BRILLIANT IIT/ MEDICAL ACADEMY

DILSUKHNAGAR, HYDERABAD

Sub:Chemistry

DATE: 5/04/2014

COLLIGATIVE PROPERTIES

Single Correct Answer

1.
The freezing point of equimolal solution in aqueous medium will be highest for:
Ca NO3 2

C6 H 5 NH 3Cl

2.
3.

La NO3 3

C6 H12O6

a)
b)
c)
d)
Which of the following 0.1 M aqueous solutions will have the lowest freezing point?
a)Glucose
b) urea
c) NaCl
0.5 M aqueous solution of glucose is isotonic with:

d)

K 2 SO4

CaCl2

4.

a) 0.5 M KCl solution

b) 0.5 M
solution
c)0.5 M urea solution
d) 1 M solution of sucrose.
Which one of the following pairs of solution can we except to be isotonic at the same
temperature?
a)0.1 M urea and 0.1 M NaCl
Na2 SO4

c)0.1 M NaCl and 0.1 M

5.
6.

The value of vant Hoff factor for

a) 3
b)2
The degree of ionization
by expression :

a)
7.

i 1
x y 1

b)

P2

K 4 Fe CN 6

c)4

and 0.1 M

Na2 SO4

, assuming complete ionization is:

d)5
Ax By

of a weak electrolyte

i 1
x y 1

and 10 g of sucrose

P1 P2 P3

9.

d)0.1 M

Ca NO3 2

c)

x y 1
i 1

is related to vant Hoff factor

d)

x y 1
i 1

The relationship between osmotic pressure at 273 K when 10 g of glucose

urea

8.

MgCl2

b) 0.1 M urea and 0.2 M

P3

P3 P1 P2

P1 ;

10 g of

are dissolved in 250 mL of water is:

P2 P1 P3

P2 P3 P1

a)
b)
c)
d)
When acetone and chloroform are mixed together, H-bonding takes place between them.
Such a liquid pair shows:
a)+ve deviation from Raoults law
b) ve deviation from Raoults law
c) no deviation from Raoults law
d) slight increase in volume
Y gm of a non- volatile solute of molar mass M is dissolved in 250 f of benzene. If Kb
is molal elevation constant, the value of
a)

4M
K bY

b)

4 K bY
M

Kb

c)

is given by:
Y
4M

Kb

d)

Y
M

Brilliant IIT/ Medical Academy, Shalivahananagar, Dilsukhnagar, Hyderabad-36,

Ph.No: 6550 7778.

10.

The relative lowering of vapour pressure caused by dissolving 71.3 g of a substance in

7.13 10 3

11.

1000g of water is
. The molecular mass of the substance is :
a)180
b) 18
c) 1.8
d) 360
Which of the following will have greatest change in freezing point?
a)0.10 M
c) 0.10 M

12.

CH 3OH aq

CH 3OH

b) 0.10 M

in ethanol

CH 3OH

d) 0.10 M

in benzene

CH 3OH

in carbon tetrachloride

A solution is prepared containing a 2:1 mol of ratio of dibromo ethane (

dibromo propane

C2 H 4 Br2

) and

C3 H 6 Br2

(
) what is the total vapour pressure over the solution assuming ideal behavior?
Vapour pressure
(mm Hg)
C2 H 4 Br2

173

C3 H 6 Br2

13.

127
a)300 mm Hg
b)158 mm Hg
c) 150 mm Hg
A solute A undergoes association in a medium as
nA

An

The degree of association is

i 1

14.

' '

, then vant Hoff factor may be given as:

1

i 1
n

K 3 PO4

BaCl2

a)
b)
c)
d) i=1
What is the correct sequence of osmotic pressure of 0.01 M aqueous solution of ?
(1)
a)

15.

d) 142 mm Hg

Al2 SO4 3

4 3 2 1

The density of

2)
b)

1 2 3 4

NH 4OH

3)
c)

4) Urea

1 2 3 4

d)

2 4 1 3

solution is found to be 0.6 g/mL. It contains 35% by mass of

NH 4OH

16.

. The normality of the solution is:

a)4.8N
b) 10N
c) 0.5N
d) 6.0 N
A liquid system containing two immiscible liquids, water and n- butyl bromide distills
900 C

17.

at
. Their vapour pressures at this temperature are in the ratio of 5:1 respectively.
The ratio of their masses distilled is:
a) 1:1
b) 1:7.5
c) 1.52:2
d) 1:1.52
The mass of glucose that should be dissolved in 100 g of water in order to produce
same lowering of vapour pressure as is produced by dissolving 1 g of urea (mol. Mass
=60) in 50 g of water is:
a) 1g
b) 2 g
c) 6 g
d) 12 g

Brilliant IIT/ Medical Academy, Shalivahananagar, Dilsukhnagar, Hyderabad-36,

Ph.No: 6550 7778.

18.

A sample of milk is found to contain 4% of butter fat by volume. The density of butter
fat is 875 kg
a)160 kg

m 3

and that of milk is 1035 kg

b) 275 kg

m 3

. The density of skimmed milk is:

c) 1000 kg

m 3

d) 1041.6 kg

m 3

19.

20.

25 C

The vapour pressure of pure benzene at

is 640 mm Hg and that of solution of
solute A is 630 mm Hg. The molality of solution is:
a) 0.2m
b) 0.4m
c) 0.5m
d) 0.1 m
Insulin
4.110

dissolved in a medium shows osmotic pressure

6 106

3 106

1.86 K kg mol-1

separate out at
?
a) 42 mg
b) 42 g
c) 38. 71 g
d) 38.71 mg
Which of the following graphs represent the behavior of ideal binary liquid mixture?
Ptotal

against

PTotal

yA

is linear

yB

KNO3

and 0.2 M

FeCl3

is non- linear

yB

Ba NO3 2

K 4 Fe CN 6

b) 0.1 M
d) 0.1 M

Al2 SO4 3

Ca NO3 2

and 0.1 M
and 0.1 M

Na2 SO4
Ba NO3 2

on reaction with
in aqueous solution gives blue colour. These are
separated by a semipermeable membrane AB as shown. Due to osomosis there is:

a)blue colour formation in side X

b) blue colour formation in side Y
c) blue colour formation in both of the sides X and Y
d) no blue colour formation
Which of the following solutions has maximum freezing point depression at equimolal
concentration ?
a)

26.

against

yB

c) Plot of
against
is linear
d) Plot of
against
is linear
In which of the following solution the depression in freezing point is lowest?

c) 0.1 M

25.

b)Plot of 1/

PTotal

PTotal

a) 0.2 M urea and 0.2 M glucose

24.

6 103

a)
b)
c)
d)
50 g of antifreeze (ethylene glycol) is added to 200 g water. What amount of ice will

a) Plot of 1/
23.

against C is

. Molecular mass of insulin is:

3

9.30 C

22.

3 10

21.

C6 H10O5 n

Co H 2O 6 Cl3

Co H 2O 4 Cl2 Cl .2 H 2O

b)

Co H 2O 5 Cl Cl2 .H 2O
Co H 2O 3 Cl3 .3H 2O

c)
d)
Mixture of volatile components A and B has total vapour pressure (in torr):
Brilliant IIT/ Medical Academy, Shalivahananagar, Dilsukhnagar, Hyderabad-36,
Ph.No: 6550 7778.

XA

P= 254- 119

PA0

XA

27.
28.

29.

Where ,
is mole fraction of A in mixture . Hence ,
and
are (in torr):
a) 254.119
b) 119,254
c) 135,254
d)154,119
If mole fraction of a solvent in a solution decreases, then:
a)vapour pressure of solution increases
b) boiling point decreases
c) osmotic pressure increases
d) feeing point of solution increases
Osmotic pressure of 40% (W/V) urea solution is 1.64 atm and that of 3.42 % (W/V)
cane sugar is 2.46 atm. When equal volumes of the above two solutions are mixed, the
osmatic pressure of resulting solution is:
a)1.64 atm
b) 2.46 atm
c) 4.10 atm
d) 2.05 atm
1
yA

The plot of
0
A
0
B

a)

and

1
xA

against

is linear with slope and intercept respectively:

P P
PB0
0
A

P
P

0
B

b)

P P
PA0

0
B
0
A

0
A

P
P

30.

0
B

PA0
PB0

and

PB0 PA0
PB0

PB0 PA0
PB0

0
B
0
A

P
P

c)
and
d)
and
A solution containing 4 g of polyvinyl chloride in 1 litre of dioxane was found to
have an osmaotic pressure of
3 10

31.

PB0

1.6 10

6 104

atm at 300K. The molecular mass of polymer is:

5 104

6.4 102

a)
b)
c)
d)
Three solutions of HCl having normality 12N, 6N and 2N are mixed to obtain a
solution of 4 N normality. Which among the following volume ratio is correct for the
above three components?
a)1:1:5
b) 1:2:6
c) 2:1:9
d) 1:2:4
H 2O2

32.

6.8 g
is dissolved in 224 mL solution. This solution will be labeled as:
a) 0.224 V
b) 20 V
c) 5 V
d) 10 V

33.

A solution weighing
solute is c g, will be:
a)

34.

c 1000

b a c

Two solutions of

b)

g has molality b. The molecular mass of solute if the mass of

b 1000

a a b

H 2 SO4

c)

of molarities

from a solution of moalrity

M2

M1

b 1000

c a c

d)

c 1000

a b a

and y are mixed in the ratio of

. If they are mixed in the ratio of

a solution of molarity
. Given:
a)2:1
b) 4:1

V1 / V2

x
1
y

c) 1:2

and

V2

V1

mL:

mL:

V1mL

V2

mL to

, they form

M1 5

M2 4

, then x:y is
d) 3:1

Brilliant IIT/ Medical Academy, Shalivahananagar, Dilsukhnagar, Hyderabad-36,

Ph.No: 6550 7778.

35.

If

PA

is the vapour pressure of a pure liquid A and the mole fraction of A in the mixture
x

of two liquids A and B is , the partial vapour present of A is :

1 x PA

36.

37.

x
P
1 x A

xPA

1 x
PA
x

a)
b)
c)
d)
Difference between diffusion and osmosis is:
a)a semipermeable membrane is required for osmosis diffusion requires no
semipermeable membrane
b)in osmosis, movement of molecules is in one direction whereas in diffusion, the
movement is in both sides
c)in osmosis only the solvent moves while in diffusion solute and solvent both move
d) all of the above
PdCl4 .6 H 2O

Compound
is hydrated complex; 1 molal aqueous solution of it has
freezing point 269.28 K. Assuming 100% ionization of complex, calculate the molecular
kf

formula of the complex: (

a)

38.

39.

Pd H 2O 6 Cl4

b)

for water=1.86 K kg

Pd H 2O 4 Cl2 Cl2 .2H 2O

Pd H 2O 3 Cl3 Cl.3H 2O

c)
d)
pH of a 0.1 M monobasic acid is measured to be 2 its osmotic pressure at given
temperature T k is :
a) 0.1 RT
b) 0.11 RT
c) 1.1 RT
d) 0.01 RT
A compound

MX 2

has observed and normal molar masses 65.6 and 164 respectively.
MX 2

0
A

41.

Pd H 2O 2 Cl4 .4 H 2O

Calculate the apparent degree of ionization of

a) 75%
b) 85%
c) 65%
40.

mol 1

.
d) 25%

150 torr

0
B

240 torr

Total vapour pressure of mixture of 1 mol A

and 2 mol B
is
200 torr. In this case:
a) there is positive deviation from Raoults law
b) There is negative deviation from Raoults law
c)There is no deviation from Raoults law
d) Molecular masses of A and B are also required for calculating the deviation.
A solution is prepared by dissolving a 2.5 g sample of an unknown compound in 34 g
C6 H 6

1.380 C

of benzene,
,boils at
higher than pure benzene. Which expression gives the
molar mass of the unknown compound?
Kb

Compound
C6 H 6
2.53

a)

2.530 Cm 1
2.50
1.38

1.38

b)

34
2.50
2.53

2.5 103

c)

2.53 1

34 1.38

2.50 103

d)

Brilliant IIT/ Medical Academy, Shalivahananagar, Dilsukhnagar, Hyderabad-36,

Ph.No: 6550 7778.

1.38
2.53
34
5

42.

43.

44.

45.

46.

If liquids A and B form an ideal solution:

a) The free energy of mixing is zero
b) the free energy as well as entropy of mixing are zero
c) enthalpy of mixing is zero d) the entropy of mixing is zero
Solute A is ternary electrolyte and solute B is a non- electrolyte. If 0.1 M solution of B
produces an osmotic pressure of 2P at temperature 3TK, then 0.05 M solution of A at T
K will produces an osmotic pressure of :
a) P
b) 1.5P
c) 2P
d) 10 P
Which concentrations can be calculated if the mole fraction and density of an aqueous
solutio0n of HCl are known ?
1. Molality
2. Molarity
3. Percentage by mass
a) 1 only
b) 3 only
c) 1 and 2 only
d) 1,2 and 3
A solute forms a pentamer when dissolved in a solvent. The vant Hoff factor i for the
solute will be:
a) 0.2
b) 0.8
c) 0.5
d) 0.6
When 1.2 g of sulphur is melted with 15 g of naphthalene, the solution freezes at
. What is the molar of this form of sulphur?
Data for naphthalene:
800 C

Melting point (m.pt)

Kf

Freezing point depression constant

mol

47.

mol

m 1

6.80 K

mol

mol 1

a) 180 g
b) 194 g
c) 260 g
d) 450 g
What is the molarity of HCl in a solution prepared by dissolving 5.5 g HCl in 200 g
ethanol if the density of the solution is 0.79 g

mL1

6 10 M

48.

77.20 C

1.7M

a) 21 M
b) 0.93 M
c)
d)
e)0.58 M
Which statement about the composition of vapour over an ideal 1:1 moalr mixture of
benzene and toluene is correct? Assume the temperature is constant at

25 C

250 C

49.

Vapour pressure data

:
Benzene
75 mm Hg
Toluene
22 mm Hg
a) The vapour will contain higher percentage of benzene
b)The vapour will contain higher percentage of toluene
c)The vapour will contain equal amount of benzene and toluene
d)Not enough information is given to make a prediction
A solution containing 0.1 g of non-volatile organic substance P(molecular mass 100)
0.20 C

in 100 g of benzene raises the boiling point of benzene by

,while a solution
containing 0.1 g of another non-volatile substance Q in the same amount of benzene
raises the boiling point of benzene by
and Q?
a)1:2
b) 2:1
c) 1:4

0.40 C

. What is the ratio if molecular masses of P

d) 4:1

Brilliant IIT/ Medical Academy, Shalivahananagar, Dilsukhnagar, Hyderabad-36,

Ph.No: 6550 7778.

50.

The vapour pressure of water at T(K) is 20 mm Hg. The following solutions are
prepared at T(K):
I. 6 g of urea (mol. Wt= 60) is dissolved in 178.2 g of water.
II. 0.01 mol of glucose is dissolved in 179.82 g of water.
Na2CO3

51.

III. 5.3 g of
(mol.wt=106) is dissolved in 179.1 g of water.
Identify the correct order in which the vapour pressures of solutions increases:
a)III,I,II
b) II,III,I
c) I,II,III
d) I,III,II
Consider 0.1 M solution of two solutes X and Y. The solute X behaves as uni-univalent
electrolyte while the solute Y dimerises solution. Which of the following statements
are corrects regarding these solutions?
1.The boiling point of solution of X will be higher than that of Y
2.The osmotic pressure of solution of Y will be lower than that of X
3.The freezing point of the solution of X will be lower than that of Y
4. The relative lowering of vapour pressure of both the solutions will be the same.
Select the correct answer the from the codes given below:
a)1,2,3
b)2,3,4
c)1,2,4
d) 1,3,4

52.

The ratio of the value of any colligative property for

Fe4 Fe CN 6

a) 0.62
53.

c) 1.4

d) 1.2

140 F

Kf

mol 1

is(
for water= 1 .86 K kg
b) 247.31g
c)236.11 g

)
d) 281.01g

The freezing point of a 0.08 molal aqueous solution of

NaHSO4

Kf

dissociation constant for the following reaction is: (

HSO

55.

to that of

The weight of ethyl alcohol which must be added to 1.0 L of water so that the solution
will freeze at
a) 263.11 g

54.

solution is nearly:
b) 0.71

K 4 Fe CN 6

for

H 2O

is -0.3720C . The
=1.86 K kg

mol 1

2
4

So

a)0.04
b) 0.02
c) 0.01
d) 0.2
What weight of solute (molecular weight=60) is required to dissolve in 180 g of water
4
th
5

to reduce the vapour pressure to

of pure water?
a) 48g
b) 96g
c) 150g
d) 175 g
56.

Relative lowering in vapour pressure of a solution containing 1 mole

is:
a)

K 2 SO4
1
55

K 2 SO4

in 54 g

is 100 % ionized.
b)

3
55

c)

3
4

d)

1
2

Brilliant IIT/ Medical Academy, Shalivahananagar, Dilsukhnagar, Hyderabad-36,

Ph.No: 6550 7778.

H 2O

57.

At

100 C

, the osmotic pressure of urea solution is 500 mm. The solution is diluted and

the temperature is raised to

Vi

59.

. The osomotic pressure of dilute solution is 105.3 mm

Vf

and

V f 5Vi

58.

250 C

are initial and final volumes of solution)

Vi V f

V f 4Vi

V f 6Vi

a)
b)
c)
d)
Consider the following aqueous solutions and assume 100% ionization in electrolytes
Al2 SO4 3

CaCl2

I. 0.1 m ureaII. 0.04 m

III.0.05 m
IV. 0.005 m NaCl
0.1M NaCl and 0.05 M BaCl2 solutions are separated by a semi- permeable membrane
in a container. For this system, choose the correct answer.
a)There is no movement of any solution across the membrane.
b)Water flows from

BaCl2

solution towards NaCl solution.

c) Water flows from NaCl solution towards

BaCl2

solution.
BaCl2

60.

61.

d) Osmotic pressure of 0.1 M NaCl is lower than the osmotic pressure of 0.05 M
(assume complete dissociation)
Which values can be obtained from the information represented by the vapour pressure
curve of a liquid?
A. Normal boiling point
B.Normal freezing point
C. Enthalpy of vaporization
a)A only
b) A and B only
C) A and C only
D) A, B and C
X is non- volatile solute and Y is a volatile solvent. The following vapour pressures
are observed by dissolving X in Y.
X
Y
( mol

L1

( mm of Hg)
P1

0.1

P2

0.25

P3

0.01
The correct order of vapour pressures is:
P1 P2 P3

62.

P3 P2 P1

P3 P1 P2

P2 P1 P3

a)
b)
c)
d)
A solution at 298 K is separated from the pure solvent by a semi-permeable membrane.
Kf

Difference in the height of the solution and the solvent is 0.9 m . If

point of the solvent are 30 K kg

mol

and freezing

and 250. 3 K respectively, the temperature at

ML1

63.

which solution freezes is (Assume, the density of solution to be 1 g

)
a) 250. 10K
b) 250. 25K
c) 250. 20K
d) 250.05 K
An aqueous solution is 1.00 molal in KI. Which changes will cause the vapour pressure
of the solution to increase?
Brilliant IIT/ Medical Academy, Shalivahananagar, Dilsukhnagar, Hyderabad-36,
Ph.No: 6550 7778.

Na2 SO4

64.

a) Addition of NaCl
b) Addition of
c) addition of 1.00 molal KI
d) addition of water
The solubility of a gas in water at 300 K under a pressure of 100 atmospheres is 4x103
kg L-1. Therefore the mass of the gas in kg dissolved 250ml of water under a pressure
of 250 atm and 300 K is:
a)

2.5 10 3

b)

2.0 103

c)

1.25 103

d)

5.0 103

65.

Pure benzene freezes at

5.3 C

. A solution of 0.223 g of phenyl acetic acid

C6 H 5CH 2COOH

66.

5.12 K kg mol-1

4.47 0 C

in 4.4 g of benzene
freezes at
. From this
observation, one can conclude that:
a) Phenyl acetic acid exists as such in benzene
b) phenyl acetic acid undergoes partial ionization in benzene
c) phenyl acetic acid undergoes complete ionization in benzene
d) phenyl acetic dimerizes in benzene
On mixing heptane and octane form an ideal solution. At 373 K , the vapour pressures
of the two liquid components (heptanes and octane) are 105 Kpa and 45Kpa
respectively. Vapour pressure of the solution obtained by mixing 25 g of heptanes and
35 g of octane will be:
mol 1

67.

mol 1

(Molar mass of heptanes=100 g

; Molar mass of octane=114 g
)
a)96.2 Kpa
b) 144.5 Kpa
c)72Kpa
d)36.1Kpa
If sodium sulphate is considered to be completely dissociated into captions and anions
T f

in aqueous solution, the change in freezing point of water

, when 0.01 mol of

Kf

sodium sulphate is dissolved in 1 kg of water is :(

a) 0.0744 K b) 0.0186 K c) 0.0372 K d) 0.0558 K
68.

A solution of

CaCl2

69.

was prepared by dissolving 0.0112 g in 1 kg of distilled water

(molar mass of Ca= 41 g

mol

=1.86 K kg

mol 1

mol 1

and Cl= 35.5 g

mol 1

). The freezing point constant of

water is 2 K kg
. The depression in the freezing point of the solution is :
a)0.0002
b) 0.002
c) 0.003
d) 0.0006
Ethylene glycol is used as an antifreeze in a cold climate. Mass of ethylene glycol
which should be added to 4 kg of water to prevent it from freezing at Kf

mol

60 C

(
for water= 1.86 K kg
and Moalr mass of ethylene glycol=62 g
a) 304.60 g
b) 800.00 g
c) 204.30 g
d) 400. 00 g
70.

A 5.2 molal aqueous solution of

alcohol in the solution ?
a) 0.050
b) 0.100

CH 3OH

will be:

mol 1

is supplied. What is the mole fraction of methyl

c) 0.190

d) 0.086

Brilliant IIT/ Medical Academy, Shalivahananagar, Dilsukhnagar, Hyderabad-36,

Ph.No: 6550 7778.

71.

The freezing point depression constant for water is

dissolved in 45 g

H 2O

1.860 Cm 1

. If 5 g

3.82 C

Na2 SO4

is

, the freezing point is changed by

. Calculate the vant

Na2 SO4

72.
73.

Hoff factor for

:
a) 0.381
b) 2.05
c) 2.63
d) 3.11
When a solution containing non-volatile solute is diluted with water:
a) Its osmotic pressures increases
b) its boiling point increases
c) its freezing point increases
d) its vapour pressure increases
The density of a solution prepared by dissolving 120 g of urea (molar mass= 60) in
1000g of water is 1.15 g/mL. The molarity of this solution is:
a)0.50M
b) 1.78 M
c) 1.02 M
d) 2.05 M
Kf

74.

for water is 1.86 K kg

mol 1

many grams of ethylene glycol

. If your automobile radiator holds 1 kg of water, how

C2 H 6O2

must you add to get the freezing point of the

2.8 C
0

solution lowered to :
a) 72 g
b) 93 g
75.

c) 39g

d) 27 g

CHCl3

CH 2Cl2

250 C

Vapour pressure of chloroform

and dichloroethane
at
are 200
mm Hg and 41.5 mm Hg respectively. Vapour pressure of solution obtained by mixing
25.5 g of

CHCl3

and 40 g of

CH 2Cl2

at the same temperature will be:

CHCl3

CH 2Cl2

(Molecular mass of
= 119.5 u and molecular mass of
= 85 u)
a) 173.9 mm Hg b) 615.0 mm Hg c) 347. 9 mm Hg d) 90.92 mm Hg
Key
1)d
13)c
25)a
37)c
49)b
61)d
73)d

2)d
14)b
26)c
38)b
50)a
62)c
74)b

3)c
15)d
27)c
39)a
51)a
63)d
75)d

4)d
16)d
28)d
40)b
52)b
64)a

5)d
17)c
29)c
41)c
53)b
65)d

6)b
18)d
30)b
42)c
54)a
66)c

7)c
19)a
31)b
43)a
55)c
67)d

8)b
20)b
32)d
44)d
56)c
68)d

9)b
21)c
33)a
45)a
57)a
69)b

10)a
22)a
34)a
46)b
58)b
70)d

11)d
23)a
35)b
47)e
59)b
71)c

12)b
24)d
36)d
48)a
60)c
72)d

Brilliant IIT/ Medical Academy, Shalivahananagar, Dilsukhnagar, Hyderabad-36,

Ph.No: 6550 7778.

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