Ideal Gas Model

fi = yi P

i 1 i i Departure Functions yP fi = fi = i yi P i i Real Ideal Solution Solution Model Model

Henrys Law Ideal Solution

f1 = h1 f1 = f1
o

f1

Real Solution

Excess i = 1 Properties fi = xi fi i 1 fi = i xi fi
1

Lewis/Randall Ideal Solution 0 x1 or y1 1

450

80
70

100

78
400 P (mm Hg)

76 74
P (mm Hg)

65

95
60 55 50 45 40 35

T(oC)

70 68 66

T( oC) 85 80 75
0 0.5 x2-propanol, y2-propanol 1

350

72

90

300

250

64 62
30

200 0 0.5 xmethanol, y methanol 1

60 0 0.5 xmethanol, ymethanol 1

0.5 x2-propanol, y2-propanol

Methanol-ethanol system
3

2-Propanol + water
4