PT. ASIA KAOLINRAYA
J, Raya Badau Km. 12 Buluh Tumbang
Tanjung Pandan - Belitung
INDONESIA
MATERIAL SAFETY DATA SHEET
Section 1. Material Identity
Product Trade Name(s) : Activated Kaolin Clay
Common Name(s) : Activated Kaolin Clay, Activated China Clay
Chemical Name Hydrous Aluminum Silicate
CAS No 70131-50-9
Physical Form : White Powder
Chemical Formula : Al2Si205(OH)4
HMIS Ratings
Health Hazard oa
Flammability 20
Reactivity 0
Max. Personal Protection :E
Manufacturer's Name & Address : PT Asia Kaolinraya, Jin. Raya Badau Km 12, Tanjung
Pandan, Belitung
Emergency Telephone 62-21-645 9781/2
Section 2. Ingredients and Hazards
Ingredient Wt.% (Approx) CASNo OSHAPEL* ACGIH TLV*
Kaolin Al2Si205(OH)4 > 98% . 2 mg/m Resp.
15 mgim3 Total
Water <2%
* Unless otherwise noted, all PEL and TLV values are reported as 8 hour time weighted
averages (TWA).
Section 3. Hazards Identification and Cautions
Appearance White Powder
Primary Routes of Entry _: Skin contact, skin absorption, eye contact, ingestion;
Hazard Classification — None (Historical basis for classification).
Target Organs : Eye, skin and lungs
Medical Conditions Aggravated by Exposure : Skin contact may aggravate existing
dermatitis. Breathing excessive quantities of dust may aggravate pre-existing
respiratory conditions.
Potential Health Effects
Eye Contact : This product may produce irritation upon contact with the
eye. See also Section 4 below.
EC Sa Ye eeePT, ASIA KAOLINRAYA
JI, Roya Badau Km. 12 Buluh Tumbang
Tanjung Pandan - Belitung
INDONESIA
Skin Contact Prolonged or repeated exposure may cause skin irritation.
Material is not expected to be absorbed through the skin in
harmful amounts or to produce an alllergic skin reaction. See
also Section 4 below.
Ingestion No adverse effect is expected. If ingested, seek medical
advice. See also Section 4 below
Inhalation The raw material for Activated Kaolin CAS No. (70131-50
-9). Inhalation of excessive quantities of kaolin dust may
irritate the respiratory tract. Prolonged exposure to respirable
kaolin dust without use of appropriate respiratory equipment
could adversely affect respiratory function including
fibrogenic response.
Sub-chronic Chronic _: None expected. No applicable information was found
concerning any potential effects resulting from sub-chronic
or chronic exposure to kaolin
Section 4. First Aid Measures
Eye Contact : Follow good industrial hygiene practices. In case of contact,
immediately flush eyes with plenty of water. Seek medical
aid if necessary.
Skin Contact : Follow good industrial hygiene practices. Wash affected
skin areas thoroughly with soap and water. Seek medical aid
if necessary
Inhalation Follow good industrial hygiene practices. If excessive
exposure by inhalation is suspected, remove to fresh air.
Seek medical aid if necessary
Ingestion Follow good industrial hygiene practices. If ingested, do not
induce vomiting. If conscious, drink two glasses of water.
Seek medical aid if necessary.
Section 5. Fire Fighting Measures
Explosion Data Not Explosive Flammability : Not Flammable or Combustible
LEL Not Applicable Flash Point: Not Applicable
UEL Not Applicable Auto-Ignition : Not Applicable
Extinguishing Media: Product will not burn
NFPA 704M Hazard Classification Health: 1 Flammable : 0 Reactivity : 0
Use appropriate extinguishing media for packaging material if applicable.
Gieseesiabeies dibieenPT. ASIA KAOLINRAYA
J, Roya Badau Km. 12 Buluh Tumbang
Tanjung Pandan - Belitung
INDONESIA
Section 6. Accidental Release Measures
Vacuum, pump or scoop spilled material into containers for reclaiming or disposal. Use
proper respiratory and personal protective equipment. Spilled material may cause
slippery conditions when wet. Care should be exercised when walking on spills on floors
or concrete pads. No neutralizing chemicals required. Material is inert and non-reactive.
Section 7. Handling and Storage
Storage in a cool, dry location is recommended. Spilled material may cause slippery
conditions when wet. Care should be exercise when walking on spills on floors or
concrete pads. Minimized dust generation & accumulation. If excessive dust is
generated, provide adequate ventilation and use proper respiratory and personal
protective equipment. MSHA/NIOSH or OSHA/NIOSH approved respirator
recommended.
Section 8. Exposure Controls/Personal Protection
OSHA Permissible Exposure Limit or ACGIH Threshold Limit Values The Raw material
for Activated Kaolin CAS No. (70131-50-9). MSHA/OSHA and ACGIH values for
“Activated Kaolin” are as follows :
Hazardous Ingredient Weight %(Approx.) CAS No. MSHA PEL OSHA PEL ACGIH TLV
1332-58-7 10mg/cu.m. Total 15mg/cu.m Total 2mg/cu.m.5mg/cu.m Resp.
Respirable
Unless otherwise noted, all PEL and TLV values are reported as 8 hour time weighted
averages (TWA)
Respiratory Protection If respirator is required, use of a MSHA/NIOSH or
OSHAV/NIOSH approved respirator is recommended.
Ventilation : Use exhaust ventilation, if required, to maintain dust
concentration below recommended exposure limits.
Protective Equipment : Wear side shield safety glasses. Rubber gloves are
recommended for prolonged exposure.
TLV: (particulate matter containing no asbestos and <1% crystalline silica) (Respirable
fraction) 2 mg/m? as TWA; A4 (not classifiable as a human carcinogen)
Section 9. Physical and Chemical Properties
Physical State : Solid Boiling Point Not Applicable
Appearance & Odor: Odorless, White Powder Freezing Point Not Applicable
pH (aqueous Suspension) : 4.0 — 8.0 Vapor Pressure —_: Not Applicable
Specific Gravity ~26 Vapor Density Not Applicable
% Solubility In Water Insoluble voc None
Melting Point Not Determined, >1,500C Evaporation Rate _: Not Applicable
Correspondence Address :PT. ASIA KAOLINRAYA
J, Rayo Badau Km. 12 Buluh Tumbang
Tanjung Pandan - Belitung
INDONESIA
Section 10. Stability and Reactivity
Chemically Stable ? Yes X No _Inertand non-reactive.
Compatible with Other Substances? Yes X No __ Inert and non-reactive.
Hazardous Decomposition/By-Products : No hazardous decomposition or byproducts
expected. Inert and non-reactive.
Conditions Contributing to Hazardous Polymerization : None, inert and non-reactive
Section 11. Toxicological Information
Kaolin — The raw material for Activated Kaolin CAS No. (70131-50-9)
Primary Route of Exposure: X Skin; X Eye Contact; X Inhalation;
Ingestion
Acute Health Hazards :
Eye contact may cause mechanical irritation if exposed to excessive amounts of kaolin.
Skin contact may aggravate existing dermatitis
Inhalation from prolonged and continuous exposure to excessive quantities of dust may
aggravate existing asthmatic or respiratory conditions. No adverse effect expected
when ingested.
Chronic Health Hazards
Prolonged inhalation of excessive levels of kaolin dust may cause a simple
pneumoconiotic condition, not normally associated with a decrement in lung function. In
cases of long term exposure to extremely high levels of dust, complicated
pneumoconiosis with lung function impairment may occur.
Carcinogenicity: NTP? No IARC? No OSHA? No
Mutagenicity None known —_Teratogenicity : None known
Reproductive Effects None known
Section 12. Transport Information
EPA Waste Number : Not Regulated
DOT Classification : Not Regulated
DOT/IMO Classification _: Not Regulated
Internal UN : Not regulated
13. Ecological Information
Ecotoxicity Not available.
BOD5 and COD — : Not available
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term
degradation products may arise.
Correspondence Address :PT. ASIA KAOLINRAYA
JI. Roya Badau Km. 12 Buluh Tumbang
Tanjung Pandan - Belitung
INDONESIA
Toxicity of the Products of Biodegradation: The product itself and its products of degradation
are not toxic.
Special Remarks on the Products of Biodegradation: Not available.
14, Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and
approved waste disposal facility. Processing, use or contamination of this product may change
the waste management options. State and local disposal regulations may differ from federal
disposal regulations. Dispose of container and unused contents in accordance with federal,
state and local requirements.
45. Regulatory Information
——-—-\Chemical Inventory Status - Part 1\—--——-
Ingredient TSCA EC Japan Australia
Activated Kaolin (70131-50-9)
Yes No Yes Yes
-\Chemical Inventory Status - Part 2\-
~Canada:
Ingredient Korea DSL NDSL Phil.
Activated Kaolin (70131-50-9) Yes No Yes Yes
Federal, State & International Regulations - Part 1\——-
-SARA 302- SARA 313——
Ingredient RQ TPQ List Chemical Catg
Activated Kaolin (70131-50-9) No No No No
\Federal, State & International Regulations - Part 2\-——-
-RCRA- -TSCA-
Ingredient CERCLA 261.33 8d)
Activated Kaolin (70131-50-9) No No No
Chemical Weapons Convention: No TSCA 12(b): No CDTA: No
SARA 311/312: Acute: Yes Chronic: No Fire: No Pressure: No
Reactivity: No (Pure / Solid)
Australian Hazchem Code: None allocated,
Poison Schedule: None allocated.
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products
Regulations (CPR) and the MSDS contains all of the information required by the CPR.
Correspondence Address :PT. ASIA KAOLINRAYA
J}, Raya Beda Km. 12 Buluh Tumbang
Tanjung Pandan - Belitung
INDONESIA
16. Other Information
NFPA Ratings: Health: 0 Flammability: 0 Reactivity: 0
Label Hazard Warning:
CAUTION! NUISANCE DUST. MAY CAUSE IRRITATION TO RESPIRATORY AND G.I.
TRACT.
Label Precautions:
Use with adequate ventilation
Keep container closed.
Avoid breathing dust.
Avoid contact with eyes, skin and clothing
Wash thoroughly after handling.
Label First Aid:
If inhaled, remove to fresh air. Get medical attention for any breathing difficulty. In case of
contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Get medical
attention if irritation develops or persists.
Product Use:
Laboratory Reagent
The information contained herein is provided in good faith but makes no representation
as to its comprehensiveness or accuracy. This document is intended only as a guide to
the appropriate precautionary handling of the material by a properly trained person
using this product. Individuals receiving the information must exercise their independent
judgment in determining its appropriateness for a particular purpose.
Date Prepared March 22, 2006
Revised 1st February 21, 2012
Revised 2" 14 August, 2012
Correspondence Address :