Name______________________________PantherID________________

CHM1045
Exam2
Spring2011
Pleasemakesuretoreadeachquestioncarefullybeforeanswering.GOODLUCK!
1. Howmuchwaterwouldyouneedtoaddto15mLofa4.4MMn2+solutiontomakea
0.04MsolutionofMn2+?
A.
B.
C.
D.
E.

1485mL
0.136mL
1500mL
1650mL
1635mL

2. Thecombustionof15.0gofheptane(C7H16)withexcessoxygenwillproducehowmuch
CO2 gas?
A.
B.
C.
D.
E.

46.1g
4.88g
4.19g
0.941g
6.59g

3. Anunknownmassofsand(Cs=0.84J/gC)initiallyat20.0Cabsorbs1.00x103kJofheat
andrisesto60.0C.Whatisthemassofthesand(inkg)?
A.
B.
C.
D.
E.

1.98x102kg
29.8kg
2.98x102kg
21.0kg
19.8kg

4. Agasmixturewithatotalpressureof740mmHgcontainsthefollowinggasesatthe
indicatedpartialpressures:CO2=115mmHg;Ar=220mmHgandO2=150mmHg.The
remaininggasinthemixtureishelium.Whatisthemolefractionofheliumgasinthis
sample?
A.
B.
C.
D.
E.

0.203
0.155
0.297
0.345
0.655

Page 1, v1

5. Howmanygramsofnitrogengasarethereina5.00Lcylinderat1.3atmand23C?
A.
B.
C.
D.
E.

48.2g
3.75g
7.49g
0.267g
96.5g

6. Whichofthefollowinggaseswillhaveaspeedof498m/sat25C?
A.
B.
C.
D.
E.

chlorine
nitrogenmonoxide
fluorine
oxygen
carbondioxide

7. Asystemreleases615kJofheatanddoes120kJofwork.Whatisthechangeininternal
energy?
A.
B.
C.
D.
E.

495kJ
735kJ
+615kJ
+495kJ
+735kJ

8. Calculatetheconcentrationofpermanganatewhen1gofpotassiumpermanganateis
dissolvedin50mLofwater.
A.
B.
C.
D.
E.

141mM
159mM
0.123mM
253mM
127mM

9. Whichofthefollowingcompoundsis/aresolubleinaqueoussolution?
i.Zn(NO3) 2
ii.Na2CO3
iii.CoS
A.
B.
C.
D.
E.

iandiii
ii
iandii
i
i,ii,andiii

Page 2, v1

10. Inwhichofthefollowingreactionsischromiumbeingoxidized:
i.4Cr+3O2>2Cr2O3
ii.2CrO42+2H+>Cr2O72+H2O
iii.2H2O+BaCrO4>H2CrO4+Ba(OH)2
A.
B.
C.
D.
E.

iandii
i,iiandiii
ii
i
iandiii

11. Thetitrationof30.0mLofanunknownconcentrationofH2SO4requires70.5mLofa
0.10MNaOHsolutiontoreachcompletion.Whatistheconcentrationofthesulfuric
acid?
A.
B.
C.
D.
E.

0.470M
0.235M
0.118M
0.043M
0.085M

12. Acompanymakesaspirinusingthefollowingreaction:
C7H6O3 +C4H6O3 > C9H8O4+C2H4O2
(salicylicacid)(aceticanhydride) (aspirin) (aceticacid)
Eachmonth,thecompanyuses103kgofsalicylicacidand103kgaceticanhydrideinthe
abovereaction.Thecompanyisalsoreportinga75%yieldofaspirinpermonth(allof
whichissold).
Ifthecompanyissellingtheaspirintheyproducefor$100/kg,andarespending$40/kg
onsalicylicacidand$30/kgforaceticanhydride,calculatehowmuchprofitthecompany
makespermonth.
A.
B.
C.
D.
E.

$27,826
$60,435
$103,913
$62,350
$97,556

Page 3, v1

13. InaNASCARrace,tirepressureisoneofthekeyvariablesthatateamcanmodifyto
improveperformance.Ifacarissetupwithtirepressureof1.20atmwhileinthegarage
(at23C)whatwillbethepressureoncethecargetsgoingonthetrack(46C)?
(Assumethevolumeofthetireisconstant)
A.
B.
C.
D.
E.

2.06atm
1.11atm
2.40atm
0.60atm
1.29atm

14. Whichofthefollowinggaseswillhaveadensityof1.25g/LatSTP?
A.
B.
C.
D.
E.

Oxygen
Carbondioxide
Carbonmonoxide
Argon
Helium

15. Convert2.35x103L*atmintokcal.
A.
B.
C.
D.
E.

56.9kcal
996kcal
9.70x104kcal
9.70x102 kcal
5.69x107kcal

Page 4, v1