Aits FT I (Paper 1) PCM (Sol) Jee (Advanced)

1
FIITJEE
JEE(Advanced)-2016
ANSWERS, HINTS & SOLUTIONS
FULL TEST I
(PAPER-1)
ALL INDIA TEST SERIES
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AITS-FT-I-(Paper-1)-PCM(Sol)-JEE(Advanced)/16
Q. No.
PHYSICS
CHEMISTRY
MATHEMATICS
1.
2.
C
C
D
D
B
C
3.
4.
5.
6.
7.
8.
B
C
A
A, B, C
C
A, B, D
9.
A, B, C, D
A, B, C
10.
A, B, C
B, C
B, C
11.
A, B, C
A, C
A, B
12.
13.
A
B
C
B
C
D
14.
15.
16.
A
(A) s, (B) pt,
(C) q, (D) pr
(A) pqt, (B) prt,
(C) s, (D) qr
3
1.
2.
1.
2.
D
(A) r, (B) pt,
(C) qs, (D) qs
(A) pqs, (B) q,
(C) rt, (D) q
4
A
(A) prt, (B) q,
(C) t, (D) s
(A) qt, (B) q,
(C) prs, (D) t
1
3.
5
9
7
3
2
1
4.
5.
6.
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website: www.fiitjee.com
2
Physics
PART I
SECTION A
1.
C
1
tan1 tan
e
vertical component after collision eucos

& Horizontal component u sin
tan
2.
u sin
1
tan1 tan
eucos
e
C
Zero
T f 2a
Ring
T
a
TR fR 2R
a R
f 0.
3.
B
I1
V t /RC1
V
e
& I2 e t /RC2
R
R
t
I1
eR C1 C2
I2
I1
e RC1
I2
4.
B
f
1
2 LC
f 50
1
2 LC / K
50 100
f 50
K
K 1 2
1
f 10 4
f
K 1.01
5.
r1 2R sin30o , r2 2R sin 60o R 3 R
i
BD B AC BCB 0 sin 60o 0 sin30 o
4
r
4
1
2
0 i
BD
4 R 3
r2
r1
30o
30o
30
30 o
6.
i
o
C
Beats
V
V
V
4 4 4
V
4 2
3
7.
B
3
sin60o sin90o
2
3 3
,
2 2
3 3
8.
C
13.6 10.2 3.4eV
1st collision
& 3.4 15 11.6eV 2nd collision.
9.
A, B, C, D
V
1
n
1
r
P.E.
T r 3/ 2
T.E.
10.
1
r
A, B, C
2
Vs2 3 8 4 25 Vs 5 volt
Vs
5
I
VR 3 1 R R 3
R 3
0.6
Z 5
VL VC I lags V.
P.F.
11.
A, B, C
1 1 1
v v
1
f v u
f u
since m is positive in the graph,
v
v

u
u
v
v
m 1
u
f
int ercept on m axis 1 & tan
12.
1
f
A
V
, OP x 2 y 2
R
origin is ins tan taneous centre of rotation
VP r OP
V 2
x y2
R
4
13.
a R
a R 2a
ac
V2
V
ac 2R R
R
R
2a
anet
ac
1
2a
45o
tan
14.
C
Q 300
15J / o C
T
20
Thermal heat capacity, C

15.
D
Specific heat capacity, S
16.
Q
300
600J / kg o C
m T 0.025 20
A
Molar heat capacity
Q
300
nT 25
20
50
30J / mol o C
SECTION B
1.
(A s) (B p, t) (C q) (D p, r)
In wrist watch spring force is not dependent on gravity.
T 2
m
K
2.
(A p, q, t) (B p, r, t) (C s) (D q, r)
In nuclear reactions energy, charge, mass and momentum remain conserved.
1.
SECTION C
for Rmax , 45o Hmax
20
sin2 45o
2 10
10m
Hmax allowed 5m,

5
20
Rmax
2.
sin2
2 10
20
30o
sin60o
10
m 20 3m.
5
1
3R3 R2
2
2
22
Msphere R3 , Isphere R3 R2
3
53
29 5
Iremaining portion Icylinder 2 Isphere
R .
30
Mcylinder R2 3R . Icylinder
5
3.
9
18 sin30o r 1
9 m / s.
18 sin 30o
18 m/s
18cos 30o
1m
60o
0.5m
4.
1 1 1

F f1 f2
1
1
1 1
1 2
1
24 4
20 20 4
20 20
5
1 2 .
9
5.
2
2
V 200
V 2 200
I
2.5A & P
500 watt
R
80
R
80
When the wire is divided into two equal parts and connected in parallel we get maximum power.
Re sis tance of each part 40
Imax 5A
2
Pmax
6.
200
V2
2000W 2kw.
Req
20
4
Q
Q
, VPB
3
6
Q Q
12 Q 24C
3 6
24
VAP
8
3
VA VP 8 VP 4volt.
VAP
6
Chemistry
PART II
SECTION A
1.
D
H
H
H
B
CH3
B 2 H6
CH3
CH3
CH3
2.
methylation
D
H
OH
OH
+
+
CH2
H+
ring. exp
-H2 O
HO
HO
HO
HO
OH
HO
OH
OH
H /excess
similar repetation
HO
HO
3.
A
At nodal surface, = 0
r
4.
2 2
= 1
z z
C
+2
Co ordination no of Fe in D is 6
-
Na
Fe
+2
(a sandwhich compound)
C
-
7
5.
C
O
O
+
Zn(Hg)
HCl
AlCl3
O
O
SOCl2
HO
HO
Cl
AlCl3
Br
NaBH4
H2SO4
NBS/CCl4
OH
ONa
OH
heat
6.
C
O
O
H
(a)
OH
OH
+ OH
O-D
D - OD
(b)
D - OD
DO-
DO
D - OD
D
D
H
DO - D
DO-
OD
O
D
D
D
O-D D
H
D - OD
DO - D
O
D
Repeat last two step
D
D
D
D
8
O
H
H
(d)
OH
OH
7.
OH
HO - H
A
Synergic bonding.
8.
9.
A, B, C
log
K2
Ho T2 T1
K1 & K 2 are eq. cons tan t

K1 2.303R T1T2
log
K2
Ea T2 T1
K1 & K 2 are rate cons tan t

K1 2.303R T1T2
B
H3C
Me
N
H3C
H3C
Me
CH3
OH
CH3
H2C
CH3
(Major product)
Due to greater probability of losing -H (9 : 3 ratio).

10.
B, C
(b) conjugate base of H2PO4 is HPO24
(c) pH of 0.1 M NaCl (aqueous solution) =
11.
1
pK w
2
A, C
A 3 3e Al
Number of moles of Al produced
4.5
0.166
27
Number of moles of electrons used 3 0.166

1
H e H2
2
Number of moles of H2 produced
1
3 0.166
2
Volume of H2 produced 1.5 0.166 22.4 5.57 5.6

12.
C
2nd step is r.d.s. in sulphonation reaction.
13.
B
2nd step is fast step in nitration.
9
14.
A
a
P V b RT
V
on converting into virial equation from, we get
b
2
3
2
RT b b ....... to higher power of n
PV RT
2
4
V
V
V
(i)
For Boyles temperature, 2nd virial co-efficient becomes zero

b
RT 2
a
TB
Rb
a
TB2
RB
2a
Ti
Ti 2TB2
Rb
15.
A
Let Boyles temperature, TB'
TB
TB'
16.
a
Rb
8a
a
2
2TB
R 2b
Rb
D
b2 = 0.04
b = 0.2 lit/mol
Vreal = 4 22.4 + 4 0.2 = 90.4 lit
SECTION B
1.
A r ,B p,t , C q,s D q,s .

(A) Sic covalent carbide (Not hydrolysed)
(B) Al4 C3 12H2O 4Al OH3 3CH4
(C) Cal2 2H2 O Ca OH2 H C C H
(D) Mg2 C3 4H2 O 2Mg OH 2 CH3 C CH
10
2.
A p,q,s , B q , C r,t D q .
Al2 SO4 3 2Al3 3SO 4
0.2M
0.3M
AlPO 4 Al PO
0.1M
3
4
0.1M
Urea
Urea
0.1M
MgCl2 Mg2 2Cl
0.1M 0.2M
SECTION C
1.
4
Based on fact
2.
7
OH
B
2Na
O
HO
O
O
B
OH 8H2O
OH
3.
3
OHC
CHO
CHO
,
NO2
Cl
C
N
4.
3
OCH3
,
H3CO
H3CO
OCH3
NH2
OCH3
OCH3
11
5.
2
1
1 100
n100; t 90 n
K
K
10
n100 2
2
n10
1
t 99
t 99
t 90
hence x 2
6.
3
S
H
Cl
H
C
S
H
0
C C
, Cl
H
0
O
H
0
12
Mathematics
PART III
SECTION A
1.
PQ r 2 1 2r cos r 2 1 r
3
& AT r 2 1 2r cos
Where 'Q ' is the angle between
OA and OT.
2
2
now, PQ 4 AT
1 r r 4 r 1 2r cos
2
P
A
3r r 3
3r r 3
1
1; r 0
8r
8r
7 13 7 13
r
,
.
6
6
cos
2.
C
Here two balls are drawn and the result is known that the two balls are white, therefore Bayess
theorem should be used.
Required probability =
3.
1
.1
1
4
1
1 6 1 3 1 1
2
.1 . . .
4
4 10 4 10 4 10
D
Let Q x f x g x in x0 x
By LMVT,
Q x Q x 0 Q' x Q' x 0 for some C x 0 ,x
Q x 0 0, Q' C f ' C g' C 0
Q x Q x0 Q x
F' C g' C x x0 0
Q x 0 f x g x .
4.
A
A
AP = 23
(-3, 4)
5
5
13
P
13
5.
D
Sn
5
2n 5
4 2 n 1 n 2
6.
5
4
A
Equation of tan gent at 'P ' is
Y y m X x
Now,
y mx
1 m2
y 2 x 2 dy
2xy
dx
putting y vx
Solving Differential equation

x 2 y 2 Cx
It passes through 1,2 C 5
Equation of curve x 2 y 2 5x 0
7.
C
x cos y sin
1
3
2
x 0, y 2cos ec,
chord A 'P;
y
2 sin
x 3
3 cos 1
x 0, OM
2 sin
cos
1
Now, OQ2 MQ2 OQ2 OQ OM
2 OM OQ OM2
OM 2OQ OM
2 sin
cos 1 sin
2 sin
1 cos
2sin 4 4 cos 2 sin 2
1 cos
sin
4 sin 2 2cos 1 cos2
1 cos
sin
8.
A, B, D
f x 0 x 3 x 2 x 1 x 2 x 1 2 0
x 3 1
2
x2 x 1
-2
-1
1
2
x3
14
9.
A, B, C
Take f x x and g x x and proceed.
10.
B, C
cos 2x
1
I tan1
dx tan tan x dx
4
1 sin 2x
x dx
4
11.
x2
x2
x
C gx x .
4
2
4
2
A, B
2 4 4 a2 1
1 a, 1 a
2
f 1 a 0 & f 1 a 0
1
a ,1
4
12.
C
The value of K1 & K2 decide the opening of parabola
A max Area OBCO
A min Area OACO
Y
c
A
X'
Y'
14.
1
4
1
K1
8
K1
(1,0)
(2, 0)
K2
1 K2 = -1
4
D
Area BFEC Area ABC AFE
or AOB BOC COA AFE

1 2
R sin 2C sin 2A sin 2B sin 2A
2
1
R2 sin2B sin 2C
2
2R
co
sA
13.
2A
E
H
O
C
15
15.
B
AE R, AF 2Rcos A
EF R
16.
3
AFE is equilateral
AFE
R 3
9
sum of square of altitudes 3
R2 .
2
4
SECTION B
1.
(A
p, r, t) (B
q) (C
t) (D
s)

A tan 1 2 3 4 0 1 2 3 4 2n
2
B x 2
4 t 2 2, TR is diameter 6
2
TR 9
4
Area of circle
C 6
D y A yB yC
2.
(A
q, t) (B
q) (C
p, r, s) (D
t)
SECTION C
1.
1
D.C' s of OP are,
1 1
,
,
3 3
1
D.C' s of AL
,
3
3
1 1
,
3 3
C (o, o, a)
cos
cosy
mn
3
mn
3
,cos
,cos
P (a, a, a)
(o, a, a)
1
1 1
D.C's of BM
,
,
3 3
3
1 1
1
D.C' s of CN
,
,
3
3
3
Let D.C' s of required line be ,m,n
M(a, o, a)
A (a, o, o)
B
(o, a, o)
N (a, a, o)
m n
3
mn
3
4 2
4
m2 n 2
3
3
4
2
2
2
2
cos cos cos y cos 1.
3
2
Hence, cos cos cos y cos2
16
2.
2
The gives equation is x 1 y 2 4
XY 4
Equationof tan gent is,
4
4
2 x t
t
t
8
A 0, & B 2t1 0
t
P t1 t
B
1 8
2t 8
2 t
4K 8 k 2.
Area
3.
1
2
2 3 25
CE a b
DE
16
16
C2
CE
1
DE
4.
5
10 1
f K 1 x dx f x dx f x 1 dx.......... f x 9
K 1 0
putting x 1 t, x 2 t............ x 9 t
1
10
f x dx f x dx f x dx.......... f x dx
0
10
f x dx 5.
0
5.
7
Every ball have two options
4 balls can be put in 24 ways.
Arrangement among themselves in 2!
1
24 23
2!
But, above count also includes the one case in which all the balls are put in one box,
Required number of ways = 23 1 = 7.
6.
2
3
K 1 K 2 K 3
K 1 K 2 K 3
1
K 2
K 2

Aits FT I (Paper 1) PCM (Sol) Jee (Advanced)

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1

ALL INDIA TEST SERIES

vertical component after collision eucos

r1 2R sin30o , r2 2R sin 60o R 3 R

int ercept on m axis 1 & tan

Thermal heat capacity, C

Hmax allowed 5m,

Repeat last two step

K1 & K 2 are eq. cons tan t

K1 & K 2 are rate cons tan t

Due to greater probability of losing -H (9 : 3 ratio).

Number of moles of Al produced

Number of moles of electrons used 3 0.166

Number of moles of H2 produced

Volume of H2 produced 1.5 0.166 22.4 5.57 5.6

on converting into virial equation from, we get

For Boyles temperature, 2nd virial co-efficient becomes zero

A r ,B p,t , C q,s D q,s .

Solving Differential equation

Now, OQ2 MQ2 OQ2 OQ OM

2sin 4 4 cos 2 sin 2

4 sin 2 2cos 1 cos2

or AOB BOC COA AFE

Let D.C' s of required line be ,m,n

Hence, cos cos cos y cos2

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