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Chapter 3
= 9.23 x
molls
nH2 = 9.23 x
moVs
0.0287
--
xN2
Similarly,
0.0287
=-
1
I
XH2
XN1
0 (end 1)
5
10
15 (end 2)
0.800
0.617
0.433
0.250
-%I
0.200
0.383
0.567
0.750
VN*
,CII~/S V H ,~cm/s
0.035 1
0.0465
0.0663
0.1148
-0.1435
-0.0749
-0.0506
-0.0383
Note that species velocities vary across the length of the connecting tube, but at any location, z, V M = 0. For example, at z = 10 cm,
from (3-8),
Unimolecular Diffusion
In unimolecular diffusion (UMD), mass transfer of component A occurs through stagnant (nonmoving) component B.
Thus,
NB = 0
(3-24)
N = NA
(3-25)
= 1 - (1 - X A ~
exp
) [NA2biZ1)]
Thus, as shown in Figure 3.lb, the mole fractions are nonlinear in distance.
An alternative and more useful form of (3-31) can be
derived from the definition of the log mean. When z = 22,
(3-3 1) becomes
The log mean (LM) of (1 - xA) at the two ends of the stagnant layer is
and
(3-32)