FORMULARIO

PV=nRT;

P1V1 = P2V2;
T1
T2

M =moles de soluto
;
V de solucin (L)

DE

Ptotal = Pparciales ;

m = moles de soluto ;
Kg de disolvente

QUMICA
n = g__
PM
XA= nA_ ;
ntotal

ntotal= nsoluto + ndisolvente

% soluto =gramos de soluto ;

gramos de solucin

gramos de solucin = gramos de soluto + gramos de disolvente

M1V1=M2V2 ; Tf=kfm;

P =Pdisolvente P solucin;

Tf =Tdisolvente T solucin;

Tb=kbm; Tb=Tsolucin Tdisolvente

P =XsolutoPdisolvente;

=MRT;

qsistema = qagua + qcalormetro + qreaccin;

qreaccin= - (mST + CT);

E = q + w ;

Hreac = aH prod bHreact;

w=-PV;

q=mST;

Sreacc = aSprod bSreactG= aGprod bGreact;

Kc =[productos]a;
[reactivos] b

Kp =Paproductos;
Pbreactivos

Qc=[productos]a ;
[reactivos] b

n = ngases prod ngases react ; Q < K hacia productos;

C=mS;

G = H - TS;

Kp = Kc(RT) n

Q>K hacia reactivos

Ec Arrhenius:

ln k2 = (Ea) (T2 - T1)

Ec. vant Hoff: ln K2= (H) T2 - T1
k1 R
T2T1
K1 R
T2T1
o
G = -RTlnK;
G = G + RTlnQ;
G = H - TS

Primer orden
Segundo Orden

ln [A]o = kt
[A]
1 [A]

1 = kt
[A]o

Orden cero
[A]o
Ecelda = Eox + Ered;

- [A] = kt

t1/2 = 0.693
k
t 1/2
= 1___
k[A]o
t 1/2
= [A]o
2k

Ecelda = (0.0591/n ) logK,

E celda = Ecelda ( 0.0591/n ) logQ,

Ecelda = ( RT/nF )lnK,

E celda = E - ( RT/nF )lnQ,

G = -nFE

S H2O = 4.184 J/gC, densidad H2O = 1g/ml, 1cm3 = 1ml, 1cal = 4.184 J
1F = 96500C, 1J = 1V C, 1 A = 1 C/S, R= 0.082 Latm /molK , R =8.314 J/ molK ,
1 atm =760mmHg = 101.325 Kpa,
K= 0C + 273

1 L atm= 101.3J