FIQ-UNCP "Termodinmica de los Procesos Quimicos II - VI Semestre" Joseph Chr

Sistema Isotrmico
Metil Acetato (1) - Metanol (2)
A12

ln 1 =
( 1+

MODELO: Van Laar

T(C) =

60

T(K) =

333.15

A12 =

0.4262

A21 =

0.4394

x1 A12 2
)
x2 A21

( 1+

x2 A21 2
)
x1 A12

A1 2

1 = e
Parmetros de Van Laar:

A21

ln 2 =

( 1+

x1 A1 2
x 2 A2 1

A2 1
)2

2 = e

( 1+

x 2 A2 1
x1 A1 2

Clculo del coeficiente de actividad:

T
333.15
333.15
333.15
333.15
333.15
333.15
333.15
333.15
333.15
333.15
333.15

x1
0.001
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
0.999

x2
0.999
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.001

A12 =

0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262

A21 =
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394

1 =
1.5301619555
1.4152490808
1.3179473171
1.2369562461
1.1702143547
1.1160821301
1.0732789072
1.0408353245
1.0180590646
1.0045123074
1.000000453

CALCULO DE LAS PRESIONES DE VAPOR:

METIL ACETATO
VP_A=
-8.05406
VP_B=
2.56375
VP_C=
-5.12994
VP_D=
0.16125
Pc=
46.9
Tc=
506.8
T=
333.15
x=
0.34264009
DIAGONAL

ECUACION DE WAGNER

METANOL
VP_A=
-8.54796
VP_B=
0.76982
VP_C=
-3.1085
VP_D=
1.54481
Pc=
80.9
Tc=
512.6
T=
333.15
x=
0.350078034

Metil Aceta

1
0.9
0.8
0.7
0.6
Y1 0.5
0.4
0.3
0.2
0.1
0
0

0.1 0.2 0.3 0.4 0.

0
0.2
0.4
0.6
0.8
1

0
0.2
0.4
0.6
0.8
1

0.6
Y1 0.5
0.4
0.3
0.2
0.1
0
0

0.1 0.2 0.3 0.4 0.

mestre" Joseph Christian Cruz Huanca

co
anol (2)
A21

ln 2 =
( 1+

x2 A21 2
)
x1 A12

A2 1

=e

( 1+

x 2 A2 1
x1 A1 2

2 =
1.00000041
1.00416758
1.01687721
1.03861229
1.07011078
1.11240598
1.16688325
1.23535711
1.32017492
1.4243557
1.55037134

)2

Pvp1
1.1259659
1.1259659
1.1259659
1.1259659
1.1259659
1.1259659
1.1259659
1.1259659
1.1259659
1.1259659
1.1259659

Pvp2
0.846540765
0.846540765
0.846540765
0.846540765
0.846540765
0.846540765
0.846540765
0.846540765
0.846540765
0.846540765
0.846540765

P
0.84741748
0.92441413
0.98545515
1.03329051
1.07058402
1.09918372
1.12021097
1.1340956
1.14055621
1.13851946
1.1261529

y1
0.00203313
0.17238185
0.30117327
0.4043695
0.49230006
0.57163803
0.64727564
0.72336191
0.80402862
0.8940927
0.99883457

y2
0.99796687
0.82761815
0.69882673
0.5956305
0.50769994
0.42836197
0.35272436
0.27663809
0.19597138
0.1059073
0.00116543

y1+y2
1
1
1
1
1
1
1
1
1
1
1

Metil Acetato (1) - Metanl (2)

Metil Acetato (1) - M

1
9
8
7
6
5
4
3
2
1
0

1.2
1
0.8
VAN LAAR
DIAGONAL

P 0.6
0.4
0.2
-1.66533453693773E-016

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

X1

0.1 0.2 0.3 0.4 0.5 0.6

X-Y

6
5
4
3
2
1
0

VAN LAAR
DIAGONAL

P 0.6
0.4
0.2
-1.66533453693773E-016

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

X1

0.1 0.2 0.3 0.4 0.5 0.6

X-Y

Metil Acetato (1) - Metanl (2)

Xvs P
Y vs P

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

X-Y

Xvs P
Y vs P

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

X-Y

FIQ-UNCP "Termodinmica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca

Sistema Isobrico
Metil Acetato (1) - Metanol (2)
A12

MODELO: Van Laar ln 1 =

( 1+

A21

ln 2 =

x1 A12 2
)
x2 A21

( 1+

x2 A21 2
)
x1 A12

A1 2
P (bar) =

1 = e
Parmetros de Van Laar:

A12 =

0.4262

A21 =

0.4394

( 1+

x1 A1 2
x 2 A2 1

A2 1
)2

2 = e

( 1+

x 2 A2

x1 A1 2

Clculo del coeficiente de actividad:

Presion
1
1
1
1
1
1
1
1
1
1
1

T
337.28919811
319.06087378
315.78861416
316.72617751
317.798954
318.89576444
320.08586279
321.31201156
322.62896764
324.06351782
325.63308599

x1
0.001
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
0.999

x2
0.999
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.001

A12 =

0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262
0.4262

METIL AC

CALCULO DE LAS PRESIONES DE VAPOR:

ECUACION DE WAGNER
METIL ACETATO
VP_A=
-8.05406
VP_B=
2.56375
VP_C=
-5.12994
VP_D=
0.16125
Pc=
46.9
Tc=
506.8

VP_A

VP_B

VP_C

METANOL
VP_A=
VP_B=
VP_C=
VP_D=
Pc=
Tc=

-8.54796
0.76982
-3.1085
1.54481
80.9
512.6

VP_D

Pc

1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0

0 0.1 0.2 0.3 0

Tc

-8.05406
-8.05406
-8.05406
-8.05406
-8.05406
-8.05406
-8.05406
-8.05406
-8.05406
-8.05406
-8.05406

2.56375
2.56375
2.56375
2.56375
2.56375
2.56375
2.56375
2.56375
2.56375
2.56375
2.56375

-5.12994
-5.12994
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085

0.16125
0.16125
0.16125
0.16125
0.16125
0.16125
0.16125
0.16125
0.16125
0.16125
0.16125

46.9
46.9
46.9
46.9
46.9
46.9
46.9
46.9
46.9
46.9
46.9

506.8
506.8
506.8
506.8
506.8
506.8
506.8
506.8
506.8
506.8
506.8

0.334472774
0.3704402648
0.3768969729
0.3750470057
0.3729302407
0.3707660528
0.3684177925
0.3659983986
0.3633998271
0.3605692229
0.357472206

stian Cruz Huanca

DIAGONAL:
0
0.2
0.4
0.6
0.8
1

A21

ln 2 =
( 1+

x2 A21 2
)
x1 A12

A2 1

=e

( 1+

x 2 A2 1
x1 A1 2

A21 =
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394
0.4394

)2

1 =
2 =
1.5301619555 1.0000004134
1.4152490808 1.0041675757
1.3179473171 1.0168772057
1.2369562461 1.0386122857
1.1702143547 1.0701107791
1.1160821301 1.1124059832
1.0732789072 1.1668832517
1.0408353245 1.2353571095
1.0180590646 1.3201749243
1.0045123074 1.4243556995
1.000000453 1.5503713415

Pvp1
1.2935408355
0.6794396654
0.7132160943
0.7372430262
0.7655267257
0.7953361709
0.8287245806
0.8642871545
0.9038304916
0.9485337825
0.9994450747

Pvp2
0.9990652929
0.9990652929
0.9990652929
0.9990652929
0.9990652929
0.9990652929
0.9990652929
0.9990652929
0.9990652929
0.9990652929
0.9990652929

y2
0.9980666403
0.9029060759
0.8127413787
0.7263490412
0.6414663234
0.5556831047
0.4663170231
0.3702607237
0.2637881895
0.1423024344
0.0015489222

METIL ACETATO (1) - METANOL (2)

METIL ACETATO (1) - METANOL (2)

y1
0.001979327
0.0961576362
0.1879962476
0.2735812098
0.3583321453
0.4438302439
0.5336715674
0.6297064207
0.7361222598
0.8575324726
0.9984460819

340

1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0

335
330
VAN
LAAR

325
T

X vs
T

320
315
310
305
-0.8

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.2

VP_A

1.2

X-Y

VP_B

VP_C

VP_D

Pc

Tc

-8.54796
-8.54796
-8.54796
-8.54796
-8.54796
-8.54796
-8.54796
-8.54796
-8.54796
-8.54796
-8.54796

0.76982
0.76982
0.76982
0.76982
0.76982
0.76982
0.76982
0.76982
0.76982
0.76982
0.76982

-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085
-3.1085

1.54481
1.54481
1.54481
1.54481
1.54481
1.54481
1.54481
1.54481
1.54481
1.54481
1.54481

80.9
80.9
80.9
80.9
80.9
80.9
80.9
80.9
80.9
80.9
80.9

512.6
512.6
512.6
512.6
512.6
512.6
512.6
512.6
512.6
512.6
512.6

0.342003125
0.3775636485
0.3839472997
0.3821182647
0.3800254506
0.3778857502
0.3755640601
0.3731720414
0.3706028723
0.3678042961
0.3647423215

1
1.2
1.4
1.6
1.8
2

y1+y2
1.0000459672
0.9990637121
1.0007376263
0.999930251
0.9997984687
0.9995133486
0.9999885905
0.9999671444
0.9999104493
0.9998349071
0.9999950041

TATO (1) - METANOL (2)

X vs
T

0.2

X-Y

1.2

Sistema Isobrico
Metil Acetato (1) - Metanol (2)
MODELO: NRTL

DATOS OBTENIDOS DEL DATABANK

Componentes
1
ethanol
2
water
3
n propanol

1
1
2

ANTA
18.9119
18.3036
17.5439

ANTB
3803.98
3816.44
3166.38

ANTC
-41.68
-46.13
-80.15

Parametos de interaccion del chemcad

Bij
Bji
2
-55.1581
670.441
3
-1.28794
28.3007
3
1005.23
223.596

Clculo del coeficiente de actividad:

R
1.987
1.987
1.987
1.987
1.987
1.987
1.987
1.987
1.987
1.987

Presion
760
760
760
760
760
760
760
760
760
760

T (K)
346.79748483
352.73058996
356.89599504
356.13459891
354.59502761
352.07591118
349.2136532
346.23318353
343.18183536
339.5426185

x1
0
0.09
0.18
0.27
0.36
0.45
0.54
0.63
0.72
0.81

x2
0.56
0.51
0.46
0.41
0.36
0.31
0.26
0.21
0.16
0.11

x3
0.44
0.4
0.36
0.32
0.28
0.24
0.2
0.16
0.12
0.08

T12
-0.0800452364
-0.0786988355
-0.0777803255
-0.0779466155
-0.0782850421
-0.0788451745
-0.0794914128
-0.0801756966
-0.0808885664
-0.0817555298

1
0.9
0.8
0.7
0.6
fraccion molar agua

0.5
0.4
0.3
0.2

ethanol
Column AM

0.9
0.8
0.7
0.6
fraccion molar agua

0.5
ethanol

0.4

Column AM

0.3
0.2
0.1
0
0

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

fraccion molar etanol

ad
ALPHA 1J
0.3031
0.3007
0.485

T21
0.9729415689
0.9565762046
0.9454118109
0.9474330492
0.9515465889
0.9583549407
0.9662099001
0.9745272984
0.9831921571
0.9937300079

ethanol
Column AM

T13
-0.0018690539
-0.0018376155
-0.0018161683
-0.0018200512
-0.0018279534
-0.0018410325
-0.0018561221
-0.0018721001
-0.0018887456
-0.0019089892

T31
0.0410698741
0.0403790583
0.0399077861
0.0399931068
0.0401667478
0.0404541424
0.0407857164
0.041136811
0.0415025726
0.0419473971

T23
1.4587861621
1.4342486485
1.4175092434
1.4205398
1.4267074621
1.4369156078
1.4486929915
1.4611637358
1.474155447
1.4899554411

T32
0.3244817114
0.3190237665
0.3153003758
0.3159744706
0.3173463602
0.3196169854
0.3222366604
0.3250105614
0.3279003425
0.3314147775

G12
1.0245584212
1.0241403902
1.0238553088
1.023906915
1.0240119498
1.0241858173
1.0243864492
1.0245989355
1.0248203454
1.0250896796

G21
0.7446070946
0.7483097761
0.7508462915
0.7503864359
0.7494514267
0.7479064449
0.7461279187
0.7442492966
0.7422972253
0.7399300936

ethanol
Column AM

Diagonal
x

0
0.1

0
0.1

0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9

0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9

G32
0.8543847754
0.8566494161
0.8581977894
0.8579172595
0.85734662
0.856402984
0.8553155787
0.8541656604
0.8529693483
0.8515166996

0.4973652956
0.4904960518
0.4859976735
0.4875190813
0.4901560111
0.4942692276
0.4992803758
0.5052476
0.5128550185
0.524945075

G13
1.0005621825
1.0005527237
1.000546271
1.0005474392
1.0005498167
1.0005537517
1.0005582917
1.000563099
1.0005681071
1.0005741978

G31
0.9877262336
0.9879314336
0.9880714448
0.9880460953
0.9879945069
0.9879091286
0.9878106347
0.9877063529
0.9875977265
0.9874656355

G23
0.4928692818
0.4987698089
0.5028356092
0.5020970742
0.5005973873
0.4981250795
0.4952878844
0.4923012703
0.4892090421
0.4854745616

-0.4017184229
-0.2681443098
-0.1799498578
-0.1214430148
-0.0806396485
-0.0521279686
-0.0322366379
-0.0185940501
-0.0095665456
-0.0039931807

-2.2613423235
-1.1833907536
-0.6621378912
-0.3856281368
-0.2251900215
-0.129120004
-0.0707460345
-0.0355928368
-0.0152235636
-0.0044816941

1
0.1146701594
0.3824952625
0.7004095277
0.9806378317
1.2024081542
1.3675505981
1.4863117317
1.5699765973
1.6291605943
1.6761008952

0.3244817114
0.234717399
0.1684314287
0.1183271092
0.0777423889
0.0440481402
0.0153965168
-0.00937801
-0.0310899636
-0.050428353

0
0.0404081919
0.0885627354
0.1493677581
0.2278093028
0.3330674556
0.4804687921
0.7000213974
1.059399551
1.7517545545

0
0.2174906141
0.2733920574
0.2724713308
0.246960374
0.2118146582
0.1734223091
0.1349301144
0.0978601584
0.0629254125

2
1.3833135045
1.6365922847
1.6995885995
1.7162920829
1.7376125369
1.8020596379
1.9528456529
2.2831898033
3.0838220278
5.8372022428

1.4587861621
1.0587817169
0.7961761091
0.6133102736
0.4745551053
0.3655854744
0.2773261427
0.2042688114
0.1427683225
0.0903144867

0
-0.0515204446
-0.1131634952
-0.19137744
-0.2928976751
-0.4302121301
-0.6246094297
-0.918778084
-1.4125327347
-2.4086625125

0
0.0704267988
0.1026305903
0.1144845291
0.1138503589
0.1057551882
0.0929804501
0.0773131171
0.0599225967
0.0416282105

3
4.3007359624
2.9378795247
2.1938175596
1.7098700316
1.3438085569
1.041986026
0.7754569295
0.5287729446
0.2982444534
0.1026202687

Pvp1
629.318047057
798.266422315
938.279542747
911.259544573
858.605040859
777.939189563
694.079874726
614.947189172
541.92505431
464.508054544

Pvp2
Pvp3
273.2467182028 289.7796552275
349.3257625623 375.2499442546
412.7525953049 446.944136773
400.4888238067 433.0566229334
376.6216852323 406.0626717534
340.1439466864 364.9007244907
302.3438355068 322.3878475959
266.8021346742 282.5730627334
234.1298745929 246.1372935895
199.6418033807 207.8879129925

y1
0
0.03615787
0.1556478785
0.3174686943
0.4890285958
0.6299237392
0.7329924904
0.8003094713
0.8364154202
0.8297835743

y2
0.2785159081
0.3836433716
0.424597919
0.3708103645
0.3099896346
0.2500230263
0.2019894995
0.1683205024
0.1520031294
0.1686690185

y3
0.7215222962
0.5802311199
0.4644539505
0.3117770701
0.2010364974
0.1200699334
0.0657889185
0.0314562085
0.0115909078
0.002245633

Y
1.0000382044
1.0000323616
1.044699748
1.0000561289
1.0000547278
1.0000166989
1.0007709085
1.0000861822
1.0000094574
1.0006982258

Diagonal
x
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1

y
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0