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  • Organometallic Complexes in Pharmaceutical Drugs

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    Fatma Taher
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    organometallic is the compounds which are having at least one direct metal-carbon bond. The metal can be main group, transition or f-group metal, also include boron, silicon, germanium, arsenic, antimony, selenium, and tellurium. The carbon-containing group(s) may be a carbonyl, alkyl, alkene, alkyne, aromatic, cyclic, or heterocyclic compound.

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    Organometallic Complexes in Pharmaceutical Drugs

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    organometallic is the compounds which are having at least one direct metal-carbon bond. The metal can be main group, transition or f-group metal, also include boron, silicon, germanium, arsenic, antimony, selenium, and tellurium. The carbon-containing group(s) may be a carbonyl, alkyl, alkene, alkyne, aromatic, cyclic, or heterocyclic compound.

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    Attribution Non-Commercial (BY-NC)
    Scarica in formato PPT, PDF, TXT o leggi online su Scribd
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    17 visualizzazioni5 pagine

    Organometallic Complexes in Pharmaceutical Drugs

    Caricato da

    Fatma Taher
    organometallic is the compounds which are having at least one direct metal-carbon bond. The metal can be main group, transition or f-group metal, also include boron, silicon, germanium, arsenic, antimony, selenium, and tellurium. The carbon-containing group(s) may be a carbonyl, alkyl, alkene, alkyne, aromatic, cyclic, or heterocyclic compound.

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    Attribution Non-Commercial (BY-NC)
    Scarica in formato PPT, PDF, TXT o leggi online su Scribd
    Segnala contenuti inappropriati
    di 5

    (a)

    [R3Sn]nx +
    Toluene Reflux

    + H2O

    (b)
    +CH3OH (excess)
    Reflux

    [R3Sn]n x + (LB)

    Toluene

    + H2O/CH3OH (4-6(

    where

    Reflux

    R= CH3, X= OH, n=1 (1,4) R=n-C4H9, X =O, n=2 (2,5) R=C6H5, X= OH, n=1 (3,6)

    Xylene

    refluxing

    AlCl3 50C

    RCOOH + nBu2SnO

    Benzene Refluxing

    C2H5OH

    Benzene RCOOH + Ph3SnOH Refluxing Ph3SnOOCR (2)

    Cu(OAc)2 DMF, reflux

    Renzene, reflux
    Ph3SnOH (1.0 eqyuiv.)

    Thione form

    Thiol form

    R = CH3 ,

    R` =

    ,
    Ph2Sb ( NS ) + C6H6 PhSb (NS) 2 + 2C H 6 6

    and

    Ph3Sb + NSH Ph3Sb + 2 NSH

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