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P R A V E E N : I S CS p e c i m e n Q u e s t i o n P a p e r 2 0 1 4 C H E MI S T R YP A P E R 1 ( T H E O R Y )
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ISC Specimen Question Paper 2014 CHEMISTRY PAPER 1 (THEORY)

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ISC Specimen Question Paper 2014 CHEMISTRY PAPER 1 (THEORY)

( T h r e eH o u r s ) ( C a n d i d a t e sa r ea l l o w e da d d i t i o n a l 1 5mi n u t e sf o r o n l yr e a d i n gt h ep a p e r . T h e ymu s t N O Ts t a r t w r i t i n gd u r i n gt h i st i me . ) A n s w e r a l l q u e s t i o n si nP a r t I a n ds i xq u e s t i o n sf r o mP a r t I I , c h o o s i n gt w oq u e s t i o n s f r o mS e c t i o nA , t w of r o mS e c t i o nBa n dt w of r o mS e c t i o nC . A l l w o r k i n g , i n c l u d i n gr o u g hw o r k , s h o u l db ed o n eo nt h es a mes h e e t a s , a n da d j a c e n t t o , t h er e s t o f t h ea n s w e r . T h ei n t e n d e dma r k sf o r q u e s t i o n so r p a r t so f q u e s t i o n sa r eg i v e ni nb r a c k e t s[ ] . B a l a n c e de q u a t i o n smu s t b eg i v e nw h e r e v e r p o s s i b l ea n dd i a g r a msw h e r et h e ya r eh e l p f u l . Wh e ns o l v i n gn u me r i c a l p r o b l e ms , a l l e s s e n t i a l w o r k i n gmu s t b es h o w n . I nw o r k i n go u t p r o b l e msu s et h ef o l l o w i n gd a t a : G a sc o n s t a n t R=1 . 9 8 7c a l d e g 1mo l 1=8 . 3 1 4J K 1mo l 1=0 . 0 8 2 1d m3a t mK 1 mo l 1 1l a t m =1d m3a t m =1 0 1 . 3J . 1F a r d a y=9 6 5 0 0C o u l o mb s . A v a g a d r o sn u mb e r =6 . 0 2 3 1 0 2 3 . P A R TI ( 2 0Ma r k s ) A n s w e r a l l q u e s t i o n s . Q u e s t i o n1 ( a ) F i l l i nt h eb l a n k sb yc h o o s i n gt h ea p p r o p r i a t ew o r d / w o r d sf r o mt h o s eg i v e ni nt h e b r a c k e t s : ( a c e t a l d e h y d e , s a l t s o l u t i o n , 0 . 6 8 , R , f o r ma l d e h y d e , b u f f e r s o l u t i o n , 0 . 5 2 4 , i , c a l c i u m f o r ma t e , 5 0mi n u t e s , b e l o w , 4 5mi n u t e s , 0 . 7 4 , v a n t H o f f f a c t o r , R a o u l t sL a w , w e a k , s t r o n g , i n c r e a s e s , d e c r e a s e s , p o s i t i v e , n e g a t i v e , a b o v e . ) [ 5 ] ( i ) T h es o l u t i o no b t a i n e db ymi x i n ga p p r o p r i a t ea mo u n t o f _ _ _ _ _ _ _ b a s ea n di t ss a l t w i t hs t r o n ga c i di sc a l l e d_ _ _ _ _ _ _ _ . ( i i ) A na q u e o u ss o l u t i o no f g l u c o s eb o i l s_ _ _ _ _ _1 0 0 o Ca n df r e e z e s_ _ _ _ _ _0 o C . ( i i i ) T h er a t i oo f t h eo b s e r v e dv a l u eo f ac o l l i g a t i v ep r o p e r t yt ot h en o r ma l v a l u eo f t h e s a mep r o p e r t yi st e r me da s_ _ _ _ _ _ _ _a n di sr e p r e s e n t e db yl e t t e r _ _ _ _ _ _ _ . ( i v ) Wh e nami x t u r eo f c a l c i u ma c e t a t ea n d_ _ _ _ _ _ _i ss u b j e c t e dt od r yd i s t i l l a t i o n _ _ _ _ _ _ _ _i so b t a i n e d . ( v ) A_ _ _ _ _ _ _ _ _c a t a l y s t i n c r e a s e st h er a t eo f ac h e mi c a l r e a c t i o nw h i l ean e g a t i v e c a t a l y s t _ _ _ _ _ _ _ _ _t h er a t eo f t h er e a c t i o n . I S CS p e c i me nQ u e s t i o nP a p e r 2 0 1 4 2 ( b ) C o mp l e t et h ef o l l o w i n gs t a t e me n t sb ys e l e c t i n gt h ec o r r e c t a l t e r n a t i v ef r o mt h e c h o i c e sg i v e n : [ 5 ] ( i ) As a t u r a t e ds o l u t i o no f A g 2 C r O 4i s2 1 0 4mo l e s / l i t r e . I t ss o l u b i l i t yp r o d u c t i s : ( 1 ) 4 4 1 0 8 ( 2 ) 3 2 1 0 1 1 ( 3 ) 2 8 1 0 9 ( 4 ) 5 6 1 0 1 2 ( i i ) Amo l e c u l ec o n t a i n sa t o msxa n dys ot h a t xo c c u r sa t t h ec o r n e r so f t h ec u b ew h i l e ya t t h ef a c ec e n t r e s . T h ef o r mu l ao f t h emo l e c u l ec a nb e : ( 1 ) x y 3 ( 2 ) X y ( 3 ) x 2 y ( 4 ) x y 2 ( i i i ) 1 5mo l e so f h y d r o g e n( H 2 ) a n d5 . 2mo l e so f i o d i n e( I 2 ) a r emi x e da n da l l o w e dt o a t t a i ne q u i l i b r i u ma t 5 0 0 o C . A t e q u i l i b r i u m, t h ec o n c e n t r a t i o no f H I i sf o u n dt ob e 1 0mo l e s . T h ee q u i l i b r i u mc o n s t a n t f o r t h ef o r ma t i o nH I i s : ( 1 ) 5 0 ( 2 ) 1 5 ( 3 ) 1 0 0 ( 4 ) 2 5 ( i v ) G l u c o s eg i v e ss i l v e r mi r r o r t e s t w i t hT o l l e n sr e a g e n t . I t s h o w st h ep r e s e n c eo f : ( 1 ) A l c o h o l i cg r o u p ( 2 ) K e t o n i cg r o u p ( 3 ) A l d e h y d i cg r o u p ( 4 ) A c i d i cg r o u p

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Popular Posts I S CS p e c i m e nQ u e s t i o n P a p e r 2 0 1 4C H E M I S T R Y P A P E R1( T H E O R Y ) I S CS p e c i m e nQ u e s t i o n P a p e r 2 0 1 4C H E M I S T R Y P A P E R1( T H E O R Y ) ( T h r e eH o u r s ) ( C a n d i d a t e s a r ea l l o w e d a d d i t i o n a l 1 5m i n u t e s f o r o n l y r e a d . . . I S CS p e c i m e nQ u e s t i o n P a p e r 2 0 1 4B I O L O G Y P A P E R1( T H E O R Y ) I S CS p e c i m e nQ u e s t i o n P a p e r 2 0 1 4B I O L O G Y P A P E R1( T H E O R Y ) ( B o t a n y a n dZ o o l o g y ) ( T h r e eh o u r s ) ( C a n d i d a t e s a r ea l l o w e d a d d i t i o n a l 1 5m i . . . I S C C H E M I S T R Y S P E C I M E N P A P E R2 0 1 3 I S C C H E M I S T R YS P E C I M E N P A P E R2 0 1 3 p r a v i k r a v i . b l o g s p o t . i n I S CS p e c i m e nQ u e s t i o n P a p e r 2 0 1 4P H Y S I C A L E D U C A T I O N I S CS p e c i m e nQ u e s t i o n P a p e r 2 0 1 4P H Y S I C A L E D U C A T I O NP A P E R1 ( T H E O R Y ) ( T h r e eh o u r s ) ( C a n d i d a t e s a r ea l l o w e d a d d i t i o n a l 1 5m i n u t e s f o r . . . K E A MC E N T R A L I S E D A L L O T M E N TT O P R O F E S S I O N A L D E G R E EC O U R S E S2 0 1 3 ( E X C E P TM B B S / B D S ) K E A MC E N T R A L I S E D A L L O T M E N TT O P R O F E S S I O N A L D E G R E EC O U R S E S2 0 1 3 ( E X C E P TM B B S / B D S ) T h ea c t i v i t i e s r e l a t e dt o t h ea l l o t m e n t t o P r o f e s s i o n a l . . .

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M A I NA N N O U N C E M E N T S F O RK E R A L AP L U SO N E A L L O T M E N T S2 0 1 3 C o m m u n i t y R a n k G e n e r a t o r M o d u l ei s n o w a v a i l a b l ei nA d m i nU s e r N o n J o i n i n g ( S p o r t s ) L i n k s a r en o wa v a i l a b l ei nH I T C U s e r . C o m p l e t eC o n f i r m . . . I S CP H Y S I C SS Y L U B U S 2 0 1 2 2 0 1 3 I S CP H Y S I C SS Y L U B U S 2 0 1 2 2 0 1 3P H Y S I C S ( 8 6 1 ) A i m s : 1 . T oe n a b l e c a n d i d a t e s t oa c q u i r e k n o w l e d g ea n dt od e v e l o p a nu n d e r s t a n d i n g. . . M A Y A N N U R K A V U P O O R A M M A Y A N N U R K A V U P O O R A M P e o p l eo f M a y a n n u r a n d K o n d a z h y c e l e b r a t e dt h e " M a . . . ( n ot i t l e )

P R A V E E N : I S CS p e c i m e n Q u e s t i o n P a p e r 2 0 1 4 C H E MI S T R YP A P E R 1 ( T H E O R Y )
( v ) I nt h ef o r ma t i o no f K 4 [ F e ( C N ) 6 ] , t h eh y b r i d i s a t i o ni n v o l v e di s : ( 1 ) d s p 2 ( 2 ) d 2 s p 3 ( 3 ) s p 3 d 2 ( 4 ) s p 3 I S CS p e c i me nQ u e s t i o nP a p e r 2 0 1 4 3 ( c ) A n s w e r t h ef o l l o w i n gq u e s t i o n s : [ 5 ] ( i ) Wh y , F e 2 +h a ss ma l l e r r a d i u st h a nMn 2 +? ( i i ) Wr i t et h eN e r n s t e q u a t i o nf o r t h ef o l l o w i n gc e l l r e a c t i o n : Z n ( s ) 22Z n( a q ) C u( a q ) C u ( s ) ++ ( i i i ) D r a wt h es t r u c t u r eo f i s o me r sf o r mo l e c u l a r f o r mu l aC 3 H 6 C l 2w h i c hc a ne x h i b i t o p t i c a l i s o me r i s m. ( i v ) Wh a t a r et h ep r o d u c t sf o r me dw h e np h e n o l a n dn i t r o b e n z e n ea r et r e a t e ds e p a r a t e l y w i t hami x t u r eo f c o n c . s u l p h u r i ca c i da n dc o n c . n i r i ca c i d ? ( v ) H o ww i l l y o up r e p a r e2 me t h y l p r o p a n2o l f r o m me t h y l ma g n e s i u mb r o mi d e . G i v eb a l a n c e de q u a t i o n s . ( d ) Ma t c ht h ef o l l o w i n g : [ 5 ] ( i ) S p e c i f i cc o n d u c t i v i t y( a ) A r g e n t i t e ( i i ) F r o t hf l o a t a t i o np r o c e s s( b ) T h e r mo s e t t i n gp l a s t i c s ( i i i ) A n i l i n e( c ) B i d e n t a t eL i g a n d ( i v ) B a k e l i t e( d ) O h m1c m1 ( v ) E t h y l e n ed i a mi n e( e ) D i a z o t i s a t i o n P A R TI I ( 5 0Ma r k s ) A n s w e r s i xq u e s t i o n sc h o o s i n gt w of r o mS e c t i o nA , t w of r o m S e c t i o nBa n dt w of r o mS e c t i o nC . S E C T I O ) A A n s w e r a n yt w oq u e s t i o n s . Q u e s t i o n2 ( a ) ( i ) Wh a t i st h emo l a r i t yo f as o l u t i o nw h i c hf r e e z e sa t 0 . 1 9 2 o Ca s s u mi n gn oc h a n g ei n t h es o l u t eb yr a i s i n gt h et e mp e r a t u r e , a t w h a t t e mp e r a t u r ew i l l t h es a mes o l u t i o n b o i l ?( K f f o r w a t e r i s1 8 6 o Ck gmo l 1a n dK bf o r w a t e r i s0 5 1 5 o Ck gmo l 1 ) [ 3 ] ( i i ) P h e n o l ( M. W. =9 4 ) a s s o c i a t e si nb e n z e n et oac e r t a i ne x t e n t t of o r md i me r . A s o l u t i o nc o n t a i n i n g2 0 go f p h e n o l i n1 0 0 0g mso f b e n z e n eh a si t sf r e e z i n gp o i n t d e c r e a s e db y0 6 9K . C a l c u l a t et h eo b s e r v e dmo l e c u l a r w e i g h t a n dt h ed e g r e eo f a s s o c i a t i o no f p h e n o l . ( K f f o r b e n z e n ei s5 1 2Kk gmo l 1 ) . [ 2 ] ( b ) I f t h r e ee l e me n t sP , Qa n dRc r y s t a l l i s ei nac u b i cs o l i dl a t t i cw i t hPa t o msa t t h ec o r n e r s , Qa t o msa t t h ec u b ec e n t r ea n dRa t o msa t t h ec e n t r eo f f a c e so f t h ec u b e , t h e nw r i t et h e [ 2 ] I S CS p e c i me nQ u e s t i o nP a p e r 2 0 1 4 4 f o r mu l ao f t h ec o mp o u n d . ( c ) S t a t et h eL eC h a t e l i e r sp r i n c i p l e . Wh a t a r et h ec o n d i t i o n sf o r g e t t i n gma x i mu my i e l do f a mmo n i ab yH a b e r sp r o c e s s ? N 2 ( g ) +3 H 2 ( g ) 2 N H 3 ( g ) +h e a t [ 3 ] Q u e s t i o n3 ( a ) ( i ) A ne l e me n t h a v i n gb c cg e o me t r yh a sa t o mi cma s s5 0 . C a l c u l a t et h ed e n s i t yo f u n i t c e l l , i f i t se d g el e n g t hi s2 9 0p m. [ 2 ] ( i i ) Wh a t i st h ee f f e c t o f d i l u t i o no nt h es t r e n g t ho f w e a ka c i d s ?E x p l a i n . [ 2 ] ( b ) T h ef o l l o w i n ge l e c t r o c h e mi c a l c e l l i ss e t u pa t 2 5 o C : Z n22Z n( a q ) ( 1 M) C d( a q ) ( 1 M) C d++ G i v e n : 22/ C d oo Z n/ Z nC d E07 6 3 V ; E04 0 3 V++= = [ 3 ] ( i ) Wr i t et h ec e l l r e a c t i o n . ( i i ) C a l c u l a t et h ee mf o f t h ec e l l . ( i i i ) C a l c u l a t et h ev a l u eG of o r t h ec e l l r e a c t i o na t 2 5 o C . ( i v ) I st h er e a c t i o ns p o n t a n e o u so r n o n s p o n t a n e o u s ? ( c ) F o r t h ef o l l o w i n gr e a c t i o n : 2 H 2 ( g ) +2 N O ( g ) 2 H 2 O ( l ) +N 2 ( g ) t h ef o l l o w i n gr a t ed a t aw a so b t a i n e d . [ 3 ] E x p e r i me n t [ N O ] ( mo l L 1 ) [ H 2 ] ( mo l L 1 ) R a t e( mo l L 1s e c 1 10 4 00 4 04 8 1 0 3 20 8 00 4 01 9 . 2 1 0 3 30 4 00 8 09 . 6 1 0 3 D e t e r mi n et h ef o l l o w i n g : ( i ) T h eo r d e r o f r e a c t i o nw i t hr e s p e c t t oN Oa n dH 2. ( i i ) T h er a t el a w . ( i i i ) T h ev a l u eo f r a t ec o n s t a n t . 4 4 5 o C 2 0 0a t m I S CS p e c i me nQ u e s t i o nP a p e r 2 0 1 4 5 Q u e s t i o n4

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Wh y A p p l eI s L o s i n g G F o r o r b u e n s dT oT h eS a m s u S a m s u n gi s g a i n i n gf a s B r a n d A p p l ei nt e r m s o f b r a n d a f f e c t i o nb u t w es e e m r e l u c t a n t t oa d m i t i t . I n I n t e r b r a n d ' s 2 0 1 3b r a n i n d e x , ab e n c h m a r k m e a s u r eo f b r a n dv a l u A p p l ec a m eo u t o nt o p e n d i n ga1 3y e a r r u nb C o c aC o l a . T h es i g n s a t h o u g ht h a t . . . R e l a t e dA r t i c l e s

( n ot i t l e ) M A G N E T I S MA N DS O M E D E T A I L SS a i l o r s u s e d m a g n e t i c c o m p a s s e s t o f i n dt h e i r w a y o nt h e w o r l d ' s o c e a n s a t l e a s t 1 0 0 0y e a r s a g o , b u t t h e . . .

A p p l eS t o c k T h i s We e k M o t l e y F o o l T M o b i l e F i g h t s B a c k a A p p l e ( N A S D A Q : A A P L t h e i P h o n e T u r n s 7 s t o c k u n d e r p e r f o r m e d S & P5 0 0a g a i nt h i s w e e a n dh a s f a l l e nn e a r l y 4 o v e r t h ep a s t t w ow e e k D u r i n gt h es a m ep e r i o d S & P5 0 0b a s i c a l l y r e m a f l a t . A p p l e ' s u n d e r p e r f o r m a n c ec o m a f t e r s i x m o n t h s o f

K e e nO n2 0 1 4 : A T p e p c h l e C & r u A n p c p h l e H a v i n gr e v i e w e d2 0 1 3 m e , R o b e r t S c o b l en o w t u r n s h i s G o o g l eG l a s s e n a b l e de y e s f o r w a r dt 2 0 1 4 . Wh a t , I a s k e dh i m a r eg o i n gt ob et h er e a b i gd e a l s i n2 0 1 4 ? A p p l ea n dA p p l e p r e d i c t s . F i r s t l y , t h e r e ' s g o i n gt ob ew h a t S c o b l

i P h o n e6L a t e s t R G u m a r o d r i s a nL i b e r t y V o i c e S o m ei n d u s t r y m e d i aa e x p e c t i n gA p p l e r e l e a s et w on e wm o d e l i P h o n e6l a t e r t h i s y e a r T h en e wi P h o n e s a r es t ob ea v a i l a b l ei n4 . 7a 5 . 5 i n c hs c r e e n s . T h i s w o u l dm a k eb o t hm o d e t h ei P h o n e6l a r g e r t h a t h ec u r r e n t 4 i n c hi P h o R e l a t e dA r t i c l e s

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P R A V E E N : I S CS p e c i m e n Q u e s t i o n P a p e r 2 0 1 4 C H E MI S T R YP A P E R 1 ( T H E O R Y )
( a ) ( i ) D e f i n et h et e r mss p e c i f i cc o n d u c t a n c ea n de q u i v a l e n t c o n d u c t a n c e . Wh a t i st h e r e l a t i o n s h i pb e t w e e ns p e c i f i ca n de q u i v a l e n t c o n d u c t a n c e ? [ 2 ] ( i i ) As o l u t i o nc o n t a i n i n g2go f a n h y d r o u sb a r i u mc h l o r i d ei n4 0 0ml o f w a t e r h a sa c o n d u c t i v i t yo f 0 0 0 5 8o h m1 c m1 . C a l c u l a t et h emo l a r a n de q u i v a l e n t c o n d u c t i v i t i e so f t h i ss o l u t i o n( a t w t . B a=1 3 7 , C l =3 5 5 ) [ 3 ] ( b ) E x p l a i nt h ef o l l o w i n g : [ 3 ] ( i ) A na q u e o u ss o l u t i o no f A l C l 3i sa c i d i ca n dt h a t o f N a 2 C O 3i sb a s i c . ( i i ) T h eh y d r o l y s i so f e s t e r sb e g i n ss l o w l yb u t b e c o me sf a s t a f t e r s o met i me . ( i i i ) T h ec o n c e n t r a t i o no f h y d r o x y l i o n si na q u e o u sa mmo n i ad e c r e a s e so nt h ea d d i t i o n o f al i t t l es o l i da mmo n i u mc h l o r i d e . ( c ) Wh a t i st h ee f f e c t o f t e mp e r a t u r eo ni o n i cp r o d u c t o f w a t e r a n dw h y ?Wh a t h a p p e n st o t h ei o n i cp r o d u c t o f w a t e r i f s o mea c i di sa d d e dt oi t ? [ 2 ] S E C T I O ) B A n s w e r a n yt w oq u e s t i o n s Q u e s t i o n5 ( a ) Wr i t et h eI U P A Cn a meo f t h ef o l l o w i n gc o o r d i n a t i o nc o mp o u n d s : [ 2 ] ( i ) [ F e( H 2 O ) 6 ] C l 3 ( i i ) [ C oB r ( N O 2 ) ( N H 3 ) 4 ] ( i i i ) K 3[ F e( C 2O 4 ) ] ( i v ) [ C r ( N H 3 ) 6 ] [ C O ( C N ) 6 ] ( b ) Wh a t t y p eo f s t r u c t u r a l i s o me r i s mi se x h i b i t e db yt h ef o l l o w i n gp a i r so f c o mp o u n d s : [ 2 ] ( i ) [ C r ( H 2 O ) 5C l ] C l 2 H 2 Oa n d[ C r ( H 2 O ) 4C l 2 ] C l 2 H 2 O ( i i ) [ C oB r ( N H 3 ) 5 ] S O 4a n d[ C o ( S O 4 ) ( N H 3 ) 5 ] B r ( i i i ) [ C r ( S C N ) ( H 2 O ) 5 ] 2 +a n d[ C r ( N C S ) ( H 2 O ) 5 ] 2 + ( i v ) [ C u( N H 3 ) 4 ] [ P t C l 4 ] a n d[ P t ( N H 3 ) 4 ] [ C uC l 4 ] ( c ) K 2[ P t C l 4 ] i si o n i s e dt og i v et h r e ei o n s , w h e nd i s s o l v e di nw a t e r . Wi l l i t f o r mw h i t e p r e c i p i t a t ew i t hA g N O 3?G i v ear e a s o n . [ 1 ] I S CS p e c i me nQ u e s t i o nP a p e r 2 0 1 4 6 Q u e s t i o n6 ( a ) Wr i t et h eb a l a n c e dc h e mi c a l e q u a t i o n sf o r t h ef o l l o w i n g : [ 3 ] ( i ) S u l p h u r d i o x i d eg a si sp a s s e dt h r o u g ha c i d i f i e dp o t a s s i u mp e r ma n g a n a t es o l u t i o n . ( i i ) P o t a s s i u md i c h r o ma t ei st r e a t e dw i t ha c i d i f i e df e r r o u ss u l p h a t es o l u t i o n . ( i i i ) S i l v e r n i t r a t ei sa d d e dt od i l u t es o l u t i o no f s o d i u mt h i o s u l p h a t e . ( b ) Wh a t i sme a n t b yL a n t h a n o i dc o n t r a c t i o n ?Wr i t et h eg e n e r a l e l e c t r o n i cc o n f i g u r a t i o no f i n n e r t r a n s i t i o ne l e me n t s . [ 2 ] Q u e s t i o n7 ( a ) S u l p h u r d i o x i d ea c t sb o t ha sa no x i d i s i n ga n dar e d u c i n ga g e n t . G i v eo n er e a c t i o ne a c h t os h o wi t so x i d i s i n ga n dr e d u c i n gn a t u r e . [ 2 ] ( b ) H o ww i l l y o uo b t a i np u r ec o p p e r f r o mi t smo s t i mp o r t a n t o r e ?Wr i t ea l l t h es t e p sa n d r e a c t i o n si n v o l v e di ni t . [ 3 ] S E C T I O ) C A n s w e r a n yt w oq u e s t i o n s . Q u e s t i o n8 ( a ) C a r r yo u t t h ef o l l o w i n gc o n v e r s i o n s : [ 6 ] ( i ) A c e t a l d e h y d et oA c e t o n e . ( i i ) P h e n o l t oB e n z o i ca c i d . ( i i i ) A c e t i ca c i dt oMe t h y l a mi n e . ( i v ) N i t r o b e n z e n et op a mi n o a z o b e n z e n e . ( b ) C o mp l e t et h ef o l l o w i n gr e a c t i o n sa n dn a met h er e a c t i o n s . [ 2 ] ( i ) C 6 H 5 N H 2+_ _ _ _ _ _ _+K O H C 6 H 5 N C+K B r +H 2 O ( i i ) ( c ) G i v eo n eg o o dc h e mi c a l t e s t t od i s t i n g u i s hb e t w e e nt h ef o l l o w i n gp a i r so f c o mp o u n d s : [ 2 ] ( i ) A c e t a l d e h y d ea n da c e t o n e . ( i i ) P h e n a l a n de t h a n a l . O | | C H 3 C H+ C H 3C H O d i l N a O H I S CS p e c i me nQ u e s t i o nP a p e r 2 0 1 4 7 Q u e s t i o n9 ( a ) A na r o ma t i cc o mp o u n d A o nt r e a t me n t w i t ha q u e o u sa mmo n i aa n dh e a t i n gf o r ms c o mp o u n d B w h i c ho nh e a t i n gw i t hB r 2a n dK O Hf o r msac o mp o u n d C o f mo l e c u l a r f o r mu l aC 6 H 7 N . I d e n t i f yt h ec o mp o u n d sA , Ba n dC . [ 3 ] ( b ) ( i ) G i v eo n ee x a mp l eo f ap o l y e s t e r a n dn a met h emo n o me r sf r o mw h i c hi t i sf o r me d . [ 3 ] ( i i ) Wr i t et h emo n o me r so f t h ef o l l o w i n gp o l y me r s : ( 1 ) T e f l o n ( 2 ) B a k e l i t e ( 3 ) N y l o n6 6 ( 4 ) P o l y s t y r e n e ( c ) ( i ) D ot h ec o mp o u n d sh a v i n g |

Blog Archive 2 0 1 3( 5 0 ) O c t o b e r J u n e( 1 3 ) M A I N A N N O U N C E M E N T SF O R K E R A L A P L U SO N E A L L O T M E N T S. . . D H S ES e c o n d A l l o t m e n t R e s u l t s a r e s c h e d u l e d t o . . . I S CS p e c i m e n Q u e s t i o n P a p e r 2 0 1 4 P H Y S I C A L E D U C A T I O . . . I S CS p e c i m e n Q u e s t i o n P a p e r 2 0 1 4 C H E M I S T R Y P A P E R . . . I S CS p e c i m e n Q u e s t i o n P a p e r 2 0 1 4 B I O L O G Y

p r a v i k r a v i . b l o g s p o t . i n / 2 0 1 3 / 0 6 / i s c s p e c i m e n q u e s t i o n p a p e r 2 0 1 4 _ 2 3 . h t m l

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P R A V E E N : I S CS p e c i m e n Q u e s t i o n P a p e r 2 0 1 4 C H E MI S T R YP A P E R 1 ( T H E O R Y )
C=Na n d N=Nb o n d ss h o wg e o me t r i c a l i s o me r i s m?I f y e s , g i v eo n ee x a mp l eo f e a c ha n dn a met h ei s o me r s . [ 4 ] ( i i ) H o wc a ny o uc h e mi c a l l yc o n v e r t me t h y l a mi n et oe t h y l a mi n e ? Q u e s t i o n1 0 ( a ) I d e n t i f yt h ep r o d u c t sA , Ba n dC . [ 3 ] ( i ) C 6 H 5 C O O HS O C l 2[ A ] N H 3[ B ] B r 2/ K O H[ C ] ( i i ) [ ] [ ] 2[ ] 32 22724 [ O ] H/ HO C HC HO HAH C NBC KC r O HS OH y d r o l y s i s + + + ( b ) G i v eb a l a n c e de q u a t i o n sf o r t h ef o l l o w i n gr e a c t i o n s : [ 4 ] ( i ) B e n z o i ca c i di st r e a t e dw i t hp h o s p h o r o u sp e n t a c h l o r i d e . ( i i ) F o r ma l d e h y d ei st r e a t e dw i t hh y d r a z i n e . ( i i i ) A n i l i n ei sh e a t e dw i t hc h l o r o f o r ma n da l c o h o l i cc a u s t i cp o t a s h . ( i v ) B e n z o y l c h l o r i d ei sh e a t e dw i t hh y d r o g e ni nt h ep r e s e n c eo f p a l l a d i u ma n db a r i u m s u l p h a t e . ( c ) ( i ) Wr i t et h r e ep o s s i b l ei s o me r sh a v i n gmo l e c u l a r f o r mu l aC 3 H 6 O 2 . [ 3 ] ( i i ) H o ww i l l y o ud i s t i n g u i s hb e t w e e np r i ma r y , s e c o n d a r ya n dt e r t i a r ya l i p h a t i c a mi n e s ? P o s t e db yp r a v e e nk r a v i n d r a na t 1 5 : 2 4
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P A P E R1 . . . I C S E C o u n c i l f o r t h e I n d i a n S c h o o l C e r t i f i c a t e E x a . . . K E A M C A T E G O R Y / C O M M U N I T Y WI S E L I S T ( P r o v i s i o n a l ) S T . . . K E A M C E N T R A L I S E D A L L O T M E N TT O P R O F E S S I O N A L D E G R E E. . . J E E M A I NC O N F I R M Y O U R+ 2 M A R K S K E A MO P T I O N E N T R YF O R A L L O T M E N TE N G I N E E R I N GC O L L . . . K E R A L A E N T R A N C E ( K E A M ) E N G I N E E R I N GR A N K L I S T P U B L I . . . J A V A P R O G R A M F O RT H E P R O C E D U R EO F S C H O O L A D M I S S I O N . . . C U S A TF I R S T A L L O T M E N TR E S U L T S P U B L I S H E D A p r i l ( 9 ) M a r c h( 2 4 ) F e b r u a r y 2 0 1 2( 1 6 )

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