1074 PDF C02

2.
VAPOR-LIQUID EQUILIBRIUM (VLE) DATA

OF BINARY COPOLYMER SOLUTIONS
2.1. Partial solvent vapor pressures or solvent activities for copolymer
solutions
_____________________________________________________________________________
Copolymers from acrylonitrile and butadiene
_____________________________________________________________________________
Average chemical composition of the copolymers, acronyms and references:
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Acrylonitrile/butadiene copolymer
21.0 wt% acrylonitrile
AN-B/21w
AN-B/33w
AN-B/51w
95GUP
95GUP
95GUP
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
AN-B/21w
AN-B/33w
AN-B/51w
Sci. Polym. Products, catalog #523

_____________________________________________________________________________
Experimental VLE data:
_____________________________________________________________________________
copolymer (B):
solvent (A):
AN-B/21w
acetonitrile
C2H3N
T/K = 333.15
wB
PA/kPa
0.989
6.8
2001 by CRC Press LLC
0.974
13.7
0.935
26.1
0.915
30.1
0.888
34.1
0.813
39.3
95GUP
75-05-8
copolymer (B):
solvent (A):
AN-B/21w
cyclohexane
95GUP
110-82-7
C6H12
T/K = 333.15
wB
PA/kPa
0.823
35.6
0.824
35.7
copolymer (B):
solvent (A):
0.790
38.1
0.784
39.7
AN-B/21w
n-hexane
0.717
43.1
95GUP
110-54-3
C6H14
T/K = 333.15
wB
PA/kPa
0.975
12.9
0.956
25.6
copolymer (B):
solvent (A):
0.918
38.8
0.896
44.5
AN-B/21w
n-octane
0.866
50.8
0.830
57.5
0.764
63.7
0.749
64.9
95GUP
111-65-9
C8H18
T/K = 333.15
wB
PA/kPa
0.964
2.90
0.948
4.19
copolymer (B):
solvent (A):
0.936
5.08
0.921
5.91
AN-B/21w
n-pentane
0.889
6.91
0.842
8.41
95GUP
109-66-0
C5H12
T/K = 333.15
wB
PA/kPa
0.984
36.0
0.979
46.8
copolymer (B):
solvent (A):
0.967
65.5
0.954
84.0
AN-B/33w
acetonitrile
0.945
97.3
0.930
113.3
C2H3N
0.922
124.8
0.911
137.6
95GUP
75-05-8
T/K = 333.15
wB
PA/kPa
0.977
6.7
0.957
13.3
copolymer (B):
solvent (A):
0.935
18.3
0.909
23.2
AN-B/33w
n-hexane
C6H14
T/K = 333.15
wB
PA/kPa
0.998
12.4
0.983
25.1
0.974
36.0
0.852
32.5
0.963
43.3
0.794
37.9
95GUP
110-54-3
copolymer (B):
solvent (A):
AN-B/33w
n-pentane
95GUP
109-66-0
C5H12
T/K = 333.15
wB
PA/kPa
0.986
26.9
0.975
53.5
copolymer (B):
solvent (A):
0.973
64.7
0.968
77.5
AN-B/33w
trichloromethane
0.964
89.7
0.956
101.7
0.950
115.7
0.945
130.1
95GUP
67-66-3
CHCl3
T/K = 333.15
wB
PA/kPa
0.920
13.6
0.830
26.8
copolymer (B):
solvent (A):
0.828
26.9
0.738
39.6
AN-B/51w
acetonitrile
0.628
52.8
0.576
59.9
0.515
66.3
0.437
73.3
95GUP
75-05-8
C2H3N
T/K = 333.15
wB
PA/kPa
0.979
6.8
0.953
13.7
copolymer (B):
solvent (A):
0.889
26.1
0.856
30.1
AN-B/51w
cyclohexane
0.818
34.1
0.707
39.3
95GUP
110-82-7
C6H12
T/K = 333.15
wB
PA/kPa
0.993
13.7
0.989
19.1
copolymer (B):
solvent (A):
0.985
19.6
0.976
26.4
AN-B/51w
n-hexane
0.968
32.0
0.953
35.6
0.940
39.7
0.909
43.1
95GUP
110-54-3
C6H14
T/K = 333.15
wB
PA/kPa
0.982
12.9
0.980
25.6
copolymer (B):
solvent (A):
0.971
38.8
0.967
44.5
AN-B/51w
n-octane
0.959
50.8
0.956
57.5
0.993
2.85
0.990
4.19
0.987
5.08
0.985
5.91
0.979
6.91
0.938
64.9
95GUP
111-65-9
C8H18
T/K = 333.15
wB
PA/kPa
0.938
63.7
0.974
8.41
copolymer (B):
solvent (A):
AN-B/51w
n-pentane
95GUP
109-66-0
C5H12
T/K = 333.15
wB
PA/kPa
0.991
36.0
0.987
46.8
0.981
65.5
0.978
84.0
0.978
97.3
0.974
113.3
0.973
124.8
0.966
137.6
_____________________________________________________________________________
Copolymers from acrylonitrile and styrene
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Acrylonitrile/styrene copolymer
S-AN/25w
S-AN/28w
S-AN/28w
S-AN/30w
98SCH
96WO2
97WO1
95GUP
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
S-AN/25w
S-AN/28w
S-AN/30w
90000
46000
147000
100000
185000
Bayer AG Leverkusen, Ger.

synthesized in the laboratory
_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B):
solvent (A):
S-AN/25w
toluene
98SCH
108-88-3
C7H8
T/K = 313.15
wB
PA/PAs
0.399
0.999
0.447
0.991
0.497
0.954
wB
PA/PAs
0.848
0.544
0.894
0.476
0.952
0.331
0.522
0.952
0.601
0.902
0.638
0.869
0.699
0.796
0.747
0.745
0.799
0.644
copolymer (B):
solvent (A):
S-AN/25w
toluene
98SCH
108-88-3
C7H8
T/K = 323.15
wB
PA/PAs
0.352
0.996
0.448
0.986
0.499
0.934
wB
PA/PAs
0.852
0.529
0.897
0.454
0.955
0.337
copolymer (B):
solvent (A):
0.524
0.918
S-AN/25w
toluene
0.603
0.877
0.643
0.848
0.702
0.779
0.750
0.717
0.802
0.628
98SCH
108-88-3
C7H8
T/K = 333.15
wB
PA/PAs
0.353
0.989
0.449
0.979
0.500
0.924
wB
PA/PAs
0.853
0.523
0.899
0.446
0.956
0.332
copolymer (B):
solvent (A):
0.525
0.909
S-AN/28w
benzene
0.604
0.872
0.644
0.843
0.704
0.776
0.751
0.711
0.803
0.625
96WO2, 97WO1
71-43-2
C6H6
T/K = 343.15
wB
PA/PAs
0.8339
0.6433
0.8053
0.7080
wB
PA/PAs
0.5892
0.9598
0.5564
0.9724
copolymer (B):
solvent (A):
0.7876
0.7415
0.7501
0.8036
S-AN/28w
propylbenzene
0.7207
0.8454
0.6967
0.8752
0.6587
0.9097
0.6384
0.9251
0.6198
0.9369
96WO2, 97WO1
103-65-1
C9H12
T/K = 398.15
wB
PA/PAs
0.8270
0.7559
0.8132
0.7834
copolymer (B):
solvent (A):
0.8018
0.8033
0.7781
0.8423
S-AN/28w
toluene
0.7649
0.8618
0.7346
0.8991
0.7179
0.9127
0.6834
0.9372
96WO2, 97WO1
108-88-3
C7H8
T/K = 343.15
wB
PA/PAs
0.7962
0.7257
0.7433
0.8126
0.7192
0.8458
0.6960
0.8735
0.6607
0.9090
0.6482
0.9172
0.6199
0.9377
0.5856
0.5856
copolymer (B):
solvent (A):
S-AN/28w
toluene
96WO2, 97WO1
108-88-3
C7H8
T/K = 373.15
wB
PA/PAs
0.8003
0.7071
0.7632
0.7752
wB
PA/PAs
0.5883
0.9567
0.5654
0.9690
copolymer (B):
solvent (A):
0.7375
0.8147
0.7157
0.8410
S-AN/28w
o-xylene
0.7093
0.8523
0.6831
0.8817
0.6686
0.8951
0.6388
0.9208
0.6056
0.9427
96WO2, 97WO1
95-47-6
C8H10
T/K = 398.15
wB
PA/PAs
0.7606
0.8048
0.7371
0.8389
copolymer (B):
solvent (A):
0.7107
0.8722
0.6838
0.9008
S-AN/28w
m-xylene
0.6593
0.9228
0.6276
0.9459
0.5960
0.9642
0.5586
0.9800
96WO2, 97WO1
108-38-3
C8H10
T/K = 398.15
wB
PA/PAs
0.7977
0.7462
0.7611
0.8162
copolymer (B):
solvent (A):
0.7428
0.8387
0.7167
0.8690
S-AN/28w
p-xylene
0.6884
0.9010
0.6460
0.9405
0.6198
0.9510
0.5894
0.9701
96WO2, 97WO1
106-42-3
C8H10
T/K = 373.15
wB
PA/PAs
0.7632
0.8081
0.7416
0.8378
copolymer (B):
solvent (A):
0.7204
0.8736
0.6997
0.8883
S-AN/28w
p-xylene
0.6566
0.9347
0.6223
0.9547
0.5917
0.9714
96WO2, 97WO1
106-42-3
C8H10
T/K = 398.15
wB
PA/PAs
0.8082
0.7188
0.7896
0.7537
copolymer (B):
solvent (A):
0.7534
0.8142
0.7263
0.8528
S-AN/28w
p-xylene
0.7006
0.8828
0.6731
0.9101
0.6519
0.9286
0.7738
0.7769
0.7547
0.8077
0.7259
0.8483
0.6931
0.8846
0.6674
0.9106
0.6028
0.9609
96WO2, 97WO1
106-42-3
C8H10
T/K = 423.15
wB
PA/PAs
0.6292
0.9439
0.6492
0.9253
0.6211
0.9444
copolymer (B):
solvent (A):
S-AN/30w
1,2-dichloroethane
95GUP
107-06-2
C2H4Cl2
T/K = 343.15
wB
PA/kPa
0.861
30.8
0.804
36.5
copolymer (B):
solvent (A):
0.757
40.7
0.719
43.9
S-AN/30w
1,2-dichloroethane
0.704
46.0
0.661
49.1
95GUP
107-06-2
C2H4Cl2
T/K = 353.15
wB
PA/kPa
0.749
45.7
0.721
50.1
0.652
57.6
0.624
59.5
0.611
60.7
_____________________________________________________________________________
Copolymers from p-bromostyrene and p-methylstyrene
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
p-Bromostyrene/p-methylstyrene copolymer
16.7 mol% p-bromostyrene
pBS-pMS/17x
pBS-pMS/33x
pBS-pMS/50x
pBS-pMS/66x
pBS-pMS/83x
63COR
63COR
63COR
63COR
63COR
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol
g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
pBS-pMS/17x
pBS-pMS/33x
pBS-pMS/50x
pBS-pMS/66x
pBS-pMS/83x
5000-10000
5000-10000
5000-10000
5000-10000
5000-10000

_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B):
solvent (A):
pBS-pMS/17x
toluene
63COR
108-88-3
C7H8
T/K = 293.20
B
aA
0.1643
0.9952
0.2633
0.9865
copolymer (B):
solvent (A):
0.3444
0.9650
0.4641
0.9259
pBS-pMS/33x
toluene
0.5449
0.8696
0.6416
0.7859
63COR
108-88-3
C7H8
T/K = 293.20
B
aA
0.1970
0.9952
0.2792
0.9860
copolymer (B):
solvent (A):
0.3648
0.9649
0.4799
0.9255
pBS-pMS/50x
toluene
0.5932
0.8708
0.6473
0.7858
63COR
108-88-3
C7H8
T/K = 293.20
B
aA
0.1857
0.9952
0.2672
0.9865
copolymer (B):
solvent (A):
0.3696
0.9652
0.4870
0.9250
pBS-pMS/66x
toluene
0.5755
0.8690
0.6629
0.7855
63COR
108-88-3
C7H8
T/K = 293.20
B
aA
0.1803
0.9952
0.3066
0.9865
copolymer (B):
solvent (A):
0.3931
0.9650
0.5074
0.9250
pBS-pMS/83x
toluene
0.5844
0.8680
0.6742
0.7852
63COR
108-88-3
C7H8
T/K = 293.20
B
aA
0.2088
0.9952
0.3489
0.9868
0.4095
0.9658
0.5417
0.9256
0.6147
0.8698
0.7028
0.7859
_____________________________________________________________________________
Copolymers from butadiene and styrene
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Butadiene/styrene copolymer
5.0 wt% styrene
23.0 wt% styrene
41.0 wt% styrene
41.0 wt% styrene
45.0 wt% styrene
45.0 wt% styrene
45.0 wt% styrene
S-BR/05w
S-BR/23w
S-BR/41w
S-BR/41w
S-BR/45w(1)
S-BR/45w(1)
S-BR/45w(2)
95GUP
95GUP
96WO1
97WO1
90IWA
91IWA
95GUP
(block copolymer without specification)
30.0 wt% styrene
30.0 wt% styrene
77.0 wt% styrene
77.0 wt% styrene
S-?-B/30w
S-?-B/30w
S-?-B/77w
S-?-B/77w
90IWA
91IWA
90IWA
91IWA
Polystyrene-b-polybutadiene-b-polystyrene
triblock copolymer
31.0 wt% styrene
S-B-S/31w
99FRE
Polystyrene-b-polybutadiene(hydrogenated)b-polystyrene triblock copolymer

13.0 wt% styrene
31.0 wt% styrene
S-B(h)-S/13w
S-B(h)-S/31w
99FRE
99FRE
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
S-BR/05w
S-BR/23w
S-BR/41w
S-BR/45w(1)
86300 181200
130430 600000

Sci. Polym. Products
_____________________________________________________________________________
continue
continue
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
S-BR/45w(2)
S-?-B/30w
S-?-B/77w
108000 140000
117650 200000

Denki Kagaku Industry
S-B-S/31w
S-B(h)-S/13w
S-B(h)-S/31w
111000
90000
48000

_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B):
solvent (A):
S-BR/05w
cyclohexane
95GUP
110-82-7
C6H12
T/K = 333.15
wB
PA/kPa
0.848
24.8
0.811
29.5
copolymer (B):
solvent (A):
0.767
33.7
0.724
37.6
S-BR/05w
2-propanone
0.677
40.7
95GUP
67-64-1
C3H6O
T/K = 323.15
wB
PA/kPa
0.944
41.5
0.933
45.3
0.928
46.5
wB
PA/kPa
0.885
59.6
0.890
59.7
0.880
61.3
copolymer (B):
solvent (A):
0.933
47.2
S-BR/05w
toluene
0.934
47.3
0.922
51.1
0.957
0.93
0.901
2.08
0.816
3.04
0.681
4.36
0.584
4.83
0.920
53.3
0.909
55.2
95GUP
108-88-3
C7H8
T/K = 308.15
wB
PA/kPa
0.921
52.3
0.487
5.45
copolymer (B):
solvent (A):
S-BR/05w
trichloromethane
95GUP
67-66-3
CHCl3
T/K = 323.15
wB
PA/kPa
0.960
8.5
wB
PA/kPa
0.362
56.4
0.894
16.3
copolymer (B):
solvent (A):
0.796
25.5
0.728
31.6
S-BR/23w
cyclohexane
0.659
38.3
0.543
45.5
0.511
47.6
0.463
50.0
0.420
53.7
C6H12
95GUP
110-82-7
C6H12
95GUP
110-82-7
T/K = 296.65
wB
PA/kPa
0.803
7.64
0.724
9.03
copolymer (B):
solvent (A):
0.672
10.03
S-BR/23w
cyclohexane
T/K = 333.15
wB
PA/kPa
0.864
24.8
0.832
29.5
copolymer (B):
solvent (A):
0.792
33.7
0.756
37.6
S-BR/23w
n-hexane
0.713
40.7
C6H14
95GUP
110-54-3
C5H12
95GUP
109-66-0
T/K = 343.15
wB
PA/kPa
0.890
48.8
0.838
61.5
copolymer (B):
solvent (A):
0.738
75.2
S-BR/23w
n-pentane
T/K = 333.15
wB
PA/kPa
0.954
84.0
0.945
97.3
copolymer (B):
solvent (A):
0.930
113.3
0.922
124.8
S-BR/23w
2-propanone
0.911
137.6
95GUP
67-64-1
C3H6O
T/K = 333.15
wB
PA/kPa
0.979
26.4
0.963
40.7
0.938
54.8
0.908
68.5
0.872
81.3
0.853
84.8
0.817
91.5
0.769
97.9
copolymer (B):
solvent (A):
S-BR/23w
2-propanone
95GUP
67-64-1
C3H6O
T/K = 323.15
wB
PA/kPa
0.951
36.3
0.939
41.5
wB
PA/kPa
0.880
59.7
0.870
61.3
copolymer (B):
solvent (A):
0.929
45.3
0.925
46.5
S-BR/23w
toluene
0.915
51.1
0.912
52.3
0.909
53.3
0.900
55.2
0.875
59.6
95GUP
108-88-3
C7H8
T/K = 308.15
wB
PA/kPa
0.971
0.93
0.969
2.08
copolymer (B):
solvent (A):
0.968
3.04
0.963
4.36
S-BR/23w
trichloromethane
0.963
4.83
0.962
5.45
95GUP
67-66-3
CHCl3
T/K = 323.15
wB
PA/kPa
0.954
8.5
wB
PA/kPa
0.379
56.4
0.889
16.3
copolymer (B):
solvent (A):
0.794
25.5
0.730
31.6
S-BR/41w
benzene
0.662
38.3
0.551
45.5
0.518
47.6
0.486
50.0
0.434
53.7
96WO1, 97WO1
71-43-2
C6H6
T/K = 343.15
wB
PA/PAs
0.7998
0.5091
0.7553
0.5897
copolymer (B):
solvent (A):
0.7207
0.6418
0.6864
0.6910
S-BR/41w
cyclohexane
0.6485
0.7388
0.6039
0.7876
0.5517
0.8357
0.4916
0.8798
96WO1, 97WO1
110-82-7
C6H12
T/K = 343.15
wB
PA/PAs
0.7831
0.6522
0.7564
0.6966
0.7197
0.7491
0.6712
0.8083
0.6394
0.8385
0.4326
0.9143
0.6008
0.8693
0.5586
0.8985
0.5234
0.9176
copolymer (B):
solvent (A):
S-BR/41w
ethylbenzene
96WO1, 97WO1
100-41-4
C8H10
T/K = 373.15
wB
PA/PAs
0.7917
0.5829
0.7604
0.6358
copolymer (B):
solvent (A):
0.7285
0.6841
0.6799
0.7471
S-BR/41w
ethylbenzene
0.6412
0.7897
0.5996
0.8271
0.5616
0.8562
0.5173
0.8854
0.4845
0.9037
96WO1, 97WO1
100-41-4
C8H10
T/K = 398.15
wB
PA/PAs
0.6887
0.7292
0.6528
0.7736
copolymer (B):
solvent (A):
0.6293
0.7973
0.5818
0.8390
S-BR/41w
mesitylene
0.5495
0.8629
0.5106
0.8876
0.4698
0.9108
96WO1, 97WO1
108-67-8
C9H12
T/K = 398.15
wB
PA/PAs
0.7694
0.6520
0.7389
0.6982
copolymer (B):
solvent (A):
0.6908
0.7617
0.6576
0.7987
S-BR/41w
toluene
0.6232
0.8311
0.5856
0.8610
0.5407
0.8911
0.5009
0.9107
96WO1, 97WO1
108-88-3
C7H8
T/K = 343.15
wB
PA/PAs
0.7619
0.5825
0.7198
0.6476
copolymer (B):
solvent (A):
0.6721
0.7125
0.6276
0.7634
S-BR/41w
toluene
0.5800
0.8103
0.5317
0.8497
0.4961
0.8753
0.4533
0.9011
96WO1, 97WO1
108-88-3
C7H8
T/K = 373.15
wB
PA/PAs
0.8168
0.4844
0.7701
0.5704
copolymer (B):
solvent (A):
0.7387
0.6214
0.6970
0.6833
S-BR/41w
p-xylene
0.6319
0.7612
0.5726
0.8178
0.5063
0.8691
0.4308
0.9143
96WO1, 97WO1
106-42-3
C8H10
T/K = 398.15
wB
PA/PAs
0.8071
0.5536
0.7593
0.6388
0.7162
0.7027
0.6784
0.7503
0.6499
0.7803
0.6075
0.8216
0.5698
0.8520
0.5201
0.8884
0.4899
0.9050
copolymer (B):
solvent (A):
S-BR/45w(2)
cyclohexane
C6H12
95GUP
110-82-7
C6H12
95GUP
110-82-7
T/K = 296.65
wB
PA/kPa
0.824
7.64
0.747
9.03
copolymer (B):
solvent (A):
0.699
10.03
S-BR/45w(2)
cyclohexane
T/K = 333.15
wB
PA/kPa
0.870
24.8
0.837
29.5
copolymer (B):
solvent (A):
0.800
33.7
0.760
37.6
S-BR/45w(1)
ethylbenzene
0.718
40.7
90IWA
100-41-4
C8H10
T/K = 373.15
wB
PA/kPa
0.9717
4.00
0.9589
5.42
wB
PA/kPa
0.8380
16.10
0.0000
34.25
copolymer (B):
solvent (A):
0.9452
6.92
0.9448
6.89
S-BR/45w(1)
ethylbenzene
0.9248
9.10
0.9112
10.00
0.9022
11.10
0.8830
12.60
0.8390
16.10
90IWA
100-41-4
C8H10
T/K = 403.15
wB
PA/kPa
0.9791
7.14
0.9738
8.79
0.9723
9.45
0.9639
11.40
0.9587
12.60
0.9559
13.80
0.9539
14.30
0.9494
15.70
0.9407
18.10
wB
PA/kPa
0.9333
19.70
0.9332
20.50
0.9308
20.40
0.9241
22.00
0.9229
22.20
0.9110
25.60
0.9081
26.50
0.9036
27.10
0.8920
29.60
wB
PA/kPa
0.8850
31.30
0.8790
32.00
0.8450
38.70
0.0000
85.55
copolymer (B):
solvent (A):
S-BR/45w(2)
n-hexane
T/K = 343.15
wB
PA/kPa
0.897
48.8
0.845
61.5
0.751
75.2
C6H14
95GUP
110-54-3
copolymer (B):
solvent (A):
S-BR/45w(1)
n-nonane
90IWA
111-84-2
C9H20
T/K = 373.15
wB
PA/kPa
0.9832
2.87
0.9516
6.45
0.9428
7.36
wB
PA/kPa
0.8270
14.90
0.8260
14.90
0.0000
20.72
copolymer (B):
solvent (A):
0.9308
8.51
S-BR/45w(1)
n-nonane
0.9093
10.20
0.9082
10.20
0.8820
12.00
0.8700
12.70
0.8460
14.00
90IWA
111-84-2
C9H20
T/K = 403.15
wB
PA/kPa
0.9819
6.86
0.9647
12.10
0.9589
13.80
wB
PA/kPa
0.8520
35.00
0.8290
37.40
0.0000
55.85
copolymer (B):
solvent (A):
0.9468
17.40
S-BR/45w(2)
n-pentane
0.9286
21.40
0.9171
24.10
0.9098
25.40
0.8960
28.00
0.8820
30.50
95GUP
109-66-0
C5H12
T/K = 333.15
wB
PA/kPa
0.978
84.0
0.978
97.3
copolymer (B):
solvent (A):
0.974
113.3
0.973
124.8
S-BR/45w(2)
2-propanone
0.966
137.6
95GUP
67-64-1
C3H6O
T/K = 323.15
wB
PA/kPa
0.954
36.3
0.939
41.5
0.926
45.3
0.922
46.5
wB
PA/kPa
0.895
55.2
0.863
59.6
0.870
59.7
0.859
61.3
copolymer (B):
solvent (A):
S-BR/45w(2)
2-propanone
0.926
47.2
0.929
47.3
0.912
51.1
0.956
40.7
0.931
54.8
0.899
68.5
0.860
81.3
0.837
84.8
0.803
91.5
0.905
53.3
95GUP
67-64-1
C3H6O
T/K = 333.15
wB
PA/kPa
0.908
52.3
0.742
97.9
copolymer (B):
solvent (A):
S-BR/45w(2)
trichloromethane
95GUP
67-66-3
CHCl3
T/K = 323.15
wB
PA/kPa
0.957
8.5
wB
PA/kPa
0.350
56.4
0.893
16.3
copolymer (B):
solvent (A):
0.795
25.5
0.728
31.6
S-?-B/30w
ethylbenzene
0.657
38.3
0.537
45.5
0.500
47.6
0.466
50.0
0.408
53.7
90IWA
100-41-4
C8H10
T/K = 373.15
wB
PA/kPa
0.9704
3.87
wB
PA/kPa
0.0000
34.25
0.9528
5.83
copolymer (B):
solvent (A):
0.9240
8.79
0.9098
10.00
S-?-B/30w
ethylbenzene
0.9022
10.70
0.8760
13.00
0.8550
14.80
0.8360
16.10
0.8130
17.80
90IWA
100-41-4
C8H10
T/K = 403.15
wB
PA/kPa
0.9752
7.93
0.9692
9.73
0.9643
11.10
0.9582
12.30
0.9533
13.80
0.9509
14.70
0.9409
17.10
0.9368
18.20
0.9270
20.40
wB
PA/kPa
0.9196
22.20
0.9145
23.50
0.9055
25.60
0.9042
25.70
0.8950
27.90
0.8860
29.60
0.8700
33.00
0.8600
34.80
0.8510
37.10
wB
PA/kPa
0.8340
39.70
0.0000
85.55
copolymer (B):
solvent (A):
S-?-B/30w
n-nonane
90IWA
111-84-2
C9H20
T/K = 373.15
wB
PA/kPa
0.9801
2.81
0.9673
4.28
0.9506
5.95
0.9489
6.17
wB
PA/kPa
0.8690
12.00
0.8470
13.20
0.8360
13.60
0.0000
20.72
0.9291
7.85
0.9229
8.44
0.9076
9.57
0.8970
10.20
0.8830
11.30
copolymer (B):
solvent (A):
S-?-B/30w
n-nonane
90IWA
111-84-2
C9H20
T/K = 403.15
wB
PA/kPa
0.9867
4.62
0.9750
8.12
0.9584
12.70
0.9459
15.90
0.9294
20.20
wB
PA/kPa
0.8720
30.60
0.8700
30.70
0.8600
32.40
0.8400
34.90
0.0000
55.85
copolymer (B):
solvent (A):
S-?-B/77w
ethylbenzene
0.9248
20.80
0.9224
21.40
0.9032
25.30
0.8950
26.80
90IWA
100-41-4
C8H10
T/K = 373.15
wB
PA/kPa
0.9780
3.85
0.9693
4.85
0.9614
5.81
0.9520
7.17
wB
PA/kPa
0.8690
15.20
0.8460
17.10
0.8400
17.60
0.0000
34.25
copolymer (B):
solvent (A):
S-?-B/77w
ethylbenzene
0.9319
9.10
0.9266
9.69
0.9140
11.10
0.8980
12.60
0.8810
14.70
90IWA
100-41-4
C8H10
T/K = 403.15
wB
PA/kPa
0.9744
10.00
0.9685
11.80
0.9572
14.70
0.9461
18.20
0.9402
20.00
0.9358
21.00
wB
PA/kPa
0.9026
29.60
0.9004
30.40
0.8940
32.10
0.8780
35.00
0.8560
40.80
0.0000
85.55
copolymer (B):
solvent (A):
S-?-B/77w
n-nonane
0.9354
21.60
0.9232
24.30
0.9213
25.00
90IWA
111-84-2
C9H20
T/K = 373.15
wB
PA/kPa
0.9847
3.41
0.9581
7.32
wB
PA/kPa
0.8480
16.40
0.0000
20.72
copolymer (B):
solvent (A):
0.9514
7.88
0.9344
10.20
S-?-B/77w
n-nonane
0.9275
10.90
0.9195
11.30
0.9037
12.80
0.8820
14.40
0.8490
16.40
90IWA
111-84-2
C9H20
T/K = 403.15
wB
PA/kPa
0.9842
7.10
0.9765
10.90
0.9579
17.40
0.9578
17.90
0.9442
22.00
0.9429
22.70
0.9330
25.40
0.9120
30.60
0.9082
31.50
continue
continue
wB
PA/kPa
0.8780
36.90
0.8620
39.90
copolymer (B):
solvent (A):
0.8300
44.20
0.0000
55.85
S-B-S/31w
cyclohexane
99FRE
110-82-7
C6H12
T/K = 323.85
wB
aA
0.9877
0.0533
0.9866
0.0543
0.9674
0.1324
0.9627
0.1488
0.9618
0.1536
0.9614
0.1529
0.9607
0.1568
0.9539
0.1766
0.9485
0.1988
wB
aA
0.9393
0.2288
0.9373
0.2358
0.9296
0.2612
0.9131
0.3128
0.9097
0.3314
0.8989
0.3539
0.8955
0.3563
0.8857
0.3886
0.8753
0.4153
wB
aA
0.8655
0.4398
0.8625
0.4606
0.8581
0.4569
0.8508
0.4745
0.8459
0.4854
0.8414
0.4948
0.8381
0.5035
0.8352
0.5092
0.8242
0.5327
wB
aA
0.8198
0.5424
0.8198
0.5424
0.8196
0.5430
copolymer (B):
solvent (A):
S-B-S/31w
cyclohexane
99FRE
110-82-7
C6H12
T/K = 348.15
wB
aA
0.9820
0.0790
0.9678
0.1282
wB
aA
0.8815
0.4112
0.7972
0.5942
copolymer (B):
solvent (A):
0.9530
0.1861
0.9542
0.1832
S-B-S/31w
cyclohexane
0.9246
0.2880
0.9256
0.2805
0.9260
0.2805
0.8773
0.4209
0.8810
0.4129
99FRE
110-82-7
C6H12
T/K = 373.15
wB
aA
0.9779
0.0915
0.9481
0.1993
copolymer (B):
solvent (A):
0.9197
0.2907
0.9167
0.2899
S-B-S/31w
cyclohexane
0.8804
0.4042
99FRE
110-82-7
C6H12
T/K = 393.15
wB
aA
0.9845
0.0513
0.9851
0.0513
0.9850
0.0512
0.9767
0.0778
0.9765
0.0778
0.9768
0.0780
0.9628
0.1198
0.9643
0.1192
0.9489
0.1666
wB
aA
0.9492
0.1661
0.9487
0.1657
0.9486
0.1660
0.9488
0.1664
0.9255
0.2324
0.9266
0.2327
0.9264
0.2326
0.8973
0.3173
0.8972
0.3166
wB
aA
0.8920
0.3046
0.8952
0.3186
0.8954
0.3159
0.8973
0.3166
copolymer (B):
solvent (A):
S-B(h)-S/13w
cyclohexane
99FRE
110-82-7
C6H12
T/K = 324.35
wB
aA
0.9963
0.0127
0.9943
0.0204
0.9929
0.0247
0.9910
0.0312
0.9888
0.0388
0.9869
0.0474
0.9868
0.0455
0.9855
0.0484
0.9839
0.0543
wB
aA
0.9807
0.0639
0.9800
0.0666
0.9710
0.0951
0.9662
0.1102
0.9555
0.1433
0.9462
0.1732
0.9460
0.1733
0.9460
0.1712
0.9452
0.1710
wB
aA
0.9404
0.1901
0.9332
0.2098
0.9129
0.2735
0.9123
0.2841
0.9118
0.2761
0.9086
0.2833
0.9078
0.2849
0.9076
0.2874
0.8396
0.5550
wB
aA
0.8381
0.5602
copolymer (B):
solvent (A):
S-B(h)-S/31w
cyclohexane
99FRE
110-82-7
C6H12
T/K = 393.15
wB
aA
0.9935
0.0241
0.9934
0.0247
0.9906
0.0347
0.9893
0.0400
0.9891
0.0390
0.9875
0.0441
0.9867
0.0472
0.9846
0.0556
0.9810
0.0716
wB
aA
0.9771
0.0854
0.9702
0.1088
0.9670
0.1139
0.9666
0.1156
0.9635
0.1307
0.9521
0.1748
0.9499
0.1748
0.9479
0.1782
0.9472
0.1774
wB
aA
0.9409
0.1938
0.9406
0.1966
0.9294
0.2323
0.9289
0.2339
0.9139
0.2772
0.9135
0.2785
0.9084
0.2885
0.9052
0.2967
0.8832
0.3551
wB
aA
0.8830
0.3557
0.8818
0.3570
0.8808
0.3600
0.8429
0.4446
0.7884
0.5502
0.7880
0.5491
0.7410
0.6734
0.7373
0.6751
0.7368
0.6738
_____________________________________________________________________________
Copolymers from dimethylsiloxane and methylphenylsiloxane
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Dimethylsiloxane/methylphenylsiloxane copolymer
15 wt% methylphenylsiloxane
DMS-MPS/15w
98SCH
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
DMS-MPS/15w
9100
41200
Dow Corning Corp., Midland, USA
_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B):
solvent (A):
DMS-MPS/15w
anisole
98SCH
100-66-3
C7H8O
T/K = 313.15
wB
PA/PAs
0.309
0.997
0.408
0.987
0.451
0.988
0.506
0.987
wB
PA/PAs
0.798
0.734
0.850
0.631
0.896
0.505
0.949
0.301
copolymer (B):
solvent (A):
DMS-MPS/15w
anisole
0.562
0.963
0.606
0.934
0.640
0.920
0.633
0.886
0.754
0.807
98SCH
100-66-3
C7H8O
T/K = 323.15
wB
PA/PAs
0.406
0.992
0.449
0.997
0.503
0.987
wB
PA/PAs
0.850
0.625
0.896
0.499
0.949
0.298
copolymer (B):
solvent (A):
0.558
0.968
DMS-MPS/15w
anisole
0.604
0.950
0.638
0.918
0.631
0.926
0.753
0.813
0.798
0.733
98SCH
100-66-3
C7H8O
T/K = 333.15
wB
PA/PAs
0.306
0.991
0.404
0.980
0.447
0.981
0.501
0.976
wB
PA/PAs
0.797
0.724
0.849
0.610
0.896
0.486
0.948
0.289
0.556
0.957
0.602
0.944
0.636
0.918
0.629
0.919
0.752
0.804
copolymer (B):
solvent (A):
DMS-MPS/15w
anisole
98SCH
100-66-3
C7H8O
T/K = 343.15
wB
PA/PAs
0.306
0.988
0.404
0.977
0.447
0.971
0.501
0.966
wB
PA/PAs
0.797
0.714
0.849
0.606
0.896
0.479
0.948
0.284
copolymer (B):
solvent (A):
DMS-MPS/15w
2-propanone
0.556
0.942
0.602
0.925
0.636
0.896
0.629
0.903
0.752
0.793
98SCH
67-64-1
C3H6O
T/K = 305.15
wB
PA/PAs
0.400
0.971
0.452
0.966
0.499
0.956
wB
PA/PAs
0.849
0.785
0.899
0.683
0.948
0.489
copolymer (B):
solvent (A):
0.549
0.948
DMS-MPS/15w
2-propanone
0.595
0.935
0.649
0.920
0.699
0.915
0.752
0.891
0.799
0.858
98SCH
67-64-1
C3H6O
T/K = 309.15
wB
PA/PAs
0.401
0.980
0.453
0.973
0.500
0.976
wB
PA/PAs
0.850
0.731
0.900
0.622
0.949
0.436
copolymer (B):
solvent (A):
0.551
0.961
DMS-MPS/15w
2-propanone
0.596
0.947
0.651
0.932
0.701
0.880
0.753
0.846
0.801
0.823
98SCH
67-64-1
C3H6O
T/K = 314.15
wB
PA/PAs
0.402
0.976
0.454
0.970
0.501
0.968
wB
PA/PAs
0.851
0.718
0.901
0.599
0.950
0.411
copolymer (B):
solvent (A):
0.552
0.949
DMS-MPS/15w
2-propanone
0.597
0.927
0.652
0.916
0.702
0.884
0.754
0.844
0.802
0.797
98SCH
67-64-1
C3H6O
T/K = 318.15
wB
PA/PAs
0.404
0.975
0.456
0.975
0.502
0.963
0.553
0.947
0.599
0.923
0.653
0.886
0.703
0.862
0.756
0.823
0.804
0.776
continue
continue
wB
PA/PAs
0.853
0.693
0.902
0.575
copolymer (B):
solvent (A):
0.951
0.374
DMS-MPS/15w
2-propanone
98SCH
67-64-1
C3H6O
T/K = 322.15
wB
PA/PAs
0.407
0.958
0.458
0.960
0.504
0.957
wB
PA/PAs
0.854
0.687
0.903
0.565
0.952
0.372
0.555
0.947
0.601
0.915
0.655
0.887
0.705
0.859
0.758
0.807
0.805
0.765
_____________________________________________________________________________
Copolymers from ethylene and vinyl acetate
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Ethylene/vinyl acetate copolymer
9.0 wt% vinyl acetate
E-VA/09w
E-VA/16w(1)
E-VA/16w(2)
E-VA/17w(1)
E-VA/17w(2)
E-VA/25w
E-VA/39w
E-VA/40w
E-VA/41w
E-VA/42w
E-VA/43w
E-VA/50w
E-VA/70w
95GUP
73BEL
73BEL
73BEL
73BEL
95GUP
75BOB
75BOB
76KIE
75BOB
76KIE
95GUP
95GUP
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
E-VA/09w
E-VA/16w(1)
E-VA/16w(2)
E-VA/17w(1)
E-VA/17w(2)
E-VA/25w
E-VA/39w
E-VA/40w
E-VA/41w
E-VA/42w
E-VA/43w
E-VA/50w
E-VA/70w
2774
4065
4231
4731
20000
3650
10100
4620
14550
7180
59500
50000

fractionated in the laboratory
88000
250000
280000
_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B):
solvent (A):
E-VA/16w(1)
benzene
73BEL
71-43-2
C6H6
T/K = 373.15
B
PA/Torr
0.0000
1335.0
0.0982
1327.9
copolymer (B):
solvent (A):
0.1729
1315.8
0.1895
1313.0
E-VA/16w(2)
benzene
0.2573
1294.9
0.2839
1287.9
0.3228
1273.6
0.3641
1254.1
73BEL
71-43-2
C6H6
T/K = 373.15
B
PA/Torr
0.0000
1335.0
0.0675
1331.6
copolymer (B):
solvent (A):
0.1307
1324.9
0.1907
1315.1
E-VA/17w(1)
benzene
0.2503
1300.7
0.3082
1284.4
0.3310
1276.5
0.0000
1335.0
0.0775
1331.0
0.1465
1323.3
0.1884
1316.8
0.2624
1300.3
0.4668
1206.0
73BEL
71-43-2
C6H6
T/K = 373.15
B
PA/Torr
0.3791
1255.0
0.3308
1278.4
0.3817
1257.8
copolymer (B):
solvent (A):
E-VA/17w(2)
benzene
73BEL
71-43-2
C6H6
T/K = 373.15
B
PA/Torr
0.0000
1335.0
0.0976
1330.8
copolymer (B):
solvent (A):
0.1647
1323.6
0.2072
1317.0
E-VA/39w
benzene
0.2609
1307.9
0.3142
1295.0
0.3670
1286.7
0.3971
1260.0
75BOB
71-43-2
C6H6
T/K = 303.15
wB
PA/Torr
0.000
118.5
0.244
118.3
0.292
118.2
0.333
116.4
wB
PA/Torr
0.739
82.0
0.760
79.2
0.835
69.7
0.872
59.7
copolymer (B):
solvent (A):
E-VA/39w
benzene
0.498
110.1
0.516
106.5
0.536
105.0
0.590
101.6
0.622
95.5
75BOB
71-43-2
C6H6
T/K = 323.15
wB
PA/Torr
0.000
269.20
0.157
268.90
0.224
267.20
0.259
265.90
0.279
266.25
wB
PA/Torr
0.489
215.40
0.646
210.10
0.719
189.80
0.848
167.70
0.870
155.15
copolymer (B):
solvent (A):
E-VA/40w
benzene
0.306
261.95
0.336
259.45
0.392
254.00
0.485
233.80
75BOB
71-43-2
C6H6
T/K = 303.15
wB
PA/Torr
0.000
118.50
0.247
118.20
0.299
117.40
0.318
117.70
0.349
116.90
wB
PA/Torr
0.518
107.50
0.622
96.20
0.672
89.00
0.712
85.65
0.779
77.15
copolymer (B):
solvent (A):
E-VA/40w
benzene
0.396
115.95
0.415
114.10
0.478
110.75
0.497
109.55
75BOB
71-43-2
C6H6
T/K = 323.15
wB
PA/Torr
0.000
269.20
0.149
269.15
0.224
261.90
0.336
257.05
0.427
242.15
wB
PA/Torr
0.758
150.90
0.801
121.35
0.802
124.35
0.888
106.00
0.907
70.20
0.513
220.85
0.559
207.05
0.618
193.25
0.665
181.80
copolymer (B):
solvent (A):
E-VA/42w
benzene
75BOB
71-43-2
C6H6
T/K = 323.15
wB
PA/Torr
0.000
269.20
0.307
265.80
0.325
258.25
wB
PA/Torr
0.692
176.40
0.730
161.40
0.749
151.70
copolymer (B):
solvent (A):
0.348
256.10
E-VA/42w
benzene
0.435
243.20
0.495
234.60
0.527
227.00
0.557
217.90
0.621
203.35
75BOB
71-43-2
C6H6
T/K = 343.15
wB
PA/Torr
0.000
548.16
0.360
519.90
0.457
494.40
wB
PA/Torr
0.647
388.10
0.674
372.10
0.679
366.60
copolymer (B):
solvent (A):
0.506
476.90
E-VA/09w
1-butanol
0.516
496.90
0.563
445.50
0.584
433.50
0.593
423.60
0.615
414.40
95GUP
71-36-3
C4H10O
T/K = 353.15
wB
PA/kPa
0.994
2.7
0.988
5.2
copolymer (B):
solvent (A):
0.983
8.0
0.973
10.8
E-VA/41w
butyl acetate
0.969
12.3
0.966
13.9
0.964
15.2
76KIE
123-86-4
C6H12O2
T/K = 323.15
wB
PA/Torr
0.1771
41.80
0.2141
40.30
copolymer (B):
solvent (A):
0.2897
38.00
0.3163
36.80
E-VA/41w
butyl acetate
0.3655
34.80
0.4005
33.80
0.4623
31.30
0.5462
28.00
76KIE
123-86-4
C6H12O2
T/K = 343.15
wB
PA/Torr
0.1802
101.40
0.2374
98.10
0.2580
96.40
0.3315
89.70
0.3655
87.40
0.4387
79.90
0.4892
75.40
0.5773
64.90
copolymer (B):
solvent (A):
E-VA/41w
butyl acetate
76KIE
123-86-4
C6H12O2
T/K = 363.15
wB
PA/Torr
0.1866
219.80
0.2591
209.60
copolymer (B):
solvent (A):
0.3132
201.10
0.3767
190.00
E-VA/25w
cyclohexane
0.4165
181.50
0.4571
175.20
0.5355
158.30
0.6488
134.80
95GUP
110-82-7
C6H12
T/K = 353.15
wB
PA/kPa
0.860
39.7
0.772
54.9
copolymer (B):
solvent (A):
0.762
55.5
0.723
60.7
E-VA/50w
cyclohexane
0.700
64.1
0.631
70.4
95GUP
110-82-7
C6H12
T/K = 353.15
wB
PA/kPa
0.896
39.7
0.841
54.9
copolymer (B):
solvent (A):
0.830
55.5
0.795
60.7
E-VA/70w
cyclohexane
0.775
64.1
0.713
70.4
95GUP
110-82-7
C6H12
T/K = 353.15
wB
PA/kPa
0.974
14.4
0.919
39.7
copolymer (B):
solvent (A):
0.877
54.9
0.867
55.5
E-VA/41w
ethyl acetate
0.844
60.7
0.809
64.1
0.758
70.4
76KIE
141-78-6
C4H8O2
T/K = 303.15
wB
PA/Torr
0.2430
118.70
0.2805
118.30
copolymer (B):
solvent (A):
0.3496
117.85
0.3565
115.60
E-VA/41w
ethyl acetate
0.3804
114.10
0.4400
111.75
0.5301
100.90
76KIE
141-78-6
C4H8O2
T/K = 323.15
wB
PA/Torr
0.2554
281.20
0.2959
279.10
0.3241
274.90
0.3707
272.80
0.3817
263.10
0.4400
257.20
0.5704
230.20
copolymer (B):
solvent (A):
E-VA/41w
ethyl acetate
76KIE
141-78-6
C4H8O2
T/K = 343.15
wB
PA/Torr
0.2302
588.20
0.2885
584.00
copolymer (B):
solvent (A):
0.3372
570.40
0.3651
566.70
E-VA/43w
ethyl acetate
0.4539
547.55
0.5754
489.10
0.7667
386.30
76KIE
141-78-6
C4H8O2
T/K = 303.15
wB
PA/Torr
0.2143
118.00
0.2476
117.20
copolymer (B):
solvent (A):
0.3038
116.20
0.3490
115.20
E-VA/43w
ethyl acetate
0.3654
111.50
0.4005
109.90
0.4487
108.00
0.4851
104.20
76KIE
141-78-6
C4H8O2
T/K = 323.15
wB
PA/Torr
0.2208
277.20
0.2558
276.40
copolymer (B):
solvent (A):
0.3170
270.50
0.3655
269.70
E-VA/43w
ethyl acetate
0.3849
259.00
0.4224
252.00
0.4764
244.00
0.5195
235.70
76KIE
141-78-6
C4H8O2
T/K = 343.15
wB
PA/Torr
0.2475
575.80
0.2894
569.50
copolymer (B):
solvent (A):
0.3003
568.10
0.3750
547.00
E-VA/41w
methyl acetate
0.4399
529.30
0.5250
488.50
0.6110
499.30
0.6960
392.10
76KIE
79-20-9
C3H6O2
T/K = 303.15
wB
PA/Torr
0.2654
265.75
0.3257
261.75
copolymer (B):
solvent (A):
0.3549
260.05
0.3651
258.75
E-VA/41w
methyl acetate
0.4123
255.25
0.5102
240.75
0.5610
232.15
0.6130
215.75
76KIE
79-20-9
C3H6O2
T/K = 323.15
wB
PA/Torr
0.2561
586.15
0.3030
584.15
0.3762
565.15
0.3879
561.65
0.4387
550.65
0.4829
535.15
0.6341
473.15
0.7189
424.65
copolymer (B):
solvent (A):
E-VA/43w
methyl acetate
76KIE
79-20-9
C3H6O2
T/K = 303.15
wB
PA/Torr
0.1951
265.75
0.2632
263.95
copolymer (B):
solvent (A):
0.3190
262.75
0.3725
258.25
E-VA/43w
methyl acetate
0.3951
257.05
0.4839
244.75
0.5363
234.15
0.5744
220.75
76KIE
79-20-9
C3H6O2
T/K = 323.15
wB
PA/Torr
0.2154
586.15
0.2744
579.15
copolymer (B):
solvent (A):
0.3706
565.05
0.4313
542.15
E-VA/41w
propyl acetate
0.4775
526.35
0.5564
490.15
0.6653
439.45
0.7667
378.15
76KIE
109-60-4
C5H10O2
T/K = 303.15
wB
PA/Torr
0.1978
42.70
0.2330
42.10
copolymer (B):
solvent (A):
0.2662
41.50
0.2815
40.70
E-VA/41w
propyl acetate
0.3335
39.50
0.3865
38.20
0.4445
36.20
0.5075
34.00
76KIE
109-60-4
C5H10O2
T/K = 323.15
wB
PA/Torr
0.2048
111.70
0.2428
108.60
copolymer (B):
solvent (A):
0.2671
106.80
0.2959
104.50
E-VA/41w
propyl acetate
0.3249
101.90
0.3701
96.20
0.4180
91.20
0.4815
84.50
76KIE
109-60-4
C5H10O2
T/K = 343.15
wB
PA/Torr
0.2200
250.60
0.2644
243.00
copolymer (B):
solvent (A):
0.2931
237.50
0.3387
227.90
E-VA/41w
propyl acetate
0.3658
220.90
0.4052
211.00
0.4434
202.70
0.5749
168.00
76KIE
109-60-4
C5H10O2
T/K = 363.15
wB
PA/Torr
0.2523
501.60
0.3126
481.40
0.3569
463.30
0.4066
443.40
0.4427
427.30
0.5364
381.80
0.6073
344.80
0.8102
245.80
copolymer (B):
solvent (A):
E-VA/16w(1)
toluene
73BEL
108-88-3
C7H8
T/K = 373.15
B
PA/Torr
0.0000
558.60
0.1459
542.50
copolymer (B):
solvent (A):
0.2589
533.10
0.3228
518.50
E-VA/16w(2)
toluene
0.3869
499.90
0.4668
472.60
0.4760
470.80
0.5356
444.60
73BEL
108-88-3
C7H8
T/K = 373.15
B
PA/Torr
0.0000
558.60
0.0496
557.20
copolymer (B):
solvent (A):
0.1272
552.10
0.2658
543.60
E-VA/17w(1)
toluene
0.3599
515.60
0.3843
510.50
0.4432
491.60
0.5039
475.70
73BEL
108-88-3
C7H8
T/K = 373.15
B
PA/Torr
0.0000
558.60
0.1209
553.00
copolymer (B):
solvent (A):
0.2005
545.60
0.2113
544.40
E-VA/17w(2)
toluene
0.3186
527.90
0.3711
513.60
0.4590
493.60
0.5357
473.80
73BEL
108-88-3
C7H8
T/K = 373.15
B
PA/Torr
0.0000
558.60
0.1116
555.60
copolymer (B):
solvent (A):
0.2037
547.20
0.2245
544.40
E-VA/39w
toluene
0.3482
528.20
0.3725
522.90
0.4318
509.00
0.4803
497.10
0.5302
485.10
75BOB
108-88-3
C7H8
T/K = 303.15
wB
PA/Torr
0.000
41.65
wB
PA/Torr
0.687
30.05
0.364
41.00
copolymer (B):
solvent (A):
0.413
41.10
0.463
40.00
E-VA/39w
toluene
0.469
39.05
0.488
40.20
0.524
38.50
0.588
36.65
0.666
28.15
75BOB
108-88-3
C7H8
T/K = 323.15
wB
PA/Torr
0.000
97.25
0.389
96.30
0.437
93.25
0.501
90.35
0.520
89.30
0.571
87.35
0.642
81.50
0.661
78.00
0.668
74.20
continue
continue
wB
PA/Torr
0.718
62.25
0.730
63.75
copolymer (B):
solvent (A):
E-VA/40w
toluene
75BOB
108-88-3
C7H8
T/K = 303.15
wB
PA/Torr
0.000
41.65
0.201
40.20
0.276
40.00
0.339
38.85
wB
PA/Torr
0.555
37.40
0.578
35.50
0.598
33.90
0.621
32.30
copolymer (B):
solvent (A):
E-VA/40w
toluene
0.414
39.50
0.436
38.20
0.465
37.50
0.523
36.90
0.546
36.00
75BOB
108-88-3
C7H8
T/K = 323.15
wB
PA/Torr
0.000
97.25
0.237
96.15
0.311
95.00
wB
PA/Torr
0.630
81.35
0.673
72.90
0.694
65.35
copolymer (B):
solvent (A):
0.328
95.95
E-VA/42w
toluene
0.438
94.60
0.495
94.00
0.515
91.00
0.568
89.35
0.604
80.60
75BOB
108-88-3
C7H8
T/K = 323.15
wB
PA/Torr
0.000
92.00
0.403
85.38
0.473
80.78
wB
PA/Torr
0.736
52.60
0.749
51.50
0.785
44.90
copolymer (B):
solvent (A):
0.519
77.83
E-VA/42w
toluene
0.537
77.30
0.567
74.50
0.571
72.13
0.600
71.00
0.673
62.00
75BOB
108-88-3
C7H8
T/K = 343.15
wB
PA/Torr
0.000
204.05
0.375
191.80
0.448
182.60
0.504
176.70
wB
PA/Torr
0.694
132.80
0.728
124.10
0.765
109.40
0.795
101.20
0.543
169.80
0.619
154.30
0.649
149.80
0.652
147.30
0.672
139.20
copolymer (B):
solvent (A):
E-VA/42w
toluene
75BOB
108-88-3
C7H8
T/K = 363.15
wB
PA/Torr
0.000
407.00
wB
PA/Torr
0.771
220.00
0.431
370.70
copolymer (B):
solvent (A):
0.506
348.70
0.524
346.00
E-VA/09w
trichloromethane
0.549
339.00
0.570
323.80
0.600
315.30
0.680
277.40
0.715
251.00
95GUP
67-66-3
CHCl3
T/K = 333.15
wB
PA/kPa
0.969
14.0
0.933
28.1
copolymer (B):
solvent (A):
0.896
40.1
0.853
53.2
E-VA/25w
trichloromethane
0.832
58.4
0.804
66.1
0.784
72.3
0.747
87.1
95GUP
67-66-3
CHCl3
T/K = 333.15
wB
PA/kPa
0.938
13.9
0.860
26.7
copolymer (B):
solvent (A):
0.772
39.9
0.680
53.2
E-VA/50w
trichloromethane
0.642
59.9
0.599
66.5
0.559
73.1
0.519
79.3
95GUP
67-66-3
CHCl3
T/K = 333.15
wB
PA/kPa
0.902
13.9
0.798
26.7
copolymer (B):
solvent (A):
0.697
39.9
0.602
53.2
E-VA/70w
trichloromethane
0.561
59.9
0.523
66.5
0.488
73.1
0.448
79.3
95GUP
67-66-3
CHCl3
T/K = 333.15
wB
PA/kPa
0.941
13.9
0.839
26.7
copolymer (B):
solvent (A):
0.713
39.9
0.597
53.2
E-VA/39w
o-xylene
0.550
59.9
0.511
66.5
0.474
73.1
0.427
79.3
75BOB
95-47-6
C8H10
T/K = 323.15
wB
PA/Torr
0.000
25.76
0.157
25.30
0.298
25.25
0.363
25.10
0.376
25.30
0.381
25.30
0.457
24.20
0.503
23.20
0.628
17.80
continue
continue
wB
PA/Torr
0.630
17.50
0.643
18.35
copolymer (B):
solvent (A):
0.730
14.80
0.817
11.90
E-VA/39w
o-xylene
0.852
10.40
0.867
8.45
75BOB
95-47-6
C8H10
T/K = 343.15
wB
PA/Torr
0.000
60.82
0.307
60.60
0.336
59.60
0.386
58.10
0.437
56.30
wB
PA/Torr
0.616
45.25
0.640
43.30
0.676
42.00
0.716
39.80
0.780
35.55
copolymer (B):
solvent (A):
E-VA/42w
o-xylene
0.442
55.50
0.504
51.00
0.577
48.20
0.588
46.50
75BOB
95-47-6
C8H10
T/K = 363.15
wB
PA/Torr
0.000
139.00
0.380
129.10
copolymer (B):
solvent (A):
0.479
120.90
0.487
120.65
E-VA/16w(1)
p-xylene
0.581
108.85
0.676
93.10
0.724
85.10
0.790
71.15
0.800
63.10
73BEL
106-42-3
C8H10
T/K = 373.15
B
PA/Torr
0.0000
242.1
0.1593
237.5
copolymer (B):
solvent (A):
0.3009
226.9
0.3797
218.4
E-VA/16w(2)
p-xylene
0.4441
209.0
0.4629
206.1
0.5091
196.6
0.5602
186.1
73BEL
106-42-3
C8H10
T/K = 373.15
B
PA/Torr
0.0000
242.1
0.1767
237.0
copolymer (B):
solvent (A):
0.2788
229.4
0.3282
225.0
E-VA/17w(1)
p-xylene
0.3886
217.7
0.4585
206.9
0.5094
199.0
0.5728
181.3
73BEL
106-42-3
C8H10
T/K = 373.15
B
PA/Torr
0.0000
242.1
0.1256
239.4
0.1878
236.5
0.2892
228.9
0.3569
223.7
0.4169
214.9
0.4525
201.6
0.5668
189.2
copolymer (B):
solvent (A):
E-VA/17w(2)
p-xylene
73BEL
106-42-3
C8H10
T/K = 373.15
B
PA/Torr
0.0000
242.1
0.1573
238.0
copolymer (B):
solvent (A):
0.2319
234.3
0.3007
229.5
E-VA/39w
p-xylene
0.3691
222.3
0.4466
212.1
0.5104
201.3
0.5857
189.0
75BOB
106-42-3
C8H10
T/K = 323.15
wB
PA/Torr
0.000
32.25
0.157
31.95
wB
PA/Torr
0.578
25.80
0.632
23.20
copolymer (B):
solvent (A):
0.180
32.20
0.325
32.00
E-VA/39w
p-xylene
0.416
31.00
0.441
29.85
0.530
27.05
0.545
26.76
0.576
25.00
75BOB
106-42-3
C8H10
T/K = 343.15
wB
PA/Torr
0.000
75.70
0.241
75.50
0.297
73.50
wB
PA/Torr
0.660
51.90
0.745
46.65
0.762
43.60
copolymer (B):
solvent (A):
0.317
72.90
E-VA/40w
p-xylene
0.420
70.05
0.464
67.05
0.542
61.40
0.578
59.35
0.640
56.60
75BOB
106-42-3
C8H10
T/K = 343.15
wB
PA/Torr
0.000
75.70
0.440
67.85
copolymer (B):
solvent (A):
0.524
62.40
0.599
57.60
E-VA/40w
p-xylene
0.605
56.70
0.615
55.50
0.643
54.30
0.748
42.70
0.802
36.20
75BOB
106-42-3
C8H10
T/K = 363.15
wB
PA/Torr
0.000
167.80
wB
PA/Torr
0.812
77.20
0.450
149.70
0.489
145.20
0.549
136.90
0.577
131.90
0.630
121.80
0.690
110.70
0.737
103.35
0.760
91.95
copolymer (B):
solvent (A):
E-VA/42w
p-xylene
75BOB
106-42-3
C8H10
T/K = 323.15
wB
PA/Torr
0.000
32.25
0.451
28.60
copolymer (B):
solvent (A):
0.512
26.85
0.597
24.45
E-VA/42w
p-xylene
0.634
23.05
0.649
22.75
0.732
19.30
0.737
18.30
0.800
14.95
75BOB
106-42-3
C8H10
T/K = 343.15
wB
PA/Torr
0.000
75.70
0.390
69.15
copolymer (B):
solvent (A):
0.477
65.15
0.575
59.20
E-VA/42w
p-xylene
0.597
56.80
0.637
53.50
0.655
52.10
0.764
40.75
0.814
37.80
75BOB
106-42-3
C8H10
T/K = 363.15
wB
PA/Torr
0.000
167.80
0.450
149.70
wB
PA/Torr
0.773
89.40
0.827
70.00
0.509
142.95
0.558
135.90
0.600
127.50
0.641
120.80
0.681
114.80
0.717
104.00
0.732
109.70
_____________________________________________________________________________
Copolymers from ethylene oxide and tert-butyl methacrylate
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Poly(ethylene oxide)-b-poly(tert-butyl methacrylate)
diblock copolymer
49 mol% ethylene oxide
EO-b-tBMA/49x
94WOH
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
Mn/
Further information
g/mol
_____________________________________________________________________________
Copolymer (B)
EO-b-tBMA/49x
8200 (= 4000 + 4200)
_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B):
solvent (A):
EO-b-tBMA/49x
toluene
94WOH
108-88-3
C7H8
T/K = 323.15
B
PA/Torr
0.0000
92.12
0.4505
86.46
0.4669
85.81
0.4983
83.88
0.5444
81.36
B
PA/Torr
0.6715
69.51
0.7086
65.20
0.7461
60.40
0.7622
57.28
0.7877
53.11
0.5827
78.58
0.6132
76.25
0.6352
74.12
0.6469
72.88
Comments: segment fraction is based on Bondi's volumina with rB = 80
copolymer (B):
solvent (A):
EO-b-tBMA/49x
toluene
94WOH
108-88-3
C7H8
T/K = 343.75
B
0.0000
PA/Torr 208.40
0.5091
184.38
0.5128
182.95
0.5663
175.99
B
0.6879
PA/Torr 152.29
0.7232
143.51
0.7501
134.77
0.7501
135.21
0.5976
170.90
0.6185
167.55
0.6439
162.12
0.6590
158.66
0.6879
151.55
_____________________________________________________________________________
Copolymers from ethylene oxide and methyl methacrylate
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Poly(ethylene oxide)-b-poly(methyl methacrylate)
diblock copolymer
51.7 mol% ethylene oxide
EO-b-MMA/52x
86KRC
Poly(ethylene oxide)-b-poly(methyl methacrylate)b-poly(ethylene oxide) triblock copolymer

61.0 mol% ethylene oxide
EO-MMA-EO/61x
86KRC
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
Further information
Mn/
g/mol
_____________________________________________________________________________
Copolymer (B)
EO-b-MMA/52x
EO-MMA-EO/61x
8900 (= 4600 + 4300)

7860 (= 2400 + 3060 + 2400)

_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B):
solvent (A):
EO-b-MMA/52x
toluene
C7H8
86KRC
108-88-3
T/K = 323.41
B
PA/kPa
0.536
10.626
0.562
10.226
0.648
9.613
0.747
7.933
0.766
7.773
copolymer (B):
solvent (A):
EO-b-MMA/52x
toluene
C7H8
86KRC
108-88-3
continue
continue
T/K = 343.27
B
PA/kPa
0.522
23.878
0.562
22.638
0.567
22.691
0.615
21.878
0.641
21.252
0.644
20.132
copolymer (B):
solvent (A):
EO-b-MMA/52x
toluene
86KRC
108-88-3
C7H8
T/K = 373.27
B
PA/kPa
0.432
69.671
B
PA/kPa
0.867
44.703
0.499
67.697
0.559
64.822
0.609
62.333
0.668
59.430
0.744
54.473
0.789
50.826
0.829
47.979
0.839
46.333
copolymer (B):
solvent (A):
EO-MMA-EO/61x
toluene
86KRC
108-88-3
C7H8
T/K = 323.08
B
PA/kPa
0.461
11.457
0.547
10.626
0.599
10.226
0.667
9.613
0.736
8.706
0.762
8.399
Comments: segment fraction is based on Bondi's volumina with rB = 73.2
copolymer (B):
solvent (A):
EO-MMA-EO/61x
toluene
86KRC
108-88-3
C7H8
T/K = 343.17
B
PA/kPa
0.535
23.878
0.573
22.638
0.583
22.691
0.629
21.878
0.654
21.252
0.697
19.772
copolymer (B):
solvent (A):
EO-MMA-EO/61x
toluene
86KRC
108-88-3
C7H8
T/K = 373.26
B
PA/kPa
0.554
69.010
0.612
66.786
0.628
65.349
0.665
63.299
0.685
61.341
0.729
57.274
0.785
56.992
0.876
54.174
_____________________________________________________________________________
Copolymers from ethylene oxide and propylene oxide
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Poly(ethylene oxide)-b-poly(propylene oxide)
diblock copolymer
40.0 mol% propylene oxide
58.0 wt% propylene oxide
EO-b-PO/40x
EO-b-PO/58w
94WOH
89MOE
Poly(ethylene oxide)-b-poly(propylene oxide)b-poly(ethylene oxide) triblock copolymer

EO-PO-EO/50x
EO-PO-EO/67w
EO-PO-EO/87w
EO-PO-EO/93w
94WOH
89MOE
89MOE
89MOE
Poly(propylene oxide)-b-poly(ethylene oxide)b-poly(propylene oxide) triblock copolymer

PO-EO-PO/50x
94WOH
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
EO-b-PO/40x
EO-b-PO/58w
4240
1700
4700
EO-PO-EO/50x
EO-PO-EO/67w
EO-PO-EO/87w
EO-PO-EO/93w
10800
1900
950
1800
PO-EO-PO/50x
10800
_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B):
solvent (A):
EO-b-PO/40x
ethylbenzene
94WOH
100-41-4
C8H10
T/K = 343.75
wB
PA/PAs
0.1075
0.9961
0.1277
0.9959
0.1496
0.9922
0.1859
0.9892
0.2135
0.9851
0.2315
0.9839
0.2626
0.9795
0.3182
0.9637
0.5333
0.9057
wB
PA/PAs
0.6201
0.8528
0.6639
0.8135
0.6987
0.7823
0.7048
0.7750
0.7339
0.7431
0.7655
0.7072
0.7805
0.6805
0.8040
0.6532
0.8290
0.6036
copolymer (B):
solvent (A):
EO-b-PO/58w
tetrachloromethane
89MOE
56-23-5
CCl4
T/K = 303.15
wB
aA
0.1004
0.9830
0.2011
0.9466
copolymer (B):
solvent (A):
0.3019
0.8884
0.4026
0.8088
EO-PO-EO/50x
toluene
0.5038
0.7088
0.6038
0.5925
0.7032
0.4620
0.8031
0.3163
0.8971
0.1704
94WOH
108-88-3
C7H8
T/K = 323.35
B
PA/Torr
0.0000
92.90
0.4191
84.97
0.4480
83.29
0.4565
82.84
B
PA/Torr
0.7184
57.08
0.7604
50.74
0.7856
46.62
0.8077
42.56
0.4877
80.76
0.5584
75.51
0.5834
73.03
0.6325
68.18
0.6906
60.69
copolymer (B):
solvent (A):
EO-PO-EO/50x
toluene
94WOH
108-88-3
C7H8
T/K = 343.75
B
PA/Torr
0.0000
208.40
0.4471
178.31
0.4635
176.28
B
PA/Torr
0.6986
130.92
0.7356
121.29
0.7556
114.87
0.4811
173.77
0.5474
163.06
0.5629
160.68
0.5818
157.33
0.6436
144.30
0.6717
138.30
copolymer (B):
solvent (A):
EO-PO-EO/67w
tetrachloromethane
89MOE
56-23-5
CCl4
T/K = 303.15
wB
aA
0.0995
0.9919
0.1993
0.9620
copolymer (B):
solvent (A):
0.2994
0.9114
0.3992
0.8383
EO-PO-EO/87w
tetrachloromethane
0.5004
0.7416
0.6004
0.6264
0.7021
0.4910
0.8014
0.3423
0.9032
0.1755
89MOE
56-23-5
CCl4
T/K = 303.15
wB
aA
0.0991
0.9810
0.1987
0.9453
copolymer (B):
solvent (A):
0.2988
0.8912
0.3986
0.8162
EO-PO-EO/93w
tetrachloromethane
0.4991
0.7204
0.5998
0.6054
0.7004
0.4746
0.8007
0.3281
0.9025
0.1677
89MOE
56-23-5
CCl4
T/K = 303.15
wB
aA
0.0991
0.9861
0.1988
0.9518
copolymer (B):
solvent (A):
0.2986
0.8964
0.3994
0.8173
PO-EO-PO/50x
toluene
0.4998
0.7179
0.6002
0.6010
0.7009
0.4674
0.8017
0.3219
0.8981
0.1712
94WOH
108-88-3
C7H8
T/K = 323.05
B
PA/Torr
0.0000
91.72
0.3885
84.97
0.4300
83.29
B
PA/Torr
0.7369
54.35
0.7580
50.74
0.7838
46.62
0.4341
82.84
0.4682
80.76
0.5138
77.99
0.5604
74.37
0.5761
73.03
0.6269
68.18
copolymer (B):
solvent (A):
PO-EO-PO/50x
toluene
94WOH
108-88-3
C7H8
T/K = 342.65
B
PA/Torr
0.0000
200.10
0.3794
181.02
0.4077
178.31
0.4516
173.77
0.5346
163.06
B
PA/Torr
0.6646
140.64
0.7063
130.92
0.7262
125.98
0.7695
114.87
0.7898
108.41
0.5629
158.86
0.6045
152.05
0.6148
150.12
0.6320
147.40
_____________________________________________________________________________
Copolymers from ethylene oxide and styrene
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Polystyrene-b-poly(ethylene oxide) diblockcopolymer
blocks are not further specified
S-b-EO/?
94WOH
Poly(ethylene oxide)-b-polystyrene-b-poly(ethylene oxide)

triblock copolymer
blocks are not further specified
EO-S-EO/?
94WOH
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
S-b-EO/?
EO-S-EO/?
45000
45000

_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B):
solvent (A):
S-b-EO/?
toluene
94WOH
108-88-3
C7H8
T/K = 322.95
wB
PA/Torr
0.0000
91.33
0.5773
82.40
0.6233
79.77
wB
PA/Torr
0.7842
65.05
0.7903
62.82
0.8222
58.71
0.6728
76.10
0.6772
75.51
0.6981
73.38
0.7255
70.90
0.7387
69.71
0.7551
67.48
copolymer (B):
solvent (A):
S-b-EO/?
toluene
94WOH
108-88-3
C7H8
T/K = 342.65
wB
PA/Torr
0.0000
200.10
0.5628
182.80
0.5805
179.74
0.6064
178.06
0.6212
175.64
wB
PA/Torr
0.7385
154.61
0.7439
152.14
0.7467
153.18
0.7841
144.15
0.8155
135.01
copolymer (B):
solvent (A):
EO-S-EO/?
toluene
0.6532
170.71
0.6839
165.13
0.7077
160.98
0.7280
156.29
94WOH
108-88-3
C7H8
T/K = 323.35
wB
PA/Torr
0.0000
92.90
0.5825
82.40
0.6191
79.77
0.6634
75.51
wB
PA/Torr
0.7666
64.11
0.7704
62.82
0.8017
58.71
0.8269
54.00
copolymer (B):
solvent (A):
EO-S-EO/?
toluene
0.6865
73.38
0.7081
70.90
0.7210
69.71
0.7379
67.48
0.7592
65.05
94WOH
108-88-3
C7H8
T/K = 343.75
wB
PA/Torr
0.0000
208.40
0.5576
182.80
0.5759
179.74
0.5978
178.06
0.6141
175.64
0.6165
174.51
0.6390
170.71
wB
PA/Torr
0.7144
154.61
0.7144
156.29
0.7209
153.18
0.7343
152.14
0.7591
144.15
0.7856
135.01
0.8057
127.11
0.6717
165.13
0.6863
160.98
_____________________________________________________________________________
Copolymers from 3-hydroxybutanoic acid and 3-hydroxypentanoic acid
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
3-Hydroxybutanoic acid/3-hydroxypentanoic acid copolymer
14 wt% 3-hydroxypentanoic acid
HBA-HPA/14w
22 wt% 3-hydroxypentanoic acid
HBA-HPA/22w
99WOH
99WOH
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
HBA-HPA/14w
HBA-HPA/22w
153000 454000
188000 529000
Aldrich Chem.Co., catalog #34739-6

Aldrich Chem.Co., catalog #34741-8
_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B):
solvent (A):
HBA-HPA/14w
chlorobenzene
C6H5Cl
99WOH
108-90-7
T/K = 373.15
wB
PA/Pa
0.7854 0.7495 0.7028 0.6566 0.6205 0.5746 0.5311 0.0000

23780.0 26315.0 28811.7 30649.7 32403.5 33602.1 34540.3 38293.0
copolymer (B):
solvent (A):
HBA-HPA/14w
chlorobenzene
C6H5Cl
99WOH
108-90-7
T/K = 388.15
wB
PA/Pa
0.7312 0.6970 0.6627 0.6245 0.5989 0.5581 0.5128 0.4885 0.0000

43492.0 46497.2 49109.0 51272.2 52716.4 54775.2 56514.4 57104.4 61455.4
copolymer (B):
solvent (A):
HBA-HPA/14w
chlorobenzene
C6H5Cl
99WOH
108-90-7
T/K = 403.15
wB
PA/Pa
0.8103 0.7537 0.7093 0.6687 0.6329 0.5908 0.5617 0.5113 0.0000

53051.4 62960.1 68848.4 74082.4 77856.2 81961.9 83886.7 86475.3 94819.4
copolymer (B):
solvent (A):
HBA-HPA/w
chlorobenzene
C6H5Cl
99WOH
108-90-7
T/K = 373.15
wB
PA/Pa
0.7663 0.7015 0.6779 0.6482 0.6289 0.5963 0.5340 0.4813 0.4220

23538.7 27283.8 28260.2 29592.8 30354.9 31698.9 33418.3 34578.6 35777.2
copolymer (B):
solvent (A):
HBA-HPA/w
chlorobenzene
99WOH
108-90-7
C6H5Cl
T/K = 388.15
wB
PA/Pa
0.0000 0.4112 0.5127 0.5600 0.6122 0.6354 0.6708 0.7046 0.7352

61455.4 57983.2 54984.1 52833.2 50178.3 48605.1 45882.6 43246.2 40658.9
wB
PA/Pa
0.7740 0.7970
37039.2 34556.4
copolymer (B):
solvent (A):
HBA-HPA/w
chlorobenzene
99WOH
108-90-7
C6H5Cl
T/K = 403.15
wB
PA/Pa
0.0000 0.5091 0.5586 0.5997 0.6354 0.6731 0.7182 0.7501 0.7877

94819.4 85015.1 81582.6 78690.6 74376.3 71199.9 64941.8 60722.3 54435.8
_____________________________________________________________________________
Copolymers from styrene and butyl methacrylate
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Styrene/butyl methacrylate copolymer
50.0 wt% styrene
S-BMA/50w
95GUP
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
S-BMA/50w
105300 200000
_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B):
solvent (A):
S-BMA/50w
2-propanone
95GUP
67-64-1
C3H6O
T/K = 333.15
wB
PA/kPa
0.978
23.5
0.956
43.3
wB
PA/kPa
0.776
98.7
0.746
100.4
copolymer (B):
solvent (A):
0.947
51.6
0.929
60.3
S-BMA/50w
trichloromethane
0.910
67.6
0.867
81.7
0.856
85.3
0.836
90.4
0.799
95.9
95GUP
67-66-3
CHCl3
T/K = 343.15
wB
PA/kPa
0.922
13.3
0.852
26.4
0.778
40.1
0.708
53.6
0.631
65.5
0.545
78.8
0.488
86.0
_____________________________________________________________________________
Copolymers from styrene and docosyl maleate
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Styrene/docosyl maleate copolymer
50.0 mol% styrene
S-DCM/50x
97MIO
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
S-DCM/50x
244500 293400
_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B):
solvent (A):
S-DCM/50x
cyclohexane
97MIO
110-82-7
C6H12
T/K = 333.15
wB
PA/Torr
0.976
50.5
0.967
76.5
0.943
106.0
wB
PA/Torr
0.710
300.5
0.630
362.5
0.000
390.0
copolymer (B):
solvent (A):
0.929
131.5
S-DCM/50x
methanol
0.906
157.5
0.881
188.5
0.846
218.0
0.809
251.5
0.765
279.0
97MIO
67-56-1
CH4O
T/K = 333.15
wB
PA/Torr
0.982
128.0
0.975
190.0
copolymer (B):
solvent (A):
0.965
247.5
0.954
296.0
S-DCM/50x
2-propanone
0.940
354.5
0.920
400.5
0.895
457.5
0.879
489.5
0.000
635.0
97MIO
67-64-1
C3H6O
T/K = 323.15
wB
PA/Torr
0.974
106.0
0.965
156.0
wB
PA/Torr
0.769
513.0
0.000
612.0
copolymer (B):
solvent (A):
0.957
196.0
0.945
243.0
S-DCM/50x
2-propanone
0.927
295.5
0.904
346.5
0.874
406.0
0.846
448.0
0.799
492.0
97MIO
67-64-1
C3H6O
T/K = 343.15
wB
PA/Torr
0.976
230.0
wB
PA/Torr
0.000
1196.0
0.964
317.5
0.950
408.5
0.937
494.5
0.915
587.0
0.890
679.5
0.858
786.0
0.827
857.5
0.806
896.0
_____________________________________________________________________________
Copolymers from styrene and dodecyl maleate
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Styrene/dodecyl maleate copolymer
50.0 mol% styrene
S-DDM/50x
97MIO
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
S-DDM/50x
177500 213000
_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B):
solvent (A):
S-DDM/50x
cyclohexane
97MIO
110-82-7
C6H12
T/K = 333.15
wB
PA/Torr
0.990
50.5
0.978
76.5
0.963
106.0
wB
PA/Torr
0.769
300.5
0.692
362.5
0.000
390.0
copolymer (B):
solvent (A):
0.941
131.5
S-DDM/50x
methanol
0.935
157.5
0.914
188.5
0.887
218.0
0.856
251.5
97MIO
67-56-1
CH4O
T/K = 333.15
wB
PA/Torr
0.976
128.0
0.966
190.0
0.950
247.5
0.931
296.0
0.907
354.5
0.835
457.5
0.821
279.0
0.808
489.5
0.000
635.0
copolymer (B):
solvent (A):
S-DDM/50x
2-propanone
97MIO
67-64-1
C3H6O
T/K = 323.15
wB
PA/Torr
0.965
106.0
0.950
156.0
wB
PA/Torr
0.665
513.0
0.000
612.0
copolymer (B):
solvent (A):
0.941
196.0
0.921
243.0
S-DDM/50x
2-propanone
0.893
295.5
0.861
346.5
0.826
406.0
0.786
448.0
0.712
492.0
97MIO
67-64-1
C3H6O
T/K = 343.15
wB
PA/Torr
0.978
230.0
wB
PA/Torr
0.000
1196.0
0.961
317.5
0.947
408.5
0.927
494.5
0.898
587.0
0.863
679.5
0.817
786.0
0.778
857.5
0.746
896.0
_____________________________________________________________________________
Copolymers from styrene and isoprene
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Polystyrene-b-polyisoprene-b-polystyrene triblock copolymer
15.0 wt% styrene
S-I-S/15w
24.2 wt% styrene
S-I-S/24w
30.0 wt% styrene
S-I-S/30w
99FRE
99FRE
99FRE
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
S-I-S/15w
S-I-S/24w
S-I-S/30w
159000
113000
105000

_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B):
solvent (A):
S-I-S/15w
cyclohexane
99FRE
110-82-7
C6H12
T/K = 323.45
wB
aA
0.9941
0.0242
0.9922
0.0298
0.9921
0.0291
0.9883
0.0449
0.9833
0.0646
0.9826
0.0661
0.9791
0.0798
0.9709
0.1097
0.9649
0.1306
wB
aA
0.9531
0.1712
0.9209
0.2792
0.8960
0.3526
0.8959
0.3529
0.8680
0.4409
0.8679
0.4412
0.8447
0.5140
0.8376
0.5505
0.8364
0.5546
wB
aA
0.8359
0.5547
0.8195
0.6841
0.8183
0.6941
copolymer (B):
solvent (A):
S-I-S/24w
cyclohexane
99FRE
110-82-7
C6H12
T/K = 323.55
wB
aA
0.9916
0.0325
0.9839
0.0602
0.9806
0.0700
wB
aA
0.8894
0.3606
0.8570
0.4376
0.8158
0.5434
copolymer (B):
solvent (A):
0.9724
0.1007
S-I-S/30w
cyclohexane
0.9581
0.1496
0.9579
0.1503
0.9445
0.1948
0.9421
0.2032
0.8907
0.3552
99FRE
110-82-7
C6H12
T/K = 323.95
wB
aA
0.9922
0.0327
0.9921
0.0321
0.9892
0.0440
0.9891
0.0439
0.9814
0.0737
0.9785
0.0854
0.9768
0.0912
wB
aA
0.9574
0.1644
0.9492
0.1925
0.9305
0.2565
0.9231
0.2791
0.9226
0.2817
0.8606
0.4405
0.7565
0.6721
0.9723
0.1086
0.9670
0.1294
_____________________________________________________________________________
Copolymers from styrene and maleic anhydride
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Styrene/maleic anhydride copolymer
50.0 mol% styrene
S-MAH/50x
97MIO
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
S-MAH/50x
96700
116000
_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B):
solvent (A):
S-MAH/50x
methanol
97MIO
67-56-1
CH4O
T/K = 333.15
wB
PA/Torr
0.932
127.5
wB
PA/Torr
0.000
635.0
0.906
175.5
copolymer (B):
solvent (A):
0.878
229.5
0.830
286.5
S-MAH/50x
2-propanone
0.794
339.0
0.761
393.0
0.737
434.5
0.700
484.5
97MIO
67-64-1
C3H6O
T/K = 323.15
wB
PA/Torr
0.902
215.5
0.856
278.0
0.819
336.5
0.783
389.0
0.771
400.0
0.714
454.0
0.657
505.0
0.621
489.0
0.000
612.0
_____________________________________________________________________________
Copolymers from styrene and methyl methacrylate
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Styrene/methyl methacrylate copolymer
44.0 wt% styrene
50.0 wt% styrene
S-MMA/44w
S-MMA/50w
Polystyrene-b-poly(methyl methacrylate) diblock copolymer

47.8 wt% polystyrene
S-b-MMA/48w
97WO2
97TAN
98WOH
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
Further information
Mn/
g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
S-MMA/44w
S-MMA/50w
S-b-MMA/48w
50600
91000
18000
85000
100000
20500 ( = 9800-b-10700)

Polysciences Inc.
Polysciences Inc.
_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B):
solvent (A):
S-MMA/44w
benzene
C6H6
97WO2
71-43-2
T/K = 343.15
wB
PA/Pa
0.0000 0.4664 0.5157 0.5797 0.6218 0.6566 0.7079 0.7615 0.8101

73128.3 67029.4 65054.9 61786.1 59190.0 56652.5 52147.8 46421.8 40015.8
copolymer (B):
solvent (A):
S-MMA/44w
ethylbenzene
C8H10
97WO2
100-41-4
continue
continue
T/K = 373.15
wB
PA/Pa
0.0000 0.5735 0.5905 0.6201 0.6489 0.6717 0.7056 0.7339 0.7653

34300.5 31378.1 31172.3 30668.1 29937.5 29296.1 28253.3 27196.9 25704.8
wB
PA/Pa
0.8097
23190.6
copolymer (B):
solvent (A):
S-MMA/44w
ethylbenzene
C8H10
97WO2
100-41-4
T/K = 398.15
wB
PA/Pa
0.0000 0.5496 0.6039 0.6328 0.6600 0.7014 0.7221 0.7575 0.7930

74321.2 68866.0 67022.9 65618.2 64243.2 61493.4 59895.5 56603.0 52693.7
wB
PA/Pa
0.8143
49661.4
copolymer (B):
solvent (A):
S-MMA/44w
mesitylene
C9H12
97WO2
108-67-8
T/K = 398.15
wB
PA/Pa
0.0000 0.6365 0.6783 0.7010 0.7321 0.7598 0.7834 0.8066 0.8293

32215.7 29635.2 28936.1 28614.0 27708.7 26822.8 25982.0 24703.0 23085.8
copolymer (B):
solvent (A):
S-MMA/44w
toluene
C7H8
97WO2
108-88-3
T/K = 343.15
wB
PA/Pa
0.0000 0.4775 0.5203 0.5674 0.6186 0.6607 0.7091 0.7520 0.7997

27250.3 24991.3 24459.9 23707.8 22857.6 21868.4 20484.1 19042.5 17017.8
copolymer (B):
solvent (A):
S-MMA/44w
toluene
C7H8
T/K = 373.15
wB
PA/Pa
0.0000 0.5029 0.5586 0.6111 0.6508 0.6930 0.7366 0.7823

74464.2 67256.1 65118.9 62594.6 59765.0 57464.0 53673.8 48736.8
97WO2
108-88-3
copolymer (B):
solvent (A):
S-MMA/44w
p-xylene
97WO2
106-42-3
C8H10
T/K = 398.15
wB
PA/Pa
0.0000 0.6109 0.6393 0.6708 0.6954 0.7112 0.7467 0.7799 0.8083

69803.4 64896.2 63967.8 63179.1 61985.4 60987.2 58209.1 54893.4 51598.7
wB
PA/Pa
0.8363
47368.6
copolymer (B):
solvent (A):
S-MMA/50w
methyl acetate
C3H6O2
97TAN
79-20-9
T/K = 323.15
wB
PA/kPa
0.919
43.10
0.879
52.81
copolymer (B):
solvent (A):
0.826
61.39
0.754
68.83
S-MMA/50w
2-propanone
0.679
74.73
0.000
78.69
C3H6O
97TAN
67-64-1
T/K = 323.15
wB
PA/kPa
0.926
51.98
0.874
64.30
copolymer (B):
solvent (A):
0.769
76.06
0.555
81.66
S-MMA/50w
trichloromethane
0.000
81.67
CHCl3
97TAN
67-66-3
T/K = 323.15
wB
PA/kPa
0.884
14.36
copolymer (B):
solvent (A):
0.749
27.96
0.626
40.43
0.492
51.86
S-b-MMA/48w
benzene
0.376
60.79
C6H6
0.000
70.17
98WOH
71-43-2
T/K = 343.15
wB
PA/Pa
0.0000 0.4524 0.5067 0.5491 0.5889 0.6291 0.6674 0.7127 0.7567

73128.3 67614.5 65530.0 63512.0 61303.5 58751.0 55877.5 51840.5 46977.5
copolymer (B):
solvent (A):
S-b-MMA/48w
ethylbenzene
C8H10
98WOH
100-41-4
continue
continue
T/K = 373.15
wB
PA/Pa
0.0000 0.5801 0.6199 0.6512 0.6990 0.7293 0.7617 0.8014

34300.5 31591.0 30891.0 30243.0 28843.5 27807.5 26384.0 24151.0
copolymer (B):
solvent (A):
S-b-MMA/48w
ethylbenzene
C8H10
98WOH
100-41-4
T/K = 398.15
wB
0.0000
PA/Pa74321.2
copolymer (B):
solvent (A):
0.5794 0.6262 0.6508 0.6833 0.7158 0.7485 0.7771 0.8144

68279.0 66465.5 65410.0 63500.0 61137.0 58201.0 54886.0 50211.5
S-b-MMA/48w
mesitylene
C9H12
98WOH
108-67-8
T/K = 398.15
wB
PA/Pa
0.0000 0.6714 0.6997 0.7223 0.7591 0.7982 0.8245

32215.7 29603.0 28965.0 28430.5 26984.0 25295.5 23646.5
copolymer (B):
solvent (A):
S-b-MMA/48w
toluene
C7H8
98WOH
108-88-3
T/K = 343.15
wB
PA/Pa
0.0000 0.5017 0.5340 0.5611 0.5960 0.6326 0.6723 0.7138 0.7469

27250.3 24751.5 24362.0 23947.5 23372.5 22699.5 21511.5 20585.0 19418.5
wB
PA/Pa
0.7782
18277.0
copolymer (B):
solvent (A):
S-b-MMA/48w
toluene
C7H8
98WOH
108-88-3
T/K = 373.15
wB
PA/Pa
0.0000 0.4832 0.5364 0.5796 0.6298 0.6663 0.6997 0.7462 0.7897

74464.2 68224.0 66668.0 64694.5 61939.0 59750.0 57404.5 53197.0 48424.0
copolymer (B):
solvent (A):
S-b-MMA/48w
p-xylene
C8H10
T/K = 398.15
wB
PA/Pa
0.0000 0.5998 0.6476 0.6895 0.7192 0.7465 0.7839 0.8124

69803.4 64910.0 63870.0 62292.5 60268.0 58328.0 54314.0 51424.0
98WOH
106-42-3
_____________________________________________________________________________
Copolymers from styrene and pentyl maleate
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Styrene/pentyl maleate copolymer
50.0 mol% styrene
S-PM/50x
97MIO
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
S-PM/50x
130000 156000
_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B):
solvent (A):
S-PM/50x
cyclohexane
97MIO
110-82-7
C6H12
T/K = 333.15
wB
PA/Torr
0.996
76.5
0.994
106.0
wB
PA/Torr
0.874
362.5
0.000
390.0
copolymer (B):
solvent (A):
0.982
131.5
0.981
157.5
S-PM/50x
methanol
0.975
188.5
0.953
218.0
0.946
251.5
0.934
279.0
0.892
300.5
97MIO
67-56-1
CH4O
T/K = 333.15
wB
PA/Torr
0.970
128.0
0.956
190.0
0.940
247.5
0.915
296.0
0.882
354.5
0.847
400.5
0.783
457.5
0.734
489.5
0.000
635.0
copolymer (B):
solvent (A):
S-PM/50x
2-propanone
97MIO
67-64-1
C3H6O
T/K = 323.15
wB
PA/Torr
0.967
106.0
0.942
156.0
wB
PA/Torr
0.631
513.0
0.000
612.0
copolymer (B):
solvent (A):
0.932
196.0
0.914
243.0
S-PM/50x
2-propanone
0.888
295.5
0.848
346.5
0.806
406.0
0.759
448.0
0.675
492.0
97MIO
67-64-1
C3H6O
T/K = 343.15
wB
PA/Torr
0.985
230.0
wB
PA/Torr
0.000
1196.0
0.968
317.5
0.950
408.5
0.924
494.5
0.891
587.0
0.849
679.5
0.794
786.0
0.745
857.5
0.706
896.0
_____________________________________________________________________________
Copolymers from vinyl acetate and vinyl chloride
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Vinyl acetate/vinyl chloride copolymer
VA-VC/10w
VA-VC/12w(1)
VA-VC/12w(2)
95GUP
98KIM
95GUP
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
VA-VC/10w
VA-VC/12w(1)
VA-VC/12w(2)
7800
14300
115000
22000
30000

_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B):
solvent (A):
VA-VC/12w(1)
benzene
98KIM
71-43-2
C6H6
T/K = 398.15
wB
aA
0.9747
0.1084
0.9689
0.1384
copolymer (B):
solvent (A):
0.9610
0.1648
0.9503
0.1991
VA-VC/12w(1)
benzene
0.9421
0.2099
0.9309
0.2593
0.9190
0.2911
98KIM
71-43-2
C6H6
T/K = 418.15
wB
aA
0.9690
0.1120
0.9630
0.1371
copolymer (B):
solvent (A):
0.9561
0.1614
0.9482
0.1846
VA-VC/12w(2)
1-butanol
0.9400
0.2166
0.9318
0.2774
0.9289
0.2869
95GUP
71-36-3
C4H10O
T/K = 353.15
wB
PA/kPa
0.993
2.7
0.984
5.2
copolymer (B):
solvent (A):
0.978
8.0
0.967
10.8
VA-VC/12w(1)
chlorobenzene
0.960
12.3
0.956
13.9
0.954
15.2
98KIM
108-90-7
C6H5Cl
T/K = 398.15
wB
aA
0.9880
0.0828
0.9841
0.0927
copolymer (B):
solvent (A):
0.9794
0.1159
0.9738
0.1517
VA-VC/12w(1)
ethylbenzene
0.9674
0.1990
0.9600
0.2268
0.9516
0.2642
98KIM
100-41-4
C8H10
T/K = 398.15
wB
aA
0.9703
0.2431
0.9611
0.3024
copolymer (B):
solvent (A):
0.9510
0.3670
0.9384
0.4353
VA-VC/12w(1)
ethylbenzene
0.9225
0.5054
0.9010
0.5755
0.8716
0.6955
98KIM
100-41-4
C8H10
T/K = 418.15
wB
aA
0.9794
0.1793
0.9748
0.2100
0.9691
0.2508
0.9622
0.2973
0.9547
0.3446
0.9460
0.3957
0.9364
0.4476
copolymer (B):
solvent (A):
VA-VC/12w(1)
ethylbenzene
98KIM
100-41-4
C8H10
T/K = 428.15
wB
aA
0.9814
0.1406
0.9773
0.1709
copolymer (B):
solvent (A):
0.9727
0.2030
0.9676
0.2360
VA-VC/12w(2)
methanol
0.9613
0.2690
0.9538
0.3260
0.9446
0.3890
95GUP
67-56-1
CH4O
T/K = 353.15
wB
PA/kPa
0.971
13.6
0.970
28.4
copolymer (B):
solvent (A):
0.968
39.9
0.963
52.5
VA-VC/12w(1)
n-octane
0.963
65.7
0.962
79.1
98KIM
111-65-9
C8H18
T/K = 398.15
wB
aA
0.9846
0.1859
0.9828
0.2023
copolymer (B):
solvent (A):
0.9809
0.2188
0.9789
0.2355
VA-VC/12w(1)
n-octane
0.9766
0.2521
0.9742
0.2686
0.9718
0.2849
98KIM
111-65-9
C8H18
T/K = 418.15
wB
aA
0.9823
0.2006
0.9804
0.2268
copolymer (B):
solvent (A):
0.9786
0.2496
0.9766
0.2606
VA-VC/12w(1)
p-xylene
0.9744
0.2738
0.9722
0.3038
0.9701
0.3296
98KIM
106-42-3
C8H10
T/K = 398.15
wB
aA
0.9884
0.0927
0.9843
0.1472
copolymer (B):
solvent (A):
0.9791
0.1970
0.9729
0.2368
VA-VC/12w(1)
p-xylene
0.9649
0.2890
0.9549
0.3436
0.9432
0.4189
98KIM
106-42-3
C8H10
T/K = 418.15
wB
aA
0.9864
0.1262
0.9815
0.1677
0.9752
0.2148
0.9675
0.2765
0.9583
0.3420
0.9476
0.4001
0.9355
0.4566
_____________________________________________________________________________
Copolymers from vinyl acetate and vinyl alcohol
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Vinyl acetate/vinyl alcohol copolymer
8.0 mol% vinyl acetate
VA-VAL/08x
VA-VAL/18x
2000NAG
2000NAG
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
VA-VAL/08x
VA-VAL/18x
B (298 K) = 1.241 g/cm3

B (298 K) = 1.234 g/cm3
70000
85000
_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B):
solvent (A):
VA-VAL/08x
water
H2O
2000NAG
7732-18-5
T/K = 298.15
B
aA
0.0039
0.999968
0.0075
0.0083
0.0113
0.0125
0.0151
0.0164
0.0206
0.999963 0.999959 0.999945 0.999917 0.999896 0.999867 0.999839
B
aA
0.0302
0.999998
0.0330
0.0360
0.0409
0.0505
0.0575
0.0635
0.0727
0.999996 0.999995 0.999992 0.999991 0.999990 0.999987 0.999980
B
aA
0.0747
0.999819
0.0883
0.0910
0.1065
0.999746 0.999738 0.999627
Comments: B = (wB/1.241) (0.99705 + 0.245 wB)
copolymer (B):
solvent (A):
VA-VAL/18x
water
2000NAG
7732-18-5
H2O
T/K = 298.15
B
aA
0.0039
0.999999
0.0076
0.0114
0.0150
0.0222
0.0305
0.0363
0.0494
0.999997 0.999994 0.999991 0.999983 0.999971 0.999961 0.999928
B
aA
0.0626
0.999883
0.0756
0.0878
0.999832 0.999767
Comments: B = (wB/1.234) (0.99705 + 0.237 wB)
2.2. Classical mass-fraction Henry's constants of solvent vapors in

molten copolymers
_____________________________________________________________________________
Copolymers from acrylonitrile and butadiene
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Acrylonitrile/butadiene copolymer
AN-B/18w
AN-B/34w(1)
AN-B/34w(2)
AN-B/34w(3)
AN-B/41w
95TRI
93ISS, 97SCH
95TRI
82LIP
86IT2
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
AN-B/18w
AN-B/34w(1)
AN-B/34w(2)
AN-B/34w(3)
AN-B/41w
100000
60000
111000
Bayer India
Perbunan 3307, Bayer AG, Ger.
Bayer India
Krynac, Polysar
no data
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B):
AN-B/18w
95TRI
Comments: Henrys constants were not corrected for solubility of the marker gas
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
n-decane
1,4-dioxane
ethyl acetate
n-heptane
n-hexane
353.15
353.15
353.15
353.15
353.15
353.15
0.2525
0.02913
0.1291
0.4129
0.4353
1.110
n-nonane
n-octane
2-propanone
tetrahydrofuran
toluene
trichloromethane
353.15
353.15
353.15
353.15
353.15
353.15
0.06916
0.1708
1.124
0.3937
0.09431
0.1960
_____________________________________________________________________________
copolymer (B):
AN-B/34w(1)
93ISS
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
n-heptane
n-heptane
n-heptane
n-heptane
n-nonane
n-nonane
333.15
353.15
373.15
393.15
333.15
353.15
373.15
393.15
333.15
353.15
0.2622
0.4657
0.8845
1.388
1.308
2.705
3.603
5.475
0.2007
0.4117
n-nonane
n-nonane
n-octane
n-octane
n-octane
n-octane
toluene
toluene
toluene
toluene
373.15
393.15
333.15
353.15
373.15
393.15
333.15
353.15
373.15
393.15
0.8153
1.414
0.5001
0.8916
1.638
2.603
0.1051
0.2108
0.3969
0.6886
_____________________________________________________________________________
copolymer (B):
AN-B/34w(1)
97SCH
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
cyclohexane
n-heptane
330.15
330.15
330.15
0.1954
0.1920
0.1420
n-hexane
toluene
330.15
330.15
0.4091
0.06506
_____________________________________________________________________________
copolymer (B):
AN-B/34w(2)
95TRI
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
n-decane
1,4-dioxane
ethyl acetate
n-heptane
n-hexane
353.15
353.15
353.15
353.15
353.15
353.15
0.3038
0.06299
0.09262
0.4173
0.7986
2.370
n-nonane
n-octane
2-propanone
tetrahydrofuran
toluene
trichloromethane
353.15
353.15
353.15
353.15
353.15
353.15
0.1434
0.3348
0.7357
0.3442
0.1289
0.2131
_____________________________________________________________________________
copolymer (B):
AN-B/34w(3)
82LIP
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
butylcyclohexane
1-chlorobutane
n-decane
n-octane
348.15
348.15
348.15
348.15
348.15
0.2346
0.02746
0.3311
0.0385
0.2395
1-octene
2-pentanone
tetrachloromethane
toluene
trichloromethane
348.15
348.15
348.15
348.15
348.15
0.2997
0.1336
0.2014
0.0921
0.1714
_____________________________________________________________________________
copolymer (B):
AN-B/41w
86IT2
Comments: Henrys constants were corrected for solubility of the marker gas N2
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
1,3-butadiene
1,3-butadiene
1,3-butadiene
1,3-butadiene
n-butane
n-butane
n-butane
n-butane
cyclohexane
cyclohexane
cyclohexane
cyclohexane
n-decane
n-decane
n-decane
n-decane
2,2-dimethylbutane
2,2-dimethylbutane
2,2-dimethylbutane
2,2-dimethylbutane
398.15
423.15
448.15
473.15
398.15
423.15
448.15
473.15
398.15
423.15
448.15
473.15
398.15
423.15
448.15
473.15
398.15
423.15
448.15
473.15
398.15
423.15
448.15
473.15
1.24
2.15
3.47
5.17
17.1
24.1
33.6
44.3
30.3
40.2
51.6
60.9
3.08
4.84
7.18
10.1
0.498
0.995
1.83
2.97
9.84
13.9
19.1
25.1
ethylbenzene
ethylbenzene
ethylbenzene
ethylbenzene
n-hexane
n-hexane
n-hexane
n-hexane
mesitylene
mesitylene
mesitylene
mesitylene
2-methylpropane
2-methylpropane
2-methylpropane
2-methylpropane
n-octane
n-octane
n-octane
n-octane
toluene
toluene
toluene
toluene
398.15
423.15
448.15
473.15
398.15
423.15
448.15
473.15
398.15
423.15
448.15
473.15
398.15
423.15
448.15
473.15
398.15
423.15
448.15
473.15
398.15
423.15
448.15
473.15
0.333
0.657
1.19
1.94
6.70
10.5
15.2
21.2
0.155
0.337
0.655
1.14
38.1
47.1
57.1
64.1
1.78
3.13
5.08
7.47
0.599
1.12
1.92
3.01
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from acrylonitrile and 2-(3-methyl-3-phenylcyclobutyl)2-hydroxyethyl methacrylate
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Acrylonitrile/2-(3-methyl-3-phenylcyclobutyl)2-hydroxyethyl methacrylate copolymer
45.0 mol% acrylonitrile
AN-MPCHEMA/45x
2000KAY
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
B = 1.075 g/cm3,
AN-MPCHEMA/45x
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B):
AN-MPCHEMA/45x
2000KAY
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
benzene
2-butanone
2-butanone
2-butanone
2-butanone
2-butanone
n-decane
n-decane
n-decane
n-decane
n-decane
n-dodecane
n-dodecane
n-dodecane
n-dodecane
n-dodecane
ethanol
ethanol
ethanol
ethanol
ethanol
423.15
433.15
443.15
453.15
463.15
423.15
433.15
443.15
453.15
463.15
423.15
433.15
443.15
453.15
463.15
423.15
433.15
443.15
453.15
463.15
423.15
433.15
443.15
453.15
463.15
3.603
4.288
4.536
4.798
5.137
4.074
4.532
4.845
5.459
5.876
1.319
1.559
1.772
1.988
2.323
0.567
0.719
0.911
1.046
1.333
7.938
8.649
9.354
9.666
10.38
methyl acetate
methyl acetate
methyl acetate
methyl acetate
methyl acetate
n-nonane
n-nonane
n-nonane
n-nonane
n-nonane
n-octane
n-octane
n-octane
n-octane
n-octane
2-propanone
2-propanone
2-propanone
2-propanone
2-propanone
toluene
toluene
toluene
toluene
toluene
423.15
433.15
443.15
453.15
463.15
423.15
433.15
443.15
453.15
463.15
423.15
433.15
443.15
453.15
463.15
423.15
433.15
443.15
453.15
463.15
423.15
433.15
443.15
453.15
463.15
4.813
5.514
5.873
6.231
6.269
1.970
2.236
2.446
2.687
3.128
2.661
2.945
3.151
3.488
3.602
5.784
6.410
6.824
7.228
8.302
2.565
2.931
3.124
3.349
3.975
_____________________________________________________________________________
continue
continue
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
ethyl acetate
ethyl acetate
ethyl acetate
ethyl acetate
ethyl acetate
methanol
methanol
methanol
methanol
methanol
423.15
433.15
443.15
453.15
463.15
423.15
433.15
443.15
453.15
463.15
3.646
4.198
4.475
4.845
5.064
12.18
13.22
13.58
14.52
15.44
n-undecane
n-undecane
n-undecane
n-undecane
n-undecane
o-xylene
o-xylene
o-xylene
o-xylene
o-xylene
423.15
433.15
443.15
453.15
463.15
423.15
433.15
443.15
453.15
463.15
0.8903
1.093
1.326
1.549
1.834
1.493
1.802
2.128
2.340
3.473
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from acrylonitrile and styrene
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Acrylonitrile/styrene copolymer
62.0 mol% acrylonitrile
S-AN/28w
S-AN/62x
97WO1
84MAT
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
S-AN/28w
S-AN/62x
46000
100000
86000

_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B):
S-AN/28w
97WO1
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
propylbenzene
propylbenzene
propylbenzene
toluene
toluene
toluene
423.15
448.15
473.15
423.15
448.15
473.15
423.15
448.15
473.15
3.50
5.42
8.10
0.55
1.055
1.80
1.65
2.75
4.30
o-xylene
o-xylene
o-xylene
m-xylene
m-xylene
m-xylene
p-xylene
p-xylene
p-xylene
423.15
448.15
473.15
423.15
448.15
473.15
423.15
448.15
473.15
0.80
1.40
2.40
0.85
1.53
2.50
0.90
1.55
2.60
_____________________________________________________________________________
copolymer (B):
S-AN/62x
84MAT
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
ethyl acetate
ethyl acetate
ethyl acetate
393.15
423.15
453.15
393.15
423.15
453.15
2.47
4.96
7.63
2.62
7.92
12.1
toluene
toluene
toluene
trichloromethane
trichloromethane
trichloromethane
393.15
423.15
453.15
393.15
423.15
453.15
1.14
2.57
4.99
1.94
4.30
7.04
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from acrylonitrile and vinylidene chloride
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Acrylonitrile/vinylidene chloride copolymer
20 wt% acrylonitrile
AN-VdC/20w
86DEM
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
AN-VdC/20w
Polysciences Inc.
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B):
AN-VdC/20w
86DEM
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
1,1-dichloroethene
1,1-dichloroethene
1,1-dichloroethene
291.0
298.0
306.0
1.498
1.847
2.437
1,1-dichloroethene
1,1-dichloroethene
314.0
323.0
2.984
3.991
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from butadiene and styrene
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
20.0 mol% styrene
25.0 mol% styrene
15.0 wt% styrene
15.0 wt% styrene
23.0 wt% styrene
23.0 wt% styrene
23.5 wt% styrene
25.0 wt% styrene
30.0 wt% styrene
40.0 wt% styrene
40.0 wt% styrene
41.0 wt% styrene
45.0 wt% styrene
77.0 wt% styrene
S-BR/20x
S-BR/25x
S-BR/15w(1)
S-BR/15w(2)
S-BR/23x
S-BR/23x
S-BR/24w
S-BR/25w
S-BR/30w
S-BR/40w(1)
S-BR/40w(2)
S-BR/41w
S-BR/45w
S-BR/77w
84MAT
87OEN
95PET
93ISS, 97SCH
93ISS
97SCH
95PET
95PET
86IT1
95PET
93ISS, 97SCH
97WO1
86IT1
86IT1
Polystyrene-b-polybutadiene-b-polystyrene
triblock copolymer
17.0 wt% styrene
31.0 wt% styrene
S-B-S/17w
S-B-S/31w
92ROM
92ROM
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
S-BR/20x
S-BR/25x
S-BR/15w(1)
S-BR/15w(2)
S-BR/23w
S-BR/24w
S-BR/25w
S-BR/30w
S-BR/40w(1)
S-BR/40w(2)
60000
170000
170000
240000
210000
107700
190000
400000
170000
200000
140000
155000
Petkim Petrokimya A.S. Yarimca, Turkey

18 wt% 1,2-vinyl, 58 wt% trans
Buna EM BT98, Buna Werke Huels/Marl
Buna EM 1500, Buna Werke Huels/Marl
15 wt% 1,2-vinyl, 53.5 wt% trans
73 wt% 1,2-vinyl
12 wt% 1,2-vinyl, 42 wt% trans
Buna EM 1516, Buna Werke Huels/Marl
_____________________________________________________________________________
continue
continue
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
S-BR/41w
S-BR/45w
S-BR/77w
S-B-S/17w
S-B-S/31w
86300
130000
117600
114800
110800
181200
600000
200000
188300
139600
Kraton D-1301X
Kraton D-1101
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B):
S-BR/20x
84MAT
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
cyclohexane
cyclohexane
cyclohexane
393.15
423.15
453.15
393.15
423.15
453.15
1.77
3.71
6.68
2.19
4.16
7.37
toluene
toluene
toluene
trichloromethane
trichloromethane
trichloromethane
393.15
423.15
453.15
393.15
423.15
453.15
0.77
1.72
3.33
1.54
3.25
5.01
_____________________________________________________________________________
copolymer (B):
S-BR/25x
87OEN
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
cyclohexane
cyclohexane
343.3
353.3
358.3
363.2
343.3
353.1
0.3031
0.3906
0.4549
0.5285
0.4648
0.6189
cyclohexane
cyclohexane
n-hexane
n-hexane
n-hexane
n-hexane
358.3
363.2
343.3
353.1
358.3
363.2
0.7113
0.8285
0.9960
1.3191
1.6120
1.8290
_____________________________________________________________________________
copolymer (B):
S-BR/15w(1)
95PET
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
cyclohexane
cyclohexane
cyclohexane
cyclohexane
n-decane
n-decane
n-decane
n-heptane
n-heptane
n-heptane
323.15
353.15
373.15
393.15
323.15
353.15
373.15
393.15
353.15
373.15
393.15
323.15
353.15
373.15
0.1145
0.3358
0.6294
0.9492
0.1382
0.3790
0.6534
1.061
0.01920
0.04503
0.09523
0.1020
0.3119
0.5884
n-heptane
n-hexane
n-hexane
n-hexane
n-hexane
n-nonane
n-nonane
n-nonane
n-nonane
n-octane
n-octane
n-octane
n-octane
393.15
323.15
353.15
373.15
393.15
323.15
353.15
373.15
393.15
323.15
353.15
373.15
393.15
0.9323
0.3059
0.7950
1.342
2.160
0.01156
0.04699
0.1027
0.2020
0.03392
0.1177
0.2424
0.4342
_____________________________________________________________________________
copolymer (B):
S-BR/15w(2)
93ISS
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
n-heptane
n-heptane
n-heptane
n-heptane
n-hexane
n-hexane
n-hexane
n-hexane
333.15
353.15
373.15
393.15
333.15
353.15
373.15
393.15
333.15
353.15
373.15
393.15
0.1707
0.3303
0.5873
0.9477
0.1523
0.3056
0.5617
0.9551
0.4348
0.7965
1.363
2.182
n-nonane
n-nonane
n-nonane
n-nonane
n-octane
n-octane
n-octane
n-octane
toluene
toluene
toluene
toluene
333.15
353.15
373.15
393.15
333.15
353.15
373.15
393.15
333.15
353.15
373.15
393.15
0.01888
0.04760
0.1051
0.2045
0.05246
0.1185
0.2412
0.4346
0.05511
0.1199
0.2310
0.3993
_____________________________________________________________________________
copolymer (B):
S-BR/15w(2)
97SCH
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
cyclohexane
n-heptane
330.15
330.15
330.15
0.1707
0.1988
0.1523
n-hexane
toluene
330.15
330.15
0.4348
0.05510
_____________________________________________________________________________
copolymer (B):
S-BR/23w
93ISS
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
n-heptane
n-heptane
n-heptane
n-heptane
n-hexane
n-hexane
n-hexane
n-hexane
333.15
353.15
373.15
393.15
333.15
353.15
373.15
393.15
333.15
353.15
373.15
393.15
0.1749
0.3401
0.6074
1.006
0.1597
0.3277
0.5969
1.036
0.4596
0.8464
1.455
2.359
n-nonane
n-nonane
n-nonane
n-nonane
n-octane
n-octane
n-octane
n-octane
toluene
toluene
toluene
toluene
333.15
353.15
373.15
393.15
333.15
353.15
373.15
393.15
333.15
353.15
373.15
393.15
0.02070
0.05108
0.1102
0.2146
0.05686
0.1268
0.2555
0.4582
0.05687
0.1225
0.2362
0.4241
_____________________________________________________________________________
copolymer (B):
S-BR/23w
97SCH
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
330.15
0.1748
n-hexane
330.15
0.4595
cyclohexane
330.15
0.2033
toluene
330.15
0.05687
n-heptane
330.15
0.1601
_____________________________________________________________________________
copolymer (B):
S-BR/24w
95PET
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
cyclohexane
cyclohexane
cyclohexane
cyclohexane
n-decane
n-decane
n-decane
n-heptane
n-heptane
n-heptane
323.15
353.15
373.15
393.15
323.15
353.15
373.15
393.15
353.15
373.15
393.15
323.15
353.15
373.15
0.1154
0.3266
0.5766
0.9507
0.1428
0.3860
0.6726
1.080
0.02042
0.04752
0.09996
0.1062
0.3140
0.5861
n-heptane
n-hexane
n-hexane
n-hexane
n-hexane
n-nonane
n-nonane
n-nonane
n-nonane
n-octane
n-octane
n-octane
n-octane
393.15
323.15
353.15
373.15
393.15
323.15
353.15
373.15
393.15
323.15
353.15
373.15
393.15
1.093
0.3247
0.8192
1.399
2.218
0.01248
0.04973
0.1070
0.2111
0.03580
0.1245
0.2504
0.4554
_____________________________________________________________________________
copolymer (B):
S-BR/25w
95PET
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
cyclohexane
cyclohexane
cyclohexane
cyclohexane
n-decane
n-decane
n-decane
n-heptane
n-heptane
n-heptane
323.15
353.15
373.15
393.15
323.15
353.15
373.15
393.15
353.15
373.15
393.15
323.15
353.15
373.15
0.1248
0.3537
0.6222
1.048
0.1490
0.4046
0.6998
1.152
0.02067
0.04801
0.1009
0.1085
0.3266
0.6031
n-heptane
n-hexane
n-hexane
n-hexane
n-hexane
n-nonane
n-nonane
n-nonane
n-nonane
n-octane
n-octane
n-octane
n-octane
393.15
323.15
353.15
373.15
393.15
323.15
353.15
373.15
393.15
323.15
353.15
373.15
393.15
1.046
0.3333
0.8652
1.443
2.338
0.01247
0.05058
0.1086
0.2130
0.03630
0.1270
0.2524
0.4627
_____________________________________________________________________________
copolymer (B):
S-BR/30w
86IT1
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
benzene
benzene
1,3-butadiene
1,3-butadiene
1,3-butadiene
1,3-butadiene
n-butane
n-butane
n-butane
n-butane
cyclohexane
cyclohexane
cyclohexane
cyclohexane
n-decane
n-decane
n-decane
n-decane
2,2-dimethylbutane
2,2-dimethylbutane
2,2-dimethylbutane
423.15
448.15
473.15
473.15
498.15
498.15
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
423.15
448.15
473.15
2.07
3.26
4.87
4.98
7.38
7.14
17.7
24.3
29.6
41.2
19.1
26.1
33.0
43.4
2.32
3.69
5.44
7.84
0.311
0.619
1.12
1.98
5.91
8.81
12.0
2,2-dimethylbutane
ethylbenzene
ethylbenzene
ethylbenzene
ethylbenzene
n-hexane
n-hexane
n-hexane
n-hexane
mesitylene
mesitylene
mesitylene
mesitylene
2-methylpropane
2-methylpropane
2-methylpropane
2-methylpropane
n-octane
n-octane
n-octane
n-octane
toluene
toluene
toluene
toluene
498.15
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
16.7
0.525
0.940
1.57
2.57
4.44
6.64
9.75
13.5
0.241
0.473
0.842
1.49
24.5
31.9
39.5
54.7
1.14
2.00
3.23
5.22
0.981
1.66
2.64
4.16
_____________________________________________________________________________
copolymer (B):
S-BR/40w(1)
95PET
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
cyclohexane
cyclohexane
323.15
353.15
373.15
393.15
323.15
353.15
0.1248
0.3537
0.6222
1.048
0.1490
0.4046
n-heptane
n-hexane
n-hexane
n-hexane
n-hexane
n-nonane
393.15
323.15
353.15
373.15
393.15
323.15
1.046
0.3333
0.8652
1.443
2.338
0.01247
_____________________________________________________________________________
continue
continue
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
cyclohexane
cyclohexane
n-decane
n-decane
n-decane
n-heptane
n-heptane
n-heptane
373.15
393.15
353.15
373.15
393.15
323.15
353.15
373.15
0.6998
1.152
0.02067
0.04801
0.1009
0.1085
0.3266
0.6031
n-nonane
n-nonane
n-nonane
n-octane
n-octane
n-octane
n-octane
353.15
373.15
393.15
323.15
353.15
373.15
393.15
0.05058
0.1086
0.2130
0.03630
0.1270
0.2524
0.4627
_____________________________________________________________________________
copolymer (B):
S-BR/40w(2)
93ISS
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
n-heptane
n-heptane
n-heptane
n-heptane
n-hexane
n-hexane
n-hexane
n-hexane
333.15
353.15
373.15
393.15
333.15
353.15
373.15
393.15
333.15
353.15
373.15
393.15
0.1838
0.3518
0.6209
1.052
0.1947
0.3826
0.6910
1.192
0.5441
0.9938
1.660
2.698
n-nonane
n-nonane
n-nonane
n-nonane
n-octane
n-octane
n-octane
n-octane
toluene
toluene
toluene
toluene
333.15
353.15
373.15
393.15
333.15
353.15
373.15
393.15
333.15
353.15
373.15
393.15
0.02543
0.06000
0.1282
0.2562
0.06921
0.1485
0.2923
0.5413
0.06121
0.1269
0.2433
0.4344
_____________________________________________________________________________
copolymer (B):
S-BR/40w(2)
97SCH
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
cyclohexane
n-heptane
330.15
330.15
330.15
0.1838
0.2323
0.1947
n-hexane
toluene
330.15
330.15
0.5440
0.06121
_____________________________________________________________________________
copolymer (B):
S-BR/41w
97WO1
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
benzene
1,3-butadiene
1,3-butadiene
1,3-butadiene
cyclohexane
cyclohexane
cyclohexane
cyclohexane
cyclohexane
ethylbenzene
ethylbenzene
ethylbenzene
ethylbenzene
ethylbenzene
mesitylene
373.15
398.15
423.15
448.15
473.15
373.15
398.15
423.15
373.15
398.15
423.15
448.15
473.15
373.15
398.15
423.15
448.15
473.15
373.15
0.670
1.24
2.05
3.23
4.85
11.0
17.7
24.0
0.853
1.35
2.40
3.83
5.64
0.138
0.303
0.560
1.02
1.65
0.065
mesitylene
mesitylene
mesitylene
mesitylene
styrene
styrene
styrene
styrene
styrene
toluene
toluene
toluene
toluene
toluene
p-xylene
p-xylene
p-xylene
p-xylene
p-xylene
398.15
423.15
448.15
473.15
373.15
398.15
423.15
448.15
473.15
373.15
398.15
423.15
448.15
473.15
373.15
398.15
423.15
448.15
473.15
0.150
0.311
0.569
0.970
0.115
0.240
0.463
0.825
1.35
0.270
0.535
0.987
1.56
2.50
0.140
0.298
0.580
0.998
1.60
_____________________________________________________________________________
copolymer (B):
S-BR/45w
86IT1
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
1,3-butadiene
1,3-butadiene
1,3-butadiene
1,3-butadiene
n-butane
n-butane
n-butane
n-butane
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
2.03
3.41
5.07
7.55
19.6
27.3
38.0
50.0
21.0
29.3
39.8
53.9
ethylbenzene
ethylbenzene
ethylbenzene
ethylbenzene
n-hexane
n-hexane
n-hexane
n-hexane
mesitylene
mesitylene
mesitylene
mesitylene
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
0.512
0.980
1.63
2.64
4.68
7.13
10.6
15.3
0.237
0.496
0.878
1.51
_____________________________________________________________________________
continue
continue
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
cyclohexane
cyclohexane
cyclohexane
cyclohexane
n-decane
n-decane
n-decane
n-decane
2,2-dimethylbutane
2,2-dimethylbutane
2,2-dimethylbutane
2,2-dimethylbutane
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
2.38
3.88
5.76
8.25
0.319
0.675
1.20
2.07
6.68
9.73
14.2
19.6
2-methylpropane
2-methylpropane
2-methylpropane
2-methylpropane
n-octane
n-octane
n-octane
n-octane
toluene
toluene
toluene
toluene
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
26.6
36.0
45.2
57.2
1.18
2.18
3.43
5.45
0.964
1.74
2.74
4.26
________________________________________________________________________________________________________________________________________________________________________
copolymer (B):
S-BR/77w
86IT1
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
benzene
benzene
benzene
benzene
1,3-butadiene
1,3-butadiene
1,3-butadiene
1,3-butadiene
n-butane
n-butane
n-butane
n-butane
cyclohexane
cyclohexane
cyclohexane
cyclohexane
n-decane
n-decane
n-decane
n-decane
2,2-dimethylbutane
2,2-dimethylbutane
2,2-dimethylbutane
2,2-dimethylbutane
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
2.38
3.80
5.77
8.22
22.8
31.8
41.0
53.5
27.0
36.0
46.8
59.9
3.10
4.78
7.08
9.74
0.469
0.899
1.63
2.68
8.28
12.4
16.6
22.1
ethylbenzene
ethylbenzene
ethylbenzene
ethylbenzene
n-hexane
n-hexane
n-hexane
n-hexane
mesitylene
mesitylene
mesitylene
mesitylene
2-methylpropane
2-methylpropane
2-methylpropane
2-methylpropane
n-octane
n-octane
n-octane
n-octane
toluene
toluene
toluene
toluene
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
423.15
448.15
473.15
498.15
0.619
1.12
1.88
2.96
5.84
8.85
13.2
18.0
0.296
0.578
1.05
1.76
29.8
40.4
55.1
69.9
1.67
2.84
4.58
6.81
1.14
1.96
3.15
4.69
________________________________________________________________________________________________________________________________________________________________________
copolymer (B):
S-B-S/17w
92ROM
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
2-butanone
2-butanone
2-butanone
cyclohexane
cyclohexane
cyclohexane
ethylbenzene
ethylbenzene
ethylbenzene
n-heptane
n-heptane
308.15
328.15
348.15
308.15
328.15
348.15
308.15
328.15
348.15
308.15
328.15
348.15
308.15
328.15
0.07361
0.1499
0.2823
0.1731
0.3592
0.6673
0.09241
0.1799
0.3255
0.00796
0.01963
0.04270
0.06244
0.1349
n-heptane
n-hexane
n-hexane
n-hexane
toluene
toluene
toluene
trichloromethane
trichloromethane
trichloromethane
p-xylene
p-xylene
p-xylene
348.15
308.15
328.15
348.15
308.15
328.15
348.15
308.15
328.15
348.15
308.15
328.15
348.15
0.2593
0.2012
0.3881
0.6846
0.02207
0.04990
0.1014
0.07124
0.1452
0.2694
0.00784
0.01940
0.04245
_____________________________________________________________________________
copolymer (B):
S-B-S/31w
92ROM
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
2-butanone
2-butanone
2-butanone
cyclohexane
cyclohexane
cyclohexane
ethylbenzene
ethylbenzene
ethylbenzene
n-heptane
n-heptane
308.15
328.15
348.15
308.15
328.15
348.15
308.15
328.15
348.15
308.15
328.15
348.15
308.15
328.15
0.07733
0.1589
0.3038
0.1740
0.3754
0.7142
0.1079
0.2108
0.3732
0.00851
0.02157
0.04671
0.07359
0.1574
n-heptane
n-hexane
n-hexane
n-hexane
toluene
toluene
toluene
trichloromethane
trichloromethane
trichloromethane
p-xylene
p-xylene
p-xylene
348.15
308.15
328.15
348.15
308.15
328.15
348.15
308.15
328.15
348.15
308.15
328.15
348.15
0.3059
0.2292
0.4552
0.7962
0.02354
0.05347
0.1081
0.06818
0.1522
0.2822
0.00844
0.02127
0.04591
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from dimethyl siloxane and bisphenol-A carbonate
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Dimethylsiloxane/bisphenol-A carbonate random copolymer
49.0 wt% dimethylsiloxane
DMS-BAC/49w
81WAR
Dimethylsiloxane/bisphenol-A carbonate alternating

block copolymer
81WAR
81WAR
81WAR
81WAR
81WAR
DMS-BAC/32w
DMS-BAC/41w
DMS-BAC/42w
DMS-BAC/57w
DMS-BAC/70w
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
Mn/
g/mol
_____________________________________________________________________________
Copolymer (B)
DMS-BAC/32w
DMS-BAC/41w
DMS-BAC/42w
DMS-BAC/49w
DMS-BAC/57w
DMS-BAC/70w
50000-100000
50000-100000
50000-100000
50000-100000
50000-100000
50000-100000
(Mn - PDMS-blocks = 10000, Mn - BAC-blocks = 19000)

(statist. react. with PDMS-2000-oligomers)
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B):
DMS-BAC/32w
81WAR
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
chlorobenzene
chlorobenzene
n-decane
n-decane
433.15
453.15
433.15
453.15
0.7975
1.223
0.7824
1.228
o-dichlorobenzene
o-dichlorobenzene
toluene
433.15
453.15
433.15
0.2116
0.3395
1.813
_____________________________________________________________________________
copolymer (B):
DMS-BAC/41w
81WAR
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
chlorobenzene
chlorobenzene
o-dichlorobenzene
433.15
453.15
433.15
0.7975
1.187
0.2088
o-dichlorobenzene
toluene
453.15
433.15
0.3456
1.724
_____________________________________________________________________________
copolymer (B):
DMS-BAC/42w
81WAR
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
chlorobenzene
chlorobenzene
chlorobenzene
n-decane
n-decane
433.15
453.15
468.15
433.15
453.15
0.8269
1.230
1.654
0.6542
1.308
n-decane
o-dichlorobenzene
o-dichlorobenzene
o-dichlorobenzene
toluene
468.15
433.15
453.15
468.15
433.15
1.438
0.2164
0.3568
0.5082
1.786
_____________________________________________________________________________
copolymer (B):
DMS-BAC/57w
81WAR
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
chlorobenzene
chlorobenzene
chlorobenzene
o-dichlorobenzene
433.15
453.15
468.15
433.15
0.7760
1.173
1.529
0.2232
o-dichlorobenzene
o-dichlorobenzene
toluene
453.15
468.15
433.15
0.3652
0.4710
1.611
_____________________________________________________________________________
copolymer (B):
DMS-BAC/49w
81WAR
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
chlorobenzene
chlorobenzene
433.15
453.15
0.8006
1.245
n-decane
n-decane
433.15
453.15
0.5934
0.9558
_____________________________________________________________________________
copolymer (B):
DMS-BAC/70w
81WAR
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
chlorobenzene
chlorobenzene
n-decane
n-decane
433.15
453.15
433.15
453.15
0.7701
1.160
0.4256
0.6596
o-dichlorobenzene
o-dichlorobenzene
toluene
433.15
453.15
433.15
0.2149
0.3593
1.541
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from ethylene and carbon monoxide
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Ethylene/carbon monoxide copolymer
10.5 wt% carbon monoxide
E-CO/11w
78DIP
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
Mn/
M w/
M /
Further information
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
E-CO/11w
no data
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B):
E-CO/11w
78DIP
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
n-octane
n-octane
n-octane
n-octane
n-octane
n-octane
n-octane
n-octane
381.23
383.21
385.20
387.20
389.21
391.22
393.23
395.24
0.3391
0.3589
0.3811
0.4028
0.4236
0.4508
0.4767
0.4961
n-octane
n-octane
n-octane
n-octane
n-octane
n-octane
n-octane
n-octane
397.23
399.24
401.24
403.23
405.23
407.23
409.23
411.23
0.5281
0.5518
0.5914
0.6135
0.6538
0.6717
0.7204
0.7422
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from ethylene and propylene
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Ethylene/propylene copolymer
unspecified contents of propylene
unspecified contents of propylene
E-P/?
E-P/?
86PRI
87PRI
Ethylene/propylene/diene terpolymer
50 mol% propylene
50 mol% propylene
E-P-D/50x
E-P-D/50x
93ISS
97SCH
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
E-P/?
E-P-D/50x
24500
90000
200000
low molecular weight EPR from Aldrich

Buna AP341, Buna-Werke Huels/Marl
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B):
E-P/?
86PRI, 87PRI
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
cyclohexane
dichloromethane
n-heptane
n-hexane
298.15
298.15
298.15
298.15
298.15
0.06423
0.05695
0.1833
0.03579
0.1212
n-octane
n-pentane
tetrachloromethane
toluene
trichloromethane
298.15
298.15
298.15
298.15
298.15
0.01007
0.4342
0.03278
0.01806
0.06564
_____________________________________________________________________________
copolymer (B):
E-P-D/50x
86PRI, 87PRI
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
n-heptane
n-heptane
n-heptane
n-heptane
n-hexane
n-hexane
n-hexane
n-hexane
333.15
353.15
373.15
393.15
333.15
353.15
373.15
393.15
333.15
353.15
373.15
393.15
0.2204
0.4018
0.6913
1.111
0.1179
0.2409
0.4517
0.7611
0.3467
0.6417
1.082
1.723
n-nonane
n-nonane
n-nonane
n-nonane
n-octane
n-octane
n-octane
n-octane
toluene
toluene
toluene
toluene
333.15
353.15
373.15
393.15
333.15
353.15
373.15
393.15
333.15
353.15
373.15
393.15
0.01394
0.03662
0.08031
0.1592
0.04125
0.09344
0.1895
0.3479
0.06840
0.1425
0.2675
0.4577
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from ethylene and vinyl acetate
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Ethylene/vinyl acetate copolymer
E-VA/04w
E-VA/09w
E-VA/15w
E-VA/29w
E-VA/30w
E-VA/40w
E-VA/40w
E-VA/45w
E-VA/49w
76LIU
76LIU
99GUO
78DIN
76LIU
82LI1
82LI2
83WAL
99GUO
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
M z/
Further information
Mn/
g/mol g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
E-VA/04w
36600
147900
392700
E-VA/09w
36600
415500
2793000
E-VA/15w
E-VA/29w
43200
E-VA/30w
42300
325800
E-VA/40w
E-VA/45w
E-VA/49w
37700
81500
194500
220000
Union Carbide, DXM-228,

MI = 0.91
MI = 2.9
11000
2238000
Union Carbide, DX-31034,

MI = 15.0
MI = 14.0
Aldrich Chem. Co.
Levapren 45N, Bayer AG, Ger.
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B):
E-VA/04w
76LIU
Comments: Henrys constants were corrected for solubility of the marker gas
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
2-butanone
2-butanone
2-butanone
2-butanone
2-butanone
carbon dioxide
carbon dioxide
carbon dioxide
carbon dioxide
carbon dioxide
ethane
ethane
ethane
ethane
ethane
ethene
ethene
ethene
ethene
ethene
methyl chloride
methyl chloride
methyl chloride
398.15
423.15
448.15
473.15
498.15
398.15
423.15
448.15
473.15
498.15
398.15
423.15
448.15
473.15
498.15
398.15
423.15
448.15
473.15
498.15
398.15
423.15
448.15
3.192
4.864
6.991
9.828
12.56
126.6
139.8
150.0
160.0
169.0
102.0
121.6
137.8
156.0
172.0
142.0
154.0
172.0
189.5
202.0
20.26
25.9
31.6
methyl chloride
methyl chloride
2-propanol
2-propanol
2-propanol
2-propanol
2-propanol
2-propanone
2-propanone
2-propanone
2-propanone
2-propanone
sulfur dioxide
sulfur dioxide
sulfur dioxide
sulfur dioxide
sulfur dioxide
vinyl acetate
vinyl acetate
vinyl acetate
vinyl acetate
vinyl acetate
473.15
498.15
398.15
423.15
448.15
473.15
498.15
398.15
423.15
448.15
473.15
498.15
398.15
423.15
448.15
473.15
498.15
398.15
423.15
448.15
473.15
498.15
37.1
44.6
7.60
10.44
13.68
17.73
22.60
8.511
11.96
15.50
20.26
25.84
22.49
28.0
33.4
40.9
48.4
3.242
4.914
7.042
9.524
12.46
_____________________________________________________________________________
copolymer (B):
E-VA/09w
76LIU
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
2-butanone
2-butanone
2-butanone
398.15
423.15
448.15
2.786
4.408
6.637
methyl chloride
methyl chloride
2-propanol
473.15
498.15
398.15
36.48
42.96
5.978
_____________________________________________________________________________
continue
continue
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
2-butanone
2-butanone
carbon dioxide
carbon dioxide
carbon dioxide
carbon dioxide
carbon dioxide
ethane
ethane
ethane
ethane
ethane
ethene
ethene
ethene
ethene
ethene
methyl chloride
methyl chloride
methyl chloride
473.15
498.15
398.15
423.15
448.15
473.15
498.15
398.15
423.15
448.15
473.15
498.15
398.15
423.15
448.15
473.15
498.15
398.15
423.15
448.15
8.714
11.35
114.5
130.7
145.9
158.0
172.0
108.4
122.6
138.8
150.0
172.0
134.8
154.0
174.0
195.5
210.0
19.25
24.32
30.40
2-propanol
2-propanol
2-propanol
2-propanol
2-propanone
2-propanone
2-propanone
2-propanone
2-propanone
sulfur dioxide
sulfur dioxide
sulfur dioxide
sulfur dioxide
sulfur dioxide
vinyl acetate
vinyl acetate
vinyl acetate
vinyl acetate
vinyl acetate
423.15
448.15
473.15
498.15
398.15
423.15
448.15
473.15
498.15
398.15
423.15
448.15
473.15
498.15
398.15
423.15
448.15
473.15
498.15
8.815
12.56
17.22
22.29
7.397
10.54
14.18
18.44
23.91
18.44
24.42
30.70
36.07
42.66
2.837
4.458
6.485
8.714
12.16
_____________________________________________________________________________
copolymer (B):
E-VA/15w
99GUO
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
cyclohexane
1,4-dioxane
ethyl acetate
393.15
393.15
393.15
393.15
0.8667
0.9070
0.7078
1.759
n-octane
tetrachloromethane
tetrahydrofuran
toluene
393.15
393.15
393.15
393.15
0.3434
0.4701
1.384
0.3710
_____________________________________________________________________________
copolymer (B):
E-VA/29w
78DIN
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
acetaldehyde
acetaldehyde
acetic acid
acetic acid
acetonitrile
acetonitrile
acrylonitrile
acrylonitrile
benzene
benzene
1-bromobutane
1-bromobutane
2-bromobutane
2-bromobutane
1-butanol
1-butanol
2-butanol
2-butanol
2-butanone
2-butanone
chlorobenzene
chlorobenzene
cyclohexane
cyclohexane
1,2-dichloroethane
1,2-dichloroethane
dichloromethane
dichloromethane
diethyl ether
diethyl ether
1,4-dioxane
1,4-dioxane
dipropyl ether
dipropyl ether
ethanol
ethanol
ethyl acetate
ethyl acetate
formic acid
formic acid
furan
furan
n-heptane
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
18.48
12.61
2.157
2.543
9.298
11.18
6.285
7.698
1.859
2.286
0.788
1.008
1.006
1.255
1.960
2.493
2.995
3.584
3.688
4.412
0.3937
0.5156
2.052
2.489
1.372
1.808
3.633
4.210
7.076
8.881
1.399
1.732
2.010
2.526
11.38
13.14
3.326
4.192
2.911
3.562
6.404
7.414
1.892
n-heptane
n-hexane
n-hexane
methanol
methanol
methylcyclohexane
methylcyclohexane
nitroethane
nitroethane
nitromethane
nitromethane
1-nitropropane
1-nitropropane
2-nitropropane
2-nitropropane
n-octane
n-octane
1-octene
1-octene
n-pentane
n-pentane
3-pentanone
3-pentanone
2-propanol
2-propanol
2-propanone
2-propanone
propionitrile
propionitrile
propyl acetate
propyl acetate
tetrachloromethane
tetrachloromethane
tetrahydrofuran
tetrahydrofuran
trichloromethane
trichloromethane
2,2,2-trifluoroethanol
2,2,2-trifluoroethanol
water
water
m-xylene
m-xylene
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
423.61
433.68
2.327
3.9045
4.600
24.03
26.45
1.271
1.554
1.943
2.424
3.695
4.543
1.376
1.712
1.387
1.756
0.9287
1.198
0.9643
1.230
8.197
9.177
1.765
2.238
7.411
8.325
8.670
10.29
4.581
5.579
1.666
2.094
1.045
1.274
2.963
3.629
1.434
1.748
3.598
4.514
37.00
53.01
0.4208
0.5640
_____________________________________________________________________________
copolymer (B):
E-VA/30w
76LIU
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
2-butanone
2-butanone
2-butanone
2-butanone
2-butanone
carbon dioxide
carbon dioxide
carbon dioxide
carbon dioxide
carbon dioxide
ethane
ethane
ethane
ethane
ethane
ethene
ethene
ethene
ethene
ethene
methyl chloride
methyl chloride
methyl chloride
398.15
423.15
448.15
473.15
498.15
398.15
423.15
448.15
473.15
498.15
398.15
423.15
448.15
473.15
498.15
398.15
423.15
448.15
473.15
498.15
398.15
423.15
448.15
2.148
3.445
5.218
7.40
10.23
101.3
120.5
138.8
157.0
176.0
109.0
130.0
150.0
177.0
203.0
133.7
152.0
178.0
203.0
226.0
15.30
21.28
27.36
methyl chloride
methyl chloride
2-propanol
2-propanol
2-propanol
2-propanol
2-propanol
2-propanone
2-propanone
2-propanone
2-propanone
2-propanone
sulfur dioxide
sulfur dioxide
sulfur dioxide
sulfur dioxide
sulfur dioxide
vinyl acetate
vinyl acetate
vinyl acetate
vinyl acetate
vinyl acetate
473.15
498.15
398.15
423.15
448.15
473.15
498.15
398.15
423.15
448.15
473.15
498.15
398.15
423.15
448.15
473.15
498.15
398.15
423.15
448.15
473.15
498.15
35.06
43.87
4.053
6.434
9.727
13.78
18.64
5.168
8.005
11.45
16.01
19.66
11.35
16.72
22.80
33.44
39.31
2.280
3.597
5.370
7.40
10.44
_____________________________________________________________________________
copolymer (B):
E-VA/40w
82LI1
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
1-butanol
chlorobenzene
1-chlorobutane
n-decane
n-hexane
348.15
348.15
348.15
348.15
348.15
348.15
0.2830
0.1335
0.03648
0.3290
0.02067
0.8660
n-octane
1-octene
n-pentane
2-pentanone
toluene
trichloromethane
348.15
348.15
348.15
348.15
348.15
348.15
0.1263
0.1255
2.533
0.1987
0.1042
0.1806
_____________________________________________________________________________
copolymer (B):
E-VA/40w
82LI1
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
1-butanol
1-butanol
1-butanol
chlorobenzene
chlorobenzene
chlorobenzene
1-chlorobutane
1-chlorobutane
1-chlorobutane
n-decane
n-decane
n-decane
n-hexane
n-hexane
n-hexane
338.15
348.15
358.15
338.15
348.15
358.15
338.15
348.15
358.15
338.15
348.15
358.15
338.15
348.15
358.15
338.15
348.15
358.15
0.2006
0.2827
0.3830
0.0851
0.1337
0.2037
0.02371
0.0365
0.0532
0.2320
0.3293
0.4367
0.01277
0.02067
0.0317
0.6424
0.8663
1.297
n-octane
n-octane
n-octane
1-octene
1-octene
1-octene
n-pentane
n-pentane
n-pentane
2-pentanone
2-pentanone
2-pentanone
toluene
toluene
toluene
trichloromethane
trichloromethane
trichloromethane
338.15
348.15
358.15
338.15
348.15
358.15
338.15
348.15
358.15
338.15
348.15
358.15
338.15
348.15
358.15
338.15
348.15
358.15
0.0859
0.1267
0.1793
0.0843
0.1256
0.1773
1.996
0.2503
2.888
0.1388
0.1986
0.2807
0.0697
0.1044
0.1459
0.1236
0.1803
0.2472
_____________________________________________________________________________
copolymer (B):
E-VA/45w
83WAL
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
2-butanone
2-butanone
dichloromethane
dichloromethane
diethyl ether
diethyl ether
ethyl acetate
ethyl acetate
methanol
343.15
373.15
343.15
373.15
343.15
373.15
343.15
373.15
343.15
0.7612
2.647
0.8012
2.785
2.980
8.418
0.6898
2.322
7.081
methanol
n-pentane
n-pentane
2-propanone
2-propanone
tetrahydrofuran
tetrahydrofuran
trichloromethane
trichloromethane
373.15
343.15
373.15
343.15
373.15
343.15
373.15
343.15
373.15
18.36
3.9346
10.49
2.444
4.888
0.7283
2.421
0.2615
0.8889
_____________________________________________________________________________
copolymer (B):
E-VA/49w
99GUO
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
cyclohexane
1,4-dioxane
ethyl acetate
393.15
393.15
393.15
393.15
0.8176
1.231
0.5046
1.253
n-octane
tetrachloromethane
tetrahydrofuran
toluene
393.15
393.15
393.15
393.15
0.5209
0.5045
1.160
0.3619
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from ethyl methacrylate and methacrylic acid
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Ethyl methacrylate/methacrylic acid copolymer
36.6 mol% methacrylic acid
EMA-MA/37x
92CHE
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
EMA-MA/37x
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B):
EMA-MA/37x
92CHE
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
benzene
413.15
423.15
433.15
443.15
453.15
4.838
6.045
7.966
9.757
11.68
n-decane
n-decane
n-decane
n-decane
n-decane
413.15
423.15
433.15
443.15
453.15
1.497
1.689
2.245
2.705
3.653
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from isobutyl methacrylate and acrylic acid
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Isobutyl methacrylate/acrylic acid copolymer
10.5 mol% acrylic acid
IBMA-AA/11x
IBMA-AA/22x
96DJA
96DJA
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
IBMA-AA/11x
IBMA-AA/22x

_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B):
IBMA-AA/11x
96DJA
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
423.15
433.15
443.15
453.15
3.917
4.705
5.752
7.537
n-decane
n-decane
n-decane
n-decane
423.15
433.15
443.15
453.15
0.6869
0.9445
1.210
1.558
_____________________________________________________________________________
copolymer (B):
IBMA-AA/22x
96DJA
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
423.15
433.15
443.15
453.15
4.290
5.239
6.937
8.613
n-decane
n-decane
n-decane
n-decane
423.15
433.15
443.15
453.15
0.8616
1.105
1.455
2.006
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from styrene and acrylic acid
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Styrene/acrylic acid copolymer
S-AA/20x
91CHE
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
S-AA/20x
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B):
S-AA/20x
91CHE
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
423.15
433.15
443.15
453.15
4.095
4.743
5.850
7.287
n-decane
n-decane
n-decane
n-decane
423.15
433.15
443.15
453.15
1.125
1.355
1.900
2.258
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from styrene and butyl methacrylate
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Styrene/butyl methacrylate copolymer
58.0 wt% styrene
S-BMA/58w
81DIP
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
S-BMA/58w
32500
72500
Xerox Corp., Can.
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B):
S-BMA/58w
81DIP
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
1-chlorobutane
cyclohexane
n-decane
dichloromethane
tert-butyl-benzene
413.15
413.15
413.15
413.15
413.15
413.15
1.900
2.282
2.802
0.3873
3.481
0.1987
n-octane
tetrachloromethane
trichloromethane
2,2,4-trimethylpentane
3,4,5-trimethylheptane
413.15
413.15
413.15
413.15
413.15
1.442
1.202
1.411
2.727
0.5778
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from styrene and isobutyl methacrylate
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Styrene/isobutyl methacrylate copolymer
80.0 wt% styrene
S-IBMA/80w
81DIP
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
S-IBMA/80w
70000
Xerox Corp., Can.
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B):
S-IBMA/80w
81DIP
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
cyclohexane
n-decane
1-chlorobutane
dichloromethane
tert-butyl-benzene
413.15
413.15
413.15
413.15
413.15
413.15
2.030
3.116
0.4494
2.553
3.869
0.2257
n-octane
tetrachloromethane
trichloromethane
2,2,4-trimethylpentane
3,4,5-trimethylheptane
413.15
413.15
413.15
413.15
413.15
1.669
1.318
1.677
3.458
0.6947
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from styrene and N,N-dimethyl aminoethyl methacrylate
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Styrene/N,N-dimethyl aminoethyl methacrylate
copolymer
6.0 mol% methacrylate
12.0 mol% methacrylate
S-DMAM/06x
S-DMAM/12x
96DJA
96DJA
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
S-DMAM/06x
S-DMAM/12x

_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B):
S-DMAM/06x
96DJA
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
423.15
433.15
443.15
453.15
8.189
9.040
10.25
12.37
n-decane
n-decane
n-decane
n-decane
423.15
433.15
443.15
453.15
2.150
2.693
3.320
4.138
_____________________________________________________________________________
copolymer (B):
S-DMAM/12x
96DJA
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
423.15
433.15
443.15
453.15
4.022
5.239
6.551
8.316
n-decane
n-decane
n-decane
n-decane
423.15
433.15
443.15
453.15
1.089
1.376
1.811
2.283
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from styrene and 2-(3-methyl-3-phenylcyclobutyl)-2-hydroxyethyl
methacrylate
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Styrene/2-(3-methyl-3-phenylcyclobutyl)-2-hydroxyethyl
methacrylate copolymer
40.0 mol% styrene
S-MPCHEMA/40x
2000KAY
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
B = 1.045 g/cm3,
S-MPCHEMA/40x
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B):
S-MPCHEMA/40x
2000KAY
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
423.15
433.15
443.15
453.15
4.600
4.106
4.536
5.210
methyl acetate
methyl acetate
methyl acetate
methyl acetate
423.15
433.15
443.15
453.15
8.734
8.734
9.491
9.889
_____________________________________________________________________________
continue
continue
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
2-butanone
2-butanone
2-butanone
2-butanone
n-decane
n-decane
n-decane
n-decane
n-dodecane
n-dodecane
n-dodecane
n-dodecane
ethanol
ethanol
ethanol
ethanol
ethyl acetate
ethyl acetate
ethyl acetate
ethyl acetate
methanol
methanol
methanol
methanol
423.15
433.15
443.15
453.15
423.15
433.15
443.15
453.15
423.15
433.15
443.15
453.15
423.15
433.15
443.15
453.15
423.15
433.15
443.15
453.15
423.15
433.15
443.15
453.15
6.389
6.773
7.758
7.994
0.8922
1.015
1.188
1.342
0.4777
0.5196
0.6539
0.7974
10.27
12.17
13.32
13.40
5.872
5.715
6.559
6.509
12.89
15.61
19.31
20.91
n-nonane
n-nonane
n-nonane
n-nonane
n-octane
n-octane
n-octane
n-octane
2-propanone
2-propanone
2-propanone
2-propanone
toluene
toluene
toluene
toluene
n-undecane
n-undecane
n-undecane
n-undecane
o-xylene
o-xylene
o-xylene
o-xylene
423.15
433.15
443.15
453.15
423.15
433.15
443.15
453.15
423.15
433.15
443.15
453.15
423.15
433.15
443.15
453.15
423.15
433.15
443.15
453.15
423.15
433.15
443.15
453.15
1.375
1.489
1.712
1.906
2.436
2.808
3.078
3.319
8.670
9.655
10.80
12.61
2.676
2.896
3.506
3.349
0.5249
0.5877
0.7918
1.044
0.9177
1.131
1.364
1.618
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from styrene and nonyl methacrylate
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Styrene/nonyl methacrylate copolymer
80 mol% styrene
S-NMA/80x
95BOG
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
S-NMA/80x
29000
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B):
S-NMA/80x
95BOG
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
1-butanol
dibutyl ether
1,4-dioxane
526.6
526.6
526.6
20.43
10.90
13.57
n-heptane
n-octane
526.6
526.6
7.083
4.418
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from tetrafluoroethylene and
2,2-bis(trifluoromethyl)-4,5-difluoro-1,3-dioxole
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Tetrafluoroethylene/2,2-bis(trifluoromethyl)4,5-difluoro-1,3-dioxole copolymer
13 mol% tetrafluoroethylene
TFE-PFD/13x
99BON
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
TFE-PFD/13x
AF2400, DuPont, Wilmington
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B):
TFE-PFD/13x
99BON
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
n-hexane
n-hexane
373.15
423.15
373.15
423.15
0.5591
1.211
0.7530
2.635
n-heptane
n-heptane
n-pentane
373.15
423.15
423.15
0.3192
0.9066
5.246
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from vinyl acetate and vinyl alcohol
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Vinyl acetate/vinyl alcohol copolymer
VA-VAL/43x
VA-VAL/61x
VA-VAL/74x
VA-VAL/95x
86CAS
86CAS
86CAS
86CAS
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
VA-VAL/43x
VA-VAL/61x
VA-VAL/74x
VA-VAL/95x

_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B):
VA-VAL/43x
86CAS
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
benzene
benzene
benzene
benzene
benzene
1-butanol
1-butanol
1-butanol
1-butanol
1-butanol
2-butanol
2-butanol
2-butanol
2-butanol
2-butanol
cyclohexanol
cyclohexanol
cyclohexanol
cyclohexanol
cyclohexanol
n-decane
n-decane
n-decane
n-decane
n-decane
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
4.263
4.953
5.646
6.548
7.552
1.019
1.290
1.651
2.039
2.560
1.926
2.309
2.972
3.575
4.365
0.1780
0.2347
0.3115
0.3926
0.5059
3.136
3.782
4.613
5.393
6.489
1-hexanol
1-hexanol
tert-butanol
tert-butanol
tert-butanol
tert-butanol
tert-butanol
n-nonane
n-nonane
n-nonane
n-nonane
n-nonane
1-octanol
1-octanol
1-octanol
1-octanol
1-octanol
1-pentanol
1-pentanol
1-pentanol
1-pentanol
1-pentanol
2-pentanol
2-pentanol
2-pentanol
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
0.6594
0.8636
1.463
1.804
2.255
2.750
3.374
5.731
6.534
7.767
8.898
10.67
0.1033
0.1335
0.1793
0.2359
0.3135
0.5446
0.6965
0.9049
1.134
1.444
1.069
1.312
1.715
_____________________________________________________________________________
continue
continue
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
1-decanol
1-decanol
1-decanol
1-decanol
1-decanol
n-dodecane
n-dodecane
n-dodecane
n-dodecane
n-dodecane
ethylbenzene
ethylbenzene
ethylbenzene
ethylbenzene
ethylbenzene
1-heptanol
1-heptanol
1-heptanol
1-heptanol
1-heptanol
n-hexadecane
n-hexadecane
n-hexadecane
n-hexadecane
n-hexadecane
1-hexanol
1-hexanol
1-hexanol
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
0.03609
0.04897
0.06846
0.08973
0.1262
0.9768
1.239
1.597
1.975
2.502
1.370
1.646
2.003
2.377
2.849
0.1767
0.2337
0.3127
0.4008
0.5250
0.1361
0.1840
0.2588
0.3406
0.4580
0.2946
0.3850
0.5211
2-pentanol
2-pentanol
1-propanol
1-propanol
1-propanol
1-propanol
1-propanol
2-propanol
2-propanol
2-propanol
2-propanol
2-propanol
n-tetradecane
n-tetradecane
n-tetradecane
n-tetradecane
n-tetradecane
toluene
toluene
toluene
toluene
toluene
n-undecane
n-undecane
n-undecane
n-undecane
n-undecane
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
2.108
2.640
2.073
2.520
3.179
3.825
4.672
3.630
4.339
5.446
6.472
7.793
0.3877
0.5024
0.6538
0.8248
1.078
2.293
2.691
3.231
3.781
4.410
1.755
2.195
2.784
3.340
4.093
_____________________________________________________________________________
copolymer (B):
VA-VAL/61x
86CAS
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
393.15
400.15
408.15
3.153
3.516
4.165
1-hexanol
1-hexanol
tert-butanol
415.15
423.15
393.15
0.5736
0.7324
1.314
_____________________________________________________________________________
continue
continue
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
1-butanol
1-butanol
1-butanol
1-butanol
1-butanol
2-butanol
2-butanol
2-butanol
2-butanol
2-butanol
cyclohexanol
cyclohexanol
cyclohexanol
cyclohexanol
cyclohexanol
n-decane
n-decane
n-decane
n-decane
n-decane
1-decanol
1-decanol
1-decanol
1-decanol
1-decanol
n-dodecane
n-dodecane
n-dodecane
n-dodecane
n-dodecane
ethylbenzene
ethylbenzene
ethylbenzene
ethylbenzene
ethylbenzene
1-heptanol
1-heptanol
1-heptanol
1-heptanol
1-heptanol
n-hexadecane
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
4.774
5.549
0.9730
1.203
1.517
1.839
2.258
1.720
2.103
2.603
3.123
3.806
0.1748
0.2230
0.2921
0.3662
0.4697
2.111
2.486
3.000
3.508
4.178
0.03048
0.04152
0.05856
0.07819
0.1067
0.7032
0.8680
1.100
1.331
1.669
0.9689
1.160
1.409
1.667
1.997
0.1546
0.1999
0.2663
0.3389
0.4385
0.08317
tert-butanol
tert-butanol
tert-butanol
tert-butanol
n-nonane
n-nonane
n-nonane
n-nonane
n-nonane
1-octanol
1-octanol
1-octanol
1-octanol
1-octanol
1-pentanol
1-pentanol
1-pentanol
1-pentanol
1-pentanol
2-pentanol
2-pentanol
2-pentanol
2-pentanol
2-pentanol
1-propanol
1-propanol
1-propanol
1-propanol
1-propanol
2-propanol
2-propanol
2-propanol
2-propanol
2-propanol
n-tetradecane
n-tetradecane
n-tetradecane
n-tetradecane
n-tetradecane
toluene
toluene
toluene
toluene
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
1.607
2.009
2.432
2.978
3.768
4.319
5.045
5.864
6.864
0.0891
0.1182
0.1609
0.2078
0.2739
0.5055
0.6332
0.8150
1.002
1.257
0.9507
1.177
1.478
1.798
2.213
1.946
2.381
2.943
3.549
4.374
3.433
4.008
4.915
5.814
6.897
0.2482
0.3131
0.4135
0.5171
0.6618
1.632
1.926
2.310
2.679
_____________________________________________________________________________
continue
continue
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
n-hexadecane
n-hexadecane
n-hexadecane
n-hexadecane
1-hexanol
1-hexanol
1-hexanol
400.15
408.15
415.15
423.15
393.15
400.15
408.15
0.1096
0.1535
0.1999
0.2669
0.2767
0.3401
0.4588
toluene
n-undecane
n-undecane
n-undecane
n-undecane
n-undecane
423.15
393.15
400.15
408.15
415.15
423.15
3.164
1.231
1.483
1.821
2.178
2.661
_____________________________________________________________________________
copolymer (B):
VA-VAL/74x
86CAS
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
benzene
benzene
1-butanol
1-butanol
1-butanol
1-butanol
1-butanol
2-butanol
2-butanol
2-butanol
2-butanol
2-butanol
cyclohexanol
cyclohexanol
cyclohexanol
cyclohexanol
cyclohexanol
n-decane
n-decane
n-decane
n-decane
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
2.159
2.578
2.982
3.449
4.142
0.8476
1.032
1.297
1.568
1.926
1.468
1.771
2.185
2.599
3.146
0.1526
0.1935
0.2518
0.3142
0.3994
1.294
1.579
1.896
2.229
1-hexanol
1-hexanol
tert-butanol
tert-butanol
tert-butanol
tert-butanol
tert-butanol
1-octanol
1-octanol
1-octanol
1-octanol
1-octanol
n-nonane
n-nonane
n-nonane
n-nonane
n-nonane
1-pentanol
1-pentanol
1-pentanol
1-pentanol
1-pentanol
2-pentanol
2-pentanol
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
0.4725
0.6012
1.117
1.355
1.683
2.013
2.457
0.0705
0.0927
0.1248
0.1538
0.2019
2.374
2.784
3.291
3.752
4.427
0.4277
0.5330
0.6834
0.8400
1.052
0.7840
0.9653
_____________________________________________________________________________
continue
continue
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
n-decane
1-decanol
1-decanol
1-decanol
1-decanol
1-decanol
n-dodecane
n-dodecane
n-dodecane
n-dodecane
n-dodecane
ethylbenzene
ethylbenzene
ethylbenzene
ethylbenzene
ethylbenzene
1-heptanol
1-heptanol
1-heptanol
1-heptanol
1-heptanol
n-hexadecane
n-hexadecane
n-hexadecane
n-hexadecane
n-hexadecane
1-hexanol
1-hexanol
1-hexanol
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
2.683
0.02294
0.03104
0.04320
0.05603
0.07616
0.4346
0.5340
0.6754
0.8251
1.020
0.6586
0.7947
0.9759
1.161
1.401
0.1254
0.1621
0.2154
0.2730
0.3546
0.04975
0.06664
0.09052
0.1171
0.1546
0.2295
0.2907
0.3788
2-pentanol
2-pentanol
2-pentanol
1-propanol
1-propanol
1-propanol
1-propanol
1-propanol
2-propanol
2-propanol
2-propanol
2-propanol
2-propanol
n-tetradecane
n-tetradecane
n-tetradecane
n-tetradecane
n-tetradecane
toluene
toluene
toluene
toluene
toluene
n-undecane
n-undecane
n-undecane
n-undecane
n-undecane
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
1.212
1.468
1.804
1.752
2.122
2.614
3.113
3.749
2.983
3.630
4.199
4.934
6.226
0.1461
0.1873
0.2452
0.3049
0.3889
1.129
1.341
1.624
1.912
2.253
0.7474
0.9156
1.126
1.344
1.638
_____________________________________________________________________________
copolymer (B):
VA-VAL/95x
86CAS
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
393.15
400.15
1.565
1.959
1-hexanol
1-hexanol
415.15
423.15
0.4028
0.5095
_____________________________________________________________________________
continue
continue
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
benzene
1-butanol
1-butanol
1-butanol
1-butanol
1-butanol
2-butanol
2-butanol
2-butanol
2-butanol
2-butanol
cyclohexanol
cyclohexanol
cyclohexanol
cyclohexanol
cyclohexanol
n-decane
n-decane
n-decane
n-decane
n-decane
1-decanol
1-decanol
1-decanol
1-decanol
1-decanol
n-dodecane
n-dodecane
n-dodecane
n-dodecane
n-dodecane
ethylbenzene
ethylbenzene
ethylbenzene
ethylbenzene
ethylbenzene
1-heptanol
1-heptanol
1-heptanol
1-heptanol
1-heptanol
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
2.322
2.790
3.271
0.7631
0.9229
1.147
1.383
1.700
1.384
1.646
2.021
2.384
2.872
0.1404
0.1760
0.2291
0.2659
0.3417
0.8262
0.9939
1.234
1.486
1.837
0.01760
0.02378
0.03340
0.04401
0.05880
0.2769
0.3432
0.4293
0.5289
0.6539
0.4671
0.5645
0.6968
0.8324
1.009
0.1085
0.1387
0.1833
0.2283
0.2941
tert-butanol
tert-butanol
tert-butanol
tert-butanol
tert-butanol
n-nonane
n-nonane
n-nonane
n-nonane
n-nonane
1-octanol
1-octanol
1-octanol
1-octanol
1-octanol
1-pentanol
1-pentanol
1-pentanol
1-pentanol
1-pentanol
2-pentanol
2-pentanol
2-pentanol
2-pentanol
2-pentanol
1-propanol
1-propanol
1-propanol
1-propanol
1-propanol
2-propanol
2-propanol
2-propanol
2-propanol
2-propanol
n-tetradecane
n-tetradecane
n-tetradecane
n-tetradecane
n-tetradecane
toluene
toluene
toluene
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
1.036
1.254
1.543
1.839
2.232
1.511
1.800
2.208
2.623
3.208
0.0560
0.0730
0.0979
0.1255
0.1697
0.3785
0.4703
0.5954
0.7288
0.9084
1.164
1.384
1.699
2.005
2.415
1.696
2.051
2.490
3.033
3.687
2.937
3.458
4.130
4.979
5.990
0.09415
0.1201
0.1580
0.1967
0.2513
0.8586
1.025
1.241
_____________________________________________________________________________
continue
continue
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
n-hexadecane
n-hexadecane
n-hexadecane
n-hexadecane
n-hexadecane
1-hexanol
1-hexanol
1-hexanol
393.15
400.15
408.15
415.15
423.15
393.15
400.15
408.15
0.02648
0.03700
0.04973
0.06603
0.08915
0.2017
0.2529
0.3273
toluene
toluene
n-undecane
n-undecane
n-undecane
n-undecane
n-undecane
415.15
423.15
393.15
400.15
408.15
415.15
423.15
1.459
1.741
0.5100
0.6146
0.7627
0.9133
1.110
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from vinyl acetate and vinyl chloride
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Vinyl acetate/vinyl chloride copolymer
3 wt% vinyl acetate
3 wt% vinyl acetate
10 wt% vinyl acetate
VA-VC/03w
VA-VC/03w
VA-VC/10w(1)
VA-VC/10w(2)
VA-VC/15w
VA-VC/17w
VA-VC/17w
79HEI
80MER
79HEI
88SAT
78OIS
79HEI
80MER
Vinyl acetate/vinyl chloride/glycidyl methacrylate

terpolymer
10.5 wt% VA, 80 wt% VC, 9.5 wt% GMA
VA-VC-GMA/10w
78OIS
Vinyl acetate/vinyl chloride/hydroxypropyl acrylate

terpolymer
5 wt% VA, 80 wt% VC, 15 wt% HPA
VA-VC-HPA/05w
34 wt% VA, 58 wt% VC, 8 wt% HPA
VA-VC-HPA/34w
78OIS
78OIS
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
VA-VC/03w
VA-VC/10w(1)
VA-VC/10w(2)
VA-VC/15w
VA-VC/17w
VA-VC-GMA/10w
VA-VC-HPA/05w
VA-VC-HPA/34w
Polysciences, Inc.
Polysciences, Inc.
no data
Union Carbide Corp.
Polysciences, Inc.
Union Carbide Corp.
Union Carbide Corp.
Union Carbide Corp.
26000
8400
10000
12000
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B):
VA-VC/03w
79HEI
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
cyclohexane
cyclohexane
1,2-dichloroethane
1,2-dichloroethane
1,4-dioxane
1,4-dioxane
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
2.24
3.02
5.09
6.48
1.53
2.13
0.85
1.26
nitroethane
nitroethane
n-heptane
n-heptane
2-propanol
2-propanol
toluene
toluene
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
0.97
1.39
6.02
7.50
6.60
8.57
1.03
1.46
_____________________________________________________________________________
copolymer (B):
VA-VC/03w
80MER
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
acetaldehyde
acetaldehyde
acetic acid
acetic acid
acetonitrile
acetonitrile
benzene
benzene
2-butanone
2-butanone
cyclohexane
cyclohexane
1,2-dichloroethane
1,2-dichloroethane
1,4-dioxane
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
398.15
15.16
18.41
3.232
3.940
4.009
5.371
2.219
2.997
2.812
3.387
5.140
6.425
1.550
2.105
0.8536
1,4-dioxane
n-heptane
n-heptane
methanol
methanol
nitroethane
nitroethane
2-propanol
2-propanol
2-propanone
2-propanone
tetrahydrofuran
tetrahydrofuran
toluene
toluene
413.15
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
1.245
5.964
7.555
13.63
17.72
0.9919
1.363
6.516
8.590
5.356
6.517
3.088
3.351
1.058
1.425
_____________________________________________________________________________
copolymer (B):
VA-VC/10w(1)
80MER
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
acetaldehyde
acetaldehyde
acetic acid
acetic acid
acetonitrile
acetonitrile
benzene
benzene
2-butanone
2-butanone
cyclohexane
cyclohexane
1,2-dichloroethane
1,2-dichloroethane
1,4-dioxane
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
398.15
12.57
16.63
2.055
2.909
3.952
5.170
2.033
2.769
2.368
3.088
4.653
6.133
1.350
1.896
0.7695
1,4-dioxane
n-heptane
n-heptane
methanol
methanol
nitroethane
nitroethane
2-propanol
2-propanol
2-propanone
2-propanone
tetrahydrofuran
tetrahydrofuran
toluene
toluene
413.15
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
1.199
5.528
7.311
12.66
15.08
0.8474
1.293
5.814
7.874
4.769
6.110
2.250
3.150
0.9481
1.369
_____________________________________________________________________________
copolymer (B):
VA-VC/10w(1)
79HEI
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
cyclohexane
cyclohexane
1,2-dichloroethane
1,2-dichloroethane
1,4-dioxane
1,4-dioxane
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
2.05
2.84
4.69
6.18
1.40
1.91
0.78
1.21
nitroethane
nitroethane
n-heptane
n-heptane
2-propanol
2-propanol
toluene
toluene
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
0.85
1.29
5.58
7.37
5.89
7.95
0.98
1.38
_____________________________________________________________________________
copolymer (B):
VA-VC/10w(2)
88SAT
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
acrylonitrile
acrylonitrile
acrylonitrile
acrylonitrile
benzene
benzene
benzene
benzene
2-butanone
2-butanone
2-butanone
2-butanone
chlorobenzene
chlorobenzene
chlorobenzene
chlorobenzene
n-decane
n-decane
n-decane
n-decane
ethylbenzene
388.15
398.15
408.15
423.15
388.15
398.15
408.15
423.15
388.15
398.15
408.15
423.15
388.15
398.15
408.15
423.15
388.15
398.15
408.15
423.15
388.15
2.64
3.29
4.10
5.38
1.67
2.02
2.74
3.42
1.90
2.19
2.76
3.74
0.293
0.382
0.501
0.719
0.679
0.849
1.03
1.49
0.413
n-nonane
n-nonane
n-nonane
n-nonane
2-propanone
2-propanone
2-propanone
2-propanone
styrene
styrene
styrene
styrene
tetrachloromethane
tetrachloromethane
tetrachloromethane
tetrachloromethane
toluene
toluene
toluene
toluene
trichloromethane
388.15
398.15
408.15
423.15
388.15
398.15
408.15
423.15
388.15
398.15
408.15
423.15
388.15
398.15
408.15
423.15
388.15
398.15
408.15
423.15
388.15
1.32
1.60
1.95
2.60
3.82
4.67
5.80
7.52
0.224
0.301
0.405
0.602
1.81
1.88
2.18
2.72
0.854
0.962
1.20
1.60
1.69
_____________________________________________________________________________
continue
continue
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
ethylbenzene
ethylbenzene
ethylbenzene
fluorobenzene
fluorobenzene
fluorobenzene
398.15
408.15
423.15
388.15
398.15
408.15
0.540
0.692
0.999
1.36
1.67
2.08
trichloromethane
trichloromethane
trichloromethane
vinyl acetate
vinyl acetate
p-xylene
398.15
408.15
423.15
388.15
398.15
388.15
1.97
2.36
3.11
2.68
3.24
0.350
_____________________________________________________________________________
copolymer (B):
VA-VC/15w
78OIS
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
2-propanone
2-propanone
2-propanone
propyl acetate
propyl acetate
383.15
403.15
423.15
383.15
403.15
4.276
6.647
9.859
1.216
2.178
propyl acetate
vinyl chloride
vinyl chloride
vinyl chloride
423.15
383.15
403.15
423.15
3.668
21.68
30.50
41.14
_____________________________________________________________________________
copolymer (B):
VA-VC/17w
80MER
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
acetaldehyde
acetaldehyde
acetic acid
acetic acid
acetonitrile
acetonitrile
benzene
benzene
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
12.28
15.16
1.513
2.292
3.436
4.688
1.978
2.769
1,4-dioxane
n-heptane
n-heptane
methanol
methanol
nitroethane
nitroethane
2-propanol
413.15
398.15
413.15
398.15
413.15
398.15
413.15
398.15
1.161
5.396
7.311
11.07
13.90
0.8003
1.255
5.558
_____________________________________________________________________________
continue
continue
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
2-butanone
2-butanone
cyclohexane
cyclohexane
1,2-dichloroethane
1,2-dichloroethane
1,4-dioxane
398.15
413.15
398.15
413.15
398.15
413.15
398.15
1.909
2.787
4.653
5.970
1.311
1.779
0.7582
2-propanol
2-propanone
2-propanone
tetrahydrofuran
tetrahydrofuran
toluene
toluene
413.15
398.15
413.15
398.15
413.15
398.15
413.15
7.559
4.031
5.507
2.059
2.917
0.9518
1.354
_____________________________________________________________________________
copolymer (B):
VA-VC/17w
79HEI
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
benzene
cyclohexane
cyclohexane
1,2-dichloroethane
1,2-dichloroethane
1,4-dioxane
1,4-dioxane
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
2.00
2.79
4.70
6.03
1.29
1.83
0.76
1.18
n-heptane
n-heptane
nitroethane
nitroethane
2-propanol
2-propanol
toluene
toluene
398.15
413.15
398.15
413.15
398.15
413.15
398.15
413.15
5.45
7.37
0.79
1.27
5.64
7.65
0.93
1.38
_____________________________________________________________________________
copolymer (B):
VA-VC-GMA/10w
78OIS
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
2-propanone
2-propanone
2-propanone
propyl acetate
propyl acetate
propyl acetate
383.15
403.15
423.15
383.15
403.15
423.15
4.327
6.809
10.23
1.246
2.189
3.678
vinyl acetate
vinyl acetate
vinyl acetate
vinyl chloride
vinyl chloride
vinyl chloride
383.15
403.15
423.15
383.15
403.15
423.15
3.131
5.107
7.984
22.39
30.90
41.04
_____________________________________________________________________________
copolymer (B):
VA-VC-HPA/05w
78OIS
_____________________________________________________________________________
T/
HA,B/
Solvent (A)
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
2-propanone
2-propanone
2-propanone
propyl acetate
propyl acetate
383.15
403.15
423.15
383.15
403.15
3.992
6.606
10.44
1.185
2.138
propyl acetate
vinyl chloride
vinyl chloride
vinyl chloride
423.15
383.15
403.15
423.15
3.698
23.10
31.61
41.64
_____________________________________________________________________________
copolymer (B):
VA-VC-HPA/34w
78OIS
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
2-propanone
2-propanone
2-propanone
383.15
403.15
423.15
3.719
6.090
9.433
vinyl chloride
vinyl chloride
vinyl chloride
383.15
403.15
423.15
18.44
26.04
35.77
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from vinyl chloride and vinylidene chloride
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Vinyl chloride/vinylidene chloride copolymer
20 wt% vinyl chloride
20 wt% vinyl chloride
VC-VdC/20w(1)
VC-VdC/20w(2)
86DEM
91DEM
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol g/mol
_____________________________________________________________________________
Copolymer (B)
VC-VdC/20w(1)
VC-VdC/20w(2)
90000
Polysciences Inc.
Borden Chem. Corp., USA
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B):
VC-VdC/20w(1)
86DEM
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
1,1-dichloroethene
1,1-dichloroethene
1,1-dichloroethene
291.15
298.15
306.15
1.628
1.982
2.766
1,1-dichloroethene
1,1-dichloroethene
314.15
323.15
3.576
4.244
_____________________________________________________________________________
copolymer (B):
VC-VdC/20w(2)
91DEM
_____________________________________________________________________________
Solvent (A)
T/
HA,B/
T/
HA,B/
K
MPa
K
MPa
_____________________________________________________________________________
Solvent (A)
benzene
cyclohexane
n-decane
n-heptane
n-nonane
363.15
363.15
363.15
363.15
363.15
2.823
9.637
0.5149
6.296
1.157
n-octane
tetrachloromethane
tetrahydrofuran
toluene
trichloromethane
363.15
363.15
363.15
363.15
363.15
0.06041
3.601
2.739
1.049
3.523
_____________________________________________________________________________
2.3. References
63COR
72PEI
73BEL
75BOB
76KIE
76LIU
78DIN
78DIP
78OIS
79HEI
80MER
81DIP
81WAR
82LI1
82LI2
83WAL
84MAT
86CAS
Corneliussen, R., Rice, S.A., and Yamakawa, H., On the thermodynamic properties of
solutions of polar polymers. A comparison of experiment and theory, J. Chem. Phys., 38,
1768, 1963.
Peinze, K., Dampfdruckmessungen in binren Lsungen aus Aromaten und Copolymeren,
Diploma paper, TH Leuna-Merseburg, 1972.
Belorussow, J., Freie Exzessenthalpie binrer Lsungen aus Aromaten und EthylenVinylacetat-Copolymeren, Diploma paper, TH Leuna-Merseburg, 1973.
Boblenz, M. and Glindemann, D., Abhngigkeit der freien Exzessenthalpie vom
Lsungsmittel in binren Mischungen mit Ethylen-Vinylacetat-Copolymerisat, Diploma
paper, TH Leuna-Merseburg, 1975.
Kiessling, D., Untersuchungen des Flssig-Dampf-Gleichgewichts von Polyethylenvinylacetat-Essigester-Systemen, Diploma paper, TH Leuna-Merseburg, 1976.
Liu, D.D. and Prausnitz, J.M., Solubilities of gases and volatile liquids in polyethylene and
in ethylene-vinyl acetate copolymers in the region 125-225 oC, Ind. Eng. Chem. Fundam.,
15, 330, 1976.
Dincer, S. and Bonner, D.C., Thermodynamic analysis of ethylene and vinylacetate
copolymer with various solvents by gas chromatography, Macromolecules, 11, 107, 1978.
DiPaola-Baranyi, G., Braun, J.-M., and Guillet, J.E., Partial molar heats of mixing of small
molecules with polymers by gas chromatography, Macromolecules, 11, 224, 1978.
Oishi, T. and Prausnitz, J.M., Solubilities of some volatile polar fluids in copolymers
containing vinyl chloride, vinyl acetate, glycidyl methacrylate, and hydroxypropyl acrylate,
Ind. Eng. Chem. Fundam., 17, 109, 1978.
Heintz, A., Lichtenthaler, R.N., and Prausnitz, J.M., Solubilities of volatile solvents in
polyvinylacetate, polyvinylchloride, and their random copolymers, Ber. Bunsenges. Phys.
Chem. 83, 926, 1979.
Merk, W., Lichtenthaler, R.N., and Prausnitz, J.M., Solubilities of fifteen solvents in
copolymers of poly(vinyl acetate) and poly(vinyl chloride) from gas-liquid chromatography.
Estimation of polymer solubility parameters, J. Phys. Chem., 84, 1694, 1980.
DiPaola-Baranyi, G., Thermodynamic miscibility of various solutes with styrene-butyl
methacrylate polymers and copolymers, Macromolecules, 14, 683, 1981.
Ward, T.C., Sheeny, D.P., Riffle, J.S., and McGrath, J.E., Inverse gas chromatography
studies of poly(dimethylsiloxane)-polycarbonate copolymers and blends, Macromolecules,
14, 1791, 1981.
Lipson, J.E.G. and Guillet, J.E., Solubilities and solubility parameters of polymers from
inverse gas chromatography, in Macromolecular Solutions, Solvent Prop. Relat. Polym.
Pap. Symp., 1982, 14.
Lipson, J.E.G. and Guillet, J.E., Measurement of solubility and solubility parameters for
small organic solutes in polymer films by gas chromatography, J. Coat. Technol., 54, 89,
1982.
Walsh, D.J., Higgins, J.S., Rostami, S., and Weerape-Ruma, K., Compatibility of ethylenevinylacetate copolymers with chlorinated polyethylenes. 2. Investigation of the
thermodynamic parameters, Macromolecules, 16, 391, 1983.
Matsumara, K., Measurement of infinite dilution activity coefficient of solvent in polymer
by gas-liquid chromatography, Kagaku Kogaku Ronbunshu, 10, 516, 1984.
Castells, R.S. and Massa, G.D., Study of polymer-solvent interactions by gas
chromatography. Copolymers of vinyl acetate and vinyl alcohol with hydrocarbons and
alcohols, J. Appl. Polym. Sci., 32, 5917, 1986.
86DEM
86IT1
86IT2
86KRC
86PRI
87OEN
87PRI
88SAT
89MOE
90IWA
91CHE
91DEM
91IWA
92CHE
92ROM
93ISS
94WOH
95BOG
95GUP
95PET
95TRI
Demertzis, P.G. and Kontominas, M.G., Interaction between vinylidene chloride and
copolymers of vinylidene chloride by inverse gas chromatography, Lebensm.-Wiss.
Technol., 19, 249, 1986.
Itsuno, S., Iwai, Y., and Arai, Y., Measurement and correlation of solubilities of hydrocarbon gases in styrene-butadiene copolymers, Kagaku Kogaku Ronbunshu, 12, 349, 1986.
Itsuno, S., Ohyama, K., Iwai, Y., and Arai, Y., Measurement and correlation of solubilities
for hydrocarbon gases in acrylonitrile-butadiene copolymer, Kagaku Kogaku Ronbunshu,
12, 734, 1986.
Krcek, M., Diploma paper, Verdampfungsgleichgewicht in Systemen aus Polymermischungen oder Blockcopolymeren und einem Lsungsmittel, TH Leuna-Merseburg, 1986.
Price, G.J., Guillet, J.E., and Purnell, J.H., Measurement of solubility parameters by gasliquid chromatography, J. Chromatogr., 369, 273, 1986.
Oener, M. and Dincer, S., Thermodynamical properties of polymer-probe pairs by gas
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2.

VAPOR-LIQUID EQUILIBRIUM (VLE) DATA

Sci. Polym. Products, catalog #523

2001 by CRC Press LLC

2001 by CRC Press LLC

2001 by CRC Press LLC

Bayer AG Leverkusen, Ger.

2001 by CRC Press LLC

2001 by CRC Press LLC

2001 by CRC Press LLC

synthesized in the laboratory

2001 by CRC Press LLC

Experimental VLE data:

2001 by CRC Press LLC

Polystyrene-b-polybutadiene(hydrogenated)b-polystyrene triblock copolymer

Sci. Polym. Products, catalog #199

2001 by CRC Press LLC

Sci. Polym. Products, catalog #201

Sci. Polym. Products

synthesized in the laboratory

2001 by CRC Press LLC

2001 by CRC Press LLC

2001 by CRC Press LLC

2001 by CRC Press LLC

2001 by CRC Press LLC

2001 by CRC Press LLC

2001 by CRC Press LLC

2001 by CRC Press LLC

2001 by CRC Press LLC

2001 by CRC Press LLC

Dow Corning Corp., Midland, USA

2001 by CRC Press LLC

2001 by CRC Press LLC

2001 by CRC Press LLC

Sci. Polym. Products, catalog #506

2001 by CRC Press LLC

2001 by CRC Press LLC

2001 by CRC Press LLC

2001 by CRC Press LLC

2001 by CRC Press LLC

2001 by CRC Press LLC

2001 by CRC Press LLC

2001 by CRC Press LLC

2001 by CRC Press LLC

2001 by CRC Press LLC

2001 by CRC Press LLC

2001 by CRC Press LLC

8200 (= 4000 + 4200)

synthesized in the laboratory

Experimental VLE data:

Comments: segment fraction is based on Bondi's volumina with rB = 80

Comments: segment fraction is based on Bondi's volumina with rB = 80

2001 by CRC Press LLC

Poly(ethylene oxide)-b-poly(methyl methacrylate)b-poly(ethylene oxide) triblock copolymer

8900 (= 4600 + 4300)

synthesized in the laboratory

Comments: segment fraction is based on Bondi's volumina with rB = 83

2001 by CRC Press LLC

Comments: segment fraction is based on Bondi's volumina with rB = 83

Comments: segment fraction is based on Bondi's volumina with rB = 83

Comments: segment fraction is based on Bondi's volumina with rB = 73.2

Comments: segment fraction is based on Bondi's volumina with rB = 73.2

Comments: segment fraction is based on Bondi's volumina with rB = 73.2