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Title: Chapter 16(1)
Started: September 27, 2009 4:09 PM
Submitted: September 27, 2009 5:09 PM
Time spent: 00:59:51
Total score: 8/12 = 66.67% Total score adjusted by 0.0 Maximum possible score: 12

1. Average Rate 2
The compound AX2 decomposes according to the equation, 2 AX2(g) => 2 AX(g) + X2(g). In
one experiment, [AX2] was measured at various times, and these data recorded:
Time (s) [AX2] mol/L
0 0.0500
2.0 0.0448
6.0 0.0300
8.0 0.0249
10.0 0.0209
20.0 0.0088

What is the average rate from 6.0 to 20.0 seconds in mol / L s? Use 3 significant figures!
[don't include units in your answer; if you want to use scientific notation, use the E format.
e.g., 0.0011 is 1.1E-3

Student Response Value Correct Answer


Equals 0.00151 (100%)
Equals 0.0015 (100%)
Equals 1.5E-3 (100%)
1. -7.57E-4 0%
Equals 1.51E-3 (100%)
Equals .00151 (100%)
Equals .0015 (100%)

Score: 0/1

2. Relative Rates of Substances 15


Consider the reaction, 2 D(g) + 3 E(g) + F(g) => 2 G(g) + H(g) When [G] is increasing at
0.81 mol/Ls, how quickly is [F] decreasing?

Student Response Value Correct Answer


Answer 1.6 0% 0.405

Score: 0/1

3. Rate Law General 1

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What is the overall reaction order for a reaction with the following rate law?

Rate = k[BrO3-][Br-][H+]2

Student Correct
Value Feedback
Response Answer
1. First 0%
2. Second 0%
3. Third 0%
4. Fourth 100%
5. Fifth 0%

Score: 1/1

4. Known Rate Law, Change Conc 47

Consider the reaction with the rate law, Rate = k[BrO3-][Br-][H+]2


By what factor does the rate change if the concentration of BrO3- is decreased by a factor of
2, that of Br- is doubled and that of H+ is doubled ?

Student Response Value Correct Answer


Equals 4 (100%)
1. 4 100%
Equals 4/1 (100%)

Score: 1/1

5. Known Rate Law, Change Conc 25

Consider the reaction with the rate law, Rate = k[BrO3-][Br-][H+]2


By what factor does the rate change if the concentration of BrO3- is tripled and that of Br- is
tripled? Just put in the number as a whole number or fraction.

Student Response Value Correct Answer


Equals 9 (100%)
1. 9 100%
Equals 9/1 (100%)

Score: 1/1

6. Determine Rate Law 37


Given the data below for the reaction, 2 A + 2 B + 4 C => D + E + 3 F, the reaction is
1.----- order in A, 2.----- order in B, 3.----- order in C and 4.----- order overall. USE WORDS
TO FILL IN THE BLANKS NOT NUMBERS (i.e., zero, first, second etc) !!!!! :
Experiment Initial conc of A, Initial conc of B, Initial conc of C, Initial rate,
mol/L mol/L mol/L mol/L.s

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1 0.1 0.2 0.4 2 x 10-3


2 0.2 0.2 0.4 4 x 10-3
3 0.3 0.4 0.4 2.4 x 10-2
4 0.4 0.6 0.2 7.2 x 10-2

Student Response Value Correct Answer


1. first 25% Equals first (25%)
2. second 25% Equals second (25%)
3. zero 25% Equals zero (25%)
4. third 25% Equals third (25%)

Score: 1/1

7. Determine Rate Law 41


Given the data below for the reaction, 2 A + 2 B + 4 C => D + E + 3 F, the reaction is
1.----- order in A, 2.----- order in B, 3.----- order in C and 4.----- order overall. USE WORDS
TO FILL IN THE BLANKS NOT NUMBERS (i.e., zero, first, second etc) !!!!! :
Experiment Initial conc of A, Initial conc of B, Initial conc of C, Initial rate,
mol/L mol/L mol/L mol/L.s
1 0.1 0.2 0.4 2 x 10-3
2 0.2 0.2 0.4 2 x 10-3
3 0.3 0.4 0.4 4 x 10-3
4 0.4 0.6 0.2 1.5 x 10-3

Student Response Value Correct Answer


1. zero 25% Equals zero (25%)
2. first 25% Equals first (25%)
3. second 25% Equals second (25%)
4. third 25% Equals third (25%)

Score: 1/1

8. Calculate k from Rate Law 21


For the reaction, 2 A(g) + 2 B(g) => C(g) + 3 D(g), the following data were obtained at
constant temperature.
Experiment Initial [A], mol/L Initial [B], mol/L Initial Rate, M/min
1 0.11 0.15 2.0 x 10-5
2 0.11 0.30 4.0 x 10-5
3 0.22 0.45 1.2 x 10-4

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4 0.22 0.60 1.6 x 10-4


Calculate the value of k to 3 significant figures.

Student Response Value Correct Answer


Equals 0.00121 (100%)
1. 1.21E-3 100% Equals .00121 (100%)
Equals 1.21E-3 (100%)

Score: 1/1

9. Units of k 1
Which of the following would be a reasonable unit for the rate constant of a first order
reaction?

Student Correct
Value Feedback
Response Answer
1. mol/L.sec 0%
2
2. mol /sec.L 0% 2

3. 1/sec 100%
4. L/mol.sec 0%
2 2
5. L /mol .sec 0%

Score: 1/1

10. IRL 1 c 2

A reaction has a rate constant of 0.0348 sec-1, how much of the compound (in mol/L) is left
after 7.41 sec, if there was 0.150 mol/L at the start? (give answer to 3 sig figs using E
notation)?

Student Response Value Correct Answer


Answer 1.48E-1 0% 0.116

Score: 0/1

11. IRL 1 t 8

A reaction has a rate constant of 0.00473 sec-1, how long will it take (in minutes) until
0.463 mol/L of the compound is left, if there was 0.629 mol/L at the start? (give answer to 3
sig figs using E notation)?

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Student Response Value Correct Answer


Answer 1.08E0 100% 1.080

Score: 1/1

12. IRL 1 kt % 4

In a first order decomposition, the constant is 0.00827 sec-1. What percentage of the
compound has decomposed after 8.24 minutes?

Student Response Value Correct Answer


Answer 59.7 0% 98.3

Score: 0/1

Done

5 of 5 27-Sep-09 5:55 PM