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AT
We use 'at' with places:
at the bus-stop
in a room / in a building
at the door
in a garden / in a park
at the cinema
in the water
in the sea
in a river
in a row / in a line
in a queue
ON
IMPORTANT NOTES
In / at / on the corner
on the table
In / at / on the front
We use 'on' with small islands:
I stayed on Maui.
We use 'on' with directions:
on the left
on the right
straight on