MATERIAL SAFETY DATA SHEET

CHEMICAL PRODUCTS
MOLYBDENUM CONCENTRATE
DIVISION CODELCO NORTE
SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product name
MOLYBDENUM CONCENTRATE
Product Code
74 (INTERNAL SAP CODE)
Manuacturer
DI!ISION CODELCO NORTE" DIRECCI#N
Su$$%&er
CODELCO" 'UER(ANOS )*7+" SANTIA,O- C'ILE"
P.one Emer/enc0
COMPLETAR
Contact Inormat&on
COMPLETAR
C.em&ca% Name
N"A"
S0non0m
N"A"
C.em&ca% (ormu%a
N"A"
C.em&ca% (am&%0
METALS SUL(IDES
SECTION 2: COMPOSITIONS / INGREDIENTS
C.em&ca% Name CAS
Concentrat&on (c"a") EU N1 SYMBOL R&23 P.ra2e2
MOLYBDENUM
S&O*
IRON
COPPER
SULP'UR
744565767
)47+768+67
744567568
744+69+67
77+464465
476 9*
: 8
: *
: 4
49647
*4)694964
*4)6+5864
*4)6)9568
*4)67**68
6
6
(
(
( ;&
6
6
))
))
))648<47<47
SECTION 3: HAZARD IDENTIFICATION
P.02&ca%<c.em&ca% .a=ard2
SUBLIME TO 49+ 1C" MAY REACT !I,OROUSLY >IT' STRON, O;IDI?ERS"
COMBINED >IT' POTASSIUM NITRATE- E;PLOSI!E >'EN 'EATED"
'uman .ea%t. .a=ard2
MAY CAUSE EYE- RESPIRATORY TRACT AND S@IN TEMPORAL IRRITATION"
TO;IC I( S>ALLO>ED" MAY INDUCE 'YPOT'YROIDISME AND ANEMIA" MAY
CAUSE LI!ER DISORDERS"
EnA&ronmenta% .a=ard2
NOT APPLICABLE
SECTION 4: FIRST AIDS
In.a%at&on
REMO!E (ROM E;POSURE TO A (RES' AIR SOURCE IMMEDIATELY" I( NOT
BREAT'IN,- ,I!E ARTI(ICIAL RESPIRATION" I( BREAT'IN, IS DI((ICULT- ,I!E
O;Y,EN" ,ET MEDICAL ATTENTION IN E!ENT O( ANY COMPLAINTS"
S3&n
IMMEDIATELY (LUS' S@IN >IT' PLENTY O( SOAP AND >ATER (OR AT LEAST
)9 MINUTES >'ILE REMO!IN, CONTAMINATED CLOT'IN, AND S'OES" >AS'
CLOT'IN, AND CLEAN S'OES BE(ORE REUSE" I( IRRITATION PERSIST-
CONSULT A SPECIALIST"
E0e2
IMMEDIATELY (LUS' EYES >IT' PLENTY O( >ATER (OR AT LEAST )9
MINUTES- LI(TIN, LO>ER AND UPPER EYELIDS OCCASIONALLY" I( IRRITATION
PERSIST- CONSULT AN EYE SPECIALIST"
In/e2t&on
,I!E TO DRIN@ 4++ m% >ATER AND INDUCE !OMITIN, IMMEDIATELY AS
DIRECTED BY MEDICAL PERSONNEL" NE!ER ,I!E ANYT'IN, BY MOUT' TO
AN UNCONSCIOUS PERSON" ,ET MEDICAL ATTENTION"
Note to P.02&c&an
NOT APPLICABLE"
SECTION 5: FIRE-FIGHTING MEASURES
EBt&n/u&2.&n/ med&a
NOT APPLICABLE"
MOLYBDENUM CONCENTRATE
(CODELCO NORTE DI!ISION)
Date I22ued C 4)"+9"*++4
Pa/e * o 4
S$ec&a% Procedure2
USE >ATER TO COOL RECIPIENT E;POSURE TO 'EAT"
Per2ona% Protect&on EDu&$ment
AS IN ANY (IRE- >EAR A SEL(6CONTAINED BREAT'IN, APPARATUS IN
PRESSURE6DEMAND- MS'A<NIOS' (APPRO!ED OR EEUI!ALENT)- AND (ULL
PROTECTI!E ,EAR (LE!EL PROTECTION C B)
SECTION 6: ACCIDENTAL RELEASE MEASURES
S$&%%<Lea32
!ENTILATE AREA O( SPILL" S>EEP UP AND CONTAINERI?E (OR RECLAMATION
OR DISPOSAL" DO NOT ALLO> TO ENTER SE>A,E SYSTEM" !ACUUMIN, OR
>ET S>EEPIN, MAY BE USED TO A!OID DUST DISPERSAL" >EAR
APPROPRIATE PERSONAL PROTECTI!E EEUIPMENT (LE!EL PROTECTIONC C)"
SECTION : HANDLING AND STORAGE
'and%&n/
>AS' T'OROU,'LY A(TER 'ANDLIN," REMO!E CONTAMINATED CLOT'IN,
AND >AS' BE(ORE REUSE" A!OID ,ENERATION O( DUST"DO NOT IN,EST OR
IN'ALE" DO NOT ALLO> CONTACT >IT' MOISTURE"
Stora/e
@EEP IN A TI,'TLY CLOSED CONTAINER" PROTECT (ROM P'YSICAL DAMA,E"
STORE IN A DRY- !ENTILATED AREA A>AY (ROM MOISTURE AND
INCOMPATIBILITIES" CONTAINERS O( T'IS MATERIAL MAY BE 'A?ARDOUS
>'EN EMPTY SINCE T'EY RETAIN PRODUCT RESIDUES (DUST- SOLIDS)
SECTION !: E"POSURE CONTROLS# PERSONAL PROTECTION
'0/en&c Contro%2
>EAR IN !ENTILATED AREA" A!OID TO EAT OR DRIN@ >'EN 'ANDLIN, T'E
PRODUCT" A!OID P'YSICAL CONTACT"
Occu$at&ona% EB$o2ure L&m&t2
MoS*
T>AC 9 m/<m4 FSOLUBLES COMPOUNDS 6- )+ m/<m4 F DUST TOTAL 6 (OS'A)G
T>AC 9 m/<m4 (AC,I')"
Iron
T>AC 9 m/<m4 (AC,I'- *++*)"
S&O*
T>AC +-) m/<m4 (OS'A)G T>AC +-) m/<m4 (AC,I')"
Co$$er
Per2ona% Protect&Ae EDu&$ment
T>AC ) m/<m4 AS COPPER DUST OR MIST (AC,I'- *+++)"
Re2$&rator2
A RESPIRATORY PROTECTION PRO,RAM T'AT MEETS OS'AHS *5 C(R C
)5)+")44 AND ANSI ?77"* REEUIREMENTS OR EUROPEAN STANDARD EN )45
MUST BE (OLLO>ED >'ENE!ER >OR@PLACE CONDITIONS >ARRANT A
RESPIRATORHS USE"
S3&n
MATERIALC NITRILE OR P!C"
E0e2
>EAR APPROPRIATE PROTECTI!E EYE,LASSES OR C'EMICAL
SA(ETY ,O,,LES AS DESCRIBED BY OS'AHS EYE AND (ACE PROTECTION
RE,ULATIONS IN *5 C(R )5)+")44 OR EUROPEAN STANDARD EN)88"
C%ot.&n/
SA(ETY S'OESG >EAR APPROPRIATE PROTECTI!E CLOT'IN,"
SECTION $: PHYSICAL AND CHEMICAL PROPERTIES
P.02&ca% 2tate
SOLID
A$$earance and odor
BLAC@ TO ,RAYIS' BLUE PO>DER" ODORLESS"
$'
NOT APPLICABLE
T1 de de2com$o2&t&on
NO APPLICABLE
(%a2. $o&nt
NOT APPLICABLE
T1 de auto&/n&t&on
NOT APPLICABLE
EB$%o2Ae2 $ro$ert&e2
NOT APPLICABLE
(&re or eB$%o2&on .a=ard
COMBINED >IT' POTASSIUM NITRATE- E;PLOSI!E >'EN 'EATED"
!a$or Pre22ure (*+1C)
NOT APPLICABLE
!a$or Den2&t0
NOT APPLICABLE
MOLYBDENUM CONCENTRATE
(CODELCO NORTE DI!ISION)
Date I22ued C 4)"+9"*++4
Pa/e 4 o 4
Den2&t0
I ) /r<cc
So%uJ&%&t0 (Kater)
INSOLUBLE IN COOL OR >ARM >ATER"
(ree=&n/<Me%t&n/ Po&nt
NOT APPLICABLE
Bo&%&n/ Po&nt
NOT A!AILABLE
S$ec&&c ,raA&t0<Den2&t0 ()4 1C)
4"7 to 9"+ (>ATER L ))
SECTION 1%: STABILITY AND REACTIVITY
C.em&ca% StaJ&%&t0
STABLE UNDER NORMAL CONDITIONS" SUBLIMES AT 49+ 1C c"a"
Cond&t&on2 to AAo&d
CONTACT INCOMPATIBLE MATERIALS- 'I,' TEMPERATURES"
Incom$at&J&%&t&e2 K&t. Ot.er Mater&a%2
STRON, O;IDI?IN, A,ENTS- 'YDRO,EN PERO;IDE"
'a=ardou2 Decom$o2&t&on Product2
SUL(UR O;IDES AND MOLYBDENUM O;IDES"
'a=ardou2 Po%0mer&=at&on
IT 'AS NOT BEEN REPORTED"
SECTION 11: TO"ICOLOGICAL INFORMATION
Potent&a% 'ea%t. Eect2C
In.a%at&on
CAUSES TEMPORAL IRRITATION TO T'E RESPIRATORY TRACT"
Contact K&t. 23&n
CAUSES MILD IRRITATION"
Contact K&t. e0e2
CAUSES MILD IRRITATION"
In/e2t&on
MAY CAUSE ,ASTROINTESTINAL IRRITATION >IT' NAUSEA- !OMITIN, AND
DIARR'EA"
C.ron&c eect2
MAY INDUCE 'YPOT'YROIDISME AND ANEMIA"
LD9+<LC9+
ORAL (LD9+- RATS)C I 8 /r<3/
A//raAat&on o Pre6eB&2t&n/ Cond&t&on2
NOT APPLICABLE
Ot.er &normat&on
IN'ALATION O( METALLIC !APORS CAUSES IRRITATION TO MOCOUS
MEMBRANES AND P'ARYN;" AT TIMES MAY CAUSE BRONC'ITIS AND
PNEUMONIA"
SECTION 12: ECOLOGICAL INFORMATION
Per2&2tence<De/radeJ&%&t0
NOT APPLICABLE
B&o6accumu%at&on
NOT APPLICABLE"
EnA&ronment eetc2
NOT CONSIDERATED SERIOUS POLLUTANT" IT IS A ESSENTIAL
MICRONUTRIENT (OR BOT' PLANTS AND ANIMALS" MOLYBDENUM IN
,ENERAL IMPLIES A LO> RIS@ TO T'E POPULATION"
SECTION 13: DISPOSAL CONSIDERATIONS
>'ATE!ER CANNOT BE SA!ED (OR RECO!ERY OR RECYCLIN, S'OULD BE MANA,ED IN AN APPROPRIATE AND
APPRO!ED >ASTE DISPOSAL (ACILITY" PROCESSIN,- USE OR CONTAMINATION O( T'IS PRODUCT MAY C'AN,E T'E
>ASTE MANA,EMENT OPTIONS" STATE AND LOCAL DISPOSAL RE,ULATIONS MAY DI((ER (ROM (EDERAL DISPOSAL
RE,ULATIONS" DISPOSE O( CONTAINER AND UNUSED CONTENTS IN ACCORDANCE >IT' (EDERAL- STATE AND LOCAL
REEUIREMENTS"
SECTION 14: TRANSPORT INFORMATION
Road<Ra&% Tran2$ort DR<RID
NOT RE,ULATED
Sea Tran2$ort IM,D
NOT RE,ULATED
A&r tran2$ort ICAO<IATA
NOT RE,ULATED
SECTION 15: REGULATORY INFORMATION
MOLYBDENUM CONCENTRATE
(CODELCO NORTE DI!ISION)
Date I22ued C 4)"+9"*++4
Pa/e 4 o 4
UE C%a22&&cat&on (87<947<EEC)
'a=ard 20mJo%
NOT APPLICABLE
R&23 $.ra2e2
NOT APPLICABLE
Saet0 $.ra2e2
S ** DO NOT BREAT' DUST"
S *9 A!OID CONTACT >IT' EYES"
SECTION 16: OTHER INFORMATION
MSDS CREATION
NGC
RE!ISION
NomJre
&rma
RIS@ PRE!ENTION
NomJre
(&rma
PREPARATION DATE DATE O( ISSUE
T'E IN(ORMATION ABO!E IS BELIE!ED TO BE ACCURATE AND REPRESENTS T'E BEST IN(ORMATION CURRENTLY
A!AILABLE TO US" 'O>E!ER- >E MA@E NO >ARRANTY O( MERC'ANTABILITY OR ANY OT'ER >ARRANTY- E;PRESS OR
IMPLIED- >IT' RESPECT TO SUC' IN(ORMATION- AND >E ASSUME NO LIABILITY RESULTIN, (ROM ITS USE" USERS
S'OULD MA@E T'EIR O>N IN!ESTI,ATIONS TO DETERMINE T'E SUITABILITY O( T'E IN(ORMATION (OR T'EIR
PARTICULAR PURPOSES"