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GROUP: 2
CONCEPT :
1. To determine the concentration of acid and base solution through titration with standard
solution.
RESULT :
1 0.00 46.50
2 0.00 44.50
3 0.00 45.50
1 0.00 24.00
2 0.00 22.50
3 0.00 22.80
CALCULATION
Concentration of HCl
= 45.00 ml
M1V1 = M2V2
(25 ml)
M1 = 0.01 M
= 0.1 mol
45.00 ml
= 0.002 M
Concentration of H2SO4
= 22.65 ml
M1V1 = M2V2
(25 ml)
M1 = 0.01 M
= 0.1 mol
22.65 ml
= 0.002 M
DISCUSSION :
Sodium hydroxide is one of the bases commonly used in the laboratory. However, it is
difficult to obtain solid sodium hydroxide in a pure form because it has a tendency to absorb
water from air, and its solution reacts with carbon dioxide. For these reasons, a solution of
sodium hydroxide must be standardized before it can be used in accurate analytical work.
In this experiment, the concentration or molarity of Hydrochloric acid, HCl and sulphuric
acid H2SO4 must determine. This molarity can be determined by use the molarity of Sodium
Hydroxide, NaOH. To determine the concentration of NaOH we can use this formula:
M1 V1 = 1
M2 V2 1
M1 is a molarity of Sodium Hydroxide, while V1 is a volume of Sodium Hydroxide, NaOH.
For M2 show the molarity and volume of Hydrochloric acid, HCl or sulphuric acid, H 2SO4. Base
on this formula, we can get the molarity of NaOH. Before determine the molarity of
Hydrochloric acid, HCl or sulphuric acid, H2SO4 the equation of the reaction of the acid and base
must be balance to get the rate of solution. The accurate value of the molarity Hydrochloric acid,
HCl or sulphuric acid, H2SO4 is 0.02M.
In order to titrate an unknown with, there must be some way to determine when the
equivalence point of the titration has been reached. In acid-base titration, dyes known as acid-
base indicators are used for this purpose. For example, the dyes known as phenolphthalein are
colorless in acidic solution but are pink in basic solution. If we add phenolphthalein to an
unknown solution of basic, the solution will be in pink color. We can then add standard acid from
a burette until the solution barely turns from pink to colorless. This color change indicates that
the acid has been neutralized and the drop of the acid that caused the solution to become
colorless has no base to react with. The solution therefore became acid, and the dye turns
colorless. The color change signals the end point of the titration, which usually coincides very
nearly with the equivalence point. Care must be taken to choose indicator whose end point
corresponds to the equivalence point of the titration.
There are many precautions when we do acid-base titration experiment. For example, in
acid-base titration 3 aliquots of unknown concentration which is if we take three reading, we
only take at 2 and three reading to calculate the average because at first reading its act as try and
error. We must can to differentiate between equivalence point and an end point. Phenolphthalein
is an indicator for acid-base titration that will show pink color for basic solution and colorless for
acid solution.
CONCLUSION :
REFERENCES :
http://www.google.com.my/search?hl=en&q=function+of+phenolphthalein&meta=&aq=2&oq=f
unction+of+pheno
http://en.wikipedia.org/wiki/Acid-base_titration#Equipment
Brown, T. L, LeMay, H.E & Bursten, B.E. (2005). Chemistry The Central Science (10th ed.). London:
Prentice Hall.
Raymond Chang (1998). Chemistry (6th ed.). New York: Mc Graw Hill.