7.

0 APPENDIX
I. PREPARATION OF CHEMICALS
For Sodium Hydroxide, NaOH
M =

0.1M =

n = 5
n =

5 =

M = 200 g # (200 gram of sodium hydroxide pellets being dilute with distilled water)
For Ethyl Acetate
M
1
=

M
1
=



M
1
= 10.1 mol/L
For 0.1M at 50L,
M
1
V
1
= M
2
V
2

(10.1 mol/L) (V
1
) = (0.1M) (50L)
V
1
=



V
1
= 0.5L
Thus, in 50L;
500mL ethyl and 49.5L water #

1. Based on the general equation obtained from calibration curve, the value below can be
calculated. (example calculation for 50mL/min at 0 min)
(i) Inlet and Outlet concentration of NaOH, (M).
y = mx + c
y = 0.007x - 0.028

Inlet Outlet
1. x: 10.24 x: 7.26
y = 0.007x - 0.028 y = 0.007 x 0.028
y = 0.007 (10.56) 0.028 y = 0.007(9.25)-0.028
y = 0.0459 M y = 0.0368M



ii)To find the conversion, X (%) at 150mL/min
Use formula of conversion, X = [(C
AO
C
A1
) / C
AO
] * 100%
C
AO
= Inlet concentration
C
A1
= Outlet concentration

1. C
AO
= Inlet concentration = 0.0459 M
C
A1
= Outlet concentration = 0.0368 M

X = [(C
AO
C
A1
) / C
AO
]

* 100
= [(0.0459-0.0368) / 0.0459] * 100
= 19.83%



(iii) To find value of k, use the formula below
Sample calculation 50mL/min at time 0:

k = [95/ (1500*0.0459)]* 0.1983/ (1-0.1983)
k = 0.3413 mL/min.mol

iv) Calculating the residence time, (min)
=

=



= 15.79 min

v) Rate of Reaction -r
A
Sample calculation 50mL/min at time 0:



=

2

= (0.3413) (00.0368)
2

= 4.6210
-4
mol/mL.min