Class XII Chemistry Ch:3 Chapter: Electrochemistry Important Formulae & Concepts

1. 2. 3.

cell

= E

cathode

E anode

E = E -

4. 5. 6. 7. 8. 9.

G = -nFEcell R=

0.059 1 log n+ (At 298 K) n [M ] 2.303RT [Anode ion] Ecell = Ecell log nF [Cathode ion] 0.059 Ecell = log K c (At 298 K) n

l 1 l = A A 1 R

Conductance:G =

Conductivity = Conductance Cell constant

1 1 l l = = ( ) =G R A A
m =
m

10. Cell constant and is denoted by the symbol G* 11. 12.

Specific conductance = Molarity x 1000 = C

Remember: Unit of m in above formula is Scm2mol-1 c 13. = m 0 m 14. K a =

c 2 1-

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15. Kohlrauschs Law of independent migration of ions: If the limiting molar conductivity of the cations is denoted by o + and that of the anions by o then the limiting molar conductivity of electrolyte is:
0 0 m = + 0 + + v

Where v+ and v- are the number of cations and anions per formula of electrolyte. 16. Faraday constant: It is equal to 96487 C mol-1 or approximately equal to 96500 C mol-1.

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