Scribd Logo
Carica

Benvenuto in Scribd!

  • Chem 212 Provide The Products For The Following Reactions. Be

    Caricato da

    kevinamy
    51 visualizzazioni1 pagina
    Be sure to: Dienes and Diels-Alder Problems 1) indicate all relevant stereochemistry. ANSWERS 2) indicate major and minor when mixtures are formed. 3) indicate which product is the kinetic product and which is the thermodynamic product if there is a difference between the two.

    Descrizione originale:

    Titolo originale

    Chem 212 Provide the Products for the Following Reactions. Be

    Copyright

    © Attribution Non-Commercial (BY-NC)

    Formati disponibili

    PDF, TXT o leggi online da Scribd

    Hai trovato utile questo documento?

    Questo contenuto è inappropriato?

    Segnala questo documento
    Be sure to: Dienes and Diels-Alder Problems 1) indicate all relevant stereochemistry. ANSWERS 2) indicate major and minor when mixtures are formed. 3) indicate which product is the kinetic product and which is the thermodynamic product if there is a difference between the two.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Scarica in formato PDF, TXT o leggi online su Scribd
    Segnala contenuti inappropriati
    51 visualizzazioni1 pagina

    Chem 212 Provide The Products For The Following Reactions. Be

    Caricato da

    kevinamy
    Be sure to: Dienes and Diels-Alder Problems 1) indicate all relevant stereochemistry. ANSWERS 2) indicate major and minor when mixtures are formed. 3) indicate which product is the kinetic product and which is the thermodynamic product if there is a difference between the two.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Scarica in formato PDF, TXT o leggi online su Scribd
    Segnala contenuti inappropriati
    di 1

    Chem 212 Provide the products for the following reactions.

    Be sure to:
    Dienes and Diels-Alder Problems 1) indicate all relevant stereochemistry.
    ANSWERS
    2) indicate major and minor when mixtures are formed.
    3) indicate which product is the kinetic product and which is the thermodynamic Br
    product if there is a difference between the two. Br

    Br Br
    OEt Br
    Br HBr
    Cl
    Br2 AgNO3
    (1 eq.) Br (1 eq.)
    Br
    Br EtOH
    EtO
    Br
    AgNO3 OEt
    Cl
    Br EtOH
    HBr
    I Br
    HI EtO (1 eq.)
    (1 eq.)
    Br
    I
    Br H2O OH
    I
    Br
    I
    Br
    Br Br
    Br Br Br Br
    Br Br Br Br Br Br
    HBr Br
    Br2
    (1 eq.) (2 eq.)
    Br Br Br Br
    Br Br
    Br
    + enantiomers
    Br Br Br
    Br Br Br
    Br Br Br
    + enantiomer
    and 2 others
    Me Me
    Me Me Me Me
    CO2Me CO2Me
    CO2Me CO2Me CO2Me CO2Me
    ∆ + ∆ ∆
    + +
    CO2Me MeO2C Me
    CO2Me CO2Me MeO2C CO2Me
    + enantiomer Me
    Me H Me
    + enantiomer
    ∆ Me Me
    + CO2Me CO2Me
    ∆ ∆ CO2Me
    + +
    Me
    O CO2Me CO2Me CO2Me
    CO2Me CO2Me
    O CO2Me
    + ∆ H Me
    CO2Me + enantiomer
    O and 2 others
    CO2Me
    ∆
    +
    CO2Me CO2Me
    CO2Me + ∆ CO2Me
    + enantiomers
    CO2Me CO2Me
    O CO2Me

    CO2Me + enantiomers
    OMe
    Br
    1. LDA (2 eq.)
    ∆ CO2Me 2.
    + enantiomers O O
    Br
    ∆ heat
    OMe
    OMe
    ∆ + enantiomer
    + O
    MeO Ph
    MeO CO2Me
    O OMe CO2Me CO2Me
    + ∆
    MeO OMe O
    ∆ CO2Me CO2Me

    OMe EtO OMe


    OEt
    O ∆ ∆ CO2Me
    ∆ OEt
    CO2Me + enantiomer
    + enantiomers and 2 others
    + enantiomer

    Potrebbero piacerti anche