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  • Determination of Acid Dissociation Constant: F (X) 1.0177282162x + 4.7906801696 R 0.9995476139

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    Christine Angelica Evangelista
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    CALCULATIONS OF EXPERIMENT 10

    Titolo originale

    Experiment 10

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    CALCULATIONS OF EXPERIMENT 10

    Copyright:

    © All Rights Reserved
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    6 visualizzazioni4 pagine

    Determination of Acid Dissociation Constant: F (X) 1.0177282162x + 4.7906801696 R 0.9995476139

    Caricato da

    Christine Angelica Evangelista
    CALCULATIONS OF EXPERIMENT 10

    Copyright:

    © All Rights Reserved
    Scarica in formato XLS, PDF, TXT o leggi online su Scribd
    Segnala contenuti inappropriati
    di 4

    Molarity of Solutions

    Solution
    Concentration
    stock methyl red
    0.0037029335
    std methyl red
    0.0001851467
    HMR
    0.0000185147
    MR0.0000185147
    1
    0.000014
    2
    0.000009
    3
    0.000005
    4
    0.000014
    5
    0.000009
    6
    0.000005

    0.507
    0.649
    0.829
    0.54
    1.192
    0.371
    1.416
    0.288

    214.3303
    15646.1107
    214.3303
    15646.1107
    214.3303
    15646.1107
    214.3303
    15646.1107

    Determination of Molar Absorptivity Constant


    Solution Number HMR
    MR1
    0.45
    0.035
    2
    0.304
    0.027
    3
    0.182
    0.019
    4
    0.014
    0.195
    5
    0.014
    0.124
    6
    0.012
    0.049
    Determination of Acid Dissociation Constant
    Solution Number pH
    HMR
    MR7
    5.16
    0.507
    0.649
    8
    4.82
    0.829
    0.54
    9
    4.46
    1.192
    0.371
    10
    4.2
    1.416
    0.288
    28720.2580
    1714.6423
    28720.2580
    1714.6423
    28720.2580
    1714.6423
    28720.2580
    1714.6423

    214.3303
    15646.1107
    214.3303
    15646.1107
    214.3303
    15646.1107
    214.3303
    15646.1107

    28720.2580
    1714.6423
    28720.2580
    1714.6423
    28720.2580
    1714.6423
    28720.2580
    1714.6423

    0.507
    0.649
    0.829
    0.54
    1.192
    0.371
    1.416
    0.288

    DETERMINATION OF ACID DISSOCIATION CONSTANT


    6
    5

    f(x) = 1.0177282162x + 4.7906801696


    R = 0.9995476139
    4
    pH

    3
    2
    1
    0
    -0.8

    -0.6

    -0.4

    -0.2

    log ([MR-]/[HMR])

    0.2

    0.4

    0.6

    HMR
    MR-

    HMR
    MR28720.2580 1714.6423
    214.3303 15646.1107

    c, HMR
    1.735769E-05
    2.863050E-05
    4.136068E-05
    4.920605E-05

    c, MR3.957774E-05
    3.137578E-05
    1.917929E-05
    1.301469E-05

    pKa= 4.7907
    Ka=

    0.000016192

    log [MR-]/[HMR]
    0.35795915
    0.03976568
    -0.3337552
    -0.5775848

    E HMR at ,\HMR
    0.5
    0.45
    0.4
    0.35

    f(x) = 28720.2579922195x + 0.0461269841


    R = 0.9973339258

    A HMR

    0.3
    0.25
    0.2
    0.15
    0.1
    0.05
    0
    0.000004

    0.000006

    0.000008

    0.000010

    0.000012

    0.000014

    0.000016

    0.000014

    0.000016

    E MR- at ,\HMR
    0.0145
    0.014

    A HMR

    0.0135

    f(x) = 214.330283524x + 0.0113492063


    R = 0.75

    0.013
    0.0125
    0.012
    0.0115
    0.011
    0.000004

    0.000006

    0.000008

    0.000010

    0.000012

    014

    0.04
    0.035
    0.03

    f(x) = 1714.6422681922x + 0.0111269841


    R = 1

    A MR-

    0.025
    0.02
    0.015
    0.01
    0.005
    0
    0.000004

    0.000016

    0.000006

    0.000008

    0.000010

    0.000012

    0.000014

    0.000016

    E MR- at ,\MR0.25
    0.2
    0.15

    A MR-

    014

    E HMR at ,\MR-

    f(x) = 15646.1106972539x - 0.0221746032


    R = 0.9997498593

    0.1
    0.05

    0.000016

    0
    0.000004

    0.000006

    0.000008

    0.000010

    0.000012

    0.000014

    0.000016

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