V-101

TANK
NH3

M-100
MIXER
NH3

E-101
VAPORIZER
NH3

C-101
COMPRESSOR
AIR

RC-101
STEAM
TURBINE
TAIL GAS

V-102
EXHAUST
STACK
TAIL GAS

F-101
FILTER
NH3 (V)

S-101
SPLITTER
NH3(v)
M-101
MIXER
NH3(v),AIR
RC-102
STEAM
TURBINE
STEAM

R-101
CONVERTER
NH3,AIR
NO
E-102
TAIL GAS
BOILER
NO

E-104
HEAT
EXCHANGER
NO
R-102
REACTOR
NO,AIR
NO2

R-103
ABATOR
NO,NO2,NH3
N2, H20
SP-101
CONDENSER
NO2

E-103
HEAT
EXCHANGER
AIR

SP-100
SEPARATOR
H20,NH3,AIR

V-103
WEAK ACID
VESSEL
HNO3

C-102
COMPRESSOR
NO2

E-106
ACID
COOLER
HNO3
V-104
FLASH
TANK
HNO3

R-104
ABSORBER
NO2,H20
HNO3

P-101
PUMP
HNO3

R-105
NEUTRALIZER
NH3(v),HNO3
NH4NO3

M-102
MIXER
NH3(v), HNO3,
H20
E-108
HEAT
EXCHANGER
HEATER
HNO3

SP-102
EVAPORATER
NH4NO3

M-103
MIXER
NH4NO3(aq),
NH4NO3(s)

T-101
PRILL TOWER
NH4NO3(aq)
NH4NO3(s)

E-107
COOLER
NH4NO3(s)

SP-103
DRYER
NH4NO3(s)

LEGEND:
C: COMPRESSOR
E : HEAT EXCHANGER/HEATER
F: FILTER/SCREEN
M: MIXER
P: PUMP
R: REACTOR
RC: TURBINE
S: SPLITTER
SP: SEPARATOR
T: TOWER
V: VESSEL/TANK

V-105
COATER
NH4NO3(s)

SP-105
SCREEN
NH4NO3(s)

SP-104
SCREEN
NH4NO3(s)

V-106
STORAGE
TANK
NH4NO3(s)

M-104
MIXER
NH4NO3(s)

26

NH3
1

S-101
3

2A

R-103

F-101

E-101

SP-102

24

R-104

12

V-101

M-100

HW

5
23

R-101

Primary Air
M-101

Tail gas

RC-101

35
32

33

34

39

CW

31

M-102
29

E-102
C-101

R-105

E-106

26A

CW

V-102

R-102

C-102

SP-101

RC-102

28
27A

CW

19

40
36

HW

E-104

18

15

37

E-108

17
14
13

10

21

22

27

M-104

V-103

26

NH4NO3
16

Secondary Air

P-101

V-104

V-106

38

20

HW

E-103

Nitric Acid Production

Ammonium Nitrate Production

CHEE2002 Project 2

PIPELINE STREAMS
Stream number
2
M ole Flow(kmol/sec) 1000
NH3 (Ammonia)
1000
O2 (Oxygen)
0
N2 (Nitrogen)
0
NO(Nitrogen Oxide)
0
NO2(Nitrogen Dioxide) 0
HNO3 (Nitric Acid)
0
H2O (Water)
0
NH4NO3
0
NH4NO3(s)
0
Temperature (K)
298
Pressure(Bar)
1

2A
1042
1042
0
0
0
0
0
0
0
0
310
1

4
1042
1042
0
0
0
0
0
0
0
0
323
4

5
500
500
0
0
0
0
0
0
0
0
323
4

V-105

SP-105

SP-104

E-107

30

M-103

AIR

SP-103

25

SP-100
11

T-101

WATER

6
333
333
0
0
0
0
0
0
0
0
323
4

7
208
208
0
0
0
0
0
0
0
0
323
4

8
10000
0
2100
7900
0
0
0
0
0
0
298
1

8A
10000
0
2100
7900
0
0
0
0
0
0
516
4

9
5000
0
1050
3950
0
0
0
0
0
0
516
4

10
5625
0
425
3950
500
0
0
750
0
0
1148
4

12
5500
500
1050
3950
0
0
0
0
0
0
493
4

14
5625
0
425
3950
500
0
0
750
0
0
323
4

14A
5358
0
175
3950
17
450
33
733
0
0
323
4

15
5625
0
425
3950
500
0
0
750
0
0
911
1

17
4592
0
175
3950
17
450
0
0
0
0
323
4

18
767
0
0
0
0
0
33
733
0
0
323
4

19
4592
0
175
3950
17
450
0
0
0
0
454
10

19A
11208
0
1225
7900
167
0
333
1583
0
0
323
10

20
5000
0
1050
3950
0
0
0
0
0
0
516
4

21
1917
0
0
0
0
0
333
1583
0
0
323
10

22
1361
0
0
0
0
0
0
1361
0
0
323
10

23
1000
0
0
0
0
0
0
1000
0
0
298
1

24
9292
0
1225
7900
167
0
0
0
0
0
323
10

25
9542
42
1183
8067
0
0
0
250
0
0
560
11

26
42
42
0
0
0
0
0
0
0
0
560
11

26A
9500
0
1183
8067
0
0
0
250
0
0
560
11

27
556
0
0
0
0
0
333
222
0
0
323
10

27A
556
0
0
0
0
0
333
222
0
0
373
3

28
889
333
0
0
0
0
333
222
0
0
342
3

28A
556
0
0
0
0
0
0
222
333
0
413
3

28B
200
0
0
0
0
0
0
200
0
0
413
3

29
356
0
0
0
0
0
0
22
333
0
413
3

30
466
0
0
0
0
0
0
22
444
0
416
1

30A
19
0
0
0
0
0
0
19
0
0
416
1

31
447
0
0
0
0
0
0
3
444
0
416
1

32
3
0
0
0
0
0
0
3
0
444
422
1

32A
10
0
2
8
0
0
0
0
0
0
298
1

32B
13
0
2
8
0
0
0
3
0
0
422
1

33
0
0
0
0
0
0
0
0
0
444

34
0
0
0
0
0
0
0
0
0
444

35
0
0
0
0
0
0
0
0
0
334

36
0
0
0
0
0
0
0
0
0
110

37
0
0
0
0
0
0
0
0
0
0

38
0
0
0
0
0
0
0
0
0
111

38A
111
0
0
0
0
0
0
0
111
0
422
1

39
0
0
0
0
0
0
0
0
0
333
1

Group 6
SEM 2 2011

Mahmudah Mohd. Akin

Pritii Tam Wai Yin
Micheal Lori
Nicholas Davie
Andrew Eggleton
Drawn By: Mahmudah Mohd Akin
Checked By: Pritii Tam Wai Yin
Approved By:

1.3. Process Flow Diagram

Nitric Acid & Ammonium
Nitrate Production
Size:
A3

Date: Drawing No: Rev:

PFD-1001
A

19
October
2011

Date : 19 October 2010

Date : 19 October 2010
Date : 19 October 2010