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B
T / C + C
2726.81
100C + 217.572
= 5.195
sat
Thus, P1 = 180.45kPa
3056.96
100C + 217.625
= 4.3076
sat
Thus, P2 = 74.2597kPa
Step 2: Find P.
P = x1 P1sat + x2 P2sat
= x1 P1sat + (1 x1 )P2sat
= 0.33(180.45kPa ) + (1 0.33)(74.2597 kPa )
= 109.3025kPa
Step 3: Calculate y1 using Raoults law.
yi P = xi Pi sat
y1 = x1 P1sat P = 0.33(180.45kPa ) 109.3025kPa = 0.5448
sat
1
y1 / P
x
i
=1
1
+ y 2 / P2sat
1
0.33 / 180.45 + (1 0.33) / 74.2597
= 92.156kPa
Step 2: Find x
yi P = xi Pi sat
x1 = y1 P P1sat
= (0.33)(92.156 ) (180.45)
= 0.1685
(c) Given x1 = 0.33 and P= 120 kPa, find y1 and T.
BUBL T Calculation:
Step 1: Start with =1, find P2sat
P2sat =
P
120
=
= 120kPa
x1 + x 2 (0.33)(1) + (1 0.33)
B
C
A ln P2sat
3056.96
217.625
13.9320 ln 120
= 116.67C
2726.81
T / C + 217.572
3056.96
T / C + 217.625
2726.81
3056.96
+
T / C + 217.572 T / C + 217.625
2726.81
3056.96
+
T / C + 217.572 T / C + 217.625
= 2.3076
Step 4: Repeat step 1 by using new until similar value of is obtained
2nd iteration:
= 2.3076
P2sat = 83.8277 kPa
T = 104.0507C
new = 2.3985
3rd iteration:
= 2.3985
P2sat = 82.10714kPa
T = 103.3502C
new = 2.40387
4th iteration:
= 2.40387
P2sat = 82.00765kPa
T = 103.3094C
new = 2.4042
5th iteration:
= 2.4042
P2sat = 82.00kPa
T = 103.307C
new = 2.4042
Thus, T = 103.307C
Step 5: Find P1sat & find y1 using Raoults law
P1sat = P2sat
= 2.4042(82.00kPa )
= 197.144kPa
y1 = x1 P1sat P
= 0.33(197.144kPa ) 120kPa
= 0.542
= 120[0.33 + 0.67(1)]
= 120kPa
B
C
A ln P1sat
2726.81
217.572
13.7819 ln 120
= 85.595C
2726.81
3056.96
+
T / C + 217.572 T / C + 217.625
ln = 0.1501
2726.81
3056.96
+
85.595 / C + 217.572 85.595 / C + 217.625
= 2.5527
Step 4: Repeat step 1 by using new until similar value of is obtained
2nd iteration:
T = 111.7005C
new = 2.34215
3rd iteration:
= 2.34215
P1sat = 227.9091kPa
T = 108.8766C
new = 2.36250
4th iteration:
= 2.36250
P1sat = 229.5446 Pa
T = 109.1563C
new = 2.3604
5th iteration:
= 2.3604
P1sat = 229.3807kPa
T = 109.1284C
new = 2.3606
= 2.5527
P1sat = 244.8347kPa
= 0.33(120kPa ) 229.3807kPa
= 0.1726
2) Assuming the validity of the De Priester charts, make the following VLE calculations
for methane(1)/ethylene(2)/ethane(3) system:
(a) BUBL P, given x1 = 0.10, x2 = 0.50, and T = -60 F
Component
xi
Methane
Ethylene
Ethane
0.10
0.50
0.40
P = 200 psia
Ki
yi=Kixi
5.600
0.560
0.700
0.350
0.445
0.178
P = 250 psia
Ki
yi=Kixi
4.600
0.460
0.575
0.288
0.380
0.152
P = 215 psia
Ki
yi=Kixi
5.150
0.515
0.650
0.325
0.420
0.168
SUM = 1.088
SUM = 0.900
SUM = 1.008
(close enough)
yi
Methane
Ethylene
Ethane
0.50
0.25
0.25
P = 190 psia
Ki
xi=yi/Ki
5.900
0.085
0.730
0.342
0.460
0.543
SUM = 0.971
P = 200 psia
Ki
xi=yi/Ki
5.600
0.089
0.700
0.357
0.445
0.562
SUM = 1.008
(close enough)
xi
Methane
Ethylene
Ethane
0.12
0.40
0.48
T = -50 F
Ki
yi=Kixi
4.900
0.588
0.680
0.272
0.450
0.216
T = -60 F
Ki
yi=Kixi
4.600
0.552
0.570
0.228
0.380
0.182
T = -57 F
Ki
yi=Kixi
4.700
0.564
0.615
0.246
0.405
0.194
SUM = 1.076
SUM = 0.962
SUM = 1.004
(close enough)
SUM = 1.084
T = -45 F
Ki
xi= yi /Ki
5.050
0.085
0.740
0.486
0.485
0.433
SUM = 1.005
(close enough)