FORMULARIO FISICOQUIMICA II

dG=SdT +VdP

x+ x 2=1
P=( 1x 2) P

~
d=V dP

P=x P 0

P=( 1x 2x3 ) P0
=
0

RT . ln (x2 )
~
V

P P
DR=
P0

%DR=

RT . lnx
~
V

~
=RT C

P P
100
0
P

=hg=P HIDR

ln

G=G +nRT . ln (P)

P 2 H VAP 1 1
=

P1
R
T T0

= 0+ RT . ln(P)

x 2=

y 2 Ptotal
P02

sol, LIQ =oLIQ , puro + RT . ln (x)

H VAP 1 1
lnx=

R
T T0

T =Kb . m2
M RT 20
Kb=
H VAP

P0 P20

Ptotal VL=

P02 + y 2 ( P0P02 )

Ptotal VV =P0 + x 2 ( P02P0 )

BL

BV

ntot(vap ) ntot (liq)

0

T =Kf . m

M RT 20,b
Kf =
H VAP

y 2=

x 2=

x 2 P2
0

P + ( P2P ) x 2
y2 P
0

0
0

P2 ( P2 P ) y 2

M RT 0, f
Kf =
H FUS

V real =V n+ V 2 n 2+ V 3 n3 +..

dG=SdT +VdP + k d k

i
P

( )

T , nk

T , nk

ai =

V i

Gmez = H mez T S mez

G mez
P

Smez =R nk ln x k

=V mez

Gmez =RT nk ln x k

Pi
P

ai= i X i o i mi

i=

RT 1 V i
O
K i PM V 1

Pi=K i X i o K i m