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Sistema Isotrmico
Metil Acetato (1) - Metanol (2)
A12
ln 1 =
( 1+
60
T(K) =
333.15
A12 =
0.4262
A21 =
0.4394
x1 A12 2
)
x2 A21
( 1+
x2 A21 2
)
x1 A12
A1 2
1 = e
Parmetros de Van Laar:
A21
ln 2 =
( 1+
x1 A1 2
x 2 A2 1
A2 1
)2
2 = e
( 1+
x 2 A2 1
x1 A1 2
x1
0.001
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
0.999
x2
0.999
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.001
A12 =
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
A21 =
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
1 =
1.5301619555
1.4152490808
1.3179473171
1.2369562461
1.1702143547
1.1160821301
1.0732789072
1.0408353245
1.0180590646
1.0045123074
1.000000453
METIL ACETATO
VP_A=
-8.05406
VP_B=
2.56375
VP_C=
-5.12994
VP_D=
0.16125
Pc=
46.9
Tc=
506.8
T=
333.15
x=
0.34264009
DIAGONAL
ECUACION DE WAGNER
METANOL
VP_A=
-8.54796
VP_B=
0.76982
VP_C=
-3.1085
VP_D=
1.54481
Pc=
80.9
Tc=
512.6
T=
333.15
x=
0.350078034
Metil Aceta
1
0.9
0.8
0.7
0.6
Y1 0.5
0.4
0.3
0.2
0.1
0
0
0
0.2
0.4
0.6
0.8
1
0
0.2
0.4
0.6
0.8
1
0.6
Y1 0.5
0.4
0.3
0.2
0.1
0
0
co
anol (2)
A21
ln 2 =
( 1+
x2 A21 2
)
x1 A12
A2 1
=e
( 1+
x 2 A2 1
x1 A1 2
2 =
1.00000041
1.00416758
1.01687721
1.03861229
1.07011078
1.11240598
1.16688325
1.23535711
1.32017492
1.4243557
1.55037134
)2
Pvp1
1.1259659
1.1259659
1.1259659
1.1259659
1.1259659
1.1259659
1.1259659
1.1259659
1.1259659
1.1259659
1.1259659
Pvp2
0.846540765
0.846540765
0.846540765
0.846540765
0.846540765
0.846540765
0.846540765
0.846540765
0.846540765
0.846540765
0.846540765
P
0.84741748
0.92441413
0.98545515
1.03329051
1.07058402
1.09918372
1.12021097
1.1340956
1.14055621
1.13851946
1.1261529
y1
0.00203313
0.17238185
0.30117327
0.4043695
0.49230006
0.57163803
0.64727564
0.72336191
0.80402862
0.8940927
0.99883457
y2
0.99796687
0.82761815
0.69882673
0.5956305
0.50769994
0.42836197
0.35272436
0.27663809
0.19597138
0.1059073
0.00116543
y1+y2
1
1
1
1
1
1
1
1
1
1
1
1
9
8
7
6
5
4
3
2
1
0
1.2
1
0.8
VAN LAAR
DIAGONAL
P 0.6
0.4
0.2
-1.66533453693773E-016
6
5
4
3
2
1
0
VAN LAAR
DIAGONAL
P 0.6
0.4
0.2
-1.66533453693773E-016
Xvs P
Y vs P
Xvs P
Y vs P
FIQ-UNCP "Termodinmica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca
Sistema Isobrico
Metil Acetato (1) - Metanol (2)
A12
A21
ln 2 =
x1 A12 2
)
x2 A21
( 1+
x2 A21 2
)
x1 A12
A1 2
P (bar) =
1 = e
Parmetros de Van Laar:
A12 =
0.4262
A21 =
0.4394
( 1+
x1 A1 2
x 2 A2 1
A2 1
)2
2 = e
( 1+
x 2 A2
x1 A1 2
T
337.28919811
319.06087378
315.78861416
316.72617751
317.798954
318.89576444
320.08586279
321.31201156
322.62896764
324.06351782
325.63308599
x1
0.001
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
0.999
x2
0.999
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.001
A12 =
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
METIL AC
ECUACION DE WAGNER
METIL ACETATO
VP_A=
-8.05406
VP_B=
2.56375
VP_C=
-5.12994
VP_D=
0.16125
Pc=
46.9
Tc=
506.8
VP_A
VP_B
VP_C
METANOL
VP_A=
VP_B=
VP_C=
VP_D=
Pc=
Tc=
-8.54796
0.76982
-3.1085
1.54481
80.9
512.6
VP_D
Pc
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
Tc
-8.05406
-8.05406
-8.05406
-8.05406
-8.05406
-8.05406
-8.05406
-8.05406
-8.05406
-8.05406
-8.05406
2.56375
2.56375
2.56375
2.56375
2.56375
2.56375
2.56375
2.56375
2.56375
2.56375
2.56375
-5.12994
-5.12994
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
0.16125
0.16125
0.16125
0.16125
0.16125
0.16125
0.16125
0.16125
0.16125
0.16125
0.16125
46.9
46.9
46.9
46.9
46.9
46.9
46.9
46.9
46.9
46.9
46.9
506.8
506.8
506.8
506.8
506.8
506.8
506.8
506.8
506.8
506.8
506.8
0.334472774
0.3704402648
0.3768969729
0.3750470057
0.3729302407
0.3707660528
0.3684177925
0.3659983986
0.3633998271
0.3605692229
0.357472206
A21
ln 2 =
( 1+
x2 A21 2
)
x1 A12
A2 1
=e
( 1+
x 2 A2 1
x1 A1 2
A21 =
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
)2
1 =
2 =
1.5301619555 1.0000004134
1.4152490808 1.0041675757
1.3179473171 1.0168772057
1.2369562461 1.0386122857
1.1702143547 1.0701107791
1.1160821301 1.1124059832
1.0732789072 1.1668832517
1.0408353245 1.2353571095
1.0180590646 1.3201749243
1.0045123074 1.4243556995
1.000000453 1.5503713415
Pvp1
1.2935408355
0.6794396654
0.7132160943
0.7372430262
0.7655267257
0.7953361709
0.8287245806
0.8642871545
0.9038304916
0.9485337825
0.9994450747
Pvp2
0.9990652929
0.9990652929
0.9990652929
0.9990652929
0.9990652929
0.9990652929
0.9990652929
0.9990652929
0.9990652929
0.9990652929
0.9990652929
y2
0.9980666403
0.9029060759
0.8127413787
0.7263490412
0.6414663234
0.5556831047
0.4663170231
0.3702607237
0.2637881895
0.1423024344
0.0015489222
y1
0.001979327
0.0961576362
0.1879962476
0.2735812098
0.3583321453
0.4438302439
0.5336715674
0.6297064207
0.7361222598
0.8575324726
0.9984460819
340
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
335
330
VAN
LAAR
325
T
X vs
T
320
315
310
305
-0.8
0.2
VP_A
1.2
X-Y
VP_B
VP_C
VP_D
Pc
Tc
-8.54796
-8.54796
-8.54796
-8.54796
-8.54796
-8.54796
-8.54796
-8.54796
-8.54796
-8.54796
-8.54796
0.76982
0.76982
0.76982
0.76982
0.76982
0.76982
0.76982
0.76982
0.76982
0.76982
0.76982
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
1.54481
1.54481
1.54481
1.54481
1.54481
1.54481
1.54481
1.54481
1.54481
1.54481
1.54481
80.9
80.9
80.9
80.9
80.9
80.9
80.9
80.9
80.9
80.9
80.9
512.6
512.6
512.6
512.6
512.6
512.6
512.6
512.6
512.6
512.6
512.6
0.342003125
0.3775636485
0.3839472997
0.3821182647
0.3800254506
0.3778857502
0.3755640601
0.3731720414
0.3706028723
0.3678042961
0.3647423215
1
1.2
1.4
1.6
1.8
2
y1+y2
1.0000459672
0.9990637121
1.0007376263
0.999930251
0.9997984687
0.9995133486
0.9999885905
0.9999671444
0.9999104493
0.9998349071
0.9999950041
X vs
T
0.2
X-Y
1.2
Sistema Isobrico
Metil Acetato (1) - Metanol (2)
MODELO: NRTL
1
1
2
ANTA
18.9119
18.3036
17.5439
ANTB
3803.98
3816.44
3166.38
ANTC
-41.68
-46.13
-80.15
Presion
760
760
760
760
760
760
760
760
760
760
T (K)
346.79748483
352.73058996
356.89599504
356.13459891
354.59502761
352.07591118
349.2136532
346.23318353
343.18183536
339.5426185
x1
0
0.09
0.18
0.27
0.36
0.45
0.54
0.63
0.72
0.81
x2
0.56
0.51
0.46
0.41
0.36
0.31
0.26
0.21
0.16
0.11
x3
0.44
0.4
0.36
0.32
0.28
0.24
0.2
0.16
0.12
0.08
T12
-0.0800452364
-0.0786988355
-0.0777803255
-0.0779466155
-0.0782850421
-0.0788451745
-0.0794914128
-0.0801756966
-0.0808885664
-0.0817555298
1
0.9
0.8
0.7
0.6
fraccion molar agua
0.5
0.4
0.3
0.2
ethanol
Column AM
0.9
0.8
0.7
0.6
fraccion molar agua
0.5
ethanol
0.4
Column AM
0.3
0.2
0.1
0
0
ad
ALPHA 1J
0.3031
0.3007
0.485
T21
0.9729415689
0.9565762046
0.9454118109
0.9474330492
0.9515465889
0.9583549407
0.9662099001
0.9745272984
0.9831921571
0.9937300079
ethanol
Column AM
T13
-0.0018690539
-0.0018376155
-0.0018161683
-0.0018200512
-0.0018279534
-0.0018410325
-0.0018561221
-0.0018721001
-0.0018887456
-0.0019089892
T31
0.0410698741
0.0403790583
0.0399077861
0.0399931068
0.0401667478
0.0404541424
0.0407857164
0.041136811
0.0415025726
0.0419473971
T23
1.4587861621
1.4342486485
1.4175092434
1.4205398
1.4267074621
1.4369156078
1.4486929915
1.4611637358
1.474155447
1.4899554411
T32
0.3244817114
0.3190237665
0.3153003758
0.3159744706
0.3173463602
0.3196169854
0.3222366604
0.3250105614
0.3279003425
0.3314147775
G12
1.0245584212
1.0241403902
1.0238553088
1.023906915
1.0240119498
1.0241858173
1.0243864492
1.0245989355
1.0248203454
1.0250896796
G21
0.7446070946
0.7483097761
0.7508462915
0.7503864359
0.7494514267
0.7479064449
0.7461279187
0.7442492966
0.7422972253
0.7399300936
ethanol
Column AM
Diagonal
x
0
0.1
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
G32
0.8543847754
0.8566494161
0.8581977894
0.8579172595
0.85734662
0.856402984
0.8553155787
0.8541656604
0.8529693483
0.8515166996
0.4973652956
0.4904960518
0.4859976735
0.4875190813
0.4901560111
0.4942692276
0.4992803758
0.5052476
0.5128550185
0.524945075
G13
1.0005621825
1.0005527237
1.000546271
1.0005474392
1.0005498167
1.0005537517
1.0005582917
1.000563099
1.0005681071
1.0005741978
G31
0.9877262336
0.9879314336
0.9880714448
0.9880460953
0.9879945069
0.9879091286
0.9878106347
0.9877063529
0.9875977265
0.9874656355
G23
0.4928692818
0.4987698089
0.5028356092
0.5020970742
0.5005973873
0.4981250795
0.4952878844
0.4923012703
0.4892090421
0.4854745616
-0.4017184229
-0.2681443098
-0.1799498578
-0.1214430148
-0.0806396485
-0.0521279686
-0.0322366379
-0.0185940501
-0.0095665456
-0.0039931807
-2.2613423235
-1.1833907536
-0.6621378912
-0.3856281368
-0.2251900215
-0.129120004
-0.0707460345
-0.0355928368
-0.0152235636
-0.0044816941
1
0.1146701594
0.3824952625
0.7004095277
0.9806378317
1.2024081542
1.3675505981
1.4863117317
1.5699765973
1.6291605943
1.6761008952
0.3244817114
0.234717399
0.1684314287
0.1183271092
0.0777423889
0.0440481402
0.0153965168
-0.00937801
-0.0310899636
-0.050428353
0
0.0404081919
0.0885627354
0.1493677581
0.2278093028
0.3330674556
0.4804687921
0.7000213974
1.059399551
1.7517545545
0
0.2174906141
0.2733920574
0.2724713308
0.246960374
0.2118146582
0.1734223091
0.1349301144
0.0978601584
0.0629254125
2
1.3833135045
1.6365922847
1.6995885995
1.7162920829
1.7376125369
1.8020596379
1.9528456529
2.2831898033
3.0838220278
5.8372022428
1.4587861621
1.0587817169
0.7961761091
0.6133102736
0.4745551053
0.3655854744
0.2773261427
0.2042688114
0.1427683225
0.0903144867
0
-0.0515204446
-0.1131634952
-0.19137744
-0.2928976751
-0.4302121301
-0.6246094297
-0.918778084
-1.4125327347
-2.4086625125
0
0.0704267988
0.1026305903
0.1144845291
0.1138503589
0.1057551882
0.0929804501
0.0773131171
0.0599225967
0.0416282105
3
4.3007359624
2.9378795247
2.1938175596
1.7098700316
1.3438085569
1.041986026
0.7754569295
0.5287729446
0.2982444534
0.1026202687
Pvp1
629.318047057
798.266422315
938.279542747
911.259544573
858.605040859
777.939189563
694.079874726
614.947189172
541.92505431
464.508054544
Pvp2
Pvp3
273.2467182028 289.7796552275
349.3257625623 375.2499442546
412.7525953049 446.944136773
400.4888238067 433.0566229334
376.6216852323 406.0626717534
340.1439466864 364.9007244907
302.3438355068 322.3878475959
266.8021346742 282.5730627334
234.1298745929 246.1372935895
199.6418033807 207.8879129925
y1
0
0.03615787
0.1556478785
0.3174686943
0.4890285958
0.6299237392
0.7329924904
0.8003094713
0.8364154202
0.8297835743
y2
0.2785159081
0.3836433716
0.424597919
0.3708103645
0.3099896346
0.2500230263
0.2019894995
0.1683205024
0.1520031294
0.1686690185
y3
0.7215222962
0.5802311199
0.4644539505
0.3117770701
0.2010364974
0.1200699334
0.0657889185
0.0314562085
0.0115909078
0.002245633
Y
1.0000382044
1.0000323616
1.044699748
1.0000561289
1.0000547278
1.0000166989
1.0007709085
1.0000861822
1.0000094574
1.0006982258
Diagonal
x
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
y
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0