Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
QUIMICA
Problema N 4
Se puede producir formaldehido apartir de metanol de una combinacin de oxigeno de
presencia de un catalizador(metales de plata-cobre) las reacciones que tienen lugar son:
R1: CH3 OH +1/2 O2 -----HCHO + H2 O
R2: CH3 OH -----HCHO + H2
R3: CH3 OH +3/2 O2 -----CO2 + 2H2 O
Tambin se puede esperar una perdida de material por combinacin completa sigue la
reaccin. Determinar la TAdiabtica de reaccin de la corriente del reactor.
La relacion de( N CH3 OH : N AIRE )=1:4
Compuest
o
CH3 OH
-238.6
HCHO
-115.9
O2
0
N2
0
CO2
-412.9
H2O
75.86
34.28
29,1
29,00
36.11
-285.84
16.83
4.268
1,158
0,2199
3.97
-0,6076
0,5723
-2.88
-8.694
1,311
-2,871
7.87
-75.04
1ERA REACCION
CH3 OH +1/2 O2 -----HCHO + H2 O
CH3 OH = 1
HCHO =1
O2
H2 O =1
=-0.5
Hallando los
=
= -1(75.86*10-3)-0.5x (29.10x10-3)+(34.28x10-3)
=0.01927
Pgina 1
=
= -1(0) -0.5(-0.6076x10-8)+1(4.268x10-5)+1(0)
=3.038x10-9
=
= -1(0)-0.5 (1.311x10-12)+1(-8.694x10-12)+1(0)
=-8.0385x10-12
-2
-9
(8.0385X10-12)/4(T4 254)
2DA REACCION
CH3 OH -----HCHO + H2
CH3 OH = -1
HCHO =1
H2 O =1
Hallando los
Pgina 2
=
=-1(16.83x10-3)+1 (4.268x10-5)+1(0.00765x10-5)
=-1.255X10-4
=
= -1(0) -1(0)+1(0.3288x10-8)+1(0)
=3.038x10-9
=
= -1(0)-0.5 (1.311x10-12)+1(-8.694x10-12)+1(0)
=9.55598x10-12
(9.5598X10-12)/4(T4 254)
3ERA REACCION
CH3 OH +3/2 O2 -----CO2 + 2H2 O
CH3 OH = -1
CO2 =1
H2 O =2
O2
=-1.5
Pgina 3
Hallando los
=
= -1(75.86X10-3)-1.5x (29.10x10-3)+(36.11x10-3)+2(75.4X10-3)
=0.0674
=
=-1(16.83x10-3)-1.5 (1.158x10-5)+1(3.97x10-5) +2(0)
=-1.4597X10-4
=
= -1(0) -1.5(0.6076x10-8)+1(-2.88-8)+1(0)
=-1.966x10-8
=
= -1(0) -1.5(1.311x10-12)+1(7.87x10-12)+2(0)
=5.9035x10-12
(5.9035X10-12)/4(T4 254)
Reemplazando en la siguiente formula:
1( T50
(75.86x10-3+16.83x10-5 T)
dt )+0.84(T50 (29.10 x10-3+1.158x10-5 T-0.6076X10-8T2) dt ) +3.16(T50 (29x103
0.2199x10-5 T+0.5723X10-8T3 -2.87X10-12 T3) dt [ 0.3(122700-0.01274 (T-25)- (1.255X10-4)/2(T2 252) - (0.3288X10-8)/3(T3 253)(9.5598X10-12)/4(T4 254)) + 0.5 (-163140+0.01927 (T-25)- (1.314X10-2)/2(T2 252) -
Pgina 4
(3.038X10-9)/3(T3 253)-(8.0385X10-12)/4(T4 254)) + 0.2 (-745980-0.0674 (T-25)(1.4597x10-4)/2(T2 252) - (1.966X10-8)/3(T3 253)+(5.9035X10-12)/4(T4 254) )
0=193949.0755+0.11797T- 12.9558 T2 +9.217X10-9 T3 +1.5305x10-12 T4
T=
Pgina 5