ppm P

A
2130
4260
6400
8530

slope=
intersep=

0.250
f(x) = 2.85382392467215E-005x - 0.0118588152
0.200
R = 0.9995517239
0.150
0.100

2.85E-05
-0.0119

A_sampel=
0.135
C_Sampel=(A_sampel-intersep)/slope
C_Sampel=
5146
C_Sampel=
5150
Intrapolasi:
dy1=
dx1=
dy2=
dx2=x-

0.050

x=
C_Sampel=

0.000
0

2000

4000

6000

8000

10000

0.048
0.110
0.173
0.230

0.063
2140
0.025
4260
5109
5110

massa sampel=
2.469
massa P dalam sampel= V*ppm
Vol=
100
=
0.1000
mg P dalam sampel=
mg Na2HPO4= Mr_Na2HPO4/Ar*P*mg_P
Mr Na2PO4=
141
Ar P=
31
mg Na2HPO4=
2342.4193548
2340
Kemurnian Na2HPO4=
=g Na2HPO4/g_sampel*100

intersep)/slope
ppm
ppm

ppm
g
mL
L

515 mg
2HPO4/Ar*P*mg_P

mg
mg=
94.78%

2.34 g

ppm Cu A
0.000
0.200
0.500
1.000
2.000

A-koreksi
0.007
0.014
0.036
0.072
0.146

0.007
0.029
0.065
0.139

slope=
0.071042
intersep= 0.002429
A_sampel=
0.027
ppm_sampel=
0.346
200 mL sampel --> 500 mL
ppm_Cu dalam sampel asli= 500/200*ppm_Cu
=
0.865 ppm

b)
blanko
sampel=
s+0,2
s+0,5
s+1

sampel 200 mL --> 50 mL

0
0.2
0.5
1

0.001
0.045
0.083
0.118
0.192

slope=
0.143524
intersep= 0.047502
sampel= intersep/slope=
"aslinya"= 50/200*ppm Cr=

ppm

el asli= 500/200*ppm_Cu

0 mL --> 50 mL
koreksi
0.044
0.082
0.117
0.191

0.331 ppm
0.083 ppm

Standar (mikrogram) Absorbansi

0
0.223
6.25E-06
0.294
1.25E-05
0.361
slope=
11040
intersep=
0.224
mikrogram Mn dalam 2,5 mikroliter sampel= intersep/slope=
=
2.03E-05 mikrogram
mikrogram Mn dalam 1 L air laut=
4.05E+01 mikrogram
=
40.5 ppb= mikrogram/L
Jadi konsentrasi Mn2+ dalam sampel air laut=
40.5 ppb

Sampel
A
28.6
28.2
B
40.7
41.2
C
73.1
72.1
BLANGKO
5.1
4.8
KOREKSI BLANKO
A
23.5
23.4
B
35.6
36.4
C
68
67.3

28.9
40.2
4.9
24
35.3

KONSENTRASI
22.1
22.0
35.2
36.1
70.5
69.7

mikrogram/mL larutan =ppm

Rerata
Sdev
22.6
22.2
0.35
34.9
35.4
0.62
70.1
0.54
dalam 100 mL larutan sampel (m
2.22
0.03
3.54
0.06
7.01
0.05
%Na2O= mg Na2O/1000*1/1 g*100
0.22% 0.003%
0.35% 0.006%
0.70% 0.005%

90
80
70
60
50

f(x) = 0.92x + 3.18

R = 0.9991830876
Column L

40
30
20
10
0

Linear (Column
L)

20 40 60 80 100

g Na2O

R
0
20
40
60
80

3.1
21.5
40.9
57.1
77.3

SUMMARY OUTPUT
Regression Statistics
Multiple R 0.999591
R Square
0.999183
Adjusted R 0.998911
Standard Err 0.960555
Observation
5
ANOVA

df
SS
MS
F Significance F
/mL larutan =ppm
Regression
1
3385.6
3385.6 3669.364 9.91E-006
RSD
Residual
3
2.768 0.922667
1.6% Total
4 3388.368
1.7%
0.8%
Coefficients
Standard Error t Stat
P-value Lower 95%Upper 95%
Lower 95,0%
Intercept
3.18 0.744043 4.273946 0.023517 0.812123 5.547877 0.812123
mL larutan sampel (mg Na2O
0.92 0.015188 60.57528 9.91E-006 0.871666 0.968334 0.871666
1.6%
1.7%
0.8% slope=
0.92
intersep=
3.18
mg Na2O/1000*1/1 g*100
sampel

Upper 95,0%
5.547877
0.968334

90
80

f(x) = 9.2x + 3.18

f(x) = 9.2x + 0.08
R = 0.9991830876
R = 0.9991830876

70
60

Column I
Linear (Column I)
terkoreksi
Linear (terkoreksi)

50
40
30
20
10
0

ppm K2Cr2O7
0
2
4
6
8
terkoreksi
slope=
intersep=
blanko
5.1
4.8
4.9

ppm Cr2O7 dalam 100 mL larutan samp

ppm Cr2O3 = Mr Cr2O3/Mr K2Cr2O7*p

faktor=

massa Cr2O3 = ppm Cr2O3*100*1E-6 (

%Cr2O3

Rerata
stdev=

R'
3.1
21.5
40.9
57.1
77.3

0
18.4
37.8
54
74.2

9.2000
0.08
A

B
28.6
28.2
28.9

C
40.7
73.1
41.2
72.1
40.2 spilled

Cr2O7 dalam 100 mL larutan sampel=

2.55
3.86
7.38
2.53
3.95
7.31
2.60
3.83
Cr2O3 = Mr Cr2O3/Mr K2Cr2O7*ppm K2Cr2O7
0.5170068027
1.32
2.00
3.82
1.31
2.04
3.78
1.34
1.98
sa Cr2O3 = ppm Cr2O3*100*1E-6 (g)
0.0001316119
0.0002 0.000382
0.00013105 0.000204 0.000378
0.0001344218 0.000198
0
0.013%
0.013%
0.013%

0.020%
0.020%
0.020%

0.038%
0.038%

0.013% 0.020% 0.038%

0.0002% 0.0003% 0.0003%

45000

40000

40021

f(x) = 2752.72x + 12590.6

R = 0.9997500089

35000

30000
26622
25000
Column J
Linear (Column J)

20000

19324

15000
12568
10000

5000

0
0

10

12

Au std
0
2.5
5
10
SUMMARY OUTPUT
Regression Statistics
Multiple R
R Square
Adjusted R
Standard E
Observatio
ANOVA
Regression
Residual
Total
Coefficients
Intercept
Au std

ppm Au sampel dalam 100 m

=intersep/slope
=
Dalam 50 mL larutan sampel
9.15
sesungguhnya=

I
12568
19324
26622
40021

SUMMARY OUTPUT

Regression Statistics
0.999875
0.99975
0.999625
227.6185
4

df

SS
MS
F Significance F
1 4.1E+008 4.1E+008 7998.285 0.000125
2 103620.4 51810.2
3 4.1E+008

Coefficients
Standard Error t Stat
P-value Lower 95%Upper 95%
Lower 95,0%
Upper 95,0%
12590.6 176.3126 71.41068 0.000196 11831.99 13349.21 11831.99 13349.21
2752.72 30.77964 89.43313 0.000125 2620.286 2885.154 2620.286 2885.154

ppm Au sampel dalam 100 mL larutan=

=intersep/slope
4.57 ppm
Dalam 50 mL larutan sampel yang "asli" =
ppm

sesungguhnya=

8.51 ppm