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Unit 10: Kinetics

Clicker Quiz 3
Use experimental data to:
Determine order of reaction
Determine rate constant
Relate reaction order to rate
laws:
Perform rate calculation with respect
to reactant concentration and time
Quantify concentrations using

What is the order of the reaction with respect to N2?

6AgCl + N2 2Ag3N + 3Cl2


Experimen Initial Rate
Initial
Initial
t#
mol/(L s) concentrati concentrati
on
on
[AgCl]o
[N2]o
1
2
3
4

0.97
15.52
1.94
7.76

3.25x10-2
7.50x10-2
3.25x10-2
1.30x10-1

4.66x10-3
1.85x10-2
9.32x10-3
4.66x10-3

Numerical Answer (Whole number)

Needs to be fixed. AgCl order incorrect


data.

What is the order of the reaction with respect to AgCl?

6AgCl + N2 2Ag3N + 3Cl2


Experimen Initial Rate
Initial
Initial
t#
mol/(L s) concentrati concentrati
on
on
[AgCl]o
[N2]o
1
2
3
4

0.97
15.52
1.94
7.76

3.25x10-2
7.50x10-2
3.25x10-2
1.30x10-1

4.66x10-3
1.85x10-2
9.32x10-3
4.66x10-3

Numerical Answer (Whole number)

What is the overall order of the reaction?

6AgCl + N2 2Ag3N + 3Cl2


Experimen Initial Rate
Initial
Initial
t#
mol/(L s) concentrati concentrati
on
on
[AgCl]o
[N2]o
1
2
3
4

0.97
15.52
1.94
7.76

3.25x10-2
7.50x10-2
3.25x10-2
1.30x10-1

4.66x10-3
1.85x10-2
9.32x10-3
4.66x10-3

Numerical Answer (Whole number)

A reaction is found to be first order. If the


reactants initial concentration is
0.0020M, and the rate constant is
0.010s-1, how much reactant remains
after 24s?
Numerical Answer (Correct Sign and Sig Figs)

What is the order of the reaction with respect to N2?

6AgCl + N2 2Ag3N + 3Cl2


Experimen Initial Rate
Initial
Initial
t#
mol/(L s) concentrati concentrati
on
on
[AgCl]o
[N2]o
1
2
3
4

0.97
15.52
1.94
7.76

3.25x10-2
7.50x10-2
3.25x10-2
1.30x10-1

Numerical Answer (1)

4.66x10-3
1.85x10-2
9.32x10-3
4.66x10-3

What is the order of the reaction with respect to AgCl?

6AgCl + N2 2Ag3N + 3Cl2


Experimen Initial Rate
Initial
Initial
t#
mol/(L s) concentrati concentrati
on
on
[AgCl]o
[N2]o
1
2
3
4

0.97
15.52
1.94
7.76

3.25x10-2
7.50x10-2
3.25x10-2
1.30x10-1

Numerical Answer (2)

4.66x10-3
1.85x10-2
9.32x10-3
4.66x10-3

What is the overall order of the reaction?

6AgCl + N2 2Ag3N + 3Cl2


Experimen Initial Rate
Initial
Initial
t#
mol/(L s) concentrati concentrati
on
on
[AgCl]o
[N2]o
1
2
3
4

0.97
15.52
1.94
7.76

3.25x10-2
7.50x10-2
3.25x10-2
1.30x10-1

Numerical Answer (3)

4.66x10-3
1.85x10-2
9.32x10-3
4.66x10-3

A reaction is found to be first order. If the


reactants initial concentration is
0.0020M, and the rate constant is
0.010s-1, what is the concentration of
reactant after 24s?
Numerical Answer (0.0016M)

Heres your goal for the following


AP question.
Complete the question independently (Watch Timer)
Compare your answer with your table partner. Which
answer is more convincing and why? Choose the
best answer (Watch Timer)
Find another table and compare answers. Which
answer is more convincing and why? Choose the
best one. 75% of group must agree on the answer.
(Watch Timer)
ALL ANSWERS MUST COME WITH JUSTIFICATION
USING SCIENCE!

2006 #5

2006 #5
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Copy down the data Table

2006 #5

2003 #5

a.

b.
c.
d.

e.

f.

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