SET-2

H$moS> Z.

Series SSO

Code No.

amob Z.

56/2/C

narjmWu H$moS >H$mo Cma-nwpVH$m Ho$ _wI-n

>na Ad` {bIo &

Roll No.

Candidates must write the Code on the

title page of the answer-book.

H$n`m OmM H$a b| {H$ Bg Z-n _o _w{V n> 15 h &

Z-n _| Xm{hZo hmW H$s Amoa {XE JE H$moS >Z~a H$mo N>m Cma-nwpVH$m Ho$ _wI-n> na
{bI| &
H$n`m OmM H$a b| {H$ Bg Z-n _| >26 Z h &
H$n`m Z H$m Cma {bIZm ew$ H$aZo go nhbo, Z H$m H$_mH$ Ad` {bI| &
Bg Z-n H$mo nT>Zo Ho$ {bE 15 {_ZQ >H$m g_` {X`m J`m h & Z-n H$m {dVaU nydm
_| 10.15 ~Oo {H$`m OmEJm & 10.15 ~Oo go 10.30 ~Oo VH$ N>m Ho$db Z-n H$mo nT>|Jo
Ama Bg Ad{Y Ho$ XmamZ do Cma-nwpVH$m na H$moB Cma Zht {bI|Jo &
Please check that this question paper contains 15 printed pages.
Code number given on the right hand side of the question paper should be
written on the title page of the answer-book by the candidate.
Please check that this question paper contains 26 questions.
Please write down the Serial Number of the question before
attempting it.
15 minute time has been allotted to read this question paper. The question
paper will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the
students will read the question paper only and will not write any answer on
the answer-book during this period.

agm`Z {dkmZ (gmpVH$)

CHEMISTRY (Theory)

{ZYm[aV g_` : 3 KQ>o

A{YH$V_ AH$ : 70

Time allowed : 3 hours

56/2/C

Maximum Marks : 70
1

P.T.O.

gm_m` {ZX}e :
(i)

g^r Z A{Zdm` h &

(ii)

Z g`m 1 go 5 VH$ A{V bKw-Cmar` Z h Ama `oH$ Z Ho$ {bE 1 AH$ h &

(iii)

Z g`m 6 go 10 VH$ bKw-Cmar` Z h Ama `oH$ Z Ho$ {bE 2 AH$ h &

(iv)

Z g`m 11 go 22 VH$ ^r bKw-Cmar` Z h Ama `oH$ Z Ho$ {bE 3 AH$ h &

(v)

Z g`m 23 _y`mYm[aV Z h Ama BgHo$ {bE 4 AH$ h &

(vi)

Z g`m 24 go 26 VH$ XrK-Cmar` Z h Ama `oH$ Z Ho$ {bE 5 AH$ h &

(vii)

`{X Amd`H$Vm hmo, Vmo bmJ Q>o~bm| H$m `moJ H$a| & H$Hw$boQ>am| Ho$ Cn`moJ H$s AZw_{V
Zht h &

General Instructions :
(i)

All questions are compulsory.

(ii)

Questions number 1 to 5 are very short answer questions and carry

1 mark each.

(iii)

Questions number 6 to 10 are short answer questions and carry 2 marks

each.

(iv)

Questions number 11 to 22 are also short answer questions and carry

3 marks each.

(v)

Question number 23 is a value based question and carry 4 marks.

(vi)

Questions number 24 to 26 are long answer questions and carry 5 marks

each.

(vii)

Use log tables, if necessary. Use of calculators is not allowed.

1.

g\o$X \$m\$moag Ama bmb \$m\$moag _| H$mZ-gm A{YH$ g{H$` h Ama `m|

Out of white phosphorus and red phosphorus, which one is more reactive
and why ?
56/2/C

2.

{ZZ `w_ _| go H$mZ

SN1 A{^{H$`m

CH3 CH2 Br

Ama

A{YH$ VrdVm go H$aoJm Ama `m|

CH3
|
CH3 C CH3
|
Br

Which would undergo SN1 reaction faster in the following pair and why ?
CH3
|
CH3 CH2 Br and CH3 C CH3
|
Br
3.

EH$ {d{Y H$mo {b{IE {OgHo$ mam d-{damoYr H$mobmBS>m| H$mo H${XV {H$`m Om gH$Vm h &

Write a method by which lyophobic colloids can be coagulated.

4.

EH$ `m{JH$ H$m gy {b{IE {Og_| Vd Y

MVw\$bH$s` [a{$ H$m 2/3dm ^mJ KoaVo h &

hcp

OmbH$ ~ZmVm h Ama

Ho$ na_mUw
1

What is the formula of a compound in which the element Y forms hcp

lattice and atoms of X occupy 2/3rd of tetrahedral voids ?
5.

{XE JE `m{JH$ H$m AmB.`y.nr.E.gr. Zm_ {b{IE

HO CH2 CH CH2 OH
|
CH3
Write the IUPAC name of the given compound :
HO CH2 CH CH2 OH
|
CH3
6.

gH$_U Vdm| H$s H$UrH$aU H$s EWpn`m `m| CVa hmoVr h

{H$g Vd H$s H$UrH$aU EWnr `yZV_ h Ama `m| ?

? 3d

loUr

(Sc

go

Zn)

_|,
2

Why do the transition elements have higher enthalpies of atomisation ?

In 3d series (Sc to Zn), which element has the lowest enthalpy of
atomisation and why ?
56/2/C

P.T.O.

7.

(i)

ZrMo {bIo H$mbog H$m AmB.`y.nr.E.gr. Zm_ {b{IE

[Co(NH3)5(NO2)](NO3)2
(ii)

{ZZ H$mbog H$m gy {b{IE :

nmoQ>{e`_ Q>oQ>mgm`ZmBS>mo{ZH$boQ>(II)

(i)

Write down the IUPAC name of the following complex :

[Co(NH3)5(NO2)](NO3)2

(ii)

Write the formula for the following complex :

Potassium tetracyanidonickelate(II)

8.

(a)

gmo{S>`_ bmoamBS> Ho$ Obr` {db`Z H$m {dwV-AnKQ>Z H$aZo na H$WmoS> na {ZZ
A{^{H$`mE hmoVr h :
Na+(aq) + e
Na(s)
H+(aq) + e

E0 = 2.71 V

1
H (g)
2 2

CZHo$ _mZH$ AnM`Z BboQ>moS> {d^d

A{^{H$`m H$s g^mdZm h Ama `m| ?

E0 = 0.00 V
(E0)

Ho$ _mZm| Ho$ AmYma na H$WmoS> na {H$g

(b)

_H$ar gob H$m gob {d^d gXm gnyU OrdZ _| WmB `m| ahVm h

(a)

Following reactions occur at cathode during the electrolysis of

aqueous sodium chloride solution :
Na+(aq) + e
Na(s)
H+(aq) + e

E0 = 2.71 V

1
H (g)
2 2

E0 = 0.00 V

On the basis of their standard reduction electrode potential (E0)

values, which reaction is feasible at the cathode and why ?
(b)

56/2/C

Why does the cell potential of mercury cell remain constant

throughout its life ?

9.

{ZZ A{^{H$`mAm| _| `w$ A{^H$maH$m| Ho$ Zm_ Xr{OE

(i)

CH3
|
?
CH3 CO CH3
CH3 C CH3

|
OH

(ii)

?
CH3 COOH
ClCH2 COOH

Name the reagents used in the following reactions :

(i)

CH3
|
?
CH3 CO CH3
CH3 C CH3

|
OH

(ii)
10.

?
CH3 COOH
ClCH2 COOH

hoZar Ho$ {Z`_ H$mo n[a^m{fV H$s{OE & Vmn_mZ Ho$ ~T>Zo na Jg| d _| h_oem H$_ KwbVr
h, `m| ?

AWdm
dmnerb KQ>H$m| dmbo {db`Z Ho$ {bE amCQ> Ho$ {Z`_ H$m H$WZ H$s{OE & EH$ AmXe
{db`Z Ama EH$ AZmXe {db`Z Ho$ ~rM Xmo AVam| H$mo {b{IE &

State Henrys law. Why do gases always tend to be less soluble in liquids
as the temperature is raised ?
OR
State Raoults law for the solution containing volatile components. Write
two differences between an ideal solution and a non-ideal solution.
11.

56/2/C

(i)

{OH$m}{Z`_ Ho$ n[aH$aU _| BVo_mb hmoZo dmbr {d{Y H$m Zm_ Xr{OE &

(ii)

Am`aZ Ho$ {ZH$fU _|

(iii)

`{X mV YmVw d AdWm _| hmoVr h Vmo YmVw AmgmBS> H$m YmVw _| AnM`Z gab
hmoVm h & `m| ?

CO

H$s `m ^y{_H$m hmoVr h

?
3

P.T.O.

12.

(i)

Name the method used for the refining of zirconium

(ii)

What is the role of CO in the extraction of Iron ?

(iii)

Reduction of metal oxide to metal becomes easier if the metal

obtained is in liquid state. Why ?

(a)

{ZZ H$mo Amn H$maU g{hV H$go g_PmEJo

(b)

(i)

bWoZmBS>m| H$s Anojm EopQ>Zm`S>m| H$m agm`Z A{YH$ O{Q>b h &

(ii)

gH$_U YmVwE H$mbog `m{JH$ ~ZmVr h &

{ZZ g_rH$aU H$mo nyU H$s{OE

2 MnO 4 + 6H+ + 5 SO32

(a)

(b)

How would you account for the following :

(i)

The chemistry of actinoids is more complicated as compared

to lanthanoids.

(ii)

Transition metals form complex compounds.

Complete the following equation :

2 MnO 4 + 6H+ + 5 SO32

13.

56/2/C

[Co(en)2Cl2]+

(i)

H$mbog

(ii)

{H$Q>b \$sS> {gmV Ho$ AmYma na `{X

BboQ>m{ZH$ {d`mg {b{IE &

(iii)

[NiCl4]2

Ho$ `m{_Vr` g_md`{d`m| H$mo Amao{IV H$s{OE &

0 > P

hmo, Vmo

d4

Am`Z Ho$ {bE

AZwMw~H$s` h O~{H$ [Ni(CO)4] {VMw~H$s` h, hmbm{H$ XmoZm|

MVw\$bH$s` h & `m| ? (Ni H$m na_mUw H$_mH$ = 28)

(i)

Draw the geometrical isomers of complex [Co(en)2Cl2]+.

(ii)

On the basis of crystal field theory, write the electronic

configuration for d4 ion if 0 > P.

(iii)

[NiCl4]2 is paramagnetic while [Ni(CO)4] is diamagnetic, though

both are tetrahedral. Why ? (Atomic number of Ni = 28)
6

14.

{ZZ A{^{H$`mAm| Ho$ CnmXm| H$s mJw{$ H$s{OE

Predict the products of the following reactions :

15.

{ZZ ~hbH$m| Ho$ EH$bH$m| Ho$ Zm_ Ama CZH$s gaMZmE {b{IE
(i)
ZmBbmZ-6
(ii)
ZmodmobH$>
(iii) `yZm-N

Write the names and structures of the monomers of the following

polymers :

16.

(i)

Nylon-6

(ii)

Novolac

(iii)

Buna-N

(i)

{ZZ _| go H$mZ-gm EH$ nm{bgHo$amBS> h ?

Q>mM, _mQ>mog, \$Q>mog, byH$mog
mH${VH$ moQ>rZ Ama AmH${VH$ moQ>rZ _| `m AVa h ?
a$ Ho$ H$XZ Ho$ {bE Omo {dQ>m{_Z CmaXm`r hmoVm h CgH$m Zm_ {b{IE &

(ii)
(iii)
56/2/C

3
P.T.O.

(i)

Which one of the following is a polysaccharide :

Starch, Maltose, Fructose, Glucose

17.

(ii)

What is the difference between native protein and denatured

protein ?

(iii)

Write the name of the vitamin responsible for the coagulation of

blood.

CaCl2

H$s Cg _mm H$mo n[aH${bV H$s{OE {OgH$mo `{X 500 g Ob _| {_bm`m OmE Vmo
Ob H$m {h_mH$ 2 K KQ> OmVm h & `h _mZH$a M{bE {H$ CaCl2 nyUV`m {dK{Q>V hmo
OmVm h & (CaCl2 H$m _moba `_mZ = 111 g mol1,
Kf Ob Ho$ {bE = 1.86 K kg mol1)

Calculate the amount of CaCl2 (molar mass = 111 g mol1) which must be
added to 500 g of water to lower its freezing point by 2 K, assuming
CaCl is completely dissociated. (K for water = 1.86 K kg mol1)
2

18.

KZd 10 g cm3 dmbm EH$ Vd H$moa b~mB 3 108 cm Ho$ gmW EH$ `y{~H$ `y{ZQ>
gob ~ZmVm h & `{X Vd H$m na_mUw `_mZ 81 g mol1 hmo, Vmo `y{~H$ `y{ZQ> gob
H$gm hmoJm ?

An element with density 10 g cm3 forms a cubic unit cell with edge
length of 3 108 cm. What is the nature of the cubic unit cell if the
atomic mass of the element is 81 g mol1 ?
19.

{ZZ H$mo Amn H$go $nmV[aV H$a|Jo

(i)

mon-1-BZ H$mo 1-bwAmoamomonoZ _|

(ii)

bmoamo~oOrZ H$mo 2-bmoamoQ>mbyBZ _|

(iii)

EWZmb H$mo monoZZmBQ>mBb _|

AWdm
_w` CnmXm| H$mo {b{IE O~
(i)
n-`y{Q>b bmoamBS> H$mo EoH$mhmbr KOH Ho$ gmW CnMm[aV {H$`m OmVm h &
(ii)
2, 4, 6-Q>mBZmBQ>mobmoamo~oOrZ H$mo Ob-AnK{Q>V {H$`m OmVm h &
(iii) _o{Wb bmoamBS> H$mo AgCN Ho$ gmW CnMm[aV {H$`m OmVm h &
56/2/C

How do you convert the following :

(i)
Prop-1-ene to 1-fluoropropane
(ii)
Chlorobenzene to 2-chlorotoluene
(iii) Ethanol to propanenitrile
OR
Write the main products when

20.

(i)

n-butyl chloride is treated with alcoholic KOH.

(ii)

2, 4, 6-trinitrochlorobenzene is subjected to hydrolysis.

(iii)

methyl chloride is treated with AgCN.

{ZZ Ho$ H$maU Xr{OE

(i)

o-ZmBQ>mo\$sZmb

AnojmH$V o-_rWmgr\$sZmb Ho$ A{YH$ Abr` h &

(ii)

`yQ>Z-1-Amb AnojmH$V S>mBE{Wb BWa Ho$ CVa dWZmH$ H$m h &

(iii)

HI

Ho$ gmW A{^{H$`m H$aHo$ (CH3)3C O CH3 _w` CnmX Ho$ $n _|

(CH3)3C I Ama CH3 OH XoVm h Z {H$ (CH3)3C OH Ama CH3 I.

Give reasons for the following :

(i)

o-nitrophenol is more acidic than o-methoxyphenol.

(ii)

Butan-1-ol has a higher boiling point than diethyl ether.

(iii)

(CH3)3C O CH3 on reaction with HI gives (CH3)3C I and

CH3 OH as the main products and not (CH3)3C OH and
CH3 I.

21.

{ZZ gob H$m

25C

na {d.dm.~. n[aH${bV H$s{OE

Sn | Sn2+ (0.001 M) | | H+ (0.01 M) | H2(g) (1 bar) | Pt(s)

E0

(Sn2 / Sn)

= 0.14 V

E0

(H / H2 )

= 0.00 V

Calculate emf of the following cell at 25C :

Sn | Sn2+ (0.001 M) | | H+ (0.01 M) | H2(g) (1 bar) | Pt(s)

E0

(Sn2 / Sn)

56/2/C

= 0.14 V

E0

(H / H2 )

= 0.00 V
P.T.O.

22.

{ZZ AdbmoH$Zm| Ho$ {bE H$maU ~VmBE :

(i)
Vmn_mZ Ho$ ~T>Zo na ^m{VH$ emofU KQ>Vm h &
(ii)
{\$Q>H$ar Ho$ S>mbZo go Ob H$m ewrH$aU hmoVm h &
(iii) ~mC{Z`Z gMbZ H$mobmBS>r {db`Z H$mo pWaVm XoVm h &

Give reasons for the following observations :

23.

(i)

Physisorption decreases with increase in temperature.

(ii)

Addition of alum purifies the water.

(iii)

Brownian movement provides stability to the colloidal solution.

OdmZ ~m| _| _Yw_oh Ama AdgmX (CXmgr) H$s ~T>Vr g`m H$mo XoIH$a, EH$ {g
Hy$b Ho$ q{gnb lr bwJmZr Zo EH$ go{_Zma H$m Am`moOZ {H$`m {Og_| A` q{gnbm| Ama
~m| Ho$ _mVm-{nVmAm| H$mo Am_{V {H$`m & `h {ZU` {b`m J`m {H$ Hy$bm| _| gS>o hE
ImZo H$s dVwE ~X H$s OmE Ama dm`dYH$ dVwE Ogo gyn, bgr, XY, Am{X CnbY
H$amB OmE & Chm|Zo `h ^r {ZU` {b`m {H$ Hy$bm| _| amoO mVH$mb H$s Eogo~br Ho$ g_`
~m| H$mo AmYm KQ>o H$m emar[aH$ `m`m_ A{Zdm` $n go H$am`m OmE & N> _mh Ho$
nMmV, lr bwJmZr Zo A{YH$Va Hy$bm| _| {\$a dm` narjU H$am`m Ama ~m| Ho$
dm` _| AZwn_ gwYma nm`m J`m &
Cn`w$ {ddaU H$mo nT>H$a {ZZ{b{IV Zm| Ho$ Cma Xr{OE :
(i)
lr bwJmZr mam {H$Z _y`m| (H$_-go-H$_ Xmo) H$mo X{eV {H$`m J`m ?
(ii)
EH$ {dmWu Ho$ $n _|, Amn Bg {df` _| H$go OmJ$H$Vm \$bmEJo ?
(iii) {V-AdgmXH$ S>J `m h ? EH$ CXmhaU Xr{OE &
(iv) EH$ Eogo _rR>mH$mar nXmW H$m Zm_ Xr{OE Omo _Yw_oh go nr{S>V amo{J`m| Ho$ {bE
{_R>mB`m ~ZmZo _| H$m_ AmVm hmo &
Seeing the growing cases of diabetes and depression among young
children, Mr. Lugani, the principal of one reputed school organized a
seminar in which he invited parents and principals. They all resolved
this issue by strictly banning junk food in schools and introducing
healthy snacks and drinks like soup, lassi, milk, etc. in school canteens.
They also decided to make compulsory half an hour of daily physical
activities for the students in the morning assembly. After six months,
Mr. Lugani conducted the health survey in most of the schools and
discovered a tremendous improvement in the health of the students.

56/2/C

10

After reading the above passage, answer the following questions :

24.

(i)

What are the values (at least two) displayed by Mr. Lugani ?

(ii)

As a student, how can you spread awareness about this issue ?

(iii)

What are antidepressant drugs ? Give an example.

(iv)

Name the sweetening agent used in the preparation of sweets for a

diabetic patient.

(a)

A{^{H$`m Xa `m h
H$aVo h &

(b)

EH$ W_ H$mo{Q> A{^{H$`m H$m Xa {Z`VmH$ Vmn_mZ H$mo 27C go 37C H$aZo na
4 102 go ~T>H$a 8 102 hmo OmVm h & BgH$s g{H$`U D$Om (Ea) H$m
n[aH$bZ H$s{OE &

Xmo H$maH$m| H$mo {b{IE Omo A{^{H$`m H$s Xa H$mo ^m{dV

(log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)

AWdm
(a)

Xa

(b)

A + B P Ho$

A{^{H$`m

{bE Xa Xr JB h

= k [A] [B]2

(i)

`{X
h ?

(ii)

A A{YH$

H$m gmU XJwZm {H$`m OmE Vmo A{^{H$`m H$s Xa H$go ^m{dV hmoVr
_mm _| {d_mZ hmo Vmo A{^{H$`m H$s gnyU H$mo{Q> `m hmoJr

EH$ W_ H$mo{Q> H$s A{^{H$`m 50% nyU hmoZo _| 23.1 {_ZQ> boVr h & Bg
A{^{H$`m H$mo 75% nyU hmoZo _| Omo g_` bJoJm CgH$m n[aH$bZ H$s{OE &

(log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)

56/2/C

11

P.T.O.

(a)

What is rate of reaction ? Write two factors that affect the rate of
reaction.

(b)

The rate constant of a first order reaction increases from 4 102

to 8 102 when the temperature changes from 27C to 37C.
Calculate the energy of activation (Ea).
(log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)
OR

(a)

For a reaction A + B P, the rate is given by

Rate = k [A] [B]2

(b)

(i)

How is the rate of reaction affected if the concentration of B

is doubled ?

(ii)

What is the overall order of reaction if A is present in large

excess ?

A first order reaction takes 23.1 minutes for 50% completion.

Calculate the time required for 75% completion of this reaction.
(log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)

25.

(a)

{ZZ H$mo H$maU XoVo hE g_PmBE :

(i)
AVhbmoOZ| AnojmH$V {dew hbmoOZm| Ho$ A{YH$ {H$`merb hmoVo h &
(ii) gm_m` Vmn_mZ na N2 H$_ g{H$` h &
(iii) AnM`Zr `dhma NH3 go BiH3 H$s Amoa ~T>Vm h &

(b)

{ZZ H$s gaMZmE Amao{IV H$s{OE

(i)

H4P2O7 (nmBamo\$m\$mo[aH$

Ab)

(ii)

XeF4

AWdm
56/2/C

12

(a)

O~ g\o$X \$m\$moag H$mo NaOH Ho$ gm {db`Z Ho$ gmW VV {H$`m OmVm h V~
H$mZ-gr Oharbr Jg {ZH$bVr h ? g~ amgm`{ZH$ g_rH$aU H$mo {b{IE &

(b)

H$mZ-gr CH$> Jg H$m dWZmH$ `yZV_ h

(c)

bmoarZ H$s Anojm bwAmoarZ ~bVa CnMm`H$ h & `m|

(d)

H3PO3 H$mo

(e)

g_rH$aU H$mo nyam H$s{OE

O~ VV {H$`m OmVm h V~ `m hmoVm h

PbS + O3
(a)

(b)

Account for the following :

(i)

Interhalogens are more reactive than pure halogens.

(ii)

N2 is less reactive at room temperature.

(iii)

Reducing character increases from NH3 to BiH3.

Draw the structures of the following :

(i)

H4P2O7 (Pyrophosphoric acid)

(ii)

XeF4
OR

(a)

Which poisonous gas is evolved when white phosphorus is heated

with conc. NaOH solution ? Write the chemical equation involved.

(b)

Which noble gas has the lowest boiling point ?

(c)

Fluorine is a stronger oxidizing agent than chlorine. Why ?

(d)

What happens when H3PO3 is heated ?

(e)

Complete the equation :

PbS + O3

56/2/C

13

P.T.O.

26.

(a)

(b)

`oH$ Ho$g Ho$ {bE EH$ Cn`w$ CXmhaU XoVo hE {ZZ A{^{H$`mAm| H$mo X{eV
H$s{OE :
(i)

hm\$_mZ ~mo_o_mBS> {ZZrH$aU A{^{H$`m

(ii)

S>mBEOmoQ>rH$aU (S>mBEOmoQ>rOoeZ)

(iii)

J{~b W{b_mBS> gbofU

`m{JH$m| Ho$ {ZZ `w_m| Ho$ ~rM AVa n> H$s{OE

(i)

Eo{ZbrZ Ama

N-_o{WbEo{ZbrZ

(ii)

(CH3)2NH Ama (CH3)3N _|

_|
5

AWdm
(a)

(b)

~oOrZ S>mBEOmo{Z`_ bmoamBS> (C6H5 N 2 Cl) {ZZ A{^H$maH$m| go A{^{H$`m

H$aVm h Vmo m _w` CnmXm| H$s gaMZmE {b{IE :
(i)

CuCN / KCN

(ii)

H2O

(iii)

CH3CH2OH

{ZZ H$mo `dpWV H$s{OE

(i)
(ii)

C2H5NH2, C2H5OH, (CH3)3N H$mo BZHo$

dWZmH$ Ho$ ~T>Vo H$_ _|

Eo{ZbrZ, p-ZmBQ>moEo{ZbrZ, p-_o{WbEo{ZbrZ H$mo BZH$s ~T>Vr jmar` j_Vm
Ho$ H$_ _|

(a)

Illustrate the following reactions giving suitable example in each

case :
(i)
Hoffmann bromamide degradation reaction
(ii) Diazotisation
(iii) Gabriel phthalimide synthesis

(b)

Distinguish between the following pairs of compounds :

(i)

Aniline and N-methylaniline

(ii)

(CH3)2NH and (CH3)3N

OR

56/2/C

14

(a)

Write the structures of main products when benzene diazonium

chloride (C6H5 N 2 Cl) reacts with the following reagents :

(b)

(i)

CuCN / KCN

(ii)

H2O

(iii)

CH3CH2OH

Arrange the following :

(i)

C2H5NH2, C2H5OH, (CH3)3N in the increasing order of

their boiling point

(ii)

56/2/C

Aniline, p-nitroaniline, p-methylaniline in the increasing

order of their basic strength

15

P.T.O.