CS CO) DO NOT OPEN THIS TEST BOOKLET UNTIL YOU ARE ASKED TO DO SO T.B.C. : P-DTQ-J-DIF Test Booklet’Series Serial No. 18017 TEST BOOKLET CHEMISTRY ‘Time Allowed : Two Hours Maximum Marks : 300 INSTRUCTIONS 1. IMMEDIATELY AFTER THE COMMENCEMENT OF THE EXAMINATION, YOU SHOULD CHECK THAT THIS TEST BOOKLET DOES NOT HAVE ANY UNPRINTED OR TORN OR MISSING PAGES OR ITEMS, ETC. IF SO, GET IT REPLACED BY A COMPLETE TEST BOOKLET. 2. ENCODE CLEARLY THE TEST BOOKLET SERIES A, B, C OR D AS THE CASE MAY BE IN THE APPROPRIATE PLACE IN THE ANSWER SHEET. 3. You have to enter your Roll Number on the Test, Booklet in the Box provided alongside. DO NOT write anything else on the Test Booklet. 4. This Test Booklet contains 120 items (questions). Each item is printed both in Hindi and English. Each item comprises four responses (answers). You will select the response which you want to mark on the Answer Sheet. In case you feel that there is more than one correct response, mark the response which you consider the best. In any case, choose ONLY ONE response for each item. 5. You have to mark all your responses ONLY on the separate Answer Sheet provided. See directions in the Answer Sheet 6. All items carry equal marks. 7. Before you proceed to mark in the Answer Sheet the response to various items in the Test Booklet, you have to fill in some particulars in the Answer Sheet as per instructions sent to you with your Admission Certificate. 8. After you have completed filling in all your responses on the Answer Sheet and the examination has concluded, you should hand over to the Invigilator only the Answer Sheet. You are permitted to take away with you the Test Booklet. 9. Sheets for rough work. are appended in the Test Booklet at the end. 10. Penalty for wrong answers : ‘THERE WILL BE PENALTY FOR WRONG ANSWERS MARKED BY A CANDIDATE IN THE OBJECTIVE TYPE QUESTION PAPERS. () There are four alternatives for the answer to every question. For each question for which a wrong answer has been given by the candidate, one-third (0-33) of the marks assigned to that question will be deducted as penalty. (ii) Ifa candidate gives more than one answer, it will be treated as a wrong answer even if one of the given answers happens to be correct and there will be same penalty as above to that question i) If a question is left blank, i.e, no answer is given by the candidate, there will be no penalty for that question. DO NOT OPEN THIS TEST BOOKLET UNTIL YOU ARE ASKED TO DO SO ear: sail ar feat wa wa GST H Ried GET OTE! “ag1, Which quantum number gives the information orbitals? about degenerate (2) Principal quantum number () Azimuthal quantum number (c) Magnetic quantum number (@) Spin quantum number What is the number of nearest neighbours of an atom in the bec type of packing? @ 6 - () 8 (co) 12 (a) 24 3. The electronic configuration [Ar]3d° stands for (a) Ni?* (b) Co* () Xe° (a) Fe 4. In square planar complexes, the hybrid orbitals are dsp”. The atomic orbitals which give rise to dsp? hybrid orbitals are (a) 4,2 ar 8 Px and py (b) da, 8 py and py (6) yp ya, 8) Pe and py (d) 4,2, 5 pz and py P-DIQV-DIF/7A 5. Sigma bonds are formed between two atoms X and Y by the overlap of 1. sp?()-sp*(v) 2. sp3(X)-1s(¥) 3. Is(X)-Is(¥) » What is the correct order of the energy released in the above three processes? fa) 1>253 (B) 3>2>1 () 2>1>3 (d) 1>3>2 6. In which one of the following pairs of orbitals does overlapping result in hyperconjugation? (a) 0-0 (b) pp () o-p (a) non 7. Which one of the following best represents the three-dimensional view of HoN°? tt (a) of by O) Hghen H a. © ON, @ a Sow1, anya Sarat & at A fea wien TET TT Ss. xX wa Y vamp & ate fen one aaa Prentt 8? frafettra aerat & oftonsr @ aaa 8 : (a) Fea wien Her 1. sp?(X)-sp3(%) fo) fih wien ten 2. sp3(x)-Is(¥) ) yaa zien ten 3. 1s(X)-Is(¥) (a Fame wien on safe ate sae a seattle sof a ae me 2. bee wan Agen FH wy % woe (a) 1>2>3 facta 1 dea Perf St 87 (&) 3>2>1 (a) 6 (}) 2>1>3 ) 8 (d) 1>3>2 fo) 12 (a) 24 6. frefafra 8 8 fea um sas-gm % cafeoares a afte oreignes em? 3. feafafad 4 8 fra gaia fee (a) 0-0 6 larjad® 8? ) pp (a) wi? ( o-p @) co¥* (d) mm (} Xe° (@) Fe?* 7. frafataad 4 a w-a uw, Ne & ‘after zal at wetter 8? 4. af unacta aigel & watts ses dap? oat WH dsp? daha wee aA aa (9) oN, Tye & 9 (@) day Py WH py @) agen (0) dja, 8, py TH p, HH ‘ © owe ) Aye yr 8 Pz TH py oN (4) ja, 5, Pe TH py ay wRow P-DTQ-J-DIF/7A. 3 [P.T.0.