Formulario de Q.A.

III
Celdas electroqumicas S = r
2

E
cel
= E
ctodo
- E
nodo
IR +
ctodo
+
nodo
p = m
S
/ (m
M
+ m
S
) = k / (k + 1)
Potenciometra q = 1 p = 1 / (k + 1)
E
celda
= E
ind
E
ref
+ E
j
v = L / t
R
= u q
E
ind
= L + (0.0592/Z
a
) log(a
1
+ k
A,B
b
1
Za/Zb
) k = m
S
/ m
M
= K
D
(V
S
/ V
M
)
pH
u
= pH
p
(E
u
E
p
)/0.0592 k = (t
R
t
M
) / t
M

Voltamperometra N = L/ H
E
apl
= E

- 0.0592/n log(i/i
l
i) H = A + B / u + C u
(i
d
)avg = 607nD

C u
opt
= (B/C)


Polarografa diferencial de impulsos w = 4
i
p
= nFAD

C/(t
m
)

(1 /1 + ) N = 16 (t
R
/ w)
2
= 5,5 (t
R
/ w
1/2
)
2

= exp[(nF/RT)(E/2)] R = (t
R,B
t
R,A
) / [(w
B
+ w
A
) / 2 ]
E
p
= E

- E/2 = K
D,B
/ K
D,A
= (t
R,B
t
M
) /(t
R,A
t
M
)
W

= 3.52 RT/nF R = (N
1/2
/ 4) [( 1) / ] [k / (k + 1)]
Extraccin lquido-lquido Deteccin
K
P,A
= [A]
o
/ [A]
a
LOD = 3s
bl
/ b
k = m
A,o
/ m
A,a
= K
P,A
(V
o
/ V
a
) = K
P,A
LDR = log (UL / LOD)
p = R = m
A,o
/ (m
A,a
+ m
A,o
) = k / (k + 1 ) GC
q = 1 - R = 1 / (k + 1) log k

= H / (2,3 R T) + A
K
D,A
= c
A,o
/ c
A,a
= K
P,A
/ (
o
/
a
) HPLC
q
n
= (1 - R)
n
= [ 1 / (k + 1) ]
n
N ~ K L / d
p

p
n
= R
n
= 1 - (1 - R)
n
= 1 - [ 1 / (k + 1) ]
n
ln k = A - B
Teoria de la cromatografia (
M
+
S
- 2
i
) (
M
-
S
) ~ 0
K
D
= C
S
/ C
M

M
=
j

j

u = L / t
M
= F / S

MeOH
= 1,29
ACN
= 1,63
THF

0,78
MeOH
=
ACN
= 1,26
THF

0,62
MeOH
= 0,79
ACN
=
THF

F = V / t = V
M
/ t
M
= V
R
/ t
R
t/ t
G
< 0,25