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Mark Riley
Aim To determine the redox reaction that has taken place after mixing some
common oxidants and reactants.
Procedure This experiment has been split into 7 parts. A separate procedure for
each test is given.
Also- See page 6 of the Practical Activities handbook
Equipment Safety glasses, test tube rack, 7 test tubes, reagents in dropping bottle
5 drops of 𝐻2 𝑂2 , 5 drops of 𝐻2 𝑆𝑂4 and 10 drops of 𝐹𝑒 𝑆𝑂4 were added to a test tube. 1 drop of
KSCN was added and as a result the solution turned blood red indicating the presence of 𝐹𝑒 3+.
𝐻2 𝑂2 has a higher oxidising strength (oxidant) and 𝐹𝑒 2+ has a higher reducing strength
(reductant) ∴ the 𝐹𝑒 2+ was oxidized and 𝐻2 𝑂2 was reduced according to the following equation.
𝐹𝑒 2+ → 𝐹𝑒 3+ + 𝑒 ×2 − 0.77V
𝐻2 𝑂2 + 2𝐻 + + 2𝑒 → 2𝐻2 𝑂 + 1.78V
𝐻2 𝑂2 has a higher oxidising strength (oxidant) and 𝐼 − has a higher reducing strength (reductant) ∴
the 𝐼− was oxidized and 𝐻2 𝑂2 was reduced according to the following equation.
2𝐼− → 𝐼2 + 2𝑒 − 0.54V
𝐻2 𝑂2 + 2𝐻 + + 2𝑒 → 2𝐻2 𝑂 + 1.78V
3 drops of 𝐾𝑀𝑛𝑂4 , 6 drops of 𝐻2 𝑆𝑂4 and 20 drops of 𝐹𝑒𝑆𝑂4 were added to a test tube. The
solution was initially purple but then turned colourless indicating that the 𝑀𝑛𝑂4− had been
reduced to 𝑀𝑛2+. 1 drop of KSCN was added and as a result the solution turned blood red
indicating the presence of 𝐹𝑒 3+.
𝑀𝑛𝑂4− has a higher oxidising strength (oxidant) and 𝐹𝑒 2+ has a higher reducing strength
(reductant) ∴ the 𝐹𝑒 2+ is oxidized and 𝑀𝑛𝑂4− is reduced according to the following equation.
𝐹𝑒 2+ → 𝐹𝑒 3+ + 𝑒 ×5 − 0.77V
3 drops of 𝐾𝑀𝑛𝑂4 , 6 drops of 𝐻2 𝑆𝑂4 and 20 drops of 𝐾𝐼(white crystalline solid, colourless in
solution) were added to a test tube. The solution was initially purple but then turned colourless
indicating that the 𝑀𝑛𝑂4− had been reduced to 𝑀𝑛2+. 3 drops of starch were added turning the
solution blue-black indicating the presence of iodine 𝐼2 . A precipitate was also present.
𝑀𝑛𝑂4− has a higher oxidising strength (oxidant) and 2𝐼− has a higher reducing strength (reductant)
∴ the 2𝐼 − is oxidized and 𝑀𝑛𝑂4− is reduced according to the following equation.
2𝐼− → 𝐼2 + 2𝑒 ×5 − 0.54V
2 drops of 𝐾2 𝐶𝑟2 𝑂7 , 6 drops of 𝐻2 𝑆𝑂4 and 15 drops of 𝐾𝐼 (white crystalline solid, colourless in
solution) were added to a test tube. The orange solution turned blue/green indicating that the
𝐶𝑟2 𝑂72− had been reduced to 𝐶𝑟 3+. 3 drops of starch were added turning the solution blue-black
indicating the presence of iodine 𝐼2 .
𝐶𝑟2 𝑂72− has a higher oxidising strength (oxidant) and 2𝐼− has a higher reducing strength
(reductant) ∴ the 2𝐼− is oxidized and 𝐶𝑟2 𝑂72− is reduced according to the following equation.
2𝐼− → 𝐼2 + 2𝑒 ×3 − 0.54V
5 drops of 𝐹𝑒𝐶𝑙3 , 5 drops of 𝐻2 𝑆𝑂4 and 5 drops of 𝐻2 𝑂2 were added to a test tube. 1 drop of
KSCN was added, the colour of the solution was unchanged indicating that no 𝐹𝑒 3+ was present.
The solution fizzled indicating a the release of oxygen gas 𝑂2 .
𝐹𝑒 3+ has a higher oxidising strength (oxidant) and 𝐻2 𝑂2 has a higher reducing strength
(reductant) ∴ the 𝐻2 𝑂2 is oxidized and 𝐹𝑒 3+ is reduced according to the following equation.
𝐹𝑒 3+ + 𝑒 → 𝐹𝑒 2+ ×2 + 0.77V
𝐻2 𝑂2 → 𝑂2 + 2𝐻 + + 2𝑒 − 0.70V
3 drops of 𝐾𝑀𝑛𝑂4 , 6 drops of H2 𝑆𝑂4 and 10 drops of 𝐻2 𝑂2 were added to a test tube. The
solution fizzled indicating the release of oxygen gas 𝑂2 .
𝑀𝑛𝑂4− has a higher oxidising strength (oxidant) and 𝐻2 𝑂2 has a higher reducing strength
(reductant) ∴ the 𝐻2 𝑂2 is oxidized and 𝑀𝑛𝑂4−is reduced according to the following equation.
𝐻2 𝑂2 → 𝑂2 + 2𝐻 + + 2𝑒 ×5 − 0.70V
Conclusion
Redox reactions were balanced in the form of chemical equations by arranging the quantities of
the substances involved so that the number of electrons lost by one substance is equaled by the
number gained by another substance. In redox reactions, the substance losing electrons
(undergoing oxidation) is a good electron donor, or reductant because lost electrons are given to
and reduce the other substance. The other substance that gained electrons (undergoing
reduction) is an electron acceptor, or oxidant. Hydrogen peroxide was capable of acting as a
reductant as well as an oxidant.