Sei sulla pagina 1di 15

20

15

10

5
Series1
Series2
Series3
0
0

-5

-10

-15

0.5

1.5

2.5

3.5

4.5

5.5

6.5

7.5

8.5

9.5 10 10.5 11 11.5 12 12.5 13 13.5 14 14.5 15 15.5 16

eq-g soluto / Litro


NNaOH =
0.5396

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37

Condiciones de Laboratorio
P (mmHg) :

NNH4OH =

0.0741

TC

NHCl =

0.4652

%HR

NCH3COOH =

0.08993

volumen
de HCL
0
0.2
0.4
0.6
0.8
1
1.2
1.4
1.6
1.8
2
2.2
2.4
2.6
2.8
3
3.2
3.4
3.6
3.8
4
4.2
4.4
4.6
4.8
5
5.2
5.4
5.6
5.8
6
6.2
6.4
6.6
6.8
7
7.2

pH de
NH4OH
11.29
11.12
10.95
10.88
10.77
10.69
10.59
10.52
10.43
10.4
10.36
10.3
10.26
10.21
10.17
10.14
10.09
10.05
10.02
9.99
9.95
9.91
9.88
9.84
9.81
9.78
9.75
9.72
9.69
9.65
9.61
9.58
9.56
9.52
9.49
9.47
9.43

PROM

DELTA V

0.1
0.3
0.5
0.7
0.9
1.1
1.3
1.5
1.7
1.9
2.1
2.3
2.5
2.7
2.9
3.1
3.3
3.5
3.7
3.9
4.1
4.3
4.5
4.7

0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2

4.9
5.1
5.3
5.5
5.7
5.9
6.1
6.3
6.5
6.7
6.9
7.1

38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77

7.4
7.6
7.8
8
8.2
8.4
8.6
8.8
9
9.2
9.4
9.6
9.8
10
10.2
10.4
10.6
10.8
11
11.2
11.4
11.6
11.8
12
12.2
12.4
12.6
12.8
13
13.2
13.4
13.6
13.8
14
14.2
14.4
14.6
14.8
15
15.2

9.39
9.37
9.33
9.29
9.26
9.22
9.19
9.16
9.12
9.08
9.04
9.01
8.97
8.92
8.86
8.8
8.75
8.71
8.63
8.57
8.46
8.37
8.27
8.13
7.9
7.49
6.41
3.16
2.76
2.49
2.35
2.24
2.14
2.04
1.98
1.94
1.89
1.85
1.82
1.78

7.3
7.5
7.7
7.9
8.1
8.3
8.5
8.7
8.9
9.1
9.3
9.5
9.7
9.9
10.1
10.3
10.5
10.7
10.9
11.1
11.3
11.5
11.7
11.9
12.1
12.3
12.5
12.7
12.9
13.1
13.3
13.5
13.7
13.9
14.1
14.3
14.5
14.7
14.9
15.1

0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2

diciones de Laboratorio
756
21
96

DELTA PH

DER PH/V

DELTA2 PH

DER2 PH/V

-0.17
-0.17
-0.07
-0.11
-0.08
-0.1
-0.07
-0.09
-0.03
-0.04
-0.06
-0.04
-0.05
-0.04
-0.03
-0.05
-0.04
-0.03
-0.03
-0.04
-0.04
-0.03
-0.04
-0.03
-0.03
-0.03
-0.03
-0.03
-0.04
-0.04
-0.03
-0.02
-0.04
-0.03
-0.02
-0.04

-0.85
-0.85
-0.35
-0.55
-0.4
-0.5
-0.35
-0.45
-0.15
-0.2
-0.3
-0.2
-0.25
-0.2
-0.15
-0.25
-0.2
-0.15
-0.15
-0.2
-0.2
-0.15
-0.2
-0.15
-0.15
-0.15
-0.15
-0.15
-0.2
-0.2
-0.15
-0.1
-0.2
-0.15
-0.1
-0.2

0
0.1
-0.04
0.03
-0.02
0.03
-0.02
0.06
-0.01
-0.02
0.02
-0.01
0.01
0.01
-0.02
0.01
0.01
1.77636E-15
-0.01
1.77636E-15
0.01
-0.01
0.01
-1.77636E-15
1.77636E-15
0
-1.77636E-15
-0.01
-1.77636E-15
0.01
0.01
-0.02
0.01
0.01
-0.02

0
0.5
-0.2
0.15
-0.1
0.15
-0.1
0.3
-0.05
-0.1
0.1
-0.05
0.05
0.05
-0.1
0.05
0.05
8.88178E-15
-0.05
8.88178E-15
0.05
-0.05
0.05
-8.88178E-15
8.88178E-15
0
-8.88178E-15
-0.05
-8.88178E-15
0.05
0.05
-0.1
0.05
0.05
-0.1

-0.04
-0.02
-0.04
-0.04
-0.03
-0.04
-0.03
-0.03
-0.04
-0.04
-0.04
-0.03
-0.04
-0.05
-0.06
-0.06
-0.05
-0.04
-0.08
-0.06
-0.11
-0.09
-0.1
-0.14
-0.23
-0.41
-1.08
-3.25
-0.4
-0.27
-0.14
-0.11
-0.1
-0.1
-0.06
-0.04
-0.05
-0.04
-0.03
-0.04

-0.2
-0.1
-0.2
-0.2
-0.15
-0.2
-0.15
-0.15
-0.2
-0.2
-0.2
-0.15
-0.2
-0.25
-0.3
-0.3
-0.25
-0.2
-0.4
-0.3
-0.55
-0.45
-0.5
-0.7
-1.15
-2.05
-5.4
-16.25
-2
-1.35
-0.7
-0.55
-0.5
-0.5
-0.3
-0.2
-0.25
-0.2
-0.15
-0.2

1.77636E-15
0.02
-0.02
-1.77636E-15
0.01
-0.01
0.01
1.77636E-15
-0.01
1.77636E-15
-1.77636E-15
0.01
-0.01
-0.01
-0.01
1.77636E-15
0.01
0.01
-0.04
0.02
-0.05
0.02
-0.01
-0.04
-0.09
-0.18
-0.67
-2.17
2.85
0.13
0.13
0.03
0.01
0
0.04
0.02
-0.01
0.01
0.01
-0.01

8.88178E-15
0.1
-0.1
-8.88178E-15
0.05
-0.05
0.05
8.88178E-15
-0.05
8.88178E-15
-8.88178E-15
0.05
-0.05
-0.05
-0.05
8.88178E-15
0.05
0.05
-0.2
0.1
-0.25
0.1
-0.05
-0.2
-0.45
-0.9
-3.35
-10.85
14.25
0.65
0.65
0.15
0.05
0
0.2
0.1
-0.05
0.05
0.05
-0.05

0
0

0.5

1.5

2.5

3.5

4.5

5.5

6.5

7.5

8.5

9.5 10 10.5 11 11.5 12 12.5 13 13.5 14 14.5 15 15.5 16

-2

-4

-6

-8
Series1
-10

-12

-14

-16

-18

pH vs Volumen de HCl
12
11.5

11
10.5
10
9.5
9
8.5
8

y = -0.1744x + 10.662
R = 0.9963

7.5
7
pH

6.5
6
5.5
5
4.5
4
3.5
3
2.5
2

y = -0.2725x + 5.8884
R = 0.9539

1.5
1
y = -10.825x + 142.08
R = 0.9227

0.5
0
0

8
Volumen

10

11

12

13

14

15

eq-g soluto / Litro


NNaOH =
0.5396

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37

Condiciones de Laboratorio
P (mmHg) :

NNH4OH =

0.0741

TC

NHCl =

0.4652

%HR

NCH3COOH =

0.08993

volumen
de NaOh
0
0.2
0.4
0.6
0.8
1
1.2
1.4
1.6
1.8
2
2.2
2.4
2.6
2.8
3
3.2
3.4
3.6
3.8
4
4.2
4.4
4.6
4.8
5
5.2
5.4
5.6
5.8
6
6.2
6.4
6.6
6.8
7
7.2

pH
4.46
4.48
4.5
4.52
4.55
4.57
4.59
4.61
4.65
4.66
4.69
4.71
4.74
4.78
4.79
4.82
4.85
4.88
4.9
4.92
4.95
4.99
5.01
5.04
5.08
5.12
5.15
5.17
5.21
5.25
5.3
5.34
5.38
5.43
5.5
5.57
5.64

PROM VOL

DELTA V

0.1
0.3
0.5
0.7
0.9
1.1
1.3
1.5
1.7
1.9
2.1
2.3
2.5
2.7
2.9
3.1
3.3
3.5
3.7
3.9
4.1
4.3
4.5
4.7

0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2

4.9
5.1
5.3
5.5
5.7
5.9
6.1
6.3
6.5
6.7
6.9
7.1

38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56

7.4
7.6
7.8
8
8.2
8.4
8.6
8.8
9
9.2
9.4
9.6
9.8
10
10.2
10.4
10.6
10.8
11

5.72
5.82
5.93
6.13
6.4
6.89
11.09
11.35
11.57
11.71
11.81
11.89
11.95
12.01
12.08
12.11
12.13
12.19
12.23

7.3
7.5
7.7
7.9
8.1
8.3
8.5
8.7
8.9
9.1
9.3
9.5
9.7
9.9
10.1
10.3
10.5
10.7
10.9

0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2

diciones de Laboratorio
756
21
96

DELTA PH

DER PH/V

PROM VOL

DELTA V

DELTA2 PH

DER2 PH/V2

0.02
0.02
0.02
0.03
0.02
0.02
0.02
0.04
0.01
0.03
0.02
0.03
0.04
0.01
0.03
0.03
0.03
0.02
0.02
0.03
0.04
0.02
0.03
0.04
0.04
0.03
0.02
0.04
0.04
0.05
0.04
0.04
0.05
0.07
0.07
0.07

0.1
0.1
0.1
0.15
0.1
0.1
0.1
0.2
0.05
0.15
0.1
0.15
0.2
0.05
0.15
0.15
0.15
0.1
0.1
0.15
0.2
0.1
0.15
0.2
0.2
0.15
0.1
0.2
0.2
0.25
0.2
0.2
0.25
0.35
0.35
0.35

0.2
0.4
0.6
0.8
1
1.2
1.4
1.6
1.8
2
2.2
2.4
2.6
2.8
3
3.2
3.4
3.6
3.8
4
4.2
4.4
4.6
4.8
5
5.2
5.4
5.6
5.8
6
6.2
6.4
6.6
6.8
7

0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2

-4.44089E-15
0
0.05
-0.05
-4.44089E-15
4.44089E-15
0.1
-0.15
0.1
-0.05
0.05
0.05
-0.15
0.1
-4.44089E-15
4.77396E-15
-0.05
-4.21885E-15
0.05
0.05
-0.1
0.05
0.05
0
-0.05
-0.05
0.1
-8.88178E-16
0.05
-0.05
0
0.05
0.1
0
-4.44089E-15

-2.22045E-14
0
0.25
-0.25
-2.22045E-14
2.22045E-14
0.5
-0.75
0.5
-0.25
0.25
0.25
-0.75
0.5
-2.22045E-14
2.38698E-14
-0.25
-2.10942E-14
0.25
0.25
-0.5
0.25
0.25
0
-0.25
-0.25
0.5
-4.44089E-15
0.25
-0.25
0
0.25
0.5
0
-2.22045E-14

0.08
0.1
0.11
0.2
0.27
0.49
4.2
0.26
0.22
0.14
0.1
0.08
0.06
0.06
0.07
0.03
0.02
0.06
0.04

0.4
0.5
0.55
1
1.35
2.45
21
1.3
1.1
0.7
0.5
0.4
0.3
0.3
0.35
0.15
0.1
0.3
0.2

7.2
7.4
7.6
7.8
8
8.2
8.4
8.6
8.8
9
9.2
9.4
9.6
9.8
10
10.2
10.4
10.6
10.8

0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2

0.05
0.1
0.05
0.45
0.35
1.1
18.55
-19.7
-0.2
-0.4
-0.2
-0.1
-0.1
1.15463E-14
0.05
-0.2
-0.05
0.2
-0.1

0.25
0.5
0.25
2.25
1.75
5.5
92.75
-98.5
-1
-2
-1
-0.5
-0.5
5.77316E-14
0.25
-1
-0.25
1
-0.5

25
20
15
Series1
10
5
0
0

10

12

Second Derivative
150
100

pH
/V

50
0
0

10

12

Series1

-50
-100
-150

Axis Title

Normal
y = 0.2533x + 9.4604
R = 0.9784

16
14
12

pH

10
8
6
4

y = 0.1485x + 4.4014
R = 0.9838

2
0
-10

-5

10

15

20

0
-10

-5

5
Vol de HCl

10

15

20

Series1

Series1

Series1
Recta Superior
Recta Inferior
Linear (Recta Superior)
Linear (Recta Inferior)

20

20

Potrebbero piacerti anche