ME 2105 Material Science for Engineers

HW 5: Chapter 10 Problems
Due at Class on Wednesday Dec. 1

From the 8
th
Edition:
10.3; 10.6; 10.9; 10.15; 10.18; 10.22; 10.34; 10.39; 10.D6
10.3 If copper (which has a melting point of 1085C) homogeneously nucleates at 849C, calculate the
critical radius given values of 1.77 10
9
J/m
3
and 0.200 J/m
2
, respectively, for the latent heat of fusion
and the surface free energy.
Solution
This problem states that copper homogeneously nucleates at 849C, and that we are to calculate the critical
radius given the latent heat of fusion (1.77 10
9
J/m
3
) and the surface free energy (0.200 J/m
2
). Solution to this
problem requires the utilization of Equation 10.6 as



r * =
2T
m
AH
f
|
\


|
.
|
|
1
T
m
T
|
\


|
.
|
|



=
(2)(0.200 J / m
2
)(1085 + 273 K)
1.77 10
9
J / m
3



(

(
1
1085C 849C
|
\

|
.
|



= 1.30 10
9
m = 1.30 nm

10.6 For some transformation having kinetics that obey the Avrami equation (Equation 10.17), the
parameter n is known to have a value of 1.7. If, after 100 s, the reaction is 50% complete, how long
(total time) will it take the transformation to go to 99% completion?
Solution
This problem calls for us to compute the length of time required for a reaction to go to 99% completion. It
first becomes necessary to solve for the parameter k in Equation 10.17. In order to do this it is best manipulate the
equation such that k is the dependent variable. We first rearrange Equation 10.17 as



exp(kt
n
) = 1 y

and then take natural logarithms of both sides:


kt
n
= ln(1 y)

Now solving for k gives


k =
ln (1 y)
t
n


And, from the problem statement, for y = 0.50 when t = 100 s and given that n = 1.7, the value of k is equal to



k =
ln (1 0.5)
(100 s)
1.7
= 2.76 10
-4


We now want to manipulate Equation 10.17 such that t is the dependent variable. The above equation may be
written in the form:


t
n
=
ln (1 y)
k


And solving this expression for t leads to


t =
ln (1 y)
k



(

(
1/n


Now, using this equation and the value of k determined above, the time to 99% transformation completion is equal
to




t =
ln (1 0.99)
2.76 10
4



(

(
1/1.7
= 305 s



10.9 The kinetics of the austenite-to-pearlite transformation obey the Avrami relationship. Using the fraction
transformedtime data given here, determine the total time required for 95% of the austenite to transform to pearlite:
Fraction Transformed Time (s)
0.2 12.6
0.8 28.2

Solution
The first thing necessary is to set up two expressions of the form of Equation 10.17, and then to solve
simultaneously for the values of n and k. In order to expedite this process, we will rearrange and do some algebraic
manipulation of Equation 10.17. First of all, we rearrange as follows:



1 y = exp kt
n
( )

Now taking natural logarithms



ln (1 y) = kt
n


Or



ln (1 y) = kt
n


which may also be expressed as



ln
1
1 y
|
\

|
.
|
= kt
n


Now taking natural logarithms again, leads to



ln ln
1
1 y
|
\

|
.
|



(

( = ln k + n ln t

which is the form of the equation that we will now use. Using values cited in the problem statement, the two
equations are thus



ln ln
1
1 0.2



(

(




`
)
= ln k + n ln(12.6 s)



ln ln
1
1 0.8



(

(




`
)
= ln k + n ln(28.2 s)

Solving these two expressions simultaneously for n and k yields n = 2.453 and k = 4.46 10
-4
.
Now it becomes necessary to solve for the value of t at which y = 0.95. One of the above equationsviz



ln (1 y) = kt
n


may be rewritten as



t
n
=
ln (1 y)
k


And solving for t leads to



t =
ln (1 y)
k



(

(
1/n


Now incorporating into this expression values for n and k determined above, the time required for 95% austenite
transformation is equal to


t =
ln (1 0.95)
4.64 10
4



(

(
1/2.453
= 35.7 s

10.15 Suppose that a steel of eutectoid composition is cooled to 550C (1020F) from 760C (1400F) in less than
0.5 s and held at this temperature.
(a) How long will it take for the austenite-to-pearlite reaction to go to 50% completion? To 100%
completion?
(b) Estimate the hardness of the alloy that has completely transformed to pearlite.

Solution
We are called upon to consider the isothermal transformation of an iron-carbon alloy of eutectoid
composition.
(a) From Figure 10.22, a horizontal line at 550C intersects the 50% and reaction completion curves at
about 2.5 and 6 seconds, respectively; these are the times asked for in the problem statement.
(b) The pearlite formed will be fine pearlite. From Figure 10.30a, the hardness of an alloy of composition
0.76 wt% C that consists of fine pearlite is about 265 HB (27 HRC).

10.18 Using the isothermal transformation diagram for an ironcarbon alloy of eutectoid composition (Figure
10.22), specify the nature of the final microstructure (in terms of microconstituents present and approximate
percentages of each) of a small specimen that has been subjected to the following timetemperature treatments. In
each case assume that the specimen begins at 760C (1400F) and that it has been held at this temperature long
enough to have achieved a complete and homogeneous austenitic structure.
(a) Cool rapidly to 700C (1290F), hold for 10
4
s, then quench to room temperature. (b) Reheat the
specimen in part (a) to 700C (1290F) for 20 h. (c) Rapidly cool to 600C (1110F), hold for 4 s, rapidly cool to
450C (840F), hold for 10 s, then quench to room temperature. (d) Cool rapidly to 400C (750F), hold for 2 s, then
quench to room temperature. (e) Cool rapidly to 400C (750F), hold for 20 s, then quench to room temperature. (f)
Cool rapidly to 400C (750F), hold for 200 s, then quench to room temperature. (g) Rapidly cool to 575C
(1065F), hold for 20 s, rapidly cool to 350C (660F), hold for 100 s, then quench to room temperature. (h) Rapidly
cool to 250C (480F), hold for 100 s, then quench to room temperature in water. Reheat to 315C (600F) for 1 h
and slowly cool to room temperature.
(a) Cool rapidly to 700C (1290F), hold for 10
4
s, then quench to room temperature.

Solution
Below is Figure 10.22 upon which is superimposed the above heat treatment.


After cooling and holding at 700C for 10
4
s, approximately 50% of the specimen has transformed to
coarse pearlite. Upon cooling to room temperature, the remaining 50% transforms to martensite. Hence, the final
microstructure consists of about 50% coarse pearlite and 50% martensite.

(b) Reheat the specimen in part (a) to 700C (1290F) for 20 h.

Solution
Heating to 700C for 20 h the specimen in part (a) will transform the coarse pearlite and martensite to
spheroidite.

(c) Rapidly cool to 600C (1110F), hold for 4 s, rapidly cool to 450C (840F), hold for 10 s, then quench
to room temperature.

Solution
Below is Figure 10.22 upon which is superimposed the above heat treatment.



After cooling to and holding at 600C for 4 s, approximately 50% of the specimen has transformed to
pearlite (medium). During the rapid cooling to 450C no transformations occur. At 450C we start timing again at
zero time; while holding at 450C for 10 s, approximately 50 percent of the remaining unreacted 50% (or 25% of
the original specimen) will transform to bainite. And upon cooling to room temperature, the remaining 25% of the
original specimen transforms to martensite. Hence, the final microstructure consists of about 50% pearlite
(medium), 25% bainite, and 25% martensite.

(d) Cool rapidly to 400C (750F), hold for 2 s, then quench to room temperature.

Solution
Below is Figure 10.22 upon which is superimposed the above heat treatment.



After cooling to and holding at 400C for 2 s, no of the transformation begin lines have been crossed, and
therefore, the specimen is 100% austenite. Upon cooling rapidly to room temperature, all of the specimen
transforms to martensite, such that the final microstructure is 100% martensite.

(e) Cool rapidly to 400C (750F), hold for 20 s, then quench to room temperature.

Solution
Below is Figure 10.22 upon which is superimposed the above heat treatment.


After cooling and holding at 400C for 20 s, approximately 40% of the specimen has transformed to
bainite. Upon cooling to room temperature, the remaining 60% transforms to martensite. Hence, the final
microstructure consists of about 40% bainite and 60% martensite.

(f) Cool rapidly to 400C (750F), hold for 200 s, then quench to room temperature.

Solution
Below is Figure 10.22 upon which is superimposed the above heat treatment.



After cooling and holding at 400C for 200 s, the entire specimen has transformed to bainite. Therefore,
during the cooling to room temperature no additional transformations will occur. Hence, the final microstructure
consists of 100% bainite.

(g) Rapidly cool to 575C (1065F), hold for 20 s, rapidly cool to 350C (660F), hold for 100 s, then
quench to room temperature.

Solution
Below is Figure 10.22 upon which is superimposed the above heat treatment.


After cooling and holding at 575C for 20 s, the entire specimen has transformed to fine pearlite. Therefore,
during the second heat treatment at 350C no additional transformations will occur. Hence, the final microstructure
consists of 100% fine pearlite.

(h) Rapidly cool to 250C (480F), hold for 100 s, then quench to room temperature in water. Reheat to
315C (600F) for 1 h and slowly cool to room temperature.

Solution
Below is Figure 10.22 upon which is superimposed the above heat treatment.


After cooling and holding at 250C for 100 s, no transformations will have occurredat this point, the
entire specimen is still austenite. Upon rapidly cooling to room temperature in water, the specimen will completely
transform to martensite. The second heat treatment (at 315C for 1 h)not shown on the above plotwill
transform the material to tempered martensite. Hence, the final microstructure is 100% tempered martensite.

10.22 Make a copy of the isothermal transformation diagram for a 0.45 wt% C iron-carbon alloy (Figure 10.39),
and then sketch and label on this diagram the time-temperature paths to produce the following microstructures:
(a) 42% proeutectoid ferrite and 58% coarse pearlite
(b) 50% fine pearlite and 50% bainite
(c) 100% martensite
(d) 50% martensite and 50% austenite
Solution
Below is shown an isothermal transformation diagram for a 0.45 wt% C iron-carbon alloy, with time-
temperature paths that will produce (a) 42% proeutectoid ferrite and 58% coarse pearlite; (b) 50% fine pearlite and
50% bainite; (c) 100% martensite; and (d) 50% martensite and 50% austenite.

10.34 Briefly describe the simplest heat treatment procedure that would be used in converting a 0.76 wt% C steel
from one microstructure to the other, as follows:
(a) Spheroidite to tempered martensite
(b) Tempered martensite to pearlite
(c) Bainite to martensite
(d) Martensite to pearlite
(e) Pearlite to tempered martensite
(f) Tempered martensite to pearlite
(g) Bainite to tempered martensite
(h) Tempered martensite to spheroidite
Solution
In this problem we are asked to describe the simplest heat treatment that would be required to convert a
eutectoid steel from one microstructure to another. Figure 10.27 is used to solve the several parts of this problem.
(a) For spheroidite to tempered martensite, austenitize at a temperature of about 760C, quench to room
temperature at a rate greater than about 140C/s, then isothermally heat at a temperature between 250 and 650C.
(b) For tempered martensite to pearlite, austenitize at a temperature of about 760C, then cool to room
temperature at a rate less than about 35C/s.
(c) For bainite to martensite, first austenitize at a temperature of about 760C, then quench to room
temperature at a rate greater than about 140C/s.
(d) For martensite to pearlite, first austenitize at a temperature of about 760C, then cool to room
temperature at a rate less than about 35C/s.
(e) For pearlite to tempered martensite, first austenitize at a temperature of about 760C, then rapidly
quench to room temperature at a rate greater than about 140C/s, then isothermally heat treat (temper) at a
temperature between 250 and 650C.
(f) For tempered martensite to pearlite, first austenitize at a temperature of about 760C, then cool to room
temperature at a rate less than about 35C/s.
(g) For bainite to tempered martensite, first austenitize at a temperature of about 760C, then rapidly
quench to room temperature at a rate greater than about 140C/s, then isothermally heat treat (temper) at a
temperature between 250 and 650C.
(h) For tempered martensite to spheroidite simply heat at about 700C for approximately 20 h.

10.39 For a eutectoid steel, describe isothermal heat treatments that would be required to yield specimens having
the following Rockwell hardnesses:
(a) 93 HRB,
(b) 40 HRC, and
(c) 27 HRC.
Solution
For this problem we are asked to describe isothermal heat treatments required to yield specimens having
several Brinell hardnesses.
(a) From Figure 10.30a, in order for a 0.76 wt% C alloy to have a Rockwell hardness of 93 HRB, the
microstructure must be coarse pearlite. Thus, utilizing the isothermal transformation diagram for this alloy, Figure
10.22, we must rapidly cool to a temperature at which coarse pearlite forms (i.e., to about 675C), allow the
specimen to isothermally and completely transform to coarse pearlite. At this temperature an isothermal heat
treatment for at least 200 s is required.
(b) This portion of the problem asks for a hardness of 40 HRC the microstructure could consist of either (1)
about 75% fine pearlite and 25% martensite (Figure 10.32), or (2) tempered martensite (Figure 10.35).
For case (1), after austenitizing, rapidly cool to about 580C (Figure 10.22), hold at this temperature for
about 4 s (to obtain 75% fine pearlite), and then rapidly quench to room temperature.
For case (2), after austenitizing, rapidly cool to room temperature in order to achieve 100% martensite.
Then temper this martensite for about 2000 s at 535C (Figure 10.35).
(c) From Figure 10.30a, in order for a 0.76 wt% C alloy to have a Rockwell hardness of 27 HRC, the
microstructure must be fine pearlite. Thus, utilizing the isothermal transformation diagram for this alloy, Figure
10.22, we must rapidly cool to a temperature at which fine pearlite forms (i.e., at about 580C), allow the specimen
to isothermally and completely transform to fine pearlite. At this temperature an isothermal heat treatment for at
least 7 s is required.

10.D6 Is it possible to produce an oil-quenched and tempered 4340 steel that has a minimum yield
strength of 1400 MPa (203,000 psi) and a ductility of at least 42%RA? If this is possible, describe the
tempering heat treatment. If it is not possible, explain why.
Solution
This problem asks if it is possible to produce an oil-quenched and tempered 4340 steel that has a minimum
yield strength of 1400 MPa (203,000 psi) and a minimum ductility of 42%RA, and, if possible, to describe the
tempering heat treatment. In Figure 10.34 is shown the tempering characteristics of this alloy. According to this
figure, in order to achieve a minimum yield strength of 1400 MPa a tempering temperature of less that about 410C
is required. On the other hand, tempering must be carried out at greater than about 360C for a minimum ductility
of 42%RA. Therefore, an oil-quenched and tempered 4340 alloy possessing these characteristics is possible;
tempering would be carried out at between 360C and 410C for 1 h.