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Para el argn las constantes de van der Waals son a =1.363 L 2atm/mol2 y b = 0.03219 L
K, 75 K, 100 K, 150 K y 200 K para 2 moles de argn en el intervalo de volmenes de 0.0
Solucin:
a=
1.363 L2atm/mol2
b=
0.03219 L/mol
P.M =
39.948
n=
2 mol
m=
79.896
Ecuacin de Van Ver Waals
P - nRT/(V-nb) + an2/V2 = 0
R=
0.08205746
Latm/mol/K
P = n*R*T/(V-n*b)-(a*POTENCIA(n,2))/POTENCIA(V,2)
V/L
0.06
0.065
0.07
0.075
0.08
0.085
0.09
0.095
0.1
0.105
0.11
0.115
0.12
0.125
0.13
0.135
0.14
0.145
0.15
0.155
0.16
0.165
P/atm a 50K
P/atm a 100 K
-3387.9024
-5261.3604
11944.6600
25179.7342
347.4441
1807.5412
-196.5753
576.0938
-326.5391
198.7967
-356.6513
41.2996
-352.7997
-32.5130
-336.1132
-68.1268
-314.8309
-84.4619
-292.5000
-90.4876
-270.7068
-90.8352
-250.1447
-88.0399
-231.0788
-83.5465
-213.5643
-78.2006
-197.5541
-72.5046
-182.9537
-66.7580
-169.6504
-61.1375
-157.5273
-55.7443
-146.4720
-50.6329
-136.3791
-45.8280
-127.1525
-41.3363
-118.7053
-37.1534
P/atm a 150 K
-7134.8184
38414.8084
3267.6384
1348.7629
724.1326
439.2504
287.7738
199.8597
145.9072
111.5249
89.0365
74.0649
63.9858
57.1630
52.5448
49.4378
47.3755
46.0387
45.2063
44.7232
44.4799
44.3984
0.17
0.175
0.18
0.185
0.19
0.195
0.2
-110.9593
-103.8449
-97.2999
-91.2690
-85.7030
-80.5578
-75.7946
-33.2681
-29.6653
-26.3282
-23.2393
-20.3810
-17.7363
-15.2891
44.4231
44.5143
44.6434
44.7904
44.9410
45.0852
45.2163
P/atm a 200K
-9008.2764
51649.8826
4727.7356
2121.4320
1249.4684
837.2012
608.0605
467.8462
376.2762
313.5374
268.9082
236.1698
211.5181
192.5267
177.5943
165.6336
155.8884
147.8217
141.0454
135.2744
130.2961
125.9502
40000.0000
P/atm a 5
P/atm a 1
P/atm a 1
30000.0000
P (atm)
P/atm a 2
20000.0000
10000.0000
0.0000
0.05
-10000.0000
0.07
0.09
0.11
v (L)
0.13
0.15
0.17
10000.0000
122.1143
118.6939
115.6151
112.8202
110.2630
107.9067
105.7217
0.0000
0.05
-10000.0000
0.07
0.09
0.11
v (L)
0.13
0.15
0.17
Waals par a e l Ar gn
11
(L)
P/atm a 50K
P/atm a 100 K
P/atm a 150 K
P/atm a 200K
0.13
0.15
0.17
0.19
11
(L)
0.13
0.15
0.17
0.19