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Exam3
Fall2006
(Closedbook,closednotes,threecribsheetsallowed))
1.Weconductafirstorderdecomposition A R S inanimperfectlymixedisothermalreactorwiththe
Ecurveshownbelow.
E(min1)
1
0.5
t(min)
TherateofreactionisgivenbyRA=kCA(mol/Lmin)withk=2min1.Whatisthemeanresidencetimein
thisreactor?
a)
Whatconversionwillbeachievedinthisreactor?Usethemodelthatpredictstheconversion
exactly.
ComparetheaboveconversiontotheonethatyoucouldobtaininaPFRandCSTRof
b)
thesamemeanresidencetimeastheabovereactor.
2.Anirreversible,exothermicreaction A P ispromotedbyanonporouscatalyst.Thereactionrateperunit
surfaceofthecatalystisgivenby
whereTs(oK)isthesurfacetemperatureandCAs(mol/m3)isthesurfaceconcentrationofA(i.egaseous
concentrationofAintheveryvicinityofthecatalystsurfaces).Theheatofreactionis HRA =5,000cal/mol.
Thecatalystmanufacturersendsussamplesoftheirnonporouscatalystforwhichtheyclaimtheobservedrate
ofreactionofalmost2.5(mol/m2s)atthebulktemperatureofTb=300KandbulkreactantconcentrationofCAb
=50(mol/m3).Attheirexperimentalconditionsthetransportcoefficientscanbeestimatedtobe:km=0.05
(m/s)andh=50(cal/m2sK).
a)Istheobservedrateofreactionclaimedbythecatalystmanufacturerpossible?Whatisattheirconditions
thecatalystsurfacetemperatureTsandreactantconcentrationCAs?Whatcontrolstherate:kineticsormass
transfer,orboth,andwhatisthemagnitudeofthefilmheattransferandmasstransfereffects?Whatisthe
effectivenessfactor ?
b)Wewanttoreproducethesefindingsandrun.thesametypeofexperimentalreactoratidenticalvelocity
conditionsandatidenticalbulktemperatureandconcentrationreportedaboveconditions.However,we
observeaverylowrateof0.040(mol/m2s).
Explainandtrytoquantifytheseobservations.Whatsurfacetemperaturesandconcentrationscorrespondtothe
rateobservedbyus?Whatarethemagnitudesofthefilmeffectsandwhatistheeffectivenessfactoratour
observedrate?Whatconclusionsdoyoureach?Canbothresultsberight?
3.Whatcanyoutellaboutthecontrollingresistance(film,diffusion,kinetic)andactivationenergyfora1st
ordercatalyticreactiononporouscatalystparticlesbasedonthedatabelowobtainedinastirredbasketreactor
thatexhibitsCSTRbehavior.Isothermalconditionsprevailinthereactorduringeachrun.
Cat. Mass
Cat. Diam.
RPM
Tb C
10
10
low
340
40
10
high
340
0.08
20
10
high
390
0.09
30
10
low
390
Run1
Flow Rate
m 3
Q
Feed Conc.
mol
CAo
m 3
Outlet Conc.
mol
CA
m 3
0.05
50
0.02
3
4
W g
d p cm
HOURSANDSECONDSANDMETERSANDCENTIMETERSETC.FIRSTNOTETHATYOUNEED
THERATEPERUNITVOLUMEOFCATALYSTPELLETNOTPERUNITMASS].
Yourgoalistofindthedominantresistance(film,pore,kinetic)andfullyexplainyouranswer.
a.
b.
c.
d.
Cantheabovelargecatalystpelletsbeconsideredinternallyisothermal?Whatisthemaximum
pellet?Isitimportant?
Whatcanwesayabouttheexternalmasstransfereffectsbasedontheresultsintheabovetable?Is
thatfindingconfirmbyyouranalysisofthefilmeffectbasedontheobservedrateandmasstransfer
coefficient.?
Whatcanwesayaboutthefilmheattransfereffects?Istheparticlesurfacetemperatureaboutthe
sameasinthebulk?Whatis Ts ?
Whatcanyousayaboutinternaldiffusioneffects?
e.
Basedonalloftheabovecanyouestimatetheactivationenergyforthisreaction?Howaboutthe
catalystparticleeffectivenessfactorvalueatthetwotemperatures?
4. SketchthecorrespondingxAvsTdiagramforthetwopackedbedreactorsoperatedadiabatically
foranexothermicreactionasperflowchartshownbelow.
A