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I.
INTRODUCTION
V. PROCEDURE
1. Prepare the fuel sample by placing it in a crucible and
weighing it on a balance. Ensure that the sample of the fuel
will not overflow the crucible. Note down the weight of the
fuel sample and place the crucible containing the fuel gently
in the loop holder.
2. The bomb head has been pre-attached with 10.5 cm long
fuse mire between the two electrodes. Bend the use wire
down just above the liquid fuel sample. The wire must not
make contact with the fuel crucible. To attach the fuse to
quick-grip electrodes, insert the ends of the wire into the
eyelet at the end of each stem and push the cap downward to
pinch the wire into place. No further threading or twisting is
required.
Fig. 2 Actual Bomb Calorimeter Set Up
Figure 1
8. Check the bomb for leaks before firing. If any gas leakage
was observed, no matter how slight, do not fire the bomb.
Instead remove it from the water bath; release the pressure
and eliminate the leak before proceeding with combustion
test.
9. Fill the jacket with water.
10. Put the cover on the jacket. Turn the stirrer by hand to be
sure that it runs freely and start the motor. Install the
Beckman thermometer; this thermometer should he
immersed in eater and not close to the bomb.
11. Let the stirrer run for at least 5 minutes to reach
equilibrium before starting a measured run.
12. The scanning of the temperature data is pre-set to be
done once a minute. At the start of the fifth minute, fire the
charge by pressing the firing button on the control unit,
keeping the circuit closed for about 5 seconds.
13. The vessel temperature will start to rise within 20-30
seconds after firing. This rise will be rapid during the first
few minutes; then it will become slower as the temperature
approaches a stable maximum as shown by the typical rise
curve. Accurate time and temperature observations must be
recorded to identify certain points needed to calculate the
calorific value of the sample.
14. Usually the temperature will reach a maximum then it
will drop very slowly. But this is not always true since a low
starting temperature may result in a slow continuous rise
without reaching a maximum. As stated, the difference
between successive readings must be noted and the readings
continued until the rate of the temperature change becomes
constant over a period of 5 minutes.
15. After the last temperature reading, stop the stirrer. Let
the bomb stand in the calorimeter vessel for at least 3
minutes. Then remove the jacket cover and extract the bomb
calorimeter. Wipe the bomb with a clean cloth.
Compound
Trial
Weight
of
Sample (g)
Max. Temp. (C)
Time at Max.
(min)
Equilibrium
17. Remove all unburned pieces of fuse wire from the bomb
electrodes.
Diesel
1
2
2.20
33.4609375
35.2578125
10.275
8.478
32.9531250
34.6250000
40.000
40.000
0.121632795
5.0315
15,517.79964
Calorific
(cal/g)
7,053.545291
Value
Compound
Trial
Weight
of
Sample (g)
Max. Temp.
(C)
Time at Max.
(min)
Equilibrium
Temp. (C)
Time
at
Equilibrium
(min)
Ave.
Radiation
Correction
Ave. Temp.
rise (C)
21,683.42176
7670.117354
5.1531328
Heat Absorbed
by Water (cal)
Compound
Trial
Weight
of
Sample (g)
Max. Temp.
(C)
Time at Max.
(min)
Equilibrium
Temp. (C)
Time
at
Equilibrium
(min)
Ave.
Radiation
Correction
Ave. Temp.
rise (C)
Corrected
Temp. Rise
(C)
Heat
Absorbed by
Water (cal)
Calorific
Value (cal/g)
7.2006054
Corrected
Temp. Rise
(C)
Heat
Absorbed by
Water (cal)
Calorific
Value (cal/g)
34.6484375
8.783
33.8984375
40.000
Kerosene
2
2.597
36.867187
5
30.140
35.507812
5
7.800
36.710937
5
42.500
34.546875
0
40.000
9201.159175
35.4453125
40.000
Diesel
10,874.76
35.1384
Kerosene
7,053.54529
1
9201.159175
8365.2008
10.0000
Biodiesel
7670.117354
8786.8068
8
12.7081
Where:
TM = maximum temperature
tM = time at maximum temperature
TE = equilibrium temperature
tE = time at equilibrium temperature
23,895.41038
11.080
Percentage
Error (%)
Slope Calculation:
TM = 33.4609375 OC
tM = 10.275 min
TE = 32.9531250 OC
tE = 40.000 min
7.93516
36.1171875
True
Value
(cal/g)
7.7473958
Biodiesel
2
2.827
Calorific
Value (cal/g)
VIII. CALCULATIONS
0.1877717
Sample
Slope=
T M T E
t E t M
Slope=
33.460937532.9531250
4010.275
33.914062
5
13.563
36.390625
0
7.950
33.578125
0
40.000
35.953125
0
25.000
Slope = 0.0170837
Radiation Correction Calculation:
n = time difference between maximum temperature and
ignition
v = change in change in temperature at the
first minute mark after the attainment of
maximum temperature and the change in
temperature at the fourth minute mark after the
first minute mark, divided by four
v = change in change in temperature before the
ignition and the change in temperature at the
beginning, divided by four
0.1597254
7.04088
0.0781250.0546875
=0.005859375
4
' v + v '
RadiationCorrection=nv +
2
v=
Radiation Correction
7.2750.01171875 +
28
28
28
28
=
=
=
=
0.570312
5.257812
5.242187
5.171875
0.005859375+0.01171875
2
n = 8.478 0.100 = 8.378 min
5.24218755.1718750
=0.017578125
4
0.57031250.5625000
v=
=0.001953125
4
' v + v '
RadiationCorrection=nv +
2
v'=
Radiation Correction
8.3780.017578125+
Slope Calculation:
TM = 35.2578125 OC
tM = 8.478 min
TE = 34.6250000 OC
tE = 40.000 min
0.00195315+0.0175781
2
Where:
TM = maximum temperature
tM = time at maximum temperature
TE = equilibrium temperature
tE = time at equilibrium temperature
Slope=
28.5703125
35.2578125
35.2421875
35.1718750
0.100 (ignition)
8.478 (max)
9.478 (minute after max)
13.478 (fourth minute mark
after the minute after max)
T M T E
t E t M
0 . 08818359+0 . 1550820
2
= 0.121632795
35.257812534.6250000
Slope=
408.478
Slope = 0.0200752
5 . 375+4 .688
2
= 5.0315 OC
2 . 14+2 . 25
2
= 15,517.79964 cal
n = 8.783 3.000 = 5.783 min
2 . 20
7.64843757.5625000
=0.01171875
4
0.46093750.4609375
v=
=0.0000000
4
'
v=
= 7,053.545291 cal/g
RadiationCorrection=nv ' +
Calculations for Kerosene
TRIAL 1:
Assumption: The end of post period is at 40-minute mark
Ignition: 3-minute mark
Radiation Correction
5.7830.01171875 +
Slope Calculation:
TM = 34.6484375 OC
tM = 8.783 min
TE = 33.8984375 OC
tE = 40.000 min
0+ 0.01171875
2
Where:
TM = maximum temperature
tM = time at maximum temperature
TE = equilibrium temperature
tE = time at equilibrium temperature
TRIAL 2:
Assumption: The end of post period is at 42.5-minute mark
Ignition: 0.1-minute mark (6 seconds after running)
Slope Calculation:
TM = 36.8671875 OC
tM = 30.140 min
TE = 36.7109375 OC
tE = 42.500 min
T T E
Slope= M
t E t M
Slope=
v + v '
2
34.648437533.8984375
408.783
Where:
TM = maximum temperature
tM = time at maximum temperature
TE = equilibrium temperature
tE = time at equilibrium temperature
Slope = 0.0240254
Radiation Correction Calculation:
n = time difference between maximum temperature and
ignition
v = change in change in temperature at the
first minute mark after the attainment of
maximum temperature and the change in
temperature at the fourth minute mark after the
first minute mark, divided by four
v = change in change in temperature before the
ignition and the change in temperature at the
Slope=
T M T E
t E t M
Slope=
36.867187536.7109375
42.530.141
Slope = 0.0126426
Slope=
T M T E
t E t M
Slope=
35.507812534.5468750
407.8
Slope = 0.0298428
v=
=0.0097656
4
0.10156250.1015625
v=
=0.0000000
4
' v + v '
RadiationCorrection=nv +
2
Radiation Correction
30.040.0097656+
0.100 (ignition)
7.14 (max)
8.14 (minute after max)
12 (fourth minute mark after
the minute after max)
0+ 0.0097656
2
27.2031250
35.5078125
35.5000000
35.3984375
27
27
27
27
8.50000008.3984375
=0.0253906
4
0.20312500.2031250
v=
=0.0000000
4
' v + v '
RadiationCorrection=nv +
2
v'=
Radiation Correction
TRIAL 3:
Assumption: The end of post period is at 40-minute mark
Ignition: 0.1-minute mark (6 seconds after running)
7.0400.0253906+
0+0.0253906
2
Slope Calculation:
TM = 35.5078125 OC
tM = 7.800 min
TE = 34.5468750 OC
tE = 40.000 min
Where:
TM = maximum temperature
tM = time at maximum temperature
=
=
=
=
0.203125
8.507812
8.500000
8.398437
= 0.1877718
Average Rise in Temperature
= 7.7473958 OC
2 . 64+2 . 50+2. 65
3
= 2.597 g
Corrected Rise in Temperature
RadiationCorrection + RiseTemperature
0 .1877718+7 . 7473958
= 7.93516 OC
Heat Absorbed by Water
= 23,895.41038 cal
8.11718758.0234375
=0.0234375
4
0.39062500.3750000
v=
=0.0039063
4
v + v '
RadiationCorrection=nv ' +
2
v'=
2 . 597
Radiation Correction
= 9201.159175 cal/g
8.0800.0234375+
Calculations for Biodiesel
TRIAL 1:
Assumption: The end of post period is at 40-minute mark
Ignition: 3-minute mark
Slope Calculation:
TM = 36.1171875 OC
tM = 11.080 min
TE = 35.4453125 OC
tE = 40.000 min
TRIAL 2:
Assumption: The end of post period is at 40-minute mark
Ignition: 3-minute mark
Where:
TM = maximum temperature
tM = time at maximum temperature
TE = equilibrium temperature
tE = time at equilibrium temperature
Slope=
Slope=
0.0039063+0.0234375
2
Slope Calculation:
TM = 33.9140625 OC
tM = 13.563 min
TE = 33.5781250 OC
tE = 40.000 min
T M T E
t E t M
Where:
TM = maximum temperature
tM = time at maximum temperature
TE = equilibrium temperature
tE = time at equilibrium temperature
36.117187535.4453125
4011.080
Slope = 0.0232322
Slope=
T M T E
t E t M
Slope=
33.914062533.5781250
4013.563
TM = maximum temperature
tM = time at maximum temperature
TE = equilibrium temperature
tE = time at equilibrium temperature
Slope = 0.0127071
Radiation Correction Calculation:
n = time difference between maximum temperature and
ignition
v = change in change in temperature at the
first minute mark after the attainment of
maximum temperature and the change in
temperature at the fourth minute mark after the
first minute mark, divided by four
v = change in change in temperature before the
ignition and the change in temperature at the
beginning, divided by four
Slope=
T M T E
t E t M
Slope=
36.390625035.9531250
257.95
Slope = 0.0256598
5.90625005.8593750
=0.01171875
4
0.71875000.6250000
v=
=0.0234375
4
' v + v '
RadiationCorrection=nv +
2
v'=
0.100 (ignition)
7.95 (max)
8.95 (minute after max)
12.95 (fourth minute mark
after the minute after max)
28.8281250
36.3906250
36.3750000
36.2968750
28
28
28
28
=
=
=
=
Radiation Correction
TRIAL 3:
Assumption: The end of post period is at 25-minute mark
Ignition: 0.1-minute mark (6 seconds after running)
Radiation Correction
Slope Calculation:
TM = 36.3906250 OC
tM = 7.950 min
TE = 35.9531250 OC
tE = 25.000 min
7.8500.0195313+
0.0019531+0.0195313
2
Where:
0.828125
8.390625
8.375000
8.296875
experimental theoretical
l X 100
theoretical
%error=l
= 0.1597254
%error=l
7670.1173548786.80688
l X 100 =
8786.80688
12.7081 %
= 7.04088 OC
Average Weight of Diesel Fuel
2 . 85+2 .81+2 . 82
3
IX. CONCLUSION
In this experiment, we used Lab VIEW in conjunction with
a bomb calorimeter to determine the calorific value of
different types of Fuel. The experiments carried out were
quite successful, and yielded valid results. The final results
of the experiment are given as follows:
= 2.827 g
Corrected Rise in Temperature
RadiationCorrection + RiseTemperature
0 .1597254 +7 . 04088
= 7.2006054 OC
Heat Absorbed by Water
Sample
Calorific
Value (cal/g)
True
Value
(cal/g)
Percentage
Error (%)
Diesel
10,874.76
35.1384
Kerosene
7,053.54529
1
9201.159175
8365.2008
10.0000
Biodiesel
7670.117354
8786.8068
8
12.7081
= 21,683.42176 cal
:
Calorific Value of Diesel
2 . 827
= 7670.117354 cal/g
experimental theoretical
l X 100
theoretical
7053.54529110874.76
l X 100 =
10874.76
35.1384 %
% Error of KEROSENE (TRIAL 1)
%error=l
experimental theoretical
l X 100
theoretical
9201.1591758365.2008
l X 100 =
8365.2008
10.0000 %
% Error of BIODIESEL (TRIAL 1)
XI.
WASTE DISPOSAL
10
XII. APPENDIX
11
Eazyl D. Salazar
finished her elementary and secondary studies at
Holy Word Academy. She was awarded as the
class salutatorian and consistently part of the top
three (3rd honorable mention) students during her
elementary and high school years respectively.
Aside from her academic awards, she was active in
participating on extra-curricular activities resulting on becoming one of
the representatives of the said school for its music team, and the short story
writer for Junior Student Convention and National Student Convention of
School of Tomorrow Philippines. She had won several awards such as
consistent 6th place for her two short stories (in Filipino), and 2 nd and 3rd
place for the Trio and Duet Female respectively. She started her tertiary
education at Adamson University under the program Chemical
Engineering from year 2010 to 2012. She then continued the said program
at Technological Institute of the Philippines after being in her previous
school for two years.
Chenny Ibaez Compuesto
I am Chenny Ibanez Compuesto, a Chemical
Engineering student. I was born on May 13, 1996
in Antipolo City. I didnt imagine that I would
take Chemical Engineering. I knew back then that
ENGINEERING isnt an easy way to be
successful. After all, my high-school crush, who
at first wanted to take this program but resorted
to BS Math in UP Diliman, warned me that it will be full of Math, and he is
right. But, because of a sudden turn of events, my dream to be a simple
chemical analyst was redirected into this new path: to be a chemical
engineer. (At least there are a few differences between a chemist and Ch.E.,
since both has board exams.) Now, I enjoy my studying here, although I
experience difficulty and pressure in keeping up with school work, extracurricular activities and varying attitudes of upperclassmen,
underclassmen and batch mates. I am currently involved as a committee
member in one of the organizations in my department, and I still compete in
the quiz bees here in TIP and even for the first time in the National Quiz
bee. I still have my aim to finish my undergraduate studies here, and soon
enough, be a topnotcher, if not, a Ch.E. board passer, but for now, Ill enjoy
every single moment that I have to make here, so that when time comes, Ill
never have any regrets.
12
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