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Documenti di Professioni
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OF
PHYSICAL PROPERTIES
PROPERTIES OF
CHEMICAL
COMPOUNDS
CHEMICAL COMPOUNDS
A
A systematic tabular presentation of accurate data
on the physical properties of 511 organic cyclic
Dow
compounds compiled by R. R. Dreisbach of the Dow
Chemical Co. These comprehensive and basic data
were determined for specially prepared,
prepared, high purity
compounds. In addition to the precisely measured
properties the author has calculated new values for
many constants based upon his new experimental
values.
R.
PEPINSKY
Number
Number fifteen
fifteen of
of the
the Advances
Advances inin Chemistry
Chemistry Series
Series
Industrial and
Edited
Edited by
b y the
the staff
staff of
of Industrial
and Engineering
Engineering Chemistry
Published
P u b l i s h e d June
J u n e 1955
1955 by
by
AMERICAN
A M E R I C A N CHEMICAL
C H E M I C A L SOCIETY
SOCIETY
1155 Sixteenth Street, N.W.
N.W.
1155
Washington,
W a s h i n g t o n , D. C.
Copyright 1955
1955 by
by
AIIERlcAN CHEMICAL
AMERICAN
CHEMICAL SoCIETY
SOCIETY
All
Reserved
AU Rights
Rightll Ruervl
Physical Properties
Of Chemical Compounds
R. R. Dreisbach
Mol.
+ 0.4)
l)/(nfi + 2) X
"c"
X l/d =
M/d = MR at 20 C.
MR (calc.): Molal refraction calculated from atomic refractive indices. See page 9.
3
(nu - d/2): Refractivity intercept equals refractive index minus one half the density,
both at the same temperature, 20 C.
D: Dielectric constant run at a frequency of 1()6 (cycles/sec.) and at 25 C. unless otherwise noted. When reported as data of The Dow Chemical Co., error about
0.005. Where Reference 5 is noted it was obtained by squaring the refractive
index at 20 C.
A, B, C: Constants of the Antoine vapor pressure equation for the liquid state, giving P
(pressure) in mm. and t (temperature) in C. This is in the range between the
temperatures as indicated. These temperatures in general are the boiling point at
30 mm. to a TR of 0.75 to 0.80. See method of obtaining A, B, C on page 6.
Antoine equation: log P = A - B/(t + C)
A, B*, K, c, tk, tx: Constants of the saturated vapor density equation
log dy(g./ml.) = A* - B/(t + C) to the temperature tk
log dy(g./ml.) = A - B/(t + C) + K/(1.1 Tc - 273.2 - t) + c
from temperature h to a reduced temperature, Ta, of 0.92
tk = Temperature at which it is necessary to change from the simple vapor density
equation to the corrected vapor density equation in the higher ranges, C.
tk = tx + K/c and tx = (1.1 Tc - 273.2) C.
A* and B where the ls.tent heat at the atmospheric boiling point is available.
Vg - VL = (31381.7 X .1Hv X dt/dp)/T
Where the ls.tent heat is not avails.ble use
M(.1Hv)/TB = 21.0 and from this .1Hv = (TB X 21.0)/M
The value 21.0 (or any other value as 21.4 say) is obtained from the nearest rels.ted
compound which has a latent heat available. Then proceed as in case where ls.tent
heat is avails.ble for Vg value at B.P.
Since d. = l/Vg
log dY710 = A - B/(ta + C) at 760 mm.
log dY30 = A - B/(tao + C) at 30 mm.
Solve for A, B, since t and d. at 760 mm. and 30 mm. and C are known.
A', B/, C / : Constants of the Antoine vapor pressure equation below 30 mm. pressure,
covering the temperature range as indicated. See method of obtaining the constants
on page 6.
A', B/*: Constants of the vapor density equation below 30 mm. These two values are
obtained by using the boiling point at 30 mm. and the pressure at 25 C. (obtained
from the values A', B I, C ') and assuming that at 25 0 C. the rels.tionship PV/RT
= 1. Then we have Vg at 25 C. = RT/MP = 62,361 X (25 + 273.2)/MP.
Then dv = I/Vg. Inserting these values of vapor density we then solve the two
equations for the values of A' and B / as in the case of A and B.
Ac, Bc, Cc: Constants of the Antoine vapor pressure equation for the liquid state from
Ta = 0.75 (or a higher Ta as indicated) to the critical temperature. See method of
obtaining the constants on page 7.
Cryoscopic Constants, A 0, BO: Cryoscopic constants for calculs.ting mole % purity.
See J. Research Nall. Bur. Standards, 35 (1945); RP 1676.
t.O C.: Temperature at which a mole of the vapor occupies 22.414 liters and the vapor is in
equilibrium with the liquid, in 0 C.
te=
B*
-C
(A * - log dvo)
dt/dp: Rate of change of boiling point with pressure, given by equation dt/dp = B/
[2.3026 X P X (A - log P)2Jo C./mm.
~Hm: Latent heat of fusion in caL/g.
~Hv: Latent heat of vaporization at the temperature designated, caL/g.
t.(d, e): The latent heat of vaporization at the temperature to as given by the equation
~Hv = d - et, and indicates the accuracy of thiR equation at the temperature t .
~Hv/T.:
Ezplanation of the methods used for calculating the variom parameter. in the foregoing:
A, B, C: The A, B, and C constants, except where given by the API reports, are calculated by means of the Thomson method [Chem. Rev. , 38, 1-39 (1946)] using the
determined boiling points at three different pressures. The three formulas for this
are &8 follows:
(y, - YI)/(YI - YI)(tt - tM(t. - tt) =1 - (t. - tl)/(t. + C)
B = (Ya - YI)/(tt - tl)(tl + C)(ta + C) and
A = YI + B/(tl + C)
where Yh Y2, and y, are equal to log PI, log P"~ and log Paat temperatures t l, t " and ta.
Unless the data for the three points are very accurate the C value can be considerably
in error. As a check on this method an empirical formula developed by Thomson
(private communication from George W. Thomson) will give a much better value of
C if the data are much in error. This formula is C = 239 - 0.19b. The A and B
values can then be readily determined from the two points given, since they are much
less critical.
A', B', C' (for pressures below 30 mm.): Applicable when molar heats of vaporization are
available at 25 0 C. and the Antoine equation can be used to obtain the boiling point
at 30 mm. Let A, B, C be the constants of the usual Antoine equation valid above
30 mm. and let A', B', C' be the constants of the Antoine equation 8Oughtforbelow
30 mm. These two equations are taken to give the same value of the p~ure
temperature slope at 30 mm.
log 30 = A - B/(tl + C) = A' - B'/(tl + C')
B/(t ,
C)' = B'/(tl + C')2
Since th t2 and all values on left hand side of equations above are known then B' and
C' are readily obtained as follows:
[B'j(t! + C')2)[(tl + C')2/B') = g2 (tl + C'>,/B' = say, h 2
Then C' = (tl - ht2)/(h - 1) and B' = g2(t 2 + C')2
Also B' = B[(tl + C')/(tl + C)2
A' = log 30 + B'/(t. + C') since PI = 30 mm.
These formulas were developed with the aid of George Thomson.
When heal8 of vaporization at 25 C. are not knoum:
In this case the C' value is estimated and A' and B' are calculated from known data.
It was noticed that C' has a value approximately 18 higher than C when latent heats
at 25 C. are known. By adding this increment to C we have C', thenB' from the
relation for the first case
B' = B [(t30 + C')/(t3o + C)2
and then A' as in first case.
Ac, Bc, Cc: This method was developed by George Thomson [Chern. Re1J8., 38,
No.1, 23 (1946)] and is similar to the one for obtaining A', B', C'. It is assumed
that the parameters A, B, C of the Antoine equation are good to a T. 0.75 or a
higher reduced temperature, and this temperature corresponds to the 25 C. in the
case of A', B', C', and the critical point corresponds to the 30 mm. point.
B/(tl + C)2.(t. - tl)/(y. - YI) = 1 + (to - tl)/(tl + Cc)
and Bc = (y. - YI)/(t. - t.)(tl + Cc)(t. + Cc); Ac = B/(t. + Cc) + y.
where tl C. = T. 0.75, t. 0 C. = critical temperature
YI = log P at t l, y. = log P.
The first equation is used to evaluate Cc, the lrecond, Bc, and the third, Ac.
As.qociation: The association in the vapor phase of organic acids seems to vary inversely
as the temperature fOJ some acids, at least for part of the range. In part of the range,
and also apparently for some acids over the whole range, the association is fairly constant. The association is given in these sheets by the formula ME = P - rt. For
instance, for acetic acid this formula would be ME = 2.225 - 0.004085 t from 0 C. to
100 C. From 100 C. to a T. of 0.92, ME = 1.85. That is to say, the vapor density
as calculated by the A *, B* formula would have to be multiplied by this correction
factor to take care of the association. Further, if the reciprocal of the density is used
as calculated to give vapor volume, it would be necessary to divide by 1.85 to get
the actual vapor volume.
t.: Where the critical temperature has not been determined, it is calculated by Watson's
equation:
T./T, = 0.283(M/d.)o.18
where d. = liquid density, g./ml. at the boiling point, and M = molecular weight.
This is used for ull hydrocarbons and halohydrocarbons.
The IB~I machines were used to set up the Antoine con8tants from determined data.
A preliminary C value was obtained from the equation C = 239. - O.19ta. A and B
were then obtained and new C values either side of the first C used and new A and B
values found. In each case above, the boiling points at the experimental pressures
were calculated and compared with the determined boiling points.
Actually the value of C was generally obtained from C = 239. - O.19ta, since the
determined values must be very very accurate to give better values of C.
i.
Decahydronaphthalene~
Aromatic phenols
Thiophenols
Aromatic amine"
11. N itrobenzenf'll
8.
9.
10.
12.
13.
14.
15.
16.
Ii.
18.
19.
20.
21.
22.
2.592
2.418
l.733
2.398
1.27
1.100
1.525
1.643
2.211
1.64
Sulfur-as SH
Sulfur-as RSR
Sulfur-as RCNS
Sulfur-as RSSR
Nitrogen
as aliphatic primary amine
as aromatic primary amine
as aliphatic secondary amine
as aromatic secondary amine
as aliphatic tertiary amine
as aromatic tertiary amine
as hydroxylamine
as hydrazine
as aliphatic cyanide
as aromatic cyanide
as aliphatic oxime
as primary amide
as secondary amide
as tertiary amide
7.69
7.97
7.91
8.11
NO as nitrites
NO as nitrosoamine
NO. as alkyl nitrite
NO. as alkyl nitrate
NO. as nitro paraffin
NO. as nitro aromatic
NO. as nitramine
Fluorine
Chlorine
Bromine
Iodine
5.91
5.37
7.44
7.59
6:72
7.30
7.51
0.955.967
8.865
13.900
2.45
3.21
2.65
3.59
3.00
4.36
2.48
2.47
3.05
3.79
3.93
2.65
2.27
2.71
This value for one fluorine atom attached to carbon. The value 1.1 is to be used for each
fluorine atom in polyfluorides.
C.................. .....
H ......................
0 ......................
o (Alcohol)...... . . . . . . . .
O.(Ester).. .. . . . . . . . . . ..
N......................
N (Nitrile). . . . . . . . . . . . ..
S .......................
F .......................
Cl..... . . . . .. .. .. . . . . . ..
Sugden
39.0
4.8
17.1
20.0
15.0
60.0
12.5
14.4
48.2
25.7
54.3
Sugden
Br...................... 68.0
I.. . . . . . . . . . . . . . . . . . . . .. 91.0
Single bond ............. .
Double bond. . . . . . . . . . . .. 23 . 2
Triple bond. . . . . . . . . . . . .. 46.6
3-Membered ring.... . . . .. 16.7
4-Membered ring......... 11.6
5-Membered ring.... . . . . . 8.5
6-Membered ring.... . . . . . 6.1
7-Membered ring ........ .
Aliphatic alcohol. .. subtract 6.0
TABLE I.
I
I
NAME
Benzene
Mole
1RefJ Molecular
"Pur. 99.9961 z'l Formula
C 6H 6
B.;fr; C
100 mm
Molecular
W.,,-ht 78. 108
~~
Ref
dt/dP
f
I
C/mm
80.100
Z6.075
_I~: ~O
R.f
5.533
F P C
F. P. 100'10
STRUCTURAL FORMULA
Z5C
BP
te
Z
Z
:
5
Z
5
Ref. Inde,.
nO ZOC
Z5
30
I. SOliZ
1.4979Z
1. 49468
0.7500
MR (Ob )
MR (Calc.)
h
f'
::!
4
4
0.0669
to
1_- _.~
Z
Z
Dielectric
Z.Z83
A I 0 to
6.90565
B 1.l.6.Q. :"C_ IZ11. 033
C
ZZO.79
I
Z
Z
Z
.1
A, IS to
1.19411
B.l!5,!... 11 Z7. 9
K
Z5.0
c
-0.13147
tk fT50to ISS.
~ IZ45C
345.8
~I
B'I _ _ o.
C'
A'.
B'.
to
C
AclI60
BCLtc
Cc
Cryos.
con.t
to
C
A
B
PV IRT
ZSC
30mm
BP
t.
tc
6Hc kcal/m
6W
4
6Ff
4
4
Visco.ity
4
centistoke.
4."
ZOC
5
30
50
70
B V 1 Z5 to
A v I 80 C
1-(B"iI - to-
~~--~+-------+-~I
7. 4Z91Z
16Z8.3Z
Z79.56
0.015Z3
0.003Z
te C
88.04
TR = O.77Tc
REFERENCES:
SOURCE:
PURIFICATION:
I-Dow
lI...:e!:':"LI--=-Z~5~.~C:.+_~0.:..!Z:..!0~8~8~":5~1r.~=:;:::-,;4;;;01t-'Z:..:6",..:;1..:;4-rZ~
Z I~
Z
d c Ilml
Vc mill
4
t.C
c
4
Pc mm
z6.1835
1.0616Z
(nD-d/Z)
0.5949
30.09
R.f
O. Z605
0.0 3 31
4
Z I--=-L""""'T----I----I---l
~--~1----~~-4~5~.----~5~1~~~~~1_~~~--r_~ m
1 300to -0.1030 4
6Hv calli
I
Pre ure
Z5C
103.57
Z
n I
_ IQO....:~ 0.0014 4
mm Z5C
9S.18
5
-0.0 6 71 4
30mm
108.19
4
0
1
964.4
5
t.
BP
94.14
Z
m'l
Density
te
9Z.65
5
n' I
Ilml ZO"C
0.87901
Z
te (d, e)
91.71
5
0' I
dt
Z5
0.87370 Z
6Hv/Te
ZO.03
5
4
30
0.86837 4
Surface tenoion
a
0.900Z5 4
::
~!~ 10~:~~1l ~ dynes/cm. ZOOC Z8.88 Z
+--=:-0::.;.:..:0:..:0~1.:.05::..j....:4!.....1I-d.,- 0 to
108.79
5.
30
Z7.49
Z
r-:b=--___
30 mm
6Hm calli
O. ZZ76
0.04Z71
0.0355
5
5
5
Z
Z
0.300
3.333
Z89.45
36936.
Z
Z
Z
Z
0.99ZZ
1.0000
0.9658
o. 9596
O. Z74
757.5Z
11.718
Z9.756
4
5
4
5
Z
0.74Z7
0.659Z
0.5156
o 4148
I
I
Z
Z
Z
5Z3.4
1.09Z90
0.4178
0.4315
0.Z516
0.34Z4
3z
3z
Z
Z
Parachor [p]
ZO"C
30
40
Suld.
Solubility in ..
Acetone
Carbon tet.
Ben.ene
Ether
n-Heptane
Ethanol
Water
#Water in
#-
(AVII
C
c liq.300.K
P
3Z0
c p vap.30(1'K
400
Z06.06
Z06.10
Z06.11
Z07. I
11
3'
3'
Z
GO
GO
GO
GO
GO
0.174
7.0
0.ZZ6
API
.!!'
GO
3 J.A.C.S .
Yea
Yea
Yes
99.
LITERATURE REFERENCES:
733 (1947); 3 z Timmerman.
4
4
IZ
ADVANCES
CHE.uSTRYSER~
No
NAME
Toluene
r Moleculer
Wei.ht 9Z.134
C 7H8
_q4 qql
Pre ur.
mm ZSC
te
Denaity
Ilml ZO"C
Z5
dt
30
4
a
b
Z8.437
1048.Z
0.88547
-0.0,9Z4
4
4
1. 49693
1. 49414
1.491Z9
Z
Z
4
0.7545
MR (Oba.)
MR (Calc.)
(aD-d/Z)
31. 095
30.9Z5
1.06346
Z
5
Z
Dielectric
A I ZO to
B ~O.!!_:~
C
Ael ZO to
B81212" .
Z.379
6.95334
1343.943
ZI9.377
3
Z
Z
Z
I.Z79Z3
4
4
5
5
5
5
IZ5~.3
Z3.
-0. 11760
175.
380.0
6Hm callI
6Hv calli
Z5C
30mm
BP
te
te (d,e)
4
4
Z
Z
4
lie"
Z5C
BP
te
30mm
Z
4
4
5
5
0.86694
0.86Z30
0.85757
ReI. Jade,.
aD ZO"C
Z5
30
dt/dP
C/mm
110.6Z5
51. 944
Z6.04
6.37
-Z6. I ?
6Hv/Te
d 1
Z5 to
~...! ~3!L.
d' 1
to
e' I
C
d c Ilml
v mill
t cC C
Pc mm
C'
A'e
B'e
to
OC
Ac I ZOO to
BcL.!c C
Cc
-,;"
7.45657
1796.9
Z84.6Z
4
4
4
0.OZ508
0.0019
Z
Z
Cryoa. A
coa.te Be
o
te C
IZZ.34
f. closed CUD
REFERENCES: 1-0_
SOURCE:
0.6808
0.0463
0.0360
4
Z
5
0.6487
17.17
Z5C
30 mm
BP
te
tc
6Hc kcal/m
6Hl
6FI
98.55
97.9
86.80
84.73
85.17
Z
5
Z
5
5
19.74
101. 98
0.1372
5
5
0.Z88
3.473
lZQ.8
Z
Z
Z
30400.
P~~RT
0.9968
0.9966
0.9613
0.95ZZ
0.Z63
901.50
Z.867
Z7.Z8Z
Z
4
4
4
5
4
Z
Z
Z
Viacoalty
cead.toke~
"
to
B'L_~
[ReI.
ReI
Ref
B.P. C
760mm
100
30
10
I
OCH
Methylbenzene
Mole
IRef.1 Moleculer
i- Pur. 99.999 Z Formule
F P. C
F.P. 100ft
STRUCTURAL FORMULA
ZO
40
60
80
B V I 40 to
A V I 90 C
t'(BV) I - -t';(A V) I
C
c p liq.
K
5
Z-API
c p vap.300"K
400
Yap.
0.67778
0.56457
0.458Z5
0.39119
I
I
I
I
440.66
!.34476
4
4
0.Z708
0.3609
I
I
h
I'
I'
h'
m
n
0
I
I
0'
0.3971 4
-0.0 3 59 4
5 to
!l1.Q. ~~
O.O~ZI
1300 to
12~ ~
-0.0654
0.0013
-0.0 6 55
4
4
4
1700 to
0.0471 4
0.0 398 4
-0.0 6 35 4
I
to
1__ ~K
I
m' I
n'
1.!.0~ ~
1
Sudace tenaion
dynea/cm. ZOC
J
30
40
Parachor [p]
ZOC
30
40
SUld.
E,.p. L.l. '!Io/wt.
u.
Olaperoion
Fleah PointC
Fire Point
M Spec.
Ultra V.
X-Ray Dil.
Inlrared
Solubility in
Acetone
Carbon tet.
Z8.53
Z7.3Z
Z6.15
Z
Z
Z
Z45.63
Z45.68
Z45.71
Z46.1
4
4
4
5
1. Z4
19.3
184.7
4.44-"-
3'
3'
Z
Yea
Yea
I
I
865.
Ben De
Ether
n-Heptane
Ethanol
Water
Water iD
GO
GO
GO
GO
7.3
0.055
API
PURIFICATION:
API
UTERATURE REFERENCES:
GO
GO
Z
Z
Cy
3-Lit.
3'
I
I
13
TABLE
I.
NAME
1t-__E_th_y_l_be_n_z_e_n_e_ _ _ _ _ _ _ _ _ _ _ _ _-i
I
I ,!
I
Mole
Ref Molecular
" Pur. 99.995 z'l Formula
C 8H IO
F P C
F. P. 100'll0
B. P. C
760 mm
100
~~
Ref
dt/dP
f
I
oc/rrun
136.186
74.10
~:: ~~
OC
Molecular
Weight 106.160
Ref
ZSC
BP
Z
Z
:
STRUCTURAL FORMULA
'
I
2H 5
I___.K.
Ref
to
te
1.8Z86
5
0.04898 Z l-.::h'""'"I-....----t----+---i
6
5
f'
I
to
0.030,
~ __ .K
30 mm
0.6866
:'
1 _ _~I_ _~~-19~.Z~-~S~I~6~Hm~:c~a~I/:I~t_~ZO~.~6~3-_r~Z~---~~-r~-~-~~~~
t-
6Hv calli
m
I 300 to -0.0734 4
Pre.aure
ZS.C
95.11
Z
n I
1_6..Q.0~~ 0.0014 4
rrun ZsC
5
9.571
30 rrun
93.00
4
0
I
-0.0 6 61 4
llZ8.
5
te
BP
81. 00
Z
m' I
I 700 to
0.0675 4
Density
0.8670Z Z
te (d )
78.97
5
n' I
l!.oQJ! ':'K 0.0 3 99 4
Ilml ZODC
0.86Z64 Z
te.e
78.94
5
0' I
-0.0 6 35 4
dt
Z5
0.8S8Z6 4
6Hv /Te
19.74
5
4
30
d
45
to
99. Z6
4
Surface tenaion
a
0.88453 4
e I 160.C
0.1341
4
dynea/cm. ZOC Z9.04
Z
t-b_ _ _ _+---'-O:..:...:0""",18.:,.7-+_4'-iI-d 'li5to
97.54
4'
30
Z7.93
Z
Ref. Index
"_e~':"'L
1:!.4~S_~C~_~O:..:.0~9~7~3~~4-l~-;;:::~:::,,4;;;0IrZ_6-'._7..:..9_IZ1
n D ZODC
1. 49588 Z It
Z
Parachor [p]
Z5
1.493Z0 Z
d c Ilml
O. Z9
ZOC Z84.3
4
30
1.4904
4
Vc mill
3.448
Z
30
Z84.4
4
tc C
346.4
Z
40
Z84.3
4
0.7SZ8
4
Pc rrun
Z81Z0.
Z
Suld. Z8S. I
5
MR (Oba.)
35.761
Z
PV/RT
Exp.
L.I.
MR (Calc.)
35.543
5
ZS.C
1. 0000
5
u.
(nD-d/Z)
I. 06Z37
Z
30 rrun
Diaperaion
1. 0000
5
Z
174.7
Dielectric
Z. Z38
5
BP
0.96SZ
4
Fla ah Point C
15.0
3
0.9547
5
A I 45 to
6.95719 Z
Fire Point
0.Z66
Z
B I 190C 14Z4. ZSS
Z
c
Yea
M. Spec.
C - - - - Z13.Z06
Z
6Hc kcal/m
Z
1048.53
Ultra V.
Yee
6Hf
Z
-Z.977
X-Ray
DU.
5
6Ff
Z8.614
Z
Infrared
507.
5
Viscoaity
Solubility in
cenUatokea
Acetone
III
0.78Z3
Z
."
ZOC
Carbon tet.
III
Z
40
0.6305
BeD De
III
O.SZS
Z
7.3ZSZS 5
60
A'I zo to
Ether
III
_0,447
2
5
_80
B'I 4SC 16ZZ.0
n-Heptane
III
C,--- Z30.7
5
B V I zo to
Ethanol
III
413.1
4
Water
O.OZO
A V '90 C
2'.48073 4
A'e ZS to
1. 69ZZ4 55 f-(B::V)-'90- -toWater in
0.114
B'e 4SC ISZZ.4
408.5
4
~~---~------+--~I
Acl190to
7.3729
5
(Av)nSO C
2'. 494Z8 4
BCLtc C 1779.0
5
K
Cc
z60.6
5
"'_t.
!e
Cryoa. A
conata. B
te C
0.03471
O. 00Z9
lSI. SZ
REFERENCES:
SOURCE:
PURIFICATION:
I-Dow
Z
Z
c p vaP.30d'K
400
0.Z9088
0.38395
Z
Z
5
Z-API
3-Lit.
API
API
LITERATURE REFERENCES: 3 Nat. Fire Prot. Aesoc. 3ZS (1949)
TABLE
XXII.
523
MISCELLANEOUS
No.
o-Chlorobenzaldehyde
NAME
Mole
% P u r . 9 9 . 61
Ref.
1
STRUCTURAL
CHO
MolecuUr
Formula
7 5
c
Ref,
RefJ
12. 19
12.39
F . P . I
F . P . TOOT
Pressure
m m 25*C
211.89
140.40
108.63
84. 31
4 3 . 53
1.24829
1.24320
1.23811
2 5
1.26865
- 0 . 00102
Ref.
n
Index
20*C
25
30
1.56620
1.56384
1.56161
M R (Obs.)
M R (Calc.)
(nD-d/2)
37.005
37.073
0.94206
48.61
0. 05615
0. 03665
30 m m
94.47
8 5 . 55
72.53
69.72
69.43
t (d.e)
e
to
^C_
to
*C
99.25
0. 1261
9 7 . 14
0.1067
I
I
I
tcT
L _ 1 K
Surface tension
dyne /cm. 2 0 C
30
40
#
Parachor
d g/ml
v ml/g
c
20 C
30
40
Sugd
e
0.59201
A 109 to
l290_^C
C
7.06216
1718.10
199.
0 9 to
B*(246_*C_
1.52895
1623. 5
PV/RT
25 C
30 m m
BP
if'
A He k c a l / m
A Hi
AFf
7.38896
1925.0
217.
A * 25 to
*109 C
1.85246
1823.9
Acl
Viscosity
centistokes
I 25 to
B'|109 C
C
#
1.0000
1.0000
0.9405
0.9222
to
C
-c
to
to
(A )|
c
Cryos. A*
consts. B*
0.01986
236.44
to
C
(B )|
v
liq.
vap.
*K
vap.
* p u r i t y 9 9 . 39 m o l e %
REFERENCES:
SOURCE:
PURIFICATION:
LITERATURE
1-Dow
31.70
30. 68
2 9 . 68
tP]
Dielectric
Ref.
to
19.37
. d I 109
l e
l_23_6_
d'"~| 25
e ! 109
1
h' i
m
cal/g
25 C
30 m m
BP
AHv/T
f
8
h
0.7974
22.67
A H m cal/g
0.2718
1307.6
Density
g / m l 2<rC
A
4
30
1
dt/dP
C/mm
25 C
BP
e
B . P . *C
760 m m
100
30
10
1
Molecular
Weight 141.567
269. 1
E x p . L . 1.%/wt.
u.
Dispersion
Flash Point C
F i r e Point
4
M . Spec.
Ultra V .
X-Ray Dif.
Infrared
Solubility i n
Acetone
C a r b o n tet.
Bensene
Ether
n-Heptane
Ethanol
Water
Water i n
grams/100 grams
2-API
Dow
3-Lit.
Distillation
REFERENCES:
17
FORMULA
4 - C a l c . f r o m d e t , data
solvent
5 - C a l c . by formula
Index
Compound
Page
No.
Acetophenone
353
m-Aminobensotrifluoride
Compound
Page
No.
p-Bromoethylbenzene
155
1 -Blomjo-2-ethylbenzene
154
344
1-Bromo-4-ethylbenzene
155
- A m i n o chlorobenzene
342
(2-Bromoethyl)cyclohexane
488
m - A m i n o chlorobenzene
343
-Bromoethylcyclohexane
488
4 - A m i n o - 1 , 3-dimethylbenzene 341
1 - B r o m o - 2 - i e o p r o p y l b e n z e n e 156
p - A m i n o ethylbenzene
339
1 -Bromo-4-ieopropylbenzene
- A m i n o ethyl Benzoate
514
1 -Bromo-2-methylbenzene
152
m - A m i n o methylbenzene
337
1-Bromo-4-methylbenzene
153
p - A m i n o methylbenzene
338
p - B r o m o p h e n y l phenyl ether
522
- A m i n o methylbenzoate
513
o-Bromoetyrene
172
4-Amino-m-xylene
341
o-Bromotoluene
152
47
n-Amylbenzene
157
p-Bromotoluene
153
2-tert-A,myl-4-methylphenol
301
o-Bromovinylbenzene
172
4-tert-Amyl-2-methylphenol
299
p-Bromovinylbenzene
173
4-tert-Amyl-3-methylphenol
300
-Butylacetanilide
512
- B u t y l aminobenzene
340
n-Butylaniline
340
2, 6 - d i - t e r t - A m y l - 4 - m e t h y l phenol
321
2-n-Amylnaphthalene
223
4-n-Amylphenol
298
4-tert-Amylphenol
297
Aniline
335
B
Benzene
11
n-Butylbenzene
25
eec-Butylbenzene
27
tert-Butylbenzene
28
n-Butylcyclohexane
453
n-Butylcyclopentane
382
4-tert-Butyl-2, 5-dimethylphenol
303
4-tert-Butyl-2, 6-dimethylphenol
304
6-tert-Butyl-2, 4-dimethylphenol
302
305
Benzenethiol
325
Benzophenone
354
Benzotrifluoride
133
6-tert-Butyl-3, 4-dimethylphenol
Benzyl alcohol
347
4, 6 - d i - t e r t - B u t y l - 2 , 3 -
Bromobenzene
150
dimethylphenol
317
156
2 -1 e r t - B u t y l - 4 - e thy lphenol
3 07
p-Bromocumene
157
4 - te r t - B u t y l - 2 - e thylphenol
306
Bromocyclohexane
487
p - B r o m o diphenyl oxide
522
o-Bromoethylbenzene
154
2, 6 - d i - t e r t - B u t y l - 4 - e t h y l phenol
4, 6 - d i - t e r t - B u t y l - 2 - e t h y l phenol
o-Bromocumene
320
318
A D V A N C E S IN C H E M I S T R Y S E R I E S
526
Compound
4, 6 - d i - t e r t - B u t y l - 3 - e t h y l phenol
Page
No.
319
Compound
Page
No.
m-eec-Butyltoluene
59
m-tert-Butyltoluene
65
1-n-Butyl-2-methylbenzene
55
p-n-Butyltoluene
57
1-n-Butyl-3-methylbenzene
56
p-eec-Butyltoluene
60
1-n-Butyl-4-methylbenzene
57
p-tert-Butyltoluene
66
1-eec-Butyl-2-methylbenzene
58
1-tec-Butyl-3-methylbenzene
59
1-sec-Butyl-4-methylbenzene
60
1 - t e r t - B u t y l - 2 -methylbenzene
64
1-tert-Butyl-3-methylbenzene
65
1- t e r t - B u t y l - 4 - m e t h y l b e n z e n e
66
2- eec-Butyl-4-methylphenol
296
2-tert-Butyl-4-methylphenol
295
4, 6 - d i - t e r t - B u t y l - 2 - m e t h y l phenol
4, 6 - d i - t e r t - B u t y l - 3 - m e t h y l phenol
2
311
312
6-di-tert-Butyl-4-methyl-
C
p-Chloroacetophenone
355
o - C h i oroaniline
342
m-Chloroaniline
343
o-Chlorobenzaldehyde
523
Chlorobenzene
134
o-Chlorobenzotrichloride
142
o-Chlorocumene
148
p-Chlorocumene
149
0 - Chloroethylbenzene
144
m-Chloroethylbenzene
145
p-Chloroethylbenzene
146
313
1 -Chloro-2-ethylbenzene
144
1 -n-Butylnaphthalene
220
1 -Chloro-3-ethylbenzene
145
2-n-Butylnaphthalene
221
1 -Chloro-4-ethylbenzene
146
2 - n-Butylphenol
292
1- C h l o r o - 2 - i e o p r o p y l b e n z e n e
148
3 - n-Butylphenol
293
1-Chloro-4-ieopropylbenzene
149
4 - n-Buiylphenol
294
1- C h l o r o - 2 -methylbenzene
139
2-tert-Butylphenol
289
4-tert-Butylphenol
291
2 -Chloro-5 -nitrobenzotrifluoride
508
phenol
2,4-di-tert-Butylphenol
308
-text-Butylphenol
289
m-tert-Butylphenol
290
p-tert-Butylphenol
291
-n-Butylphenol
292
m-n-Butylphenol
293
-n-Butylphenol
294
2,4, 6 - t r i - t e r t - B u t y l p h e n o l
322
- B u t y l toluene
55
o-aec-Butyltoluene
58
o - t e r t - B u tyltoluene
64
m-n-Butyltoluene
56
4-Chloro-3-nitrobenzotrifluoride
509
p-Chlorophenethyl alcohol
352
o-Chlorophenol
324
p - C h l o r o - p - p h e n y l ethyl a l c o h o l
352
o-Chloroetyrene
170
p-Chloroetyrene
171
- C h l o r otoluene
139
2- C h l o r o - a a a - t r i H u o r o - 5 nit r otoluene
4 - C h l o r o - a , a, -trifluoro-3nit r otoluene
509
o-Chlorovinylbenzene
170
508
INDEX
527
C o m pound
Compound
Page
No.
p-Chlorovinylbenzene
171
1 -Cyclohexylundecane
460
0 - Cresol
274
Cyclooctatetraene
517
m-Creeol
275
p-Creeol
276
Cumene
Page
No.
18
Cyclohexane
441
Cyclohexene
489
1- C y c l o h e x y l d e c a n e
459
1-Cyclohexyldocosane
471
1-Cyclohexyldodecane
461
1 -Cyclohexyldotriacontane
481
1-Cyclohexyleicosane
469
1-Cyclohexylheneicoeane
470
1 -Cyclohexylhentriacontane
480
1 -Cyclohexylheptacosane
476
1-Cyclohexylheptadecane
466
1 -Cyclohexylheptane
456
1-Cyclohexylhexacosane
475
1-Cyclohexylhexadecane
465
1 -Cyclohexylhexane
455
1-Cyclohexylhexatriacont&ne
485
1 -Cyclohexylnonacosane
478
1-Cyclohexylnonadecane
468
1-Cyclohexylnonane
458
1-Cyclohexyloctacosane
477
1 -Cyclohexyloctadecane
467
1 -Cyclohexyloctane
457
1-Cyclohexylpentacosane
474
1 -Cyclohexylpentadecane
464
1-Cyclohexylpentatriacontane
484
1-Cyclohexyltetracosane
473
1 -Cyclohexyltetradecane
463
1 -Cyclohexyltetratriacontane
483
1-Cyclohexyltriacontane
479
1-Cyclohexyltricosane
472
1 -Cyclohexyltridecane
462
1 -Cyclohexyltritriacontane
482
Cyclopentane
359
Cyclopentene
415
1-Cyclopentyldecane
388
1 -Cyclopentyldocosane
400
1 -Cyclopentyldodecane
390
1 - C y c l o p entyldotriacontane
410
1-Cyclopentyleicoeane
398
1 -Cyclopentylheneicosane
399
1 -Cyclopentylhentriacontane
409
1-Cyclopentylheptacoeane
405
1 -Cyclopentylheptadecane
395
1 -Cyclopentylheptane
385
1-Cyclopentylhexacosane
404
1 -Cyclopentylhexadecane
394
1 -Cyclopentylhexane
384
1-Cyclopentylhexatriacontane
414
1 -Cyclopentylnonacosane
407
1 -Cyclopentylnonadecane
397
1 -Cyclopentylnonane
387
1 -Cyclopentyloctacoeane
406
1 -Cyclopentyloctadecane
396
1 -Cyclopentyloctane
386
1 -Cyclopentylpentacoeane
403
1-Cyclopentylpentadecane
393
1 -Cyclopentylpentane
383
1 -Cyclopentylpentatriacontane
1-Cyclopentyltetracoeane
413
402
1-Cyclopentyltetradecane
392
1-Cyclopentyltetratriacontane
412
1 -Cyclopentyltriacontane
408
1 -Cyclopentyltricosane
401
1-Cyclopentyltridecane
391
1 -Cyclopentyltritriacontane
411
3 89
528
A D V A N C E S IN C H E M I S T R Y S E R I E S
Compound
3, 4 - D i e t h y l t o l u e n e
cie-Decahydronaphthalene
Compound
Page
No.
263
3, 5-Diethyltoluene
Page
No.
89
90
t r a n s - D e cahydronaphthalene
264
2 - D i i obutyl- 4 -methylphenol
316
n-Decylbenzene
105
4 - D i i o b u t y l - 2 - m e thylphenol
314
n-Decylcyclohexane
459
4 - D i i eobutyl - 3 - m e t h y l p h e n o l
315
n-Decylcyclopentane
388
4 - D i i eobutylphenol
309
1 -n-Decylnaphthalene
232
o-Diieopropylbenzene
99
2 -n-Decylnaphthalene
233
100
o-Dibromobenzene
151
101
1, 2 - D i b r o m o b e n z e n e
141
1, 2 - D i i e o p r o p y l b e n z e n e
99
o-Dichlorobenzene
135
100
m-Dichlorobenzene
136
1, 4 - D i i e o p r o p y l b e n z e n e
101
p-Dichlorobenzene
137
1, 2 - D i m e t h y l b e n z ene
14
1,2 - D i c h l o r obenzene
135
15
1, 3 - D i c h l o r o b e n z e n e
136
1, 4 - D i m e thy lb en ene
16
1, 4 - D i c h l o r obenzene
137
2, 4 - D i m e t h y l b e n z e n e t h i o l
332
3 4-Dichlorobenzotrichloride
143
2, 5 - D i m e t h y l b e n z e n e t h i o l
333
2, 4 - D i c h l o r o b e n z y l c h l o r i d e
141
2, 3 - D i m e t h y l c u m ene
79
3 , 4 - D i e h l o r o - 1 -methylbenzene 140
2 4 - D i m e t h y l cumene
82
3, 4 - D i c h l o r o t o l u e n e
140
2 5 - D i m e t h y l cumene
84
2, 5 - D i c h l o r o - p - x y l e n e
147
2, 6 - D i m e t h y l cumene
81
- D i e thylbenz ene
35
3, 4 - D i m e t h y l c u m e n e
80
m-Diethylbenzene
36
3, 5 - D i m e t h y l cumene
83
p - D i e thylben ene
37
1,1 - D i m e t h y l c y c l o h e x a n e
444
1, 2 - D i e t h y l b e n z e n e
35
1, c i e - 2 - D i m e t h y l c y c l o h e x a n e
445
1, 3-Diethylbenzene
36
1, 4 - D i e t h y l b e n z e n e
37
1, t r a n s - 2 - D i m e t h y l c y c l o
hexane
446
1, c i e - 3 - D i m e t h y l c y c l o h e x a n e
447
2 3 - D i e t h y l - 1 -methylbenzene
85
2 4 - D i e t h y l - 1 -methylbenzene
86
2 5 - D i e t h y l - 1 -methylbenzene
87
2, 6 - D i e t h y l - 1 - m e t h y l b e n z e n e
88
3, 4 - D i e t h y l - 1 - m e t h y l b e n z e n e
1, t r a n s - 3 - D i m e t h y l c y c l o
hexane
448
1, c i e - 4 - D i m e t h y l c y c l o h e x a n e
449
89
1, t r a n s - 4 - D i m e t h y l c y c l o
hexane
450
496
3 5 - D i e t h y l - 1 - m e thylbenz ene
90
1,2 - D i m e t h y l c y c l o h e x e n e
2,3-Diethyltoluene
85
I, 3 - D i m e t h y l c y c l o h e x e n e
497
2,4-Diethyltoluene
86
1,4 - D i m e t h y l c y c l o h e x e n e
498
5-Diethyltoluene
87
1, 5 - D i m e t h y l c y c l o h e x e n e
499
6-Diethyltoluene
88
1, 6 - D i m e t h y l c y c l o h e x e n e
500
INDEX
529
Compound
Page
No.
Compound
Page
No.
2 . 3 - Dimethylcyclohexene
500
6-Dimethylphenol
280
2 . 4 - Dimethylcyclohexene
499
3 4-Dimethylphenol
281
3 . 3 - Dimethylcyclohexene
501
3, 5 - D i m e t h y l p h e n o l
282
4 . 4 - Dimethylcyclohexene
502
(I,
1-Dimethylpropyl)benzene
52
53
1, 1-Dimethylcyclopentane
362
(1, 2 - D i m e t h y l p r o p y l ) b e n z e n e
c i s - l , 2-Dimethylcyclopentane
363
trans-1, 2-Dimethylcyclopentane
364
1, 2 - D i m e t h y l - 3 - n - p r o p y l benzene
73
1, 2 - D i m e t h y l - 4 - n - p r o p y l benzene
74
75
1, 3 - D i m e t h y l - 4 - n - p r o p y l benzene
76
1, 3 - D i m e t h y l - 5 - n - p r o p y l benzene
77
1, 4 - D i m e t h y l - 2 - n - p r o p y l benzene
78
(2, 2 - D i m e t h y l p r o p y l ) b e n z e n e
54
c i s - l , 3-Dimethylcyclopentane
365
trans-1, 3-Dimethylcyclopentane
366
1.2- D i m e t h y l c y c l o p e n t e n e
422
1.3- Dimethylcyclopentene
423
1.4- Dimethylcyclopentene
424
1.5- Dimethylcyclopentene
425
3 . 3 - Dimethylcyclopentene
426
4 . 4 - Dimethylcyclopentene
427
1,10-Dimethyl-(cis-Deca.hydro)naphthalene
270
1, 1 0 - D i m e t h y l - ( t r a n s - D e c a hydro) naphtha le ne
271
1, 2 - D i m e t h y l - 3 - i s o p r o p y l b e n z e n e
79
1, 2 - D i m e t h y l - 4 - i e o p r o p y l b e n z e n e
80
1, 3 - D i m e t h y l - 2 - i s o p r o p y l b e n z e n e
81
1, 3 - D i m e t h y l - 4 - i s o p r o p y l b e n z e n e
82
1, 3 - D i m e t h y l - 5 - i s o p r o p y l b e n z e n e
83
1, 4 - D i m e t h y l - 2 - i s o p r o p y l b e n z e n e
1 . 2 - Dimethylnaphthalene
84
208
249
250
1, c i s - 4 - D i m e t h y l - l , 2, 3, 4 T e t r a h y d r o n a phtha lene
251
1,1 - D i m e t h y l - 1 , 2, 3, 4 - T e t r a
hydronaphthalene
248
1, 5 - D i m e t h y l - l , 2, 3, 4 - T e t r a
hydronaphthalene
254
253
2, 2 - D i m e t h y l - l , 2, 3, 4 - T e t r a
hydronaphthalene
252
255
2, 6 - D i m e t h y l - l , 2, 3, 4 - T e t r a
hydronaphthalene
256
2, 7 - D i m e t h y l - l , 2, 3, 4 - T e t r a
hydronaphthalene
257
258
5, 6 - D i m e t h y l - l , 2, 3, 4 - T e t r a
hydronaphthalene
259
1, 3-Dimethylnaphthalene
209
210
1, 5 -Dimethylnaphthalene
211
1, 6-Dimethylnaphthalene
212
213
1, 8-Dimethylnaphthalene
214
2, 3-Dimethylnaphthalene
215
2, 6-Dimethylnaphthalene
216
2, 7-Dimethylnaphthalene
217
2 . 3 - Dimethylphenol
277
2 . 4 - Dimethylphenol
278
2, 5 - D i m e t h y l p h e n o l
279
530
A D V A N C E S IN C H E M I S T R Y S E R I E S
Compound
5, 7 - D i m e t h y l - 1 , 2, 3, 4 - T e t r a
hydronaphthalene
Page
No.
260
5, 8 - D i m e t h y l - l , 2, 3, 4 - T e t r a
hydronaphthalene
261
6, 7 - D i m e t h y l - l , 2, 3, 4 - T e t r a
hydronaphthalene
Compound
Page
No.
-Ethyl aniline
339
E t h y l anthranilate
514
Ethylbenzene
13
2 - Ethylbenzenethiol
329
262
3- Ethylbenzenethiol
330
2, c i e - 5 - D i m e t h y l t h i a c y c l o p e n t a n e 434
4 - Ethylbenzene thiol
331
2, t r a n s - 5 - D i m e t h y l t h i a c y c l o -
0 - E t h y l cumene
70
435
m - E t h y l cumene
71
2, 2 - D i m e t h y l t h i a c y c l o p r o p a n e
440
p - E t h y l cumene
72
2, 2 - D i m e t h y l t h i i r a n e
440
Ethylcyclohexane
443
2, 3-Dimethylthiophene
188
1- E t h y l c y c l o h e x e n e
493
2 . 4 - Dimethylthiophene
189
3- Ethylcyclohexene
494
2 . 5 - Dimethylthiophene
190
4 - Ethylcyclohexene
495
3 , 4 - D i m e thylthiophene
191
Ethylcyclopentane
361
419
pentane
2 . 4 - Dimethylthiophenol
332
1- E t h y l c y c l o p e n t e n e
2 . 5 - Dimethylthiophenol
333
3- Ethylcyclopentene
420
D i p h e n y l ether
521
4 - Ethylcyclopentene
421
Diphenylketone
354
Diphenylmethane
518
9-Ethyl-(cis-Decahydronaphthalene)
268
D i p h e n y l oxide
521
n-Docosylbenzene
117
a-Docoeylcyclohexane
471
n-Docoeylcyclopentane
400
n-Dodecylbenzene
107
n-Dodecylcyclohexane
461
n-Dodecylcyclopentane
390
1- n-Dodecylnaphthalene
236
2 - n-Dodecylnaphthalene
237
n-Dotriacontylbenzene
127
n-Dotriacontylcyclohexane
481
n-Dotriacontylcyclopentane
410
Durene
46
n-Eicoeylbenzene
115
n-Eicoeylcyclohexane
469
n-Eicoeylcyclopentane
398
9-Ethyl-(trane-Decahydronaphthalene)
2 - E t h y l - l , 3 - d i m e thylbenz ene
269
38
2 - E t h y l - 1 , 4-dimethylbenzene
39
3 - E t h y l - 1 , 2 -dimethylbenzene
40
4 - E t h y l - l , 2-dimethylbenzene
41
4 - E t h y l - l , 3-dimethylbenzene
42
5- E t h y l - 1 , 3-dimethylbenzene
43
Ethylene sulfide
1-Ethyl-2-isopropylbenzene
437
70
1-Ethyl-3-isopropylbenzene
71
1- E t h y l - 4 - i s o p r o p y l b e n z e n e
72
2- Ethyl-l-methylbenzene
22
3- Ethyl-1-methylbenzene
23
4- Ethyl-l-methylbenzene
24
1-Ethyl-1-methylcyclopentane
369
cie-1 -Ethyl-2-methylcyclopentane
370
trans-l -Ethyl-2-methylcyclo
pentane
371
INDEX
531
Compound
c i s - l -Ethyl-3-methylcyclopentane
Page
No.
372
trans-1-Ethyl-3-methylcyclo-
pentane
373
2- Ethyl-3-methylthiophene
196
3- Ethyl-2-methylthiophene
197
4 - Ethyl-2-methylthiophene
198
5- Ethyl-2-methylthiophene
199
1 -Ethylnaphthalene
206
2-Ethylnaphthalene
207
o-Ethylnitrobenzene
346
o-Ethylphenethyl alcohol
350
p-Ethylphenethyl alcohol
351
2- Ethylphenol
283
3- Ethylphenol
284
4- Ethylphenol
285
o-Ethylphenol
283
m-Ethylphenol
284
p-Ethylphenol
285
0 - E t h y l - - p h e n y l ethyl
alcohol
p - E t h y l - p - p h e n y l ethyl
350
alcohol
Compound
Page
No.
2 - Ethylthiacyclopentane
432
3- Ethylthiacyclopentane
433
2-Ethylthiacyclopropane
439
2 - E t h y l -( 1 thiaethyl) -benzene
182
o-Ethyl-(l-thiaethyl)-benzene
182
2-Ethylthiirane
439
2 - Ethylthiophene
186
3 - Ethylthiophene
187
o-Ethylthiophenol
329
m-Ethylthiophenol
330
p-Ethylthiophenol
331
o-Ethyltoluene
22
m - E t h y l toluene
23
-Ethyl toluene
24
2 - E t h y l - l , 3, 5 - t r i m e t h y l b e n z e n e
91
3 - E t h y l - 1 , 2, 4 - t r i m e t h y l b e n z e n e
92
4 - E t h y l - 1 , 2, 3 - t r i m e t h y l b e n z e n e
93
5 - E t h y l - l , 2, 3 - t r i m e t h y l b e n z e n e
94
5 - E t h y l - 1 , 2, 4 - t r i m e t h y l b e n z e n e
95
6- E t h y l - l , 2, 4 - t r i m e t h y l b e n z e n e
96
m-Ethylvinylbenzene
166
167
351
p-Ethylvinylbenzene
E t h y l phenyl ketone
356
2-Ethyl-m-xylene
E t h y l phenyl sulfide
176
2- Ethyl-p-xylene
39
(1-Ethylpropyl)benzene
49
3- Ethyl--xylene
40
38
1- E t h y l - 2 - n - p r o p y l b e n z e n e
67
4- Ethyl--xylene
41
1-Ethyl-3-n-propylbenzene
68
4- Ethyl-m-xylene
42
l-Ethyl-4-n-propylbenzene
69
5- E t h y l - m - x y l e n e
43
m - E t h y l sty r ene
166
p-Ethylstyrene
167
1- E t h y l - 1 , 2 , 3, 4 - T e t r a
hydronaphthalene
244
F
Fluorobenzene
132
Furan
516
Furfurane
516
2 - E t h y l - l , 2, 3, 4 - T e t r a
hydronaphthalene
245
5 - E t h y l - 1 , 2, 3, 4 - T e t r a hydronaphthalene
246
6 - E t h y l - 1 , 2, 3, 4 - T e t r a
hydronaphthalene
247
Hemimellitene
3 - Ethyltetrahydrothiophene
433
n-Heneicosylbenzene
H
19
116
532
A D V A N C E S IN C H E M I S T R Y S E R I E S
Compound
Compound
Page
No.
470
Isobutylbenzene
26
n-Heneicosylcyclopentane
399
1 -Ieobutyl-2-methylbenzene
61
1 -Hentriacontane
126
1 -I o b u t y l - 3 - m e t h y l b e n z e n e
62
n-Hentriacontylbenzene
126
1 -Is o b u t y l - 4 - m e t h y l b e n z e n e
63
- H e n t r i a c onty le y c lohexane
480
o-Isobutyltoluene
61
409
m -1 obuty 11 oluen e
62
n-Heptacosylbenzene
122
p-Ieobutyltoluene
63
n - H e p t a c o s y l c y c lohexane
476
Ieodurene
45
n-Heptacosylcyclopentane
n-Heneicosylcyclohexane
n-Hentriacontylcyclopentane
Page
No.
405
Ieopentylbenzene
n-Heptadecylbenzene
112
Ieopropenylbenzene
n-Heptadecylcyclohexane
466
n-Heptadecylcyclopentane
395
Ieopropylcyclohexane
452
n-Heptylbenzene
368
51
160
18
102
Ieopropylcyclopentane
n-Heptylcyclohexane
456
p - I s o p r o p y l - - m e t h y l t y r ene
169
-Heptylcyclopentane
385
I s o p r o p y l phenyl sulfide
179
1 -n-Heptylnaphthalene
226
p-Ieopropylstyrene
168
2-n-Heptylnaphthalene
227
194
486
3-Isopropylthiophene
195
n-Hexacosylbenzene
121
n-Hexacosylcyclohexane
475
o-Isopropyltoluene
(o-Cymene)
32
33
}f-Hexachlorocyclohexane
n-Hexacosylcyclopentane
404
n-Hexadecylbenzene
111
n-Hexadecylcyclohexane
465
n-Hexade cylcyclopentane
394
p-Ieopropylvinylbenzene
C-Hexane
486
n-Hexatriacontylbenzene
131
485
Mesitylene
414
M e t h y l a n thr a n i late
n-Hexylbenzene
98
34
168
Methylbenzene
21
513
12
n-Hexylcyclohexane
455
n-Hexylcyclopentane
384
3-Methylbenzenethiol
327
1 -n-Hexylnaphthalene
224
4 -Methylbenzenethiol
328
2 -n-Hexylnaphthalene
225
M e t h y l benzoate
357
297
- M e t h y l benzyl alcohol
348
- te r t - H y d r o x y benzene
(1 -Methylbutyl)benzene
(2-Methylbutyl)benzene
I
Iodobenzene
158
Methylcyclohexane
326
48
50
442
INDEX
533
C ompound
1 -Methylcyclohexene
490
3 -Methylcyclohexene
491
4-Methylcyclohexene
492
M e thy le y c 1 open ta ne
360
C ompound
Page
No.
2 - M e t h y l - l , 2, 3, 4 - T e t r a
hydronaphthalene
241
5 - M e t h y l - l , 2, 3, 4 - T e t r a
hydronaphthalene
242
243
504
1 -Methylcyclopentene
416
3-Methylcyclopentene
417
2 - M e thylthia c yc lohexane
418
3 - M e t h y l t h i a c y c lohexane
505
4 - M e thylthia c yc lohexa ne
506
4 - M ethylcyclopentene
Page
No.
1 -Methyl-(trane-Decahydronaphthalene)
9-Methyl-(cie-Decahydronaphthalene)
9-Methyl-(trane-Decahydronaphthalene)
265
266
267
1 -Methyl-2-ieopropylbenzene
32
1 -Methyl-3-isopropylbenzene
33
1 -Methyl-4-isopropylbenzene
34
2 - M e thylthia c yc lopentane
430
431
2 - M e thylthia c y c l o p r o p a n e
438
2 - M e thy 1 thii r a e
438
p - M e t h y l - ( l -thioethyl) benzene
177
4 - M e t h y l - ( 1 - thioethyl) benzene
177
184
1 - Methylnaphthalene
204
2 -Methylthiophene
205
3 - M e thy 1 thiophene
185
2-Methylphenol
274
326
m-Methylphenol
275
327
p-Methylphenol
276
- M e thy 1 thiophen ol
328
( 2 - M e t h y l -1 - thiopropyl) benzene
179
180
4 - M e t h y l - ( 1 -thiopropyl) benzene
181
m - M e t h y l - ( 1 - thiopropyl) benzene
180
p-Methyl-(l -thiopropyl)benzene
181
2 - M e t h y l -1 -phenylbutane
50
52
3 - M e t h y l -1 -phenylbutane
51
3-Methyl-2-phenylbutane
53
M e t h y l phenyl ketone
353
M e t h y l phenyl sulfide
175
1 - M e t h y l - 2 - p r opylbenz ene
29
1 -Methyl-3-propylbenzene
30
1 -Methyl-4-propylbenzene
31
a -Methylstyrene
160
- M e t h y l s t y r ene
161
162
m - M e t h y l s t y r ene
163
p-Methyletyrene
164
l - M e t h y l - 1 , 2 , 3, 4 - T e t r a h y d r o
naphthalene
162
163
p-Methylvinylbenzene
164
Morpholine
515
240
Naphthalene
203
534
Compound
Neopentylbenzene
Compound
Page
No.
54
Nitrobenzene
345
m-Nitrobenzotrifluoride
507
Page
No.
n-Pentetriac ontylbenzene
130
n-Pentatriacontylc yclo
hexane
484
413
n-Nonacoaylbenzene
124
n-Nonacoeylcyclohexane
478
n-Nonacosylcyclopentane
407
n-Nonadecylbenzene
114
n-Pentylcyclopentane
383
n-Nonadecylcyclohexane
468
222
397
2 -n-Pentylnaphthalene
223
n-Nonylbenzene
104
Phenethyl alcohol
n-Nonylcyclohexane
458
349
p-Phenetidine
n-Nonylcyclopenian*
387
511
1 -n-Nonylnaphthalene
230
Phenol
273
2 -n-Nonylnmphthalene
231
n-Pentylbenzene
n-P enty le yc lohexane
1 -Phenyl butane
47
454
27
1 -Phenyldecane
105
1 -Phenyldocoeane
117
n-Octacoeylbenzene
1 -Phenyldodecane
107
123
1 -Phenyldotriac ontane
127
477
1 -Phenyleicoaane
115
n-Octecosylcyclopentane
406
348
- Oc tadecylbenz ene
113
n-Octadecylcyclohexane
467
349
- Octedecylcyc lopentane
396
Phenyl fluoride
132
1 -Phenylheneicoaane
116
n-Octylbenzene
103
1 -Phenylheptacoeane
122
457
1 -Phenylheptadecane
tr-Octylcyclopentane
386
112
1 - Phenylheptane
102
1 -n-Octylnaphthalene
228
1 -Phenylhexacoaane
121
2-n-Oc tylnaphthalene
229
1 -Phenylhexadecane
111
p-tert-Octylphenol
323
1 - Phenylhexane
98
1 -Phenylhexatriac ontane
131
Phenylhydrazine
510
n-Pentacoeylbenzene
120
2 -Phenyl-2 -methylpropane
474
1 -Phenylnonacosane
n-Pentacosylcyclopentane
403
1 -Phenylnonadecane
114
n-Pentadecylbenzene
110
1 -Phenylnonane
104
464
1 -Phenyloctacoeane
123
n-Pentadecylcyclopentane
393
1 -Phenyloctadecane
113
Pentemethylbenmene
97
1 -Phenyloctane
28
124
53$
INDEX
Compound
P a ge
No.
1 -Phenylpentacoeane
120
5 -Propyl-m-xylene
77
1 -Phenylpentadecane
110
Pseudocumene
20
2 - Phenylpentane
3 -Phenylpentane
C ompound
Page
No.
48
S
49
1 -Phenylpentatriacontane
130
Spiropentane
519
1 -Phenyltetracosane
119
Styrne
159
1 -Phenyltetradecane
109
1 -Phenyltetratriacontane
129
1 -Phenyltriacontane
125
o, a, a a - T e t r a c h l o r o t o l u e n e
1 -Phenyltricoeane
118
n-Tetracosylbenzene
119
1 -Phenyltridecane
108
n-Tetracosylcyclohexane
473
1 -Phenyltritriacontane
128
n-Tetracosylcyclopentane
402
106
n-Tetradecylbenzene
109
n-Tetradecylcyclohexane
463
392
1 -Phenylundecane
Prehnitene
44
T
9
142
Propenylbenzene
161
n-Tetradecylcyclopentane
Propiophenone
356
435
Tetrahydro-p-isoxazine
515
n - P r opy lb en ene
17
n-Propylcyclohexane
451
n-Propylcyclopentane
367
1 -n-Propylnaphthalene
218
2 -n-Propylnaphthalene
219
2 -Propylphenol
286
3-Propylphenol
287
o-Propylphenol
286
m-Propylphenol
287
p-Propylphenol
288
n - P r o p y l phenyl sulfide
178
2 - P r opylthiophene
192
T e t r a h y d r o-2 - m e t h y l - 1 - t h i a p y r a n
504
505
Tetrahydro-4-methyl-l-thiapyran
506
Tetrahydro-2-methylthiophene
430
T e t r a h y d r o - 3 - m e thylthiophene
431
1, 2, 3, 4 - T e t r a h y d r o n a p h t h a l e n e
239
T e t r a hyd r othiophen e
429
1, 2, 3, 4 - T e t r a m e t h y l b e n z e n e
44
1, 2, 3, 5 - T e t r a m e t h y l b e n z e n e
45
1,2, 4, 5 - T e t r a m e t h y l b e n z e n e
46
o-Propyltoluene
29
m-Propyltoluene
30
n - T e tr a t r i a c ontylc y c lohexane
483
p - P r opyltoluene
31
n-Tetratriacontylcyclopentane
412
2-Propyl-m-xylene
75
( 1 -thiabutyl) -benzene
178
2-Propyl-p-xylene
78
T nia cyclobutane
520
3 - P r opyl - o - x y 1 ene
73
Thiacyclohexane
503
4 - P r opyl - - x y l e n e
74
T h i a c y c lopentane
429
4-Propyl-m-xylene
76
Thia cyclopropane
437
3-Propylthiophene
193
323
129
536
A D V A N C E S IN C H E M I S T R Y S E R I E S
Compound
Page
No.
( 1 - T h i a ethyl) -bensene
175
(1-Thiapropyl)-benzene
176
Tbiophene
183
Thiophenol
325
Toluene
12
Compound
Page
No.
1, c i e - 2 , t r a n e - 4 - T r i
m e thylcyclopentane
380
l,trans-2, c i s - 3 - T r i m e t h y l c yc lopentane
378
1, t r a n s - 2 , c i s - 4 - T r i m e t h y l c y c lopentane
381
o-Toluidine
336
m-Toluidine
337
p-Toluidine
338
n-Triacontylbensene
125
- T r i t r i a c ontylbens ene
128
n-Triacontylcyclohexane
479
n-Tritriacontylcyclohexane
482
n-Triacontylcyclopentane
408
n-Tritriacontylcyclopentane
411
2, 4, 6 - T r i a l l y l p h e n o l
310
T r i m e t h y l e n e sulfide
520
2, 3, 4 - r i m e thylthiophene
200
2, 3, 5 - T r i m e t h y l t h i o p h e n e
201
1,2,4-Trichlorobenzene
138
, 2, 4 - T r i c h l o r o t o l u e n e
141
n-Undecyclbenxene
106
n-Tricoeylbenzene
118
n-UndecyclcycloheTane
460
n-Tricosylcyclohexane
472
n-Undecylcyclopentane
389
n - T i c s y l c y c lopentane
401
234
n-Tridecylbenzene
108
2 -n-Undecylnaphthalene
235
n-Tridecylcyclohexane
462
n-Tridecylcyclopentane
391
, , - T r i f l u o r o - m nitrotoluene
, , - T r i i l u o r o t o l u e n e
507
133
1,2, 3 - T r i m e t h y l b e n z e n e
19
1,2,4-Trimethylbenzene
20
1, 3, 5 - T r i m e t h y l b e n z e n e
21
1, 1, 2 - T r i m e t h y l c y c l o pentane
1,1, 3 - T r i m e t h y l c y c l o pentane
374
375
1, c i s - 2 , c i s - 3 - T r i m e t h y l c y c lopentane
376
1, c i s - 2 , t r a n s - 3 - T r i x n e t h y l cyclopentane
377
1, c i s - 2 , c i s - 4 - T r i m e t h y l cyclopentane
379
Vinylbenzene
159
m - and - Vinyltoluene
165
o-Xylene
14
m-Xylene
15
p-Xylene
16
2 . 3 - Xylenol
277
2 . 4 - Xylenol
278
2 . 5 - Xylenol
279
2 . 6 - Xylenol
280
3.4- Xylenol
281
3 . 5 - Xylenol
282