Some Basic concepts of chemistry

1 mole = 6.02 1023 particles = 1g. atom or 1 g molecule NA = 6.02 1023 1 a.m.u = Equivalent mass = Average atomic mass = g

Molarity (M) =

Molarity (m) =

Normality (N) =

Mole fraction Atomic mass = Equivalent mass Valency Dilution formula : M1V1 = M2V2

Atomic Structure E = h = h = h0 + K.E (Photoelectric effect) (a0 = 52.9 m)

deBroglie equation

Equilibrium Heisenberg uncertainity principle : Number of orbitals in a shell = n2 Number of electrons in a shell = 2n2 Number of radial nodes = (n l 1) (H = number of Hybrid orbitals) Bond order = States of matter Boyles law : P1V1 = P2V2 Charles law : Ideal gas equation : PV = nRT Daltons law : PTotal = P1 + P2 + P3 + ...... Density = g/cm3 KP = KC(RT)n Kw = [H+] [OH] pH = log [H+] pKw = pH + pOH Ka = C2 Kw = Ka Kb Ksp = [Ar+]x [Bx]y

Chemical Bonding

Solid State

Packing fraction : Simple cubic = Braggs equation d = nsin

, FCC =

, BCC =

Solution Henrys law X(g) = KH.P Raoults law : v.p. of solution = xAPA0 + XBPB0 Relative lowering of V.P. : Tb = i kbm Tf = i kfm = CRT

dgas =

Grahams Law

Vander waals equation : CP CV = nRT Kinetic gas equation :

Chemical Thermodynamics U = qv, H = qp H = U + ngRT C = (C = Heat capacity)

Electrochemistry G =

U = q + w (First law) H = G = H TS G = RT ln K

Aluminium Chloride :

Berrilium Chloride : BeCl2 : CO : , CO2 : O = C = O

W = ZIt

Chemical Kinetics Rate = K[A]x [B]y SiO2 :

K = Linear Silicone :

k = Ae Ea/RT

Temperature coefficient =

Yellow P :

Important Structureal formula

Hydrogen peroxide : H2O2 : Water :

P4O10 :

NO2 :

N2O5 :

Orthoboric acid (H3BO3) :

HNO3 :

Diborane (B2H6) :

H4P2O7 :

Boron triflouride (BF3) :

SO2 :

H2SO4 :

BrF3 :

HClO4 :

MnO4 :

Cr2O72 :