Sei sulla pagina 1di 21

Pump Calibration Curve:

Pump#1 (EtAc)
Pump#2 (NaOH)
Pump Setting V#olume (mL) time (sec)
flowrate (L/s) Pump Setting V#olume (mL)
4
3
18.49 0.00016225
4
4
7

10

5.5

8.64 0.00069444
4.65

0.0011828

6.8

10

7.5

Pump 1 EtaC
0.0014
y = 0.0002x - 0.0005
R = 0.9994

Flow Rate (L/s)

0.0012
0.001
0.0008
0.0006

Pump 1 EtaC

0.0004

Linear (Pump 1 EtaC)

0.0002
0
0

10

Pump Setting #

15

time (sec)
flowrate (L/s)
18.97 0.00021086
8.77 0.00077537
5.41 0.00138632

Pump 2 NaOH
0.0016
y = 0.0002x - 0.0006
R = 0.9995

Flow Rate (L/s)

0.0014
0.0012
0.001
0.0008

Pump 2 NaOH

0.0006

Linear (Pump 2 NaOH)

0.0004
0.0002
0
0

10

Pump Setting #

15

Conductivity Calibration:
Conversion: 1S=0.001mS
For 50 mL of Solution
Conversion
Sodium Acetate
NaOH
Total
%
Target mass (g)
Actual mass (g)
Target mass (g)
Actual mass (g) Volume
100
0.04102
0
50
0.03692
0.002000
80
0.03281
0.004000
0.02871
0.006000
60
0.02461
0.007999
0.02051
0.009999
40
0.01641
0.011999
0.01231
0.013999
20
0.00820
0.015999
0.00410
0.017999
0
0
0.019999

with NaOH at Initial Concentration of


0.01M
y = 22.804x2 - 159.25x + 267.08
R = 0.9998

Conversion (%)

100
80
60

Series1

40

Poly. (Series1)

20
0
0

0.5

1.5

Conductivity Reading (mS)

2.5

S=0.001mS

Conductivity reading
mS
1289
1.289

1719

1.719

2340

2.34

2790

2.79

Order of Reaction:
Trial #2: 0.1M NaOH, 0.01M EtAc

Time (s)
0
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300
310
320
330

Trial #3: 0.01M NaOH, 0.1M EtAc

Conductivity Reading
(mS)
Time (s)
11.83
11.81
11.76
11.55
11.32
11.2
11.05
10.87
10.71
10.56
10.43
10.31
10.22
10.13
10.06
10
9.93
9.89
9.84
9.79
9.75
9.71
9.66
9.63
9.58
9.57
9.54
9.51
9.48
9.46
9.44
9.42
9.4
9.38

0
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300
310
320
330

Conductivity
Reading
(mS)
1.556
1.539
1.515
1.495
1.464
1.443
1.422
1.401
1.382
1.359
1.35
1.336
1.324
1.311
1.3
1.288
1.278
1.266
1.255
1.245
1.236
1.227
1.217
1.209
1.2
1.193
1.186
1.179
1.173
1.167
1.16
1.153
1.147
1.139

340
350
360
370
380
390
400
410
420
430
440
450
460

9.36
9.34

340
350
360
370
380
390
400
410
420
430
440
450
460

1.132
1.127
1.122
1.117
1.114
1.109
1.104
1.1
1.096
1.094
1.091
1.088
1.085

Trial #1: Temp=26


Time (s)
Conductivity Reading (mS)
0
3.45
10
3.38
20
3.3
30
3.13
40
3
50
2.9
60
2.82
70
2.76
80
2.7
90
2.65
100
2.61
110
2.57
120
2.53
130
2.48
140
2.47
150
2.44
160
2.42
170
2.39
180
2.37
190
2.35
200
2.34
210
2.32
220
2.31
230
2.3
240
2.28
250
2.27
260
2.26
270
2.25
280
2.23
290
2.22
300
2.21

Trial #1: Temp=26


Time (s)
Specific Conductance, (mS/cm)
0
3.45

10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300

3.38
3.3
3.13
3
2.9
2.82
2.76
2.7
2.65
2.61
2.57
2.53
2.48
2.47
2.44
2.42
2.39
2.37
2.35
2.34
2.32
2.31
2.3
2.28
2.27
2.26
2.25
2.23
2.22
2.21

Trial #3: Temp=38


Time (s)
Conductivity Reading (mS)
0
2.26
10
2.33
20
2.35
30
2.35
40
2.35
50
2.35

60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300

2.34
2.33
2.32
2.3
2.29
2.28
2.27
2.25
2.24
2.23
2.21
2.2
2.19
2.19
2.17
2.17
2.16
2.16
2.16
2.15
2.15
2.14
2.14
2.13
2.13

*** dont use temp 33, Not good data (I think NaOH wasn't added)
Trial #2: Temp=33
Time (s)
0
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300

Conductivity Reading (mS)


0.824
0.831
0.839
0.843
0.845
0.846
0.846
0.846
0.846
0.846
0.846
0.846
0.846
0.845
0.844
0.844
0.843
0.843
0.843
0.842
0.842
0.841
0.839
0.838
0.838
0.836
0.835
0.834
0.833
0.832
0.832

Specific Conductance (Corrected), (mS/cm) (K0 - Kt) = A


3.448

Trial #3: Temp=38


Time (s)
0
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300

(Kt - K) = B
0
3.1659

3.378
3.298
3.128
2.998
2.898
2.818
2.758
2.698
2.648
2.608
2.568
2.528
2.478
2.468
2.438
2.418
2.388
2.368
2.348
2.338
2.318
2.308
2.298
2.278
2.268
2.258
2.248
2.228
2.218
2.208

Specific Conductance (Corrected), (mS/cm) (K0 - Kt) = A


2.258
2.328
2.348
2.348
2.348
2.348

0.07
0.15
0.32
0.45
0.55
0.63
0.69
0.75
0.8
0.84
0.88
0.92
0.97
0.98
1.01
1.03
1.06
1.08
1.1
1.11
1.13
1.14
1.15
1.17
1.18
1.19
1.2
1.22
1.23
1.24

3.0959
3.0159
2.8459
2.7159
2.6159
2.5359
2.4759
2.4159
2.3659
2.3259
2.2859
2.2459
2.1959
2.1859
2.1559
2.1359
2.1059
2.0859
2.0659
2.0559
2.0359
2.0259
2.0159
1.9959
1.9859
1.9759
1.9659
1.9459
1.9359
1.9259

0
-0.07
-0.09
-0.09
-0.09
-0.09

(Kt - K) = B
1.9759
2.0459
2.0659
2.0659
2.0659
2.0659

2.338
2.328
2.318
2.298
2.288
2.278
2.268
2.248
2.238
2.228
2.208
2.198
2.188
2.188
2.168
2.168
2.158
2.158
2.158
2.148
2.148
2.138
2.138
2.128
2.128

-0.08
-0.07
-0.06
-0.04
-0.03
-0.02
-0.01
0.01
0.02
0.03
0.05
0.06
0.07
0.07
0.09
0.09
0.1
0.1
0.1
0.11
0.11
0.12
0.12
0.13
0.13

2.0559
2.0459
2.0359
2.0159
2.0059
1.9959
1.9859
1.9659
1.9559
1.9459
1.9259
1.9159
1.9059
1.9059
1.8859
1.8859
1.8759
1.8759
1.8759
1.8659
1.8659
1.8559
1.8559
1.8459
1.8459

ial #3: Temp=38


Conductivity Reading (mS)
2.26
2.33
2.35
2.35
2.35
2.35
2.34
2.33
2.32
2.3
2.29
2.28
2.27
2.25
2.24
2.23
2.21
2.2
2.19
2.19
2.17
2.17
2.16
2.16
2.16
2.15
2.15
2.14
2.14
2.13
2.13

A/B
0

(0t)/(t ) Vs Time at 29

(0t)/(t ) Vs Time at 29
0.8
(0t)/(t )

y = 0.002x + 0.1063

0.6
0.4
0.2
0
0

100

200

300

Time (in s)

Conductivity Reading (mS/cm)

0.022610549
0.049736397
0.112442461
0.165690931
0.210252686
0.248432509
0.278686538
0.310443313
0.338137707
0.361150522
0.384968721
0.409635336
0.441732319
0.44832792
0.468481841
0.482232314
0.503347737
0.517762117
0.532455588
0.539909529
0.555037084
0.562712868
0.570464805
0.586201714
0.594189033
0.602257199
0.610407447
0.626959248
0.635363397
0.643854821

Conductivity Vs Time at
299 K
4
3
2
1
0
0

100

A/B
0
-0.034214771
-0.043564548
-0.043564548
-0.043564548
-0.043564548

Conductivity Vs Time at 311 K

200
Time (in s)

Conductivity Reading (mS/cm)

Conductivity Vs Time at 311 K


2.4
2.35
2.3
2.25
2.2
2.15
2.1
0

100

200

300

400

Time (s)

(0t)/(t ) Vs Time at 311 K


0.1
(0t)/(t )

-0.038912398
-0.034214771
-0.029470996
-0.019842254
-0.01495588
-0.010020542
-0.0050355
0.005086729
0.010225472
0.015417031
0.025961888
0.031316875
0.036728055
0.036728055
0.047722573
0.047722573
0.053307746
0.053307746
0.053307746
0.058952784
0.058952784
0.064658656
0.064658656
0.07042635
0.07042635

y = 0.0004x - 0.0497

0.05
0
-0.05
-0.1

50

100

150

200

Time (s)

250

300

350

Vs Time at 299K

Vs Time at 299K

Linear (A/B)
Linear (A/B)
300

400

ivity Vs Time at
299 K

300
Time (in s)

400

350

CSTR
Trial #1
Flowrate
#8 pump setting
initial cond (mS)
2.81
Conductivity (mS)
1.282
Time (min)
42.37

Trial #2
Flowrate
#9 pump setting
initial cond (mS)
2.88
Conductivity (mS)
2.09
Time (min)
30.15

PFR
Trial #1
Flowrate
#8 pump setting
initial cond (mS)
3.55
Conductivity (mS)
1.6
Time (min)
8.4

Trial #2
Flowrate
#9 pump setting
initial cond (mS)
3.61
Conductivity (mS)
1.8
Time (min)
9.1

PFR
Trial #1:
Flow Rate
Time (s)
0
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300
310
320
330
340

Cond (mS)
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.05
0.34
1.2
3.06
5.32
7.64
10.15
12.25
13.67
13.36
12.46
11.86

350
360
370
380
390
400
410
420
430
440
450
460
470
480
490
500
510
520
530
540
550
560
570

10.86
8.99
7.75
6.25
5.33
4.27
3.55
2.96
2.31
1.96
1.58
1.16
1.02
0.7
0.42
0.32
0.15
0.1
0.05
0
0