NCEA Level 3 Chemistry 91390 (3.

4) page 1 of 5
SAMPLE ASSESSMENT SCHEDULE
Chemistry 91390 (3.4): Demostr!te "#erst!#i$ o% thermo&hemi&!' (ri&i('es !# the (ro(erties o% (!rti&'es !# s")st!&es
Assessmet Criteri!
A&hie*emet A&hie*emet +ith Merit A&hie*emet +ith E,&e''e&e
Demonstrate understanding ivolves !es"ri#ig$
i!etifyig$ amig$ !ra%ig$ a! givig a a""o&t of
the properties of parti"les$ the properties of s&#sta"es
they form$ a! thermo"hemi"al pri"iples. 'his re(&ires
the &se of "hemistry vo"a#&lary$ sym#ols$ a!
"ovetios a! may i"l&!e relate! "al"&latios.
Demonstrate in-depth understanding ivolves ma)ig
a! e*plaiig li)s #et%ee the properties of parti"les$
the properties of s&#sta"es they form$ thermo"hemi"al
pri"iples$ a! relate! "al"&latios. 'his re(&ires
e*plaatios that &se "hemistry vo"a#&lary$ sym#ols$
a! "ovetios.
Demonstrate comprehensive understanding
typi"ally ivolves ela#oratig$ +&stifyig$ relatig$
eval&atig$ "omparig a! "otrastig$ or
aalysig li)s #et%ee the properties of parti"les$
the properties of s&#sta"es they form$
thermo"hemi"al pri"iples$ a! relate!
"al"&latios. 'his re(&ires the "osistet &se of
"hemistry vo"a#&lary$ sym#ols$ a! "ovetios.
E*i#e&e St!temet
-e E,(e&te# &o*er!$e A&hie*emet Merit E,&e''e&e
(a)
1s
,
,s
,
,p
-
1s
,
,s
,
,p
-
3s
,
3p
-
3!
10
4s
,
4p
3
1s
,
,s
,
,p
-
3s
,
3p
-
3!
,
. (a) (i)$ '/0
"ofig&ratios "orre"t.
(#) (i)
1oth Cl a! Cl
2
have their vale"e ele"tros i the same eergy
level #&t Cl
2
has oe more ele"tro$ %hi"h "a&ses greater
ele"tro 2 ele"tro rep&lsio. 3e"e Cl
2
has a larger ra!i&s.
Na
4
has oe less eergy level tha Na. 3e"e Na
4
has a smaller
ra!i&s.
. (#) "orre"t statemet
regar!ig eergy level.
05
. (#) ele"tro6ele"tro
rep&lsio
05
greater attra"tio of
ele"tros.
05
. (#) (ii) !es"ri#es
i"reases &"lear "harge i
. (#) li)s ma!e a!
"orre"tly e*plaie! for oe
pair of spe"ies.
. (#) ele"tro6ele"tro
rep&lsio a! i"rease!
&m#er of protos &se! to
+&stify !iffere"es i atomi"
ra!ii a! ioisatio eergy.
(#) (ii) Cl a! Na have the same &m#er of eergy levels. 3o%ever$ Cl
has a greater &m#er of protos "a&sig a stroger attra"tio to
ele"tros tha Na.
3e"e Cl has a greater first ioisatio eergy.
NCEA Level 3 Chemistry 91390 (3.4) page , of 5
Cl
(") (i)
ICl2

IF5
. (") (i)$ Le%is str&"t&res
10'3 "orre"t
05
10'3 !iagrams "orre"t
05
10'3 shapes "orre"t.
05
7iagram8shape a! Le%is
!iagram for oe
. (") (i)$ Le%is str&"t&res
a! shape for 10'3
"ol&ms "orre"t.
Nee!s s(&are #ra")ets a!
egative "harge
Liear 9(&are #ase! pyrami!
(") (ii)
Cl is more ele"troegative tha :; therefore the :2Cl #o! is
polar i #oth mole"&les.
:Cl3 is a trigoal pyrami! so this mole"&le is ot symmetri"al.
'his meas that the !ipole momets !o ot "a"el a! the
mole"&le is polar.
:Cl5 is a trigoal #ipyrami! so the mole"&le is symmetri"al. 'his
meas that the !ipole momets "a"el a! the mole"&le is o
polar.
. (") (ii)$ polarities of 10'3
mole"&les "orre"t.
05
9hapes of #oth mole"&les
"orre"t
05
9tates ele"troegativity of
Cl is greater tha that of :
05
5e"ogi<es the :6Cl #o!
is polar
05
7es"ri#es :Cl3 as
&symmetri"al a! :Cl5 as
symmetri"al
. (") (ii)$ li)s ma!e
#et%ee '/0 of=
ele"troegativity
!ipole momet
symmetry.
. (") (ii)$ li)s ma!e
#et%ee '35EE of=
ele"troegativity
!ipole momet
symmetry.
Not A"hieve! N> No respose; o relevat evi!e"e.
N1 Ca!i!ate provi!es ay 0NE statemet for A"hievemet.
NCEA Level 3 Chemistry 91390 (3.4) page 3 of 5
N, Ca!i!ate provi!es ay '/0 statemets for A"hievemet.
A"hievemet
A3 Ca!i!ate provi!es ay '35EE statemets for A"hievemet.
A4 Ca!i!ate provi!es ay ?0@5 statemets for A"hievemet.
Aerit
A5 Ca!i!ate provi!es ay '/0 statemets for Aerit.
A- Ca!i!ate provi!es ALL '35EE statemets for Aerit.
E*"elle"e
EB Ca!i!ate provi!es ay 0NE statemet for E*"elle"e.
EC Ca!i!ate provi!es 10'3 statemets for E*"elle"e.
T+o E,(e&te# &o*er!$e A&hie*emet Merit E,&e''e&e
(a) (i) 9(s) 4 0,(g) 90,(g)
. (a) (i) or (ii)$ either
e(&atio "orre"t.
. (a) (ii)$ li)s the rea"tios
are the same to the val&es
#eig the same.
(a) (ii)
fH (90,$ g) "a #e represete! #y=
9(s) 4 0,(g) 90,(g)
'his is the same as the e(&atio i (i) a#ove$ ie$ "H (9$ s).
3e"e the val&es for fH (90,$ g) a! "H (9$ s) %ill #e the
same.
(#)
M(N33) D 1B.0 g mol
21
n(N33) D m8M D 50.081B.0 D ,.94 mol
Eergy (50.0 g N33) D ,.94 2 1,-B84 D
2931 )E or 931 )E eergy pro!&"e!
. (#) (i)$ eergy "al"&late!
"orre"tly.
. (#) a! (")$ "orre"t
as%er %ith &it for
"al"&latio. (Ca"l&latio
sho% evi!e"e of the
"orre"t &se of sigifi"at
fig&res
(") 7esire! e(&atio is=
2 ,E(A 4 3E(1 4 ,E(C 2 -E(4
4N33(g) ,N,(g) 4 -3,(g) FrH D 41C4
-3,(g) 4 30,(g) -3,0(g) FrH D 2145,
,N,(g) 4 ,0,(g) 4N0(g) FrH D 43-0
-3,0 (g) -3,0(l) FvapH D 2,4-
. (")$ "al"&latio sho%s a
error. Eg$ &se of Fvap3 or
m&ltipli"atio fa"tor.
. (")$ %or)ig lea!ig to
sesi#le as%er for
"al"&latio (errors may
i"l&!e &its$ sig$
arithmeti").
NCEA Level 3 Chemistry 91390 (3.4) page 4 of 5
, 9, 2 3 4C4 4 , 1C0 2 - 41
D 1C4 2145, 4 3-0 2 ,4-
D 2 1154 )E mol
21
(61150 )Emol
61
3 sig fig)
Not A"hieve!
N> No respose; o relevat evi!e"e.
N1 Ca!i!ate provi!es some a""&rate statemets %itho&t as%erig ay (&estios "ompletely.
N, Ca!i!ate provi!es ay 0NE statemet for A"hievemet.
A"hievemet
A3 Ca!i!ate provi!es ay '/0 statemets for A"hievemet.
A4 Ca!i!ate provi!es ay '35EE statemets for A"hievemet.
Aerit
A5 Ca!i!ate provi!es ay 0NE statemet for Aerit.
A- Ca!i!ate provi!es 10'3 statemets for Aerit.
E*"elle"e
EB Aior errors (eg omissio or ia""&ra"ies) from the E*"elle"e "riteria.
EC Ca!i!ate provi!es ALL the evi!e"e from the E*"elle"e "riteria.
Three E,(e&te# &o*er!$e A&hie*emet Merit E,&e''e&e
(a) (i)
Etropy "hage is 4 8 etropy i"reases. .os i sol&tio
(geerally) have higher etropy tha soli!s.
. (a)$ '/0 etropy
"hages "orre"t.
(a) (ii)
Etropy "hage is 2 8 etropy !e"reases. A larger mole"&le has
forme! from a smaller oe 8 the &m#er of parti"les has
!e"rease!.
(a) (iii)
Etropy "hage is 4 8 etropy i"reases. 'he &m#er of
mole"&les of gas has i"rease!.
(#)
'he etropy "hage i a spotaeo&s rea"tio is positive.
3o%ever$ the etropy "hage of the steam %he it "o!eses is
egative as gases have higher etropy tha li(&i!s.
/he steam "o!eses$ eergy is give o&t to its s&rro&!igs.
'his i"reases the etropy of the s&rro&!igs. 3e"e the total
etropy "hage (etropy "hage of the steam a! etropy
"hage of the s&rro&!igs) is positive as this is a spotaeo&s
rea"tio.
. (#)$ etropy "hage i a
spotaeo&s rea"tio is
positive.
. (#)$ etropy "hage
li)e! to etropy of system
a! s&rro&!igs.
(") /ater has a hy!roge atom #o!e! to a atom %ith high . (")$ %ater has hy!roge . (")$ a "ompariso ma!e . (")$ "ompariso ma!e
NCEA Level 3 Chemistry 91390 (3.4) page 5 of 5
ele"troegativity (o*yge) so hy!roge #o!ig o""&rs #et%ee
mole"&les. 'he other t%o mole"&les !o ot have hy!roge
#o!ig #et%ee mole"&les. 3y!roge #o!ig is the strogest
of the itermole"&lar for"es; he"e it has the highest #oilig
poit.
'he istataeo&s !ipoles preset i 0, a! 3,9 are similar as
the si<e of the ele"tro "lo&!s is similar. 0, is a o6polar
mole"&le so it has this istataeo&s !ipole oly. As %ell as
havig these istataeo&s !ipoles 3,9 is a polar mole"&le a!
has permaet !ipole for"es #et%ee mole"&les. 'he effe"t of
these for"es of attra"tio #et%ee mole"&les gives 3,9 a higher
#oilig poit tha 0,.
#o!ig #et%ee parti"les.
. (")$ o*yge has
istataeo&s !ipoles
#et%ee parti"les.
. (")$ hy!roge s&lphi!e is
a polar mole"&le that has
permaet !ipoles #et%ee
parti"les.
#et%ee the parti"les
preset i t%o s&#sta"es.
#et%ee all '35EE
s&#sta"es li)e! to all the
for"es of attra"tio preset.
Not A"hieve!
N> No respose; o relevat evi!e"e.
N1 Ca!i!ate provi!es some a""&rate statemets %itho&t as%erig ay (&estios "ompletely.
N, Ca!i!ate provi!es ay 0NE statemet for A"hievemet.
A"hievemet
A3 Ca!i!ate provi!es ay '/0 statemets for A"hievemet.
A4 Ca!i!ate provi!es ay '35EE statemets for A"hievemet.
Aerit
A5 Ca!i!ate provi!es ay 0NE statemet for Aerit.
A- Ca!i!ate provi!es 10'3 statemets for Aerit.
E*"elle"e
EB Aior errors (eg omissio or ia""&ra"ies) from the E*"elle"e "riteria.
EC Ca!i!ate provi!es ALL the evi!e"e from the E*"elle"e "riteria.