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Free Energy for

solutions of polymers

References

Equilibrium Thermodynamics

With the realtions between the enthalpy


and entropy of the mixture, they proposed the next equation for the description of free energy:
Gm=kT[(n1ln 1 + n2 ln2)+n12]
1.

In which:
= parameter of interaction ofFloryHuggings. This parameter is the adimensional quantity that defines the energy of
interaction of polymers and dissolvent
molecules.

depa.fquim.unam.mx/amyd/archivero/
TEORIADEECUACIONESDEESTADO
_3411.pdf

= volume fractions

2.

T= temperature

Activity
For the vinculation of
measurable quantities of the expressions of
Flory-Huggings, we can differientiate the
equation of the free energy of mixture with
respect to n1, for the chemical potential, and
then relate it to the activity.

Song, Ya. & Sadus, R. (2000,


January). Equations of State for the
Calculation of Fluid-Phase Equilibria.
AlChE, 46, 169-196. 2015,
October 02. School of Information
Technology. Retrieved from: http://

La teora de Flory-Huggings en la
ingeniera de soluciones y mezclas
de polmeros (2008). Retrieved
form: http://www.izt.uam.mx/
newpage/contactos/anterior/n68ne/
polimeros-v4a.pdf

Redlich-Kwong
and
Flory-Huggings
Equation of state

So, this is the expression for activity of the


disolvent:

Team:
And the polymer:
ITESM CEM
Professor: Yara Almanza
Group 2

Ana Laura Sandoval Hernndez

A01372751

Lesly Gabriela Mendoza Lpez

A01168196

Mara Andrea Mendoza Garca

A01410878

Aline Ximena Zanela Lomeli

A01373960

Jacqueline Aguilar Lechuga

A01372769

Redlich-Kwong
Equation of state
The Redlich-Kwong EOS relates temperature, pressure, and volume of gases; it is generally more accurate than
van der Waals and the ideal gas equation at temperatures above the critical
temperature. [1]And its represented
by:

It retains the original van der Waals


hard-sphere term with the addition of a
tem-

perature-dependent attractive term.

The RedlichKwong equation is


adequate for calculation of gas phase
properties in different substances
when the ratio of the pressure to the
critical pressure (reduced pressure) is
less than about one-half of the ratio of
the temperature to the critical temperature (reduced temperature):

the solvent of molecules and the


polymer-polymer interaction.

In order to predict a thermodynamic


behavior of a polymer solution, is

In mixtures (vapour-liquid), this EOS


is needs to have an adjustment in the
value of interaction paramater in the
mixing rule for a term for the accuracy of the prediction of critical properties.

necessary to have an expression for


the free energy of mixing from their
molecular states of the system.

Each contact of the pure polymer and


pure solvent involves an energy
change.

Flory Huggings

For the thermodynamic analysis of


the polymeric solutions, we requires
the calculation of the entropy and
enthalpy of the mixture, and with

This theory refers to the solvent of


molecules and the polymer-polymer
interaction, and consider a interaction parameter that gives a measure
of the interactios between the polymer chains, [2]

theresults, we can deduce the free


energy associated and the activity of
each species. From there, we can
vinculate the theory with measurable
properties.
Using a net modelling, we can see the
Flory-Huggins approach

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