Practica 4 ELV No Ideal Cloroformo-Metanol

ELV NO IDEAL
SISTEMA CLOROFORMO (1) - METANOL (2)

COEFICIENTE ACTIVIDAD GAMMA POR
A) ECUACION DE VAN LAAR
B) ECUACION DE MARGULES
Prof. Eva Lpez Merida
Laboratorio de Termodinmica Qumica 1-
METANOL (2)
D GAMMA POR
AN LAAR
ARGULES
Qumica 1- ESIQIE
INTRODUCE EN LA TABLA VERDE LOS DATOS EXPERIMENTALES

TEMPERATURA, INDICE DE REFRACCION DE LIQUIDO, INDICE DE REFRACCION DE CONDENSADOS
a=
12.922
b=
-28.704
c=
15.511
TEMP
fraccion mol
Indice de
Indice de
fraccion mol
EBULL
CLOROFORMO
Refraccion
Refraccion
CLOROFORMO
T(C)
X1
n(liquido)
n(condensado)
Y1 (exp)
61
60
59
58
55
53
48
48
46
46
45
0.00
0.10
0.20
0.30
0.40
0.50
0.60
0.70
0.80
0.90
1.00
1.324
1.3276
1.3286
1.331
1.3356
1.3845
1.3982
1.4083
1.4176
1.4311
1.4407
1.3255
1.3278
1.3314
1.3369
1.3382
1.4004
1.4146
1.4155
1.4171
1.4183
1.4364
0.0000
0.1797
0.2001
0.2319
0.2395
0.6552
0.7642
0.7712
0.7839
0.7934
1.0000
N DE CONDENSADOS
CORRELACION DE DATOS PARA EL CLCULO DE FRACCION MOL DE FASE VAPOR

CORRELACION CUADRATICA - MINIMOS CUADRADOS
39.587
28.697
20.824
15.127
10.821
7.712
5.500
3.073
3.106
3.116
3.138
3.182
3.674
3.822
3.934
4.038
4.194
4.308
2.321
2.340
2.345
2.358
2.382
2.654
2.733
2.793
2.849
2.931
2.990
1.753
1.763
1.765
1.772
1.784
1.917
1.955
1.983
2.010
2.048
2.076
1.324
1.328
1.329
1.331
1.336
1.385
1.398
1.408
1.418
1.431
1.441
0.000
0.176
0.353
0.531
0.714
0.958
1.173
1.388
1.608
1.843
2.076
0.000
0.133
0.266
0.399
0.534
0.692
0.839
0.986
1.134
1.288
1.441
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
Curva de Calibracin
Fraccin mol versus Indice de refraccin
1.00
y = 12.922x2 - 28.704x + 15.511
R = 0.9302
0.90
fraccin mol (cloroformo)
0.80
0.70
0.60
0.50
0.40
0.30
0.20
0.10
0.00
1.3
1.32
1.34
1.36
1.38
1.4
1.42
indice de refraccin /(liq)
1.44
1.46
1.3
1.32
1.34
1.36
1.38
1.4
1.42
indice de refraccin /(liq)
1.44
1.46
DE FASE VAPOR
39.587
28.697
20.824
28.697
20.824
15.127
20.824
15.127
11
10.821
7.712
5.500
74210.2743 -204416.577
-204416.577 563124.021
140623.981
-387421
140623.981
-387421
266561.973
12.922
-28.704
15.511
TEMPERATURA DE EBULLICION (PUROS)=

Constantes de
A=
P(mmHg)
Antoine
T(C)
Log base 10
53.8671
6.9371
58.0042
8.0724
1171.2
227
1574.99
238.87
B=
C=
Cloroformo
Metanol
X2
X1
n(liq)
n(cond)
Y1
T(C)
T(C)
Psat(1)
Psat(2)
1.00
0.90
0.80
0.70
0.60
0.50
0.40
0.30
0.20
0.10
0.00
0.00
0.10
0.20
0.30
0.40
0.50
0.60
0.70
0.80
0.90
1.00
1.324
1.3276
1.3286
1.331
1.3356
1.3845
1.3982
1.4083
1.4176
1.4311
1.4407
1.3255
1.3278
1.3314
1.3369
1.3382
1.4004
1.4146
1.4155
1.4171
1.4183
1.4364
0.000
0.180
0.200
0.232
0.239
0.655
0.764
0.771
0.784
0.793
1.000
61
60
59
58
55
53
48
48
46
46
45
61.0000
60.00
59.00
58.00
55.00
53.00
48.00
48.00
46.00
46.00
45.0000
742.1
718.2
695.0
672.4
608.0
567.9
476.6
476.6
443.6
443.6
427.8
660.9
634.7
609.4
584.9
516.3
474.5
382.1
382.1
349.6
349.6
334.3
Resultados Experimentales
60
58
56
Temperatura C
54
52
50
48
46
44
42
40
0.0
0.1
0.2
0.3
0.4
0.5
X,Y
0.6
Parametros A(12), A(21)

A12=
A21=
0.08820
1.35904
Determinacion del Parmetro A12 por mi

2.5333
3.0250
3.8500
gamma(1)
gamma(2)
Ln(gamma1)
Ln(gamma2)
1.464
0.842
0.672
0.576
1.350
1.563
1.352
1.292
1.163
0.840
0.960
1.098
1.436
0.850
0.903
1.168
1.808
3.457
0.38107
-0.17187
-0.39690
-0.55157
0.30010
0.44669
0.30176
0.25633
0.15062
-0.17433
-0.04095
0.09307
0.36195
-0.16227
-0.10228
0.15493
0.59232
1.24041
X1^4
X1^3
0.0001
0.0016
0.0081
0.0256
0.0625
0.1296
0.2401
0.4096
0.6561
1.0000
X1^2
0.001
0.008
0.027
0.064
0.125
0.216
0.343
0.512
0.729
1.000
0.01
0.04
0.09
0.16
0.25
0.36
0.49
0.64
0.81
1.00
Resultados Experimentales
perimentales
1.0
0.9
fraccin mol cloroformo Y1
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.0
0.6
0.7
0.8
0.9
1.0
0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
fraccin mol cloroformo X1
0.8
0.9
1.0
del Parmetro A12 por minimos cuadrados

5.5000
0.5427
X1
X1^2*LnG1
0.10
0.20
0.30
0.40
0.50
0.60
0.70
0.80
0.90
1.00
0.0038
-0.0069
-0.0357
-0.0883
0.0750
0.1608
0.1479
0.1640
0.1220
0.0000
0.6339
X1*LnG1
0.0381
-0.0344
-0.1191
-0.2206
0.1501
0.2680
0.2112
0.2051
0.1356
0.0000
0.7162
LnG1
0.3811
-0.1719
-0.3969
-0.5516
0.3001
0.4467
0.3018
0.2563
0.1506
0.0000
2.533
3.025
3.850
3.025
3.850
5.500
18.939
-20.833
4.167
-20.833
24.129
-5.250
Determinacion de A12
Dilucin Infinita
3.0
y = 1.3009x2 - 0.8412x + 0.0882

R = 0.1706
Ln(gamma 1)
2.5
2.0
1.5
1.0
0.5
0.0
0.0
0.1
0.2
0.3
0.4
0.5
0.6
fraccin mol X1
0.9
1.0
0.7
0.8
0.9
1.0
Determinacion del Parmetro A21 por minimos cuadrados

2.5333
3.0250
3.8500
5.5000
X2^4
3.850
5.500
10.000
X2^3
1.0000
0.6561
0.4096
0.2401
0.1296
0.0625
0.0256
0.0081
0.0016
0.0001
0.5427
0.6339
0.7162
4.167 0.05559022
-5.250 0.22978757
1.383 -0.07616304
X2^2
1.00
0.73
0.51
0.34
0.22
0.13
0.06
0.03
0.01
0.00
X2
1.00
0.81
0.64
0.49
0.36
0.25
0.16
0.09
0.04
0.01
Determinacin de A21
Dilucin Infinita
3
y = 3.307x2 - 4.5101x + 1.4259
R = 0.7115
2.5
Ln(gamma 2)
2
1.5
1
0.5
0
-0.5
0.0
0.1
0.2
0.3
0.4
0.5
0.6
fraccin mol X2
0.7
0.8
0.9
1.0
1.00
0.90
0.80
0.70
0.60
0.50
0.40
0.30
0.20
0.10
A21 por minimos cuadrados

0.0016
X2^2*LnG2
0.2596
X2*LnG2
1.9629
LnG2
0
0
0
-0.1412059 -0.15689545 -0.17432828
-0.02621032 -0.0327629 -0.04095363
0.04560297 0.06514709 0.09306728
0.13030302 0.21717171 0.36195285
-0.0405667 -0.0811334 -0.1622668
-0.01636433 -0.04091082 -0.10227706
0.01394343 0.04647808 0.15492695
0.02369276 0.11846379 0.59231894
0.0124041 0.12404101 1.24041007
2.533
3.025
3.850
3.025
3.850
5.500
3.850
5.500
10.000
18.939
-20.833
4.167
-20.833
24.129
-5.250
4.167
-5.250
1.383
0.0016
0.2596
1.9629
2.800513
-4.074465
1.359044
Mtodo de Newton-Raphson para ELV con ecuacin de van Laar con treinta iteracione
MetanolCloroformo
A= 8.0724 6.9371
B=
1575 1171.2
C= 238.87
227
T(m)
58.0
57.6
57.2
56.8
56.3
55.9
55.5
55.1
54.7
54.3
53.9
T(m)
58.0
57.5
57.0
56.5
56.0
55.5
55.1
54.6
54.2
53.8
53.9
T(m)
58.0
57.5
56.9
56.4
55.8
55.3
54.8
54.3
53.9
53.5
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
Van Laar
A12=
0.0882
A21= 1.359044
Teb1=
Teb2=
P=
gamma(1) gamma(2) Psat(1)

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
663
654
645
636
628
619
610
602
593
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
661
650
640
629
619
610
600
592
584
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
672
660
648
637
625
614
604
594
585
578
53.9 Cloroformo
58.0 Metanol
585 mmHg
Psat(2)
585
575
565
556
546
537
528
519
510
501
492
Psat(2)
585
573
561
550
539
528
518
508
499
492
492
Psat(2)
585
572
559
546
534
523
512
501
492
485
Pcalc
585.0
590.0
595.0
599.8
604.6
609.0
612.9
615.9
616.9
613.3
585.0
Pcalc
585.0
587.9
590.9
594.1
597.2
600.2
603.0
605.2
606.1
604.0
585.0
Pcalc
585.0
586.7
588.5
590.5
592.5
594.6
596.5
598.1
598.9
597.6
8.0724
1574.99
238.87
F(T)
0.00
4.99
9.96
14.84
19.56
23.98
27.89
30.86
31.91
28.35
0.00
F(T)
0.00
2.90
5.93
9.05
12.17
15.21
17.98
20.18
21.13
18.98
0.00
F(T)
0.00
1.68
3.53
5.50
7.54
9.59
11.52
13.12
13.92
12.64
F(T)
55.24
56.63
57.96
59.25
60.47
61.62
62.67
63.57
64.22
64.32
61.99
F(T)
55.24
56.37
57.46
58.51
59.52
60.47
61.36
62.14
62.76
63.03
61.99
F(T)
55.24
56.22
57.16
58.06
58.93
59.75
60.51
61.20
61.79
62.17
53.9
T(m)
58.0
57.4
56.8
56.3
55.7
55.1
54.6
54.1
53.6
53.3
53.9
T(m)
58.0
57.4
56.8
56.2
55.6
55.0
54.5
53.9
53.5
53.2
53.9
T(m)
58.0
57.4
56.8
56.2
55.6
55.0
54.4
53.9
53.4
53.1
53.9
T(m)
58.0
57.4
1.000
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
1.000
0.900
1.00
3.89
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
660
647
634
622
611
600
589
580
574
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
659
646
633
621
609
597
587
577
572
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
659
646
633
620
607
596
585
575
570
585

1.09
1.09
1.00
1.00
672
659
492
Psat(2)
585
571
558
544
532
519
508
497
487
481
492
Psat(2)
585
571
557
543
530
517
505
494
484
478
492
Psat(2)
585
570
556
542
529
516
503
492
482
477
492
Psat(2)
585
570
585.0
Pcalc
585.0
586.0
587.1
588.3
589.7
591.0
592.4
593.5
594.1
593.4
585.0
Pcalc
585.0
585.6
586.2
587.0
587.9
588.8
589.7
590.5
591.0
590.6
585.0
Pcalc
585.0
585.3
585.7
586.2
586.8
587.4
588.0
588.5
588.9
588.7
585.0
Pcalc
585.0
585.2
0.00
F(T)
0.00
0.97
2.09
3.33
4.66
6.03
7.36
8.50
9.13
8.39
0.00
F(T)
0.00
0.56
1.24
2.02
2.87
3.78
4.69
5.49
5.97
5.56
0.00
F(T)
0.00
0.33
0.73
1.22
1.77
2.37
2.98
3.54
3.90
3.68
0.00
F(T)
0.00
0.19
61.99
F(T)
55.24
56.13
56.98
57.79
58.56
59.28
59.96
60.59
61.15
61.59
61.99
F(T)
55.24
56.08
56.87
57.62
58.33
58.99
59.61
60.19
60.72
61.21
61.99
F(T)
55.24
56.05
56.81
57.52
58.19
58.81
59.39
59.94
60.45
60.95
61.99
F(T)
55.24
56.03
56.8
56.1
55.5
54.9
54.3
53.8
53.3
53.0
53.9
T(m)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.8
53.3
53.0
53.9
T(m)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.3
53.0
53.9
10
T(m)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.2
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
645
632
619
607
595
584
574
569
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
659
645
632
619
606
594
583
573
568
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
659
645
632
618
606
594
582
573
568
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
672
659
645
632
618
605
593
582
572
556
542
528
515
502
491
481
475
492
Psat(2)
585
570
556
541
528
514
502
490
480
475
492
Psat(2)
585
570
556
541
527
514
501
489
480
474
492
Psat(2)
585
570
556
541
527
514
501
489
479
585.4
585.7
586.1
586.5
586.9
587.3
587.5
587.4
585.0
Pcalc
585.0
585.1
585.3
585.4
585.7
585.9
586.2
586.5
586.7
586.6
585.0
Pcalc
585.0
585.1
585.2
585.3
585.4
585.6
585.8
585.9
586.1
586.1
585.0
Pcalc
585.0
585.0
585.1
585.2
585.3
585.4
585.5
585.6
585.7
0.44
0.74
1.09
1.48
1.89
2.28
2.55
2.43
0.00
F(T)
0.00
0.11
0.26
0.45
0.67
0.93
1.20
1.47
1.66
1.60
0.00
F(T)
0.00
0.06
0.15
0.27
0.41
0.58
0.76
0.94
1.08
1.06
0.00
F(T)
0.00
0.04
0.09
0.16
0.25
0.36
0.48
0.61
0.70
56.77
57.46
58.10
58.70
59.25
59.77
60.27
60.79
61.99
F(T)
55.24
56.02
56.75
57.42
58.05
58.62
59.16
59.66
60.15
60.67
61.99
F(T)
55.24
56.02
56.74
57.40
58.01
58.58
59.10
59.59
60.07
60.60
61.99
F(T)
55.24
56.01
56.73
57.39
57.99
58.55
59.07
59.55
60.02
53.0
53.9
11
T(m)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.2
53.0
53.9
12
T(m)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
13
T(m)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
14
T(m)
58.0
0.900
1.000
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
1.000
1.04
1.00
1.20
3.89
567
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
659
645
631
618
605
593
582
572
567
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
659
645
631
618
605
593
582
572
567
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
659
645
631
618
605
593
582
572
567
585

1.09
1.00
672
474
492
Psat(2)
585
570
556
541
527
514
501
489
479
474
492
Psat(2)
585
570
555
541
527
513
501
489
479
473
492
Psat(2)
585
570
555
541
527
513
500
489
479
473
492
Psat(2)
585
585.7
585.0
Pcalc
585.0
585.0
585.1
585.1
585.2
585.2
585.3
585.4
585.5
585.5
585.0
Pcalc
585.0
585.0
585.0
585.1
585.1
585.1
585.2
585.3
585.3
585.3
585.0
Pcalc
585.0
585.0
585.0
585.0
585.1
585.1
585.1
585.2
585.2
585.2
585.0
Pcalc
585.0
0.70
0.00
F(T)
0.00
0.02
0.05
0.10
0.16
0.23
0.31
0.39
0.46
0.46
0.00
F(T)
0.00
0.01
0.03
0.06
0.10
0.14
0.19
0.25
0.30
0.30
0.00
F(T)
0.00
0.01
0.02
0.04
0.06
0.09
0.12
0.16
0.19
0.20
0.00
F(T)
0.00
60.55
61.99
F(T)
55.24
56.01
56.73
57.38
57.98
58.53
59.04
59.52
59.99
60.52
61.99
F(T)
55.24
56.01
56.72
57.38
57.97
58.52
59.03
59.50
59.97
60.50
61.99
F(T)
55.24
56.01
56.72
57.37
57.97
58.52
59.02
59.49
59.95
60.49
61.99
F(T)
55.24
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
15
T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
16
T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
17
T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
659
645
631
618
605
593
581
572
567
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
659
645
631
618
605
593
581
572
567
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
659
645
631
618
605
593
581
572
567
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
672
659
645
631
618
605
593
581
570
555
541
527
513
500
489
479
473
492
Psat(2)
585
570
555
541
527
513
500
489
479
473
492
Psat(2)
585
570
555
541
527
513
500
489
479
473
492
Psat(2)
585
570
555
541
527
513
500
489
585.0
585.0
585.0
585.0
585.1
585.1
585.1
585.1
585.1
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.1
585.1
585.1
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.1
585.1
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
0.00
0.01
0.02
0.04
0.06
0.08
0.10
0.13
0.13
0.00
F(T)
0.00
0.00
0.01
0.01
0.02
0.03
0.05
0.07
0.08
0.09
0.00
F(T)
0.00
0.00
0.00
0.01
0.01
0.02
0.03
0.04
0.05
0.06
0.00
F(T)
0.00
0.00
0.00
0.00
0.01
0.01
0.02
0.03
56.01
56.72
57.37
57.97
58.51
59.01
59.48
59.94
60.48
61.99
F(T)
55.24
56.01
56.72
57.37
57.97
58.51
59.01
59.48
59.94
60.47
61.99
F(T)
55.24
56.01
56.72
57.37
57.96
58.51
59.01
59.47
59.94
60.47
61.99
F(T)
55.24
56.01
56.72
57.37
57.96
58.51
59.01
59.47
53.2
52.9
53.9
18
T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
19
T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
20
T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
21
T(m)
0.800
0.900
1.000
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
1.06
1.04
1.00
1.06
1.20
3.89
572
567
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
659
645
631
618
605
593
581
572
567
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
659
645
631
618
605
593
581
572
567
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
659
645
631
618
605
593
581
572
567
585
479
473
492
Psat(2)
585
570
555
541
527
513
500
489
479
473
492
Psat(2)
585
570
555
541
527
513
500
488
479
473
492
Psat(2)
585
570
555
541
527
513
500
488
479
473
492
Psat(2)
585.0
585.0
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
0.03
0.04
0.00
F(T)
0.00
0.00
0.00
0.00
0.01
0.01
0.01
0.02
0.02
0.02
0.00
F(T)
0.00
0.00
0.00
0.00
0.00
0.01
0.01
0.01
0.01
0.02
0.00
F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.01
0.01
0.01
0.00
F(T)
59.93
60.46
61.99
F(T)
55.24
56.01
56.72
57.37
57.96
58.51
59.00
59.47
59.93
60.46
61.99
F(T)
55.24
56.01
56.72
57.37
57.96
58.51
59.00
59.47
59.93
60.46
61.99
F(T)
55.24
56.01
56.72
57.37
57.96
58.51
59.00
59.47
59.93
60.46
61.99
F(T)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
22
T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
23
T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
24
T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
1.000
0.900
0.800
0.700
0.600
0.500
0.400
1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
659
645
631
618
605
593
581
572
567
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
659
645
631
618
605
593
581
572
567
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
659
645
631
618
605
593
581
572
567
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.00
1.00
1.00
1.00
1.00
1.01
1.01
672
659
645
631
618
605
593
585
570
555
541
527
513
500
488
479
473
492
Psat(2)
585
570
555
541
527
513
500
488
479
473
492
Psat(2)
585
570
555
541
527
513
500
488
479
473
492
Psat(2)
585
570
555
541
527
513
500
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.01
0.00
F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
55.24
56.01
56.72
57.37
57.96
58.51
59.00
59.47
59.93
60.46
61.99
F(T)
55.24
56.01
56.72
57.37
57.96
58.51
59.00
59.47
59.93
60.46
61.99
F(T)
55.24
56.01
56.72
57.37
57.96
58.51
59.00
59.47
59.93
60.46
61.99
F(T)
55.24
56.01
56.72
57.37
57.96
58.51
59.00
53.7
53.2
52.9
53.9
25
T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
26
T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
27
T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
28
T(m)
0.700
0.800
0.900
1.000
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
1.07
1.06
1.04
1.00
1.02
1.06
1.20
3.89
581
572
567
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
659
645
631
618
605
593
581
572
567
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
659
645
631
618
605
593
581
572
567
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
659
645
631
618
605
593
581
572
567
585
488
479
473
492
Psat(2)
585
570
555
541
527
513
500
488
479
473
492
Psat(2)
585
570
555
541
527
513
500
488
479
473
492
Psat(2)
585
570
555
541
527
513
500
488
479
473
492
Psat(2)
585.0
585.0
585.0
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
0.00
0.00
0.00
0.00
F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
F(T)
59.47
59.93
60.46
61.99
F(T)
55.24
56.01
56.72
57.37
57.96
58.50
59.00
59.47
59.93
60.46
61.99
F(T)
55.24
56.01
56.72
57.37
57.96
58.50
59.00
59.47
59.93
60.46
61.99
F(T)
55.24
56.01
56.72
57.37
57.96
58.50
59.00
59.47
59.93
60.46
61.99
F(T)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
29
T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
30
T(m)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
659
645
631
618
605
593
581
572
567
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
659
645
631
618
605
593
581
572
567
585

1.09
1.09
1.09
1.09
1.08
1.08
1.08
1.07
1.06
1.04
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.01
1.02
1.06
1.20
3.89
672
659
645
631
618
605
593
581
572
567
585
585
570
555
541
527
513
500
488
479
473
492
Psat(2)
585
570
555
541
527
513
500
488
479
473
492
Psat(2)
585
570
555
541
527
513
500
488
479
473
492
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
55.24
56.01
56.72
57.37
57.96
58.50
59.00
59.47
59.93
60.46
61.99
F(T)
55.24
56.01
56.72
57.37
57.96
58.50
59.00
59.47
59.93
60.46
61.99
F(T)
55.24
56.01
56.72
57.37
57.96
58.50
59.00
59.47
59.93
60.46
61.99
ar con treinta iteraciones

H
T(m+1)
58.0
57.5
57.0
56.5
56.0
55.5
55.1
54.6
54.2
53.8
53.9
T(m+1)
58.0
57.5
56.9
56.4
55.8
55.3
54.8
54.3
53.9
53.5
53.9
T(m+1)
58.0
57.4
56.8
56.3
55.7
55.1
54.6
54.1
53.6
53.3
Y1 teorica
Y1 (EXP)
T(C) EXP
0.000
0.124
0.244
0.360
0.472
0.580
0.683
0.780
0.870
0.945
1.000
0.000
0.180
0.200
0.232
0.239
0.655
0.764
0.771
0.784
0.793
1.000
61
60
59
58
55
53
48
48
46
46
45
Y1
0.000
0.123
0.242
0.357
0.467
0.572
0.673
0.768
0.855
0.931
1.000
Y1
0.000
0.123
0.241
0.355
0.464
0.567
0.666
0.759
0.846
0.922
53.9
T(m+1)
58.0
57.4
56.8
56.2
55.6
55.0
54.5
53.9
53.5
53.2
53.9
T(m+1)
58.0
57.4
56.8
56.2
55.6
55.0
54.4
53.9
53.4
53.1
53.9
T(m+1)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.8
53.3
53.0
53.9
T(m+1)
58.0
57.4
1.000
Y1
0.000
0.123
0.241
0.354
0.462
0.564
0.662
0.754
0.839
0.915
1.000
Y1
0.000
0.123
0.241
0.353
0.460
0.562
0.659
0.750
0.835
0.911
1.000
Y1
0.000
0.123
0.240
0.353
0.460
0.561
0.657
0.748
0.832
0.908
1.000
Y1
0.000
0.123
56.8
56.1
55.5
54.9
54.3
53.8
53.3
53.0
53.9
T(m+1)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.3
53.0
53.9
T(m+1)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.2
53.0
53.9
T(m+1)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.2
0.240
0.352
0.459
0.560
0.656
0.746
0.830
0.906
1.000
Y1
0.000
0.123
0.240
0.352
0.459
0.560
0.655
0.745
0.829
0.905
1.000
Y1
0.000
0.123
0.240
0.352
0.459
0.560
0.655
0.745
0.828
0.904
1.000
Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.655
0.744
0.828
53.0
53.9
T(m+1)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
T(m+1)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
T(m+1)
58.0
57.4
56.8
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
T(m+1)
58.0
0.904
1.000
Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.655
0.744
0.827
0.903
1.000
Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000
Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000
Y1
0.000
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000
Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000
Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000
Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
53.2
52.9
53.9
T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
T(m+1)
0.827
0.903
1.000
Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000
Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000
Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000
Y1
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000
Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000
Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000
Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
53.7
53.2
52.9
53.9
T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
T(m+1)
0.744
0.827
0.903
1.000
Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000
Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000
Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000
Y1
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
T(m+1)
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000
Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000
Y1
0.000
0.123
0.240
0.352
0.458
0.559
0.654
0.744
0.827
0.903
1.000
Mtodo de Newton-Raphson para ELV con ecuacin de Margules con treinta iteracion
Metanol Cloroformo
A= 8.0724 6.9371
B=
1575 1171.2
C= 238.87
227
T(m)
58.0
57.6
57.2
56.8
56.3
55.9
55.5
55.1
54.7
54.3
53.9
T(m)
58.0
57.3
56.4
55.5
54.8
54.2
53.7
53.4
53.1
53.1
53.9
T(m)
58.0
57.2
55.9
54.7
53.6
52.9
52.4
52.1
52.0
52.2
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
Margules
A12=
0.0882
A21= 1.359044
Teb1=
Teb2=
P=

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
663
654
645
636
628
619
610
602
593
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
657
638
619
603
591
582
575
570
569
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
672
654
628
602
581
566
556
550
548
553
53.9 Cloroformo
58.0 Metanol
585 mmHg
Psat(2)
585
575
565
556
546
537
528
519
510
501
492
Psat(2)
585
569
548
528
511
498
489
482
476
476
492
Psat(2)
585
565
537
510
488
472
462
457
454
459
Pcalc
585.0
600.3
631.9
668.3
698.0
715.2
719.4
713.8
699.7
669.4
585.0
Pcalc
585.0
594.0
613.6
637.3
657.5
669.6
672.9
669.5
660.5
640.9
585.0
Pcalc
585.0
590.2
602.2
617.3
630.6
638.8
641.3
639.3
633.8
621.5
8.0724
1574.99
238.87
F(T)
0.00
15.35
46.93
83.27
113.05
130.18
134.44
128.78
114.74
84.41
0.00
F(T)
0.00
8.99
28.59
52.33
72.53
84.56
87.91
84.49
75.50
55.91
0.00
F(T)
0.00
5.24
17.21
32.33
45.60
53.76
56.26
54.32
48.77
36.52
F(T)
55.24
57.85
62.22
66.97
70.80
73.05
73.75
73.30
71.99
69.28
61.99
F(T)
55.24
57.06
59.91
63.00
65.54
67.09
67.64
67.46
66.80
65.47
61.99
F(T)
55.24
56.60
58.49
60.47
62.11
63.14
63.57
63.56
63.33
62.91
53.9
T(m)
58.0
57.1
55.7
54.2
52.9
52.0
51.5
51.2
51.2
51.6
53.9
T(m)
58.0
57.0
55.5
53.8
52.4
51.5
50.9
50.7
50.7
51.2
53.9
T(m)
58.0
57.0
55.4
53.6
52.1
51.1
50.6
50.3
50.4
51.0
53.9
T(m)
58.0
57.0
1.000
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
1.000
0.900
1.00
3.89
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
652
622
591
566
549
539
534
534
542
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
651
618
584
557
539
529
524
524
534
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
650
616
580
551
532
522
517
518
530
585

1.09
1.32
1.00
0.99
672
650
492
Psat(2)
585
563
531
498
473
455
445
440
439
447
492
Psat(2)
585
562
527
491
463
445
434
430
430
440
492
Psat(2)
585
561
524
487
457
438
427
423
424
435
492
Psat(2)
585
561
585.0
Pcalc
585.0
588.0
595.3
604.7
613.2
618.6
620.4
619.4
616.1
608.6
585.0
Pcalc
585.0
586.8
591.1
596.9
602.3
605.8
607.0
606.5
604.6
600.2
585.0
Pcalc
585.0
586.0
588.6
592.2
595.5
597.7
598.6
598.4
597.3
594.7
585.0
Pcalc
585.0
585.6
0.00
F(T)
0.00
3.05
10.29
19.73
28.25
33.63
35.42
34.37
31.07
23.61
0.00
F(T)
0.00
1.77
6.12
11.95
17.32
20.79
22.04
21.51
19.60
15.16
0.00
F(T)
0.00
1.02
3.63
7.20
10.54
12.75
13.60
13.36
12.28
9.69
0.00
F(T)
0.00
0.59
61.99
F(T)
55.24
56.33
57.62
58.90
59.92
60.60
60.93
61.03
61.06
61.23
61.99
F(T)
55.24
56.17
57.11
57.93
58.56
58.99
59.25
59.41
59.60
60.13
61.99
F(T)
55.24
56.08
56.80
57.34
57.72
57.99
58.19
58.38
58.67
59.43
61.99
F(T)
55.24
56.03
55.3
53.5
52.0
50.9
50.3
50.1
50.2
50.8
53.9
T(m)
58.0
57.0
55.3
53.4
51.9
50.8
50.2
49.9
50.0
50.7
53.9
T(m)
58.0
57.0
55.2
53.4
51.8
50.7
50.1
49.9
49.9
50.7
53.9
10
T(m)
58.0
57.0
55.2
53.3
51.7
50.6
50.0
49.8
49.9
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
614
577
548
528
518
513
514
527
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
650
613
576
546
526
515
511
512
525
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
649
613
575
544
524
513
509
511
524
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
672
649
613
575
544
523
512
508
510
523
484
454
434
423
419
420
432
492
Psat(2)
585
560
522
483
452
431
420
416
417
430
492
Psat(2)
585
560
522
482
450
430
419
414
416
429
492
Psat(2)
585
560
521
481
450
429
418
413
415
587.1
589.3
591.4
592.8
593.3
593.3
592.7
591.2
585.0
Pcalc
585.0
585.3
586.3
587.6
588.9
589.7
590.1
590.1
589.8
588.9
585.0
Pcalc
585.0
585.2
585.8
586.6
587.3
587.9
588.1
588.1
588.0
587.5
585.0
Pcalc
585.0
585.1
585.4
585.9
586.4
586.7
586.9
586.9
586.8
2.15
4.32
6.39
7.78
8.35
8.25
7.66
6.17
0.00
F(T)
0.00
0.34
1.27
2.59
3.86
4.73
5.11
5.08
4.76
3.92
0.00
F(T)
0.00
0.20
0.75
1.55
2.33
2.87
3.12
3.12
2.96
2.49
0.00
F(T)
0.00
0.12
0.44
0.93
1.40
1.74
1.90
1.92
1.83
56.62
56.98
57.20
57.37
57.54
57.75
58.09
58.97
61.99
F(T)
55.24
55.99
56.51
56.77
56.89
57.00
57.14
57.35
57.73
58.68
61.99
F(T)
55.24
55.98
56.44
56.64
56.70
56.77
56.89
57.11
57.50
58.50
61.99
F(T)
55.24
55.97
56.41
56.56
56.59
56.63
56.74
56.96
57.36
50.6
53.9
11
T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.8
49.9
50.6
53.9
12
T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.6
53.9
13
T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.6
53.9
14
T(m)
58.0
0.900
1.000
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
1.000
1.02
1.00
2.45
3.89
523
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
649
613
574
543
523
512
507
509
522
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
649
612
574
543
522
511
507
509
522
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
649
612
574
543
522
511
507
508
522
585

1.09
1.00
672
428
492
Psat(2)
585
560
521
481
449
428
417
413
414
428
492
Psat(2)
585
560
521
481
449
428
417
413
414
427
492
Psat(2)
585
560
521
481
449
428
417
412
414
427
492
Psat(2)
585
586.6
585.0
Pcalc
585.0
585.1
585.3
585.6
585.8
586.1
586.2
586.2
586.1
586.0
585.0
Pcalc
585.0
585.0
585.2
585.3
585.5
585.6
585.7
585.7
585.7
585.6
585.0
Pcalc
585.0
585.0
585.1
585.2
585.3
585.4
585.4
585.4
585.4
585.4
585.0
Pcalc
585.0
1.58
0.00
F(T)
0.00
0.07
0.26
0.55
0.85
1.05
1.16
1.18
1.14
1.00
0.00
F(T)
0.00
0.04
0.15
0.33
0.51
0.64
0.70
0.72
0.70
0.63
0.00
F(T)
0.00
0.02
0.09
0.20
0.31
0.39
0.43
0.44
0.44
0.40
0.00
F(T)
0.00
58.38
61.99
F(T)
55.24
55.96
56.38
56.52
56.52
56.54
56.65
56.87
57.27
58.31
61.99
F(T)
55.24
55.96
56.37
56.49
56.48
56.49
56.60
56.81
57.22
58.26
61.99
F(T)
55.24
55.96
56.36
56.47
56.45
56.46
56.56
56.78
57.19
58.23
61.99
F(T)
55.24
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.6
53.9
15
T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
16
T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
17
T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
649
612
574
543
522
511
507
508
522
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
649
612
574
543
522
511
507
508
522
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
649
612
574
543
522
511
507
508
521
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
672
649
612
574
543
522
511
507
560
521
481
449
428
416
412
414
427
492
Psat(2)
585
560
521
481
448
428
416
412
414
427
492
Psat(2)
585
560
521
481
448
427
416
412
414
427
492
Psat(2)
585
560
521
481
448
427
416
412
585.0
585.1
585.1
585.2
585.2
585.3
585.3
585.3
585.3
585.0
Pcalc
585.0
585.0
585.0
585.1
585.1
585.1
585.2
585.2
585.2
585.2
585.0
Pcalc
585.0
585.0
585.0
585.0
585.1
585.1
585.1
585.1
585.1
585.1
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.1
585.1
585.1
0.01
0.05
0.12
0.18
0.23
0.26
0.27
0.27
0.25
0.00
F(T)
0.00
0.01
0.03
0.07
0.11
0.14
0.16
0.17
0.17
0.16
0.00
F(T)
0.00
0.00
0.02
0.04
0.07
0.09
0.10
0.10
0.10
0.10
0.00
F(T)
0.00
0.00
0.01
0.03
0.04
0.05
0.06
0.06
55.95
56.36
56.46
56.44
56.44
56.54
56.75
57.17
58.21
61.99
F(T)
55.24
55.95
56.35
56.46
56.43
56.43
56.53
56.74
57.15
58.20
61.99
F(T)
55.24
55.95
56.35
56.45
56.42
56.43
56.52
56.73
57.14
58.19
61.99
F(T)
55.24
55.95
56.35
56.45
56.42
56.42
56.52
56.73
49.8
50.5
53.9
18
T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
19
T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
20
T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
21
T(m)
0.800
0.900
1.000
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
1.09
1.02
1.00
1.72
2.45
3.89
508
521
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
649
612
574
543
522
511
507
508
521
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
649
612
574
543
522
511
507
508
521
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
649
612
574
543
522
511
507
508
521
585
414
427
492
Psat(2)
585
560
521
481
448
427
416
412
413
427
492
Psat(2)
585
560
521
481
448
427
416
412
413
427
492
Psat(2)
585
560
521
481
448
427
416
412
413
427
492
Psat(2)
585.1
585.1
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
0.06
0.06
0.00
F(T)
0.00
0.00
0.01
0.02
0.02
0.03
0.04
0.04
0.04
0.04
0.00
F(T)
0.00
0.00
0.00
0.01
0.01
0.02
0.02
0.02
0.02
0.03
0.00
F(T)
0.00
0.00
0.00
0.01
0.01
0.01
0.01
0.01
0.02
0.02
0.00
F(T)
57.14
58.19
61.99
F(T)
55.24
55.95
56.35
56.45
56.42
56.42
56.51
56.73
57.14
58.19
61.99
F(T)
55.24
55.95
56.35
56.45
56.42
56.42
56.51
56.72
57.13
58.18
61.99
F(T)
55.24
55.95
56.35
56.45
56.42
56.42
56.51
56.72
57.13
58.18
61.99
F(T)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
22
T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
23
T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
24
T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
1.000
0.900
0.800
0.700
0.600
0.500
0.400
1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
649
612
574
543
522
511
507
508
521
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
649
612
574
543
522
511
507
508
521
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
649
612
574
543
522
511
507
508
521
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.00
0.99
0.97
0.96
0.97
1.02
1.13
672
649
612
574
543
522
511
585
560
521
481
448
427
416
412
413
427
492
Psat(2)
585
560
521
481
448
427
416
412
413
427
492
Psat(2)
585
560
521
481
448
427
416
412
413
427
492
Psat(2)
585
560
521
481
448
427
416
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
0.00
0.00
0.00
0.00
0.01
0.01
0.01
0.01
0.01
0.01
0.00
F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.01
0.01
0.00
F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
55.24
55.95
56.35
56.45
56.42
56.42
56.51
56.72
57.13
58.18
61.99
F(T)
55.24
55.95
56.35
56.45
56.42
56.42
56.51
56.72
57.13
58.18
61.99
F(T)
55.24
55.95
56.35
56.45
56.42
56.42
56.51
56.72
57.13
58.18
61.99
F(T)
55.24
55.95
56.35
56.45
56.42
56.42
56.51
49.7
49.8
50.5
53.9
25
T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
26
T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
27
T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
28
T(m)
0.700
0.800
0.900
1.000
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
1.18
1.09
1.02
1.00
1.34
1.72
2.45
3.89
507
508
521
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
649
612
574
543
522
511
507
508
521
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
649
612
574
543
522
511
507
508
521
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
649
612
574
543
522
511
507
508
521
585
412
413
427
492
Psat(2)
585
560
521
481
448
427
416
412
413
427
492
Psat(2)
585
560
521
481
448
427
416
412
413
427
492
Psat(2)
585
560
521
481
448
427
416
412
413
427
492
Psat(2)
585.0
585.0
585.0
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
0.00
0.00
0.00
0.00
F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
F(T)
56.72
57.13
58.18
61.99
F(T)
55.24
55.95
56.35
56.45
56.42
56.41
56.51
56.72
57.13
58.18
61.99
F(T)
55.24
55.95
56.35
56.45
56.42
56.41
56.51
56.72
57.13
58.18
61.99
F(T)
55.24
55.95
56.35
56.45
56.42
56.41
56.51
56.72
57.13
58.18
61.99
F(T)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
29
T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
30
T(m)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
X1
X2
0.000
0.100
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
1.000
1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
649
612
574
543
522
511
507
508
521
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
649
612
574
543
522
511
507
508
521
585

1.09
1.32
1.46
1.52
1.49
1.40
1.29
1.18
1.09
1.02
1.00
1.00
0.99
0.97
0.96
0.97
1.02
1.13
1.34
1.72
2.45
3.89
672
649
612
574
543
522
511
507
508
521
585
585
560
521
481
448
427
416
412
413
427
492
Psat(2)
585
560
521
481
448
427
416
412
413
427
492
Psat(2)
585
560
521
481
448
427
416
412
413
427
492
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
Pcalc
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
585.0
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
F(T)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
55.24
55.95
56.35
56.45
56.42
56.41
56.51
56.72
57.13
58.18
61.99
F(T)
55.24
55.95
56.35
56.45
56.42
56.41
56.51
56.72
57.13
58.18
61.99
F(T)
55.24
55.95
56.35
56.45
56.42
56.41
56.51
56.72
57.13
58.18
61.99
es con treinta iteraciones
T(m+1)
58.0
57.3
56.4
55.5
54.8
54.2
53.7
53.4
53.1
53.1
53.9
T(m+1)
58.0
57.2
55.9
54.7
53.6
52.9
52.4
52.1
52.0
52.2
53.9
T(m+1)
58.0
57.1
55.7
54.2
52.9
52.0
51.5
51.2
51.2
51.6
Y1 teorica
Y1 (EXP)
T(C) EXP
0.000
0.150
0.328
0.502
0.648
0.753
0.822
0.864
0.896
0.935
1.000
0.000
0.180
0.200
0.232
0.239
0.655
0.764
0.771
0.784
0.793
1.000
61
60
59
58
55
53
48
48
46
46
45
Y1
0.000
0.148
0.319
0.481
0.614
0.709
0.772
0.814
0.848
0.897
1.000
Y1
0.000
0.148
0.314
0.468
0.591
0.679
0.738
0.779
0.816
0.871
53.9
T(m+1)
58.0
57.0
55.5
53.8
52.4
51.5
50.9
50.7
50.7
51.2
53.9
T(m+1)
58.0
57.0
55.4
53.6
52.1
51.1
50.6
50.3
50.4
51.0
53.9
T(m+1)
58.0
57.0
55.3
53.5
52.0
50.9
50.3
50.1
50.2
50.8
53.9
T(m+1)
58.0
57.0
1.000
Y1
0.000
0.147
0.311
0.460
0.576
0.660
0.716
0.756
0.794
0.853
1.000
Y1
0.000
0.147
0.309
0.454
0.567
0.647
0.702
0.742
0.780
0.842
1.000
Y1
0.000
0.147
0.308
0.451
0.561
0.639
0.693
0.732
0.771
0.834
1.000
Y1
0.000
0.147
55.3
53.4
51.9
50.8
50.2
49.9
50.0
50.7
53.9
T(m+1)
58.0
57.0
55.2
53.4
51.8
50.7
50.1
49.9
49.9
50.7
53.9
T(m+1)
58.0
57.0
55.2
53.3
51.7
50.6
50.0
49.8
49.9
50.6
53.9
T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.8
49.9
0.308
0.449
0.558
0.634
0.687
0.727
0.766
0.830
1.000
Y1
0.000
0.147
0.307
0.448
0.555
0.631
0.684
0.723
0.762
0.827
1.000
Y1
0.000
0.146
0.307
0.447
0.554
0.629
0.681
0.721
0.760
0.825
1.000
Y1
0.000
0.146
0.307
0.447
0.553
0.628
0.680
0.719
0.759
50.6
53.9
T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.6
53.9
T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.6
53.9
T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.6
53.9
T(m+1)
58.0
0.824
1.000
Y1
0.000
0.146
0.307
0.447
0.553
0.628
0.679
0.718
0.758
0.823
1.000
Y1
0.000
0.146
0.307
0.447
0.553
0.627
0.679
0.718
0.757
0.822
1.000
Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.679
0.718
0.757
0.822
1.000
Y1
0.000
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.757
0.822
1.000
Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.757
0.822
1.000
Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.822
1.000
Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
49.8
50.5
53.9
T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
T(m+1)
0.756
0.822
1.000
Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000
Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000
Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000
Y1
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000
Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000
Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000
Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
49.7
49.8
50.5
53.9
T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
T(m+1)
0.717
0.756
0.821
1.000
Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000
Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000
Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000
Y1
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
T(m+1)
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000
Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000
Y1
0.000
0.146
0.307
0.446
0.552
0.627
0.678
0.717
0.756
0.821
1.000
Resultados ELV NO IDEAL cloroformo - metanol

ecuacion de VAN LAAR
X1
T(C) Exp
A12=
A21=
T (C) Teorica
0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1.0
61.0
60.0
59.0
58.0
55.0
53.0
48.0
48.0
46.0
46.0
45.0
58.0
57.4
56.7
56.1
55.5
54.9
54.3
53.7
53.2
52.9
53.9
0.0882
1.3590
Y exp
0.0000
0.1797
0.2001
0.2319
0.2395
0.6552
0.7642
0.7712
0.7839
0.7934
1.0000
Y teorica
0.0000
0.1228
0.2402
0.3520
0.4583
0.5591
0.6542
0.7435
0.8267
0.9027
1.0000
ELV cloroformo - metanol X versus Y

Ecuacin de van Laar
1.0
0.9
0.8
0.7
Y1
0.6
0.5
0.4
0.3
0.2
0.1
0.0
0.0
0.1
0.2
0.3
0.4
0.5
X1
0.6
0.7
0.8
0.9
X1
Experimental
Teorico Van Laar
T (C)
T versus x,y ELV cloroformo-metanol

Ecuacin de van Laar
60
59
58
57
56
55
54
53
52
51
50
49
48
47
46
45
44
43
42
41
40
0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
x,y
0.9
1.0
Liquido Experimental
Liquido Teorico
Vapor Experimental
Vapor Teorico
0.9
1.0
Resultados ELV NO IDEAL cloroformo - metanol

ecuacion de Margules
X1
T(C) Exp
A12=
A21=
T (C) Teorica
0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1.0
61.0
60.0
59.0
58.0
55.0
53.0
48.0
48.0
46.0
46.0
45.0
58.0
56.9
55.2
53.3
51.7
50.6
50.0
49.7
49.8
50.5
53.9
0.0882
1.3590
Y exp
0.0000
0.1797
0.2001
0.2319
0.2395
0.6552
0.7642
0.7712
0.7839
0.7934
1.0000
Y teorica
0.0000
0.1464
0.3067
0.4464
0.5522
0.6265
0.6781
0.7170
0.7564
0.8214
1.0000
ELV cloroformo - metanol X versus Y

Ecuacin de Margules
1.0
0.9
0.8
0.7
Y1
0.6
0.5
0.4
0.3
0.2
0.1
0.0
0.0
0.1
0.2
0.3
0.4
0.5
X1
0.6
0.7
0.8
0.9
X1
Experimental
Teorico Margules
T (C)
T versus x,y ELV cloroformo-metanol

Ecuacin de Margules
60
59
58
57
56
55
54
53
52
51
50
49
48
47
46
45
44
43
42
41
40
0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
x,y
0.9
1.0
Liquido Experimental
Liquido Teorico
Vapor Experimental
Vapor Teorico
0.9
1.0

Practica 4 ELV No Ideal Cloroformo-Metanol

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Practica 4 ELV No Ideal Cloroformo-Metanol

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ELV NO IDEAL

SISTEMA CLOROFORMO (1) - METANOL (2)

INTRODUCE EN LA TABLA VERDE LOS DATOS EXPERIMENTALES

CORRELACION DE DATOS PARA EL CLCULO DE FRACCION MOL DE FASE VAPOR

indice de refraccin /(liq)

indice de refraccin /(liq)

TEMPERATURA DE EBULLICION (PUROS)=

Parametros A(12), A(21)

Determinacion del Parmetro A12 por mi

fraccin mol cloroformo X1

del Parmetro A12 por minimos cuadrados

y = 1.3009x2 - 0.8412x + 0.0882

Determinacion del Parmetro A21 por minimos cuadrados

A21 por minimos cuadrados

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

ar con treinta iteraciones

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)

gamma(1) gamma(2) Psat(1)