORBER
Column Diameter=5ft
RECOVERY UNIT
Idea is to recover the useful components from the
aqueous solution like ACN, AN etc.
No. of stages: 10
Random Packing: Saddles made up of ceramic,
diameter=0.5in
Total tower height=40ft
Column diameter=5ft
CATALYST
Adnan Raf
2k11-Che-15
HAZOP STUDY
A HAZOP survey is one of the most common and
widely accepted methods of systematic
qualitative hazard analysis.
It is used for both new or existing facilities and can
be applied to a whole plant, a production unit, or
a piece of equipment
4c
4d
4e
5a
Meanings
No
Less
Quantitative decrease
More
Quantitative increase
Part of
Qualitative decrease
As well as
Qualitative increase
Reverse
Logical opposite of
Other than
Complete substitution
5b