.

2 Equilibrium

Warm Up

How do you obtain balance in your life?

Reaction Rates

Clicker Quiz

Kinetics and
Equilibrium

11.1 Reaction Rates

11.2 Equilibrium

2 Equilibrium

Clicker Quiz #1

What do reactants require for a chemical

reaction to take place?
A) Sufficient energy and stability
B) Sufficient energy and orientation
C) Stability and orientation
D) High temperature and low pressure

.2 Equilibrium

Clicker Quiz #2

Powdered magnesium will react faster with

hydrochloric acid compared to large pieces because

A) It has a higher concentration

B) It acts as a catalyst
C) It has higher collision energy
D) It has a higher surface area

.2 Equilibrium

Clicker Quiz #3

Which segment represents activation

energy?

.2 Equilibrium

Clicker Quiz #4
The following reaction is
A) Exothermic B) Endothermic

.2 Equilibrium

Clicker Quiz #5

According to Table I in the Chemistry Reference Tables, the formation of C 2H6(g) from
its elements is
A) Exothermic B) Endothermic

1.2 Equilibrium

Reflect

What has improved from last class?

What do you want to get better at doing?

1.2 Equilibrium

Notes

11.2 Equilibrium
Essential Question: What makes a
reaction spontaneous?
Mastery Skill: I can predict shifts
in equilibrium concentrations.

1.2 Equilibrium

Notes

Reversible Reactions
conversion of reactants to products and vice
versa occur at the same time.
Forward Reaction: 2SO2(g) + O2(g)

2SO3(g)

Reverse Reaction: 2SO2(g) + O2(g)

2SO3(g)

Equilibrium Reaction: 2SO2(g) + O2(g)

2SO3(g)

1.2 Equilibrium

Notes

Before Equilibrium

Equilibrium Established

How is this a dynamic equilibrium?

1.2 Equilibrium

Notes

Stressing the System

Le Chatelier's principle: If stress is applied to
a system in dynamic equilibrium, the system
adjusts to counteract the change.

Concentration!
Temperature!
Pressure/Volume!
Exception!! Pure liquids and solids do not affect equilibrium!

1.2 Equilibrium

Notes

e: C3H8(g) + 5O2(g)
Effect
If you..
Reaction
Increase CH
4
Reaction
Increase CO
2
Decrease
H2Reaction
O
Reaction
Increase heat
Reaction
Increase pressure

3CO2(g) + 4H2O(g) + e

shifts
shifts
shifts
shifts
shifts

to
to
to
to
to

the right
the left
the right
the left
left

1.2 Equilibrium

#1

Which factors must be equal in a reversible

chemical reaction at equilibrium?

A.the activation energies of the

forward and reverse reactions
B. the concentrations of the
reactants and products
C. the rates of the forward and
reverse reactions
D.the potential energies of the
reactants and products

1.2 Equilibrium
#2
Which two factors must be equal when a
chemical reaction reaches equilibrium?

A. the concentration of the reactants and

the concentration of the products
B. the rate of the forward reaction and
the rate of the reverse reaction
C. the number of reactant particles and
the number of product particles
D. the mass of the reactants and the
mass of the products

1.2 Equilibrium

#3

Given the reaction at equilibrium:

What occurs when the concentration of
H2(g) is increased?
A.The rate of the forward reaction
increases and the concentration of N 2(g)
decreases.
B. The rate of the forward reaction and the
concentration of N2(g) both increase.
C. The rate of the forward reaction
decreases and the concentration of
N2(g) increases.
D.The rate of the forward reaction and the
concentration of N2(g) both decrease.

1.2 Equilibrium

#4

Given the reaction:

Once equilibrium is reached, which
statement is accurate?

A.The concentration of Ag+(aq) is

greater than the concentration of
Cl-(aq).
B. The rates of the forward and
reverse reactions are equal.
C. The AgCl(s) will be completely
consumed.
D.The entropy of the forward
reaction will continue to decrease.

1.2 Equilibrium

#5
Given the reaction at equilibrium:

Which change will result in adecreasein the amount of NO(g) formed?

A. Increase pressure
B. Decrease concentration of N2
C. Increasing the concentration of O 2(g)
D. Increasing the temperature

1.2 Equilibrium

#6

Given the reaction at equilibrium: . . .

Which change will cause the equilibrium
to shift?

A. Increase in pressure
B. Increase in volume
C. Addition of heat
D. Addition of a catalyst

1.2 Equilibrium

#7

Given the reaction at equilibrium:

The concentration of A(g) can be
increased by

A.lowering the temperature

B. increasing the concentration
ofAB(g)
C. adding a catalyst
D.increasing the concentration
ofB(g)

1.2 Equilibrium

#8

Given the equilibrium reaction in a closed

system as shown:

What will be the result of an increase in

temperature?
A.The equilibrium
will shift to the

left and [H2] will increase.

B. The equilibrium will shift to the
right and [HI] will increase.
C. The equilibrium will shift to the
left and [H2] will decrease.
D.The equilibrium will shift to the
right and [HI] will decrease.

Equilibrium Position

.2 Equilibrium

Reflect

11.2 Mastery Skill: I can predict

shifts in equilibrium
concentrations.
Profession Practition Apprentic Novice-1
Quantity

al-4

er-3

e-2

Most-All
questions
answered
correctly

Most-All
questions
answered
correctly

Some-Most
questions
answered
correctly

Few-No
questions
answered
correctly

Some
annotation or
problem
solving, but not
much.

Very little
besides final
answer is
written.

Work is
incomplete.

Descript Annotating and

problem solving
ion
always used.

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