SINGLE OPTION CORRECT

25.

What is the wavelength of the radiation emitted producing a line in the Lyman series
when an electron falls fourth stationary state in hydrogen atom. (RH = 1.1 x 10-7 m-1)
(A) 96.97 nm
(B) 969.7 nm
(C) 9697 nm
(D) None

Sol.
26.

A
For the reaction .
PCl5(g)
PCl3(g) + Cl2(g) the forward reaction at constant temperature is favoured
by
1. Introducing an inert gas at constant volume
2. Introducing chlorine gas at constant volume
3. Introducing an inert gas at constant pressure
4. Increasing the volume of the container
5. Introducing PCl5 at constant volume
(A) 1, 2
(B) 4, 5
(C) 2, 3, 4
(D) 3, 4, 5

Sol.

27.

The linear structure is assumed by

(i) SnCl2
(iii) NO2
(A) (i) , (iii) and (iiii)
(C) (i) , (iii) and (iv)

(ii) NCO (iv) CS2

(B) (ii) , (iii) and (iv)
(D) None

PN 2 O4 2 x 2 4

Sol.

28.

One mole of N2O4(g) at 300 K is kept in a closed container under one atmosphere . It is
heated to 600k when N2O4 (g) decomposes to NO2(g). If the resultant pressure is 2.4
atm, the percentage dissociation by mass of N2O4(g) is
(A) 10%
(B) 20%
(C) 30%
(D) 40 %

Sol.

B
2NO2 (g)
Equilibrium
1-
2
Where is the degree of dissociation
V is constant

N 2 O 4 ( g)

P1 P2

T1 T2

1
P
2
300 600
P2 = 2 atm
After dissociation of N2O4 at 600 K

PN 2 O4 2(1 )
= 2- 2

PN 2 O4 2 x 2 4
Total pressure = 2 - 2 + 4
= 2 +2